JP6951247B2 - 非フッ素化乳化剤を用いた重合によって得ることができる過酸化物硬化性フルオロポリマー - Google Patents
非フッ素化乳化剤を用いた重合によって得ることができる過酸化物硬化性フルオロポリマー Download PDFInfo
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- JP6951247B2 JP6951247B2 JP2017544604A JP2017544604A JP6951247B2 JP 6951247 B2 JP6951247 B2 JP 6951247B2 JP 2017544604 A JP2017544604 A JP 2017544604A JP 2017544604 A JP2017544604 A JP 2017544604A JP 6951247 B2 JP6951247 B2 JP 6951247B2
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- Prior art keywords
- fluorinated
- emulsifier
- ether
- fluoropolymer
- curable
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- 238000000034 method Methods 0.000 claims description 71
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- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 59
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- 229910001511 metal iodide Inorganic materials 0.000 description 1
- ZIYVHBGGAOATLY-UHFFFAOYSA-N methylmalonic acid Chemical compound OC(=O)C(C)C(O)=O ZIYVHBGGAOATLY-UHFFFAOYSA-N 0.000 description 1
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- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical group FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- FOKCKXCUQFKNLD-UHFFFAOYSA-N pent-1-enyl hypofluorite Chemical compound C(CC)C=COF FOKCKXCUQFKNLD-UHFFFAOYSA-N 0.000 description 1
- 150000002972 pentoses Chemical class 0.000 description 1
- CSJWOWRPMBXQLD-UHFFFAOYSA-N perfluoromethylvinylether group Chemical group FC(=C(C(F)(F)F)F)OC(=C(F)C(F)(F)F)F CSJWOWRPMBXQLD-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
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- 239000000049 pigment Substances 0.000 description 1
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- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
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- 238000005070 sampling Methods 0.000 description 1
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- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000001542 size-exclusion chromatography Methods 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- VHDOAHBIZRSCPJ-UHFFFAOYSA-M sodium;1,4-bis(6-methylheptoxy)-1,4-dioxobutane-2-sulfonate Chemical compound [Na+].CC(C)CCCCCOC(=O)CC(S([O-])(=O)=O)C(=O)OCCCCCC(C)C VHDOAHBIZRSCPJ-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 1
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- 229960004793 sucrose Drugs 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical group NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 125000002130 sulfonic acid ester group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- VXHFNALHLRWIIU-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)OC(=O)C(C)(C)C VXHFNALHLRWIIU-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- GRPURDFRFHUDSP-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,2,4-tricarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C(C(=O)OCC=C)=C1 GRPURDFRFHUDSP-UHFFFAOYSA-N 0.000 description 1
- KJWHEZXBZQXVSA-UHFFFAOYSA-N tris(prop-2-enyl) phosphite Chemical compound C=CCOP(OCC=C)OCC=C KJWHEZXBZQXVSA-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/22—Vinylidene fluoride
- C08F214/222—Vinylidene fluoride with fluorinated vinyl ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/22—Vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/26—Tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/28—Hexyfluoropropene
- C08F214/282—Hexyfluoropropene with fluorinated vinyl ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F216/125—Monomers containing two or more unsaturated aliphatic radicals, e.g. trimethylolpropane triallyl ether or pentaerythritol triallyl ether
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/08—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing fluorine
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15156170.1 | 2015-02-23 | ||
