JP7012433B2 - 無溶媒の電極製造 - Google Patents
無溶媒の電極製造 Download PDFInfo
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- JP7012433B2 JP7012433B2 JP2016571108A JP2016571108A JP7012433B2 JP 7012433 B2 JP7012433 B2 JP 7012433B2 JP 2016571108 A JP2016571108 A JP 2016571108A JP 2016571108 A JP2016571108 A JP 2016571108A JP 7012433 B2 JP7012433 B2 JP 7012433B2
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- Prior art keywords
- binder
- dry
- fluoropolymer
- electrode
- dispersion
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- UWHSPZZUAYSGTB-UHFFFAOYSA-N 1,1,3,3-tetraethylurea Chemical compound CCN(CC)C(=O)N(CC)CC UWHSPZZUAYSGTB-UHFFFAOYSA-N 0.000 description 1
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- 125000003821 2-(trimethylsilyl)ethoxymethyl group Chemical group [H]C([H])([H])[Si](C([H])([H])[H])(C([H])([H])[H])C([H])([H])C(OC([H])([H])[*])([H])[H] 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
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- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 1
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910052493 LiFePO4 Inorganic materials 0.000 description 1
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- 229910013290 LiNiO 2 Inorganic materials 0.000 description 1
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- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
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- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
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- 125000005600 alkyl phosphonate group Chemical group 0.000 description 1
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
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- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
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- 150000007942 carboxylates Chemical class 0.000 description 1
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- 239000008199 coating composition Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- FDPIMTJIUBPUKL-UHFFFAOYSA-N dimethylacetone Natural products CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 1
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- 239000010439 graphite Substances 0.000 description 1
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- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 1
- CPSYWNLKRDURMG-UHFFFAOYSA-L hydron;manganese(2+);phosphate Chemical compound [Mn+2].OP([O-])([O-])=O CPSYWNLKRDURMG-UHFFFAOYSA-L 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910000398 iron phosphate Inorganic materials 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- 229940094522 laponite Drugs 0.000 description 1
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 description 1
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 1
- 229910002102 lithium manganese oxide Inorganic materials 0.000 description 1
- 229910021450 lithium metal oxide Inorganic materials 0.000 description 1
- ILXAVRFGLBYNEJ-UHFFFAOYSA-K lithium;manganese(2+);phosphate Chemical compound [Li+].[Mn+2].[O-]P([O-])([O-])=O ILXAVRFGLBYNEJ-UHFFFAOYSA-K 0.000 description 1
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 1
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 description 1
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- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0404—Methods of deposition of the material by coating on electrode collectors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0416—Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/621—Binders
- H01M4/622—Binders being polymers
- H01M4/623—Binders being polymers fluorinated polymers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
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| JP6874690B2 (ja) * | 2015-12-24 | 2021-05-19 | 日本ゼオン株式会社 | 非水系二次電池電極用バインダー組成物、非水系二次電池電極用スラリー組成物、非水系二次電池用電極、および非水系二次電池 |
| CN110476282A (zh) * | 2017-09-25 | 2019-11-19 | 株式会社Lg化学 | 制造二次电池的电极的方法及由此制造的电极 |
| KR102261501B1 (ko) | 2017-09-29 | 2021-06-07 | 주식회사 엘지에너지솔루션 | 전극 합제의 제조 방법 및 전극 합제 |
| CN111247669B (zh) * | 2017-11-02 | 2025-05-09 | 特斯拉公司 | 用于储能装置电极制备的方法和设备 |
| KR102520396B1 (ko) * | 2017-11-06 | 2023-04-12 | 주식회사 엘지에너지솔루션 | 양극의 제조 방법 |
| US11367864B2 (en) * | 2018-11-08 | 2022-06-21 | Tesla, Inc. | Intermittently coated dry electrode for energy storage device and method of manufacturing the same |
