JP6969030B2 - 立方晶窒化硼素焼結体および切削工具 - Google Patents
立方晶窒化硼素焼結体および切削工具 Download PDFInfo
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- JP6969030B2 JP6969030B2 JP2021514634A JP2021514634A JP6969030B2 JP 6969030 B2 JP6969030 B2 JP 6969030B2 JP 2021514634 A JP2021514634 A JP 2021514634A JP 2021514634 A JP2021514634 A JP 2021514634A JP 6969030 B2 JP6969030 B2 JP 6969030B2
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- boron nitride
- cubic boron
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- 229910052582 BN Inorganic materials 0.000 title claims description 52
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 title claims description 52
- 238000005520 cutting process Methods 0.000 title claims description 45
- 239000002245 particle Substances 0.000 claims description 171
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 40
- 239000010936 titanium Substances 0.000 claims description 39
- 150000001875 compounds Chemical class 0.000 claims description 31
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 30
- 229910052799 carbon Inorganic materials 0.000 claims description 28
- 229910052760 oxygen Inorganic materials 0.000 claims description 28
- 239000006104 solid solution Substances 0.000 claims description 28
- 229910052757 nitrogen Inorganic materials 0.000 claims description 27
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 26
- 239000001301 oxygen Substances 0.000 claims description 26
- 229910052782 aluminium Inorganic materials 0.000 claims description 24
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 18
- 229910052796 boron Inorganic materials 0.000 claims description 17
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 14
- 239000010955 niobium Substances 0.000 claims description 11
- 238000004458 analytical method Methods 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 229910021480 group 4 element Inorganic materials 0.000 claims description 6
- 229910021478 group 5 element Inorganic materials 0.000 claims description 6
- 229910021476 group 6 element Inorganic materials 0.000 claims description 6
- 229910052758 niobium Inorganic materials 0.000 claims description 6
- 229910052721 tungsten Inorganic materials 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 5
- 229910052735 hafnium Inorganic materials 0.000 claims description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims description 5
- 230000000737 periodic effect Effects 0.000 claims description 5
- 229910052715 tantalum Inorganic materials 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 description 57
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- 238000002156 mixing Methods 0.000 description 41
- 239000000843 powder Substances 0.000 description 33
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- 239000011812 mixed powder Substances 0.000 description 21
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- 229910010413 TiO 2 Inorganic materials 0.000 description 10
- 238000009826 distribution Methods 0.000 description 10
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 9
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- 229910052751 metal Inorganic materials 0.000 description 9
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 7
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- 150000004767 nitrides Chemical class 0.000 description 5
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- 230000001603 reducing effect Effects 0.000 description 4
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- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 229910010293 ceramic material Inorganic materials 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
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- 238000010586 diagram Methods 0.000 description 3
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- 150000001247 metal acetylides Chemical class 0.000 description 3
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- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910010038 TiAl Inorganic materials 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 239000010953 base metal Substances 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
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- 239000000565 sealant Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000001238 wet grinding Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
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- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910021386 carbon form Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
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- 238000011156 evaluation Methods 0.000 description 1
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- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
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| JPS61197469A (ja) * | 1985-02-26 | 1986-09-01 | 三菱マテリアル株式会社 | 切削工具用立方晶窒化硼素基焼結材料の製造方法 |
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| AU2006307587A1 (en) * | 2005-10-28 | 2007-05-03 | Element Six (Production) (Pty) Ltd | Cubic boron nitride compact |
| KR101252332B1 (ko) * | 2006-06-12 | 2013-04-08 | 스미또모 덴꼬오 하드메탈 가부시끼가이샤 | 복합 소결체 |
| JP5895690B2 (ja) * | 2012-05-08 | 2016-03-30 | 信越化学工業株式会社 | 有機修飾無機充填材の製造方法及び有機修飾無機充填材、並びに熱伝導性シリコーン組成物 |
| JP5305056B1 (ja) * | 2012-05-16 | 2013-10-02 | 三菱マテリアル株式会社 | 立方晶窒化ほう素基焼結体製切削工具 |
| JP6343888B2 (ja) | 2013-08-27 | 2018-06-20 | 三菱マテリアル株式会社 | 耐欠損性にすぐれた立方晶窒化硼素焼結体切削工具 |
| US9950962B2 (en) * | 2013-10-22 | 2018-04-24 | Tungaloy Corporation | Cubic boron nitride sintered body and coated cubic boron nitride sintered body |
| JP6650106B2 (ja) * | 2014-11-27 | 2020-02-19 | 三菱マテリアル株式会社 | 立方晶窒化ほう素基焼結体および立方晶窒化ほう素基焼結体製切削工具 |
| MX2017000970A (es) * | 2015-05-29 | 2017-05-01 | Sumitomo Electric Hardmetal Corp | Cuerpo sinterizado y herramienta de corte. |
| US20180117678A1 (en) * | 2016-03-30 | 2018-05-03 | Sumitomo Electric Hardmetal Corp. | Surface-coated cubic boron nitride sintered material, and cutting tool including the same |
| JP6881200B2 (ja) | 2017-09-29 | 2021-06-02 | 三菱マテリアル株式会社 | 掘削チップ、掘削工具、および掘削チップの製造方法 |
| US11383300B2 (en) * | 2017-10-30 | 2022-07-12 | Sumitomo Electric Industries, Ltd. | Sintered material and cutting tool including the same |
| JP6822987B2 (ja) | 2018-01-31 | 2021-01-27 | 株式会社タムラ製作所 | 感光性樹脂組成物 |
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