| EP15156170.1A EP3059265B1 (en) | 2015-02-23 | 2015-02-23 | Peroxide curable fluoropolymers obtainable by polymerization with non-fluorinated emulsifiers |
| PCT/US2016/018845 WO2016137851A1 (en) | 2015-02-23 | 2016-02-22 | Peroxide curable fluoropolymers obtainable by polymerization with non-fluorinated emulsifiers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018505952A JP2018505952A (ja) | 2018-03-01 |
| JP2018505952A5 JP2018505952A5 (OSRAM) | 2019-04-04 |
| JP6951247B2 true JP6951247B2 (ja) | 2021-10-20 |
Family
ID=52484409
Family Applications (1)
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| CN107849200B (zh) | 2015-07-13 | 2020-07-28 | 3M创新有限公司 | 氟化嵌段共聚物 |
| KR20190077405A (ko) * | 2016-11-09 | 2019-07-03 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 퍼옥사이드 경화성 부분 플루오르화 중합체 |
| WO2018136324A1 (en) | 2017-01-18 | 2018-07-26 | 3M Innovative Properties Company | Fluorinated block copolymers derived from nitrile cure-site monomers |
| WO2018136332A1 (en) | 2017-01-18 | 2018-07-26 | 3M Innovative Properties Company | Fluorinated block copolymers derived from cure-site monomers |
| US11261280B2 (en) | 2017-01-18 | 2022-03-01 | 3M Innovative Properties Company | Fluorinated block copolymers |
| EP3896052A1 (en) * | 2017-05-19 | 2021-10-20 | 3M Innovative Properties Co. | Methods of making a polyfluorinated allyl ether and compounds relating to the methods |
| RU2020121824A (ru) * | 2017-12-06 | 2022-01-10 | ЭйДжиСи Инк. | Фторированный эластичный сополимер и способ получения фторированного эластичного сополимера |
| EP3527634A1 (en) * | 2018-02-15 | 2019-08-21 | 3M Innovative Properties Company | Fluoropolymers and fluoropolymer dispersions |
| EP3781610B1 (en) * | 2018-04-20 | 2022-09-14 | Solvay Specialty Polymers Italy S.p.A. | Process for the manufacture of polyether polymers |
| JP7370346B2 (ja) | 2018-06-20 | 2023-10-27 | ソルベイ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | （パー）フルオロポリエーテルポリマー |
| EP3824001A1 (en) | 2018-07-20 | 2021-05-26 | 3M Innovative Properties Company | Tetrafluroethylene fluoropolymers containing perfluorinated allyl ethers |
| JP7277799B2 (ja) * | 2018-10-03 | 2023-05-19 | ダイキン工業株式会社 | ポリテトラフルオロエチレンの製造方法 |
| EP3868799B1 (en) * | 2018-10-18 | 2023-10-11 | Daikin Industries, Ltd. | Fluorine-containing elastomer, crosslinkable composition and molded article |
| WO2020126449A1 (en) * | 2018-12-20 | 2020-06-25 | Solvay Specialty Polymers Italy S.P.A. | Vinylidene fluoride polymer dispersion |
| WO2020196779A1 (ja) * | 2019-03-27 | 2020-10-01 | Ａｇｃ株式会社 | 含フッ素重合体の製造方法、水性分散液および含フッ素重合体組成物 |
| JP7209813B2 (ja) * | 2019-03-29 | 2023-01-20 | 株式会社クレハ | 非フッ素化界面活性剤を用いたフッ化ビニリデン系重合体組成物及びその製造方法 |
| WO2021085423A1 (ja) * | 2019-10-30 | 2021-05-06 | Ａｇｃ株式会社 | 含フッ素共重合体、含フッ素共重合体組成物および架橋ゴム物品 |
| WO2021100835A1 (ja) * | 2019-11-19 | 2021-05-27 | ダイキン工業株式会社 | フルオロポリマーの製造方法 |
| JP7352110B2 (ja) * | 2019-11-19 | 2023-09-28 | ダイキン工業株式会社 | フルオロポリマーの製造方法、ポリテトラフルオロエチレンの製造方法、パーフルオロエラストマーの製造方法および組成物 |
| CN114829425B (zh) * | 2019-12-27 | 2023-10-24 | 大金工业株式会社 | 含氟聚合物的制造方法、含氟弹性体和水性分散液 |
| WO2022030389A1 (ja) * | 2020-08-05 | 2022-02-10 | ダイキン工業株式会社 | 含フッ素エラストマー水性分散液の製造方法 |
| JP2025538879A (ja) * | 2022-11-30 | 2025-12-02 | サイエンスコ スペシャルティ ポリマーズ イタリー エス．ピー．エー． | フッ素化界面活性剤を使用せずに水性エマルジョン中でフルオロエラストマーを製造する方法 |
| JP7792546B1 (ja) | 2025-07-14 | 2025-12-25 | ユニマテック株式会社 | フルオロポリマー水性分散液の製造方法、フルオロモノマーの重合方法、フルオロポリマーの製造方法 |
| JP7792545B1 (ja) | 2025-07-14 | 2025-12-25 | ユニマテック株式会社 | フルオロポリマー水性分散液の製造方法、フルオロモノマーの重合方法、フルオロポリマーの製造方法 |
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| WO1992006071A1 (en) | 1990-09-28 | 1992-04-16 | The Procter & Gamble Company | Phase transfer assisted process for glucamide detergents |
| CA2268301A1 (en) | 1996-10-11 | 1998-04-23 | Nippon Carbide Kogyo Kabushiki Kaisha | Polymer obtained by emulsion polymerization method |