| US11355741B2 (en) * | 2018-12-20 | 2022-06-07 | Ppg Industries Ohio, Inc. | Battery electrode coatings applied by waterborne electrodeposition |
| US11268711B2 (en) | 2018-12-21 | 2022-03-08 | Robert Bosch Gmbh | Electrostatic charging air cleaning device |
| US11524304B2 (en) * | 2018-12-21 | 2022-12-13 | Robert Bosch Gmbh | Electrostatic charging air cleaning device and collection electrode |
| CN114868208B (zh) * | 2019-12-23 | 2025-01-07 | 阿科玛股份有限公司 | 用于锂离子电池的具有聚合物粘合剂的涂层电极 |
| FR3106701B1 (fr) * | 2020-01-29 | 2022-07-22 | Arkema France | Formulation d’electrode pour batterie li-ion et procede de fabrication d’electrode sans solvant |
| FR3106702B1 (fr) * | 2020-01-29 | 2022-10-07 | Arkema France | Formulation d’electrode pour batterie li-ion et procede de fabrication d’electrode sans solvant |
| FR3106703B1 (fr) * | 2020-01-29 | 2022-07-22 | Arkema France | Formulation d’electrode pour batterie li-ion et procede de fabrication d’electrode sans solvant |
| US11482696B2 (en) | 2020-02-26 | 2022-10-25 | Ppg Industries Ohio, Inc. | Method of coating an electrical current collector and electrodes resulting therefrom |
| DK180885B1 (en) | 2020-11-18 | 2022-06-14 | Blue World Technologies Holding ApS | Method of producing a self-supported electrode film in a wet process without organic solvent |
| KR20220164094A (ko) * | 2021-06-03 | 2022-12-13 | 주식회사 엘지에너지솔루션 | 양극 첨가제 및 이를 함유하는 리튬 이차전지용 양극 |
| JP7517277B2 (ja) * | 2021-07-14 | 2024-07-17 | トヨタ自動車株式会社 | 電極製造装置 |
| EP4203085A1 (en) | 2021-12-22 | 2023-06-28 | Arkema France | Binder for dry-coated electrode |
| CN116314792A (zh) * | 2023-01-17 | 2023-06-23 | 深圳市研一新材料有限责任公司 | 一种干电极粘结剂、负极干粉混合物及其应用 |
| WO2025038735A2 (en) * | 2023-08-14 | 2025-02-20 | Fastcap Systems Corporation | Solvent free preparation of electrodes, fluorine free electrodes and energy storage devices produced thereby |
| US12431505B2 (en) * | 2023-11-27 | 2025-09-30 | Atlas Power Technologies Inc. | Dry electrode for energy storing devices |
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| JP2010114030A (ja) | 2008-11-10 | 2010-05-20 | Toyota Motor Corp | 電極板の製造方法 |
| JP2012528466A (ja) | 2009-05-29 | 2012-11-12 | アーケマ・インコーポレイテッド | 水性ポリフッ化ビニリデン組成物 |
| WO2013180166A1 (ja) | 2012-05-29 | 2013-12-05 | 日本ゼオン株式会社 | 電気化学素子電極用複合粒子、電気化学素子電極、及び電気化学素子 |
| JP2013247050A (ja) | 2012-05-29 | 2013-12-09 | Nippon Zeon Co Ltd | 電気化学素子電極用複合粒子、電気化学素子電極、及び電気化学素子 |
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| US6200703B1 (en) | 1995-12-26 | 2001-03-13 | Kureha Kagaku Kogyo Kabushiki Kaisha | Binder solution and electrode-forming composition for non-aqueous-type battery |
| JP3703582B2 (ja) | 1996-02-22 | 2005-10-05 | 呉羽化学工業株式会社 | 電極バインダー、電極バインダー溶液、電極合剤、電極構造体および電池 |
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-
2015
- 2015-06-03 WO PCT/US2015/033881 patent/WO2015187769A2/en not_active Ceased
- 2015-06-03 CN CN201580029238.XA patent/CN106415892A/zh active Pending
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- 2015-06-03 CN CN202111172267.5A patent/CN113889658B/zh active Active
- 2015-06-03 KR KR1020167034924A patent/KR102558603B1/ko active Active
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2020
- 2020-08-07 JP JP2020135341A patent/JP2020191299A/ja active Pending
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| WO2005001861A1 (ja) | 2003-06-30 | 2005-01-06 | Zeon Corporation | 電気二重層キャパシタ用電極の製造方法 |
| JP2010114030A (ja) | 2008-11-10 | 2010-05-20 | Toyota Motor Corp | 電極板の製造方法 |
| JP2012528466A (ja) | 2009-05-29 | 2012-11-12 | アーケマ・インコーポレイテッド | 水性ポリフッ化ビニリデン組成物 |
| WO2013180166A1 (ja) | 2012-05-29 | 2013-12-05 | 日本ゼオン株式会社 | 電気化学素子電極用複合粒子、電気化学素子電極、及び電気化学素子 |
| JP2013247050A (ja) | 2012-05-29 | 2013-12-09 | Nippon Zeon Co Ltd | 電気化学素子電極用複合粒子、電気化学素子電極、及び電気化学素子 |
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| Publication number | Publication date |
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| KR20170016859A (ko) | 2017-02-14 |
| US20170125815A1 (en) | 2017-05-04 |
| KR102558603B1 (ko) | 2023-07-25 |
| WO2015187769A9 (en) | 2016-05-06 |
| CN106415892A (zh) | 2017-02-15 |
| CN113889658B (zh) | 2025-01-07 |
| WO2015187769A2 (en) | 2015-12-10 |
| JP2017525087A (ja) | 2017-08-31 |
| JP2020191299A (ja) | 2020-11-26 |
| WO2015187769A3 (en) | 2016-03-17 |
| CN113889658A (zh) | 2022-01-04 |
| US10707492B2 (en) | 2020-07-07 |
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