| TW494125B (en) | 1997-07-11 | 2002-07-11 | Rohm And Haas Compary | Preparation of fluorinated polymers |
| DE19857111A1 (de) | 1998-12-11 | 2000-06-15 | Dyneon Gmbh | Wäßrige Dispersionen von Fluorpolymeren |
| US6512063B2 (en) | 2000-10-04 | 2003-01-28 | Dupont Dow Elastomers L.L.C. | Process for producing fluoroelastomers |
| US6841616B2 (en) | 2003-03-28 | 2005-01-11 | Arkema Inc. | Polymerization of halogen-containing monomers using siloxane surfactant |
| US20060281845A1 (en) | 2005-06-10 | 2006-12-14 | Ramin Amin-Sanayei | Aqueous process for making fluoropolymers |
| US8080621B2 (en) | 2005-06-10 | 2011-12-20 | Arkema Inc. | Aqueous process for making fluoropolymers |
| US8338518B2 (en) | 2005-06-10 | 2012-12-25 | Arkema Inc. | Aqueous process for making a stable fluoropolymer dispersion |
| US20070015937A1 (en) | 2005-07-15 | 2007-01-18 | 3M Innovative Properties Company | Process for recovery of fluorinated carboxylic acid surfactants from exhaust gas |
| JP5106396B2 (ja) | 2005-08-08 | 2012-12-26 | アーケマ・インコーポレイテッド | 非フッ素化界面活性剤を用いたフルオロポリマーの重合 |
| US8124699B2 (en) | 2005-08-08 | 2012-02-28 | Arkema Inc. | Polymerization of fluoropolymers using alkyl phosphonate surfactants |
| US9029477B2 (en) * | 2006-03-03 | 2015-05-12 | 3M Innovative Properties Company | Compositions comprising melt-processable thermoplastic fluoropolymers and methods of making the same |
| US7678859B2 (en) | 2006-09-14 | 2010-03-16 | 3M Innovative Properties Company | Preparation and stabilization of fluoropolymer dispersions |
| US7521513B2 (en) | 2006-11-29 | 2009-04-21 | Dupont Performance Elastomers Llc | Semi-batch process for producing fluoroelastomers |
| US20080146757A1 (en) | 2006-12-19 | 2008-06-19 | Lyons Donald F | Process for producing fluoroelastomers |
| JP2008297528A (ja) | 2007-06-04 | 2008-12-11 | Daikin Ind Ltd | ビニリデンフルオライド系重合体の製造方法 |
| WO2009126504A2 (en) | 2008-04-07 | 2009-10-15 | Arkema Inc. | Polymerization of fluoropolymers using polycaprolactone |
| DE102009030846A1 (de) | 2009-06-26 | 2010-12-30 | Merck Patent Gmbh | Fluortenside |
| RU2522749C2 (ru) | 2009-07-31 | 2014-07-20 | Зм Инновейтив Пропертиз Компани | Соединения фторполимера, содержащие многоатомные соединения, и способы из производства |
| EP2284200A1 (en) * | 2009-07-31 | 2011-02-16 | 3M Innovative Properties Company | Aqueous fluoropolymer dispersions containing a polyol comprising at least one long chain residue and method for producing them |
| GB201012944D0 (en) | 2010-08-02 | 2010-09-15 | 3M Innovative Properties Co | Peroxide curable fluoroelastomers containing modifiers and iodine or bromine endgroups |
| EP2627683B1 (en) | 2010-10-15 | 2014-08-13 | Solvay Specialty Polymers Italy S.p.A. | Fluoroelastomers |
| US20140039130A1 (en) | 2011-04-11 | 2014-02-06 | Unimatec Co., Ltd. | Method for producing fluorine-containing elastomer |
| US9711816B2 (en) | 2011-08-04 | 2017-07-18 | 3M Innovative Properties Company | Low equivalent weight polymers |
| GB2517481A (en) | 2013-08-22 | 2015-02-25 | 3M Innovative Properties Co | Method of making peroxide fluoropolymers using non-fluorindated emulsifiers |
| EP2868674B1 (en) * | 2013-10-30 | 2019-11-20 | 3M Innovative Properties Company | Peroxide curable fluoropolymers obtainable by polymerization using non-fluorinated polyhydroxy emulsifiers |
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2016
- 2016-02-22 KR KR1020177026524A patent/KR20170120148A/ko not_active Withdrawn
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|---|---|
| WO2016137851A1 (en) | 2016-09-01 |
| CN107257810B (zh) | 2019-12-31 |
| KR20170120148A (ko) | 2017-10-30 |
| EP3059265B1 (en) | 2020-10-07 |
| CN107257810A (zh) | 2017-10-17 |
| JP2018505952A (ja) | 2018-03-01 |
| US10875948B2 (en) | 2020-12-29 |
| US20180030182A1 (en) | 2018-02-01 |
| EP3059265A1 (en) | 2016-08-24 |
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