JP6931354B2 - Soecにより最適化された一酸化炭素製造方法 - Google Patents
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Description
[本発明の特徴]
1.二酸化炭素(CO2)と天然ガス及び/またはナフサを含む供給物流から一酸化炭素(CO)を製造する方法であって、
・合成ガス生成ステップであって、第一の合成ガス流を前記供給物流から生成するステップ、
・CO2除去ステップであって、CO2の少なくとも一部を前記第一の合成ガス流から除去し、そしてそれによって生成したCO2リサイクル流を前記合成ガス生成ステップにリサイクルして戻し、そして第二の合成ガス流が前記CO2除去ステップにおいて生成されるステップ、
・CO精製ステップであって、前記第二の合成ガス流からCOを生成するステップ、
を含み、
該方法が、CO2流が供給されるSOECユニットを更に含み、前記SOECユニットはCOを生成し、このCOは第一の合成ガス流にフィードバックされ、それによって、前記第一の合成ガス流中のCO濃度が高められる、方法。
2.SOECユニットに供給されるCO2流が、上記CO2リサイクル流の少なくとも一部を含むリサイクルバイパス流である、前記特徴1による方法。
3.合成ガス生成ステップに供給されるCO2インポート流を含む、上記特徴のいずれか一つによる方法。
4.SOECユニットに供給されるCO2インポート流を含む、上記特徴のいずれか一つによる方法。
5.前記SOECユニットが、前記CO2リサイクル流から前記SOECユニット及びパイプを通して前記第一の合成ガス流に戻る時の圧力差を前記リサイクルバイパス流が克服できるように適合された圧縮機を含む、上記特徴2による方法。
6.前記SOECユニットが、過剰の圧力からSOECユニットを保護するために前記CO2リサイクル流の下流に減圧弁を含む、上記特徴5による方法。
7.前記SOECユニットが、SOECユニットに供給されたCO2の5〜99%をCOに転化する、上記特徴のいずれか一つによる方法。
8.前記SOECユニットが、SOECユニットに供給されたCO2の20〜60%をCOに転化する、上記特徴のいずれか一つによる方法。
9.前記第一の合成ガス流の圧力が2〜25Bar(g)である、上記特徴のいずれか一つによる方法。
10.前記第一の合成ガス流の圧力が15〜25Bar(g)である、上記特徴のいずれか一つによる方法。
11.前記CO2リサイクル流の圧力が0〜5Bar(g)である、上記特徴のいずれか一つによる方法。
12.前記合成ガス生成ステップが、水素化、脱流、予備改質及び改質を含む、上記特徴のいずれか一つによる方法。
13.前記CO精製ステップが、極低温または膜CO精製を含む、上記特徴のいずれか一つによる方法。
本願は特許請求の範囲に記載の発明に係るものであるが、本願の開示は以下も包含する:
1.
二酸化炭素(CO2)と天然ガス及び/またはナフサを含む供給物流から一酸化炭素(CO)を製造する方法であって、
・合成ガス生成ステップであって、第一の合成ガス流を前記供給物流から生成するステップ、
・CO2除去ステップであって、CO2の少なくとも一部を前記第一の合成ガス流から除去し、そしてそれによって生成したCO2リサイクル流を前記合成ガス生成ステップにリサイクルして戻し、そして第二の合成ガス流が前記CO2除去ステップにおいて生成されるステップ、及び
・CO精製ステップであって、前記第二の合成ガス流からCOを生成するステップ、
を含み、
該方法が、CO2流が供給されるSOECユニットを更に含み、前記SOECユニットはCOを生成し、このCOは前記第一の合成ガス流にフィードバックされ、それによって、前記第一の合成ガス流中のCO濃度が高められる、方法。
2.
SOECユニットに供給されるCO2流が、上記CO2リサイクル流の少なくとも一部を含むリサイクルバイパス流である、前記1に記載の方法。
3.
合成ガス生成ステップに供給されるCO2インポート流を含む、前記1または2に記載の方法。
4.
SOECユニットに供給されるCO2インポート流を含む、前記1〜3のいずれか一つに記載の方法。
5.
前記SOECユニットが、前記CO2リサイクル流から前記SOECユニット及びパイプを通して前記第一の合成ガス流に戻る時の圧力差を前記CO2リサイクルバイパス流が克服できるように適合された圧縮機を含む、前記2に記載の方法。
6.
前記SOECユニットが、過剰の圧力からSOECユニットを保護するために前記CO2リサイクル流の下流に減圧弁を含む、前記5に記載の方法。
7.
前記SOECユニットが、SOECユニットに供給されたCO2の5〜99%をCOに転化する、前記1〜6のいずれか一つに記載の方法。
8.
前記SOECユニットが、SOECユニットに供給されたCO2の20〜60%をCOに転化する、前記1〜7のいずれか一つに記載の方法。
9.
前記第一の合成ガス流の圧力が2〜25Bar(g)である、前記1〜8のいずれか一つに記載の方法。
10.
前記第一の合成ガス流の圧力が15〜25Bar(g)である、前記1〜9のいずれか一つに記載の方法。
11.
前記CO2リサイクル流の圧力が0〜5Bar(g)である、前記1〜10のいずれか一つに記載の方法。
12.
前記合成ガス生成ステップが、水素化、脱流、予備改質及び改質を含む、前記1〜11のいずれか一つに記載の方法。
13.
前記CO精製ステップが、極低温または膜CO精製を含む、前記1〜12のいずれか一つに記載の方法。
02.合成ガス生成ステップ
03.第一の合成ガス流
04.CO2除去ステップ
05.CO2リサイクル流
06.第二のの合成ガス流
07.CO精製ステップ
08.SOECユニット
09.CO2流
10.CO2インポート流
Claims (11)
- 二酸化炭素(CO2)と天然ガス及び/またはナフサを含む供給物流から一酸化炭素(CO)を製造する方法であって、
・合成ガス生成ステップであって、第一の合成ガス流を前記供給物流から生成するステップ、
・CO2除去ステップであって、CO2の少なくとも一部を前記第一の合成ガス流から除去し、そしてそれによって生成したCO2リサイクル流を前記合成ガス生成ステップにリサイクルして戻し、そして第二の合成ガス流が前記CO2除去ステップにおいて生成されるステップ、及び
・CO精製ステップであって、前記第二の合成ガス流からCOを生成するステップ、
を含み、
該方法が、CO2流が供給されるSOECユニットを更に含み、前記SOECユニットはCOを生成し、このCOは前記第一の合成ガス流にフィードバックされ、それによって、前記第一の合成ガス流中のCO濃度が高められ、
SOECユニットに供給されるCO2流が、上記CO2リサイクル流の少なくとも一部を含むリサイクルバイパス流であり、及び
前記SOECユニットが、前記CO2リサイクル流から前記SOECユニット及びパイプを通して前記第一の合成ガス流に戻る時の圧力差を前記CO2リサイクルバイパス流が克服できるように適合された圧縮機を含む、方法。 - 合成ガス生成ステップに供給されるCO2インポート流を含む、請求項1に記載の方法。
- SOECユニットに供給されるCO2インポート流を含む、請求項1または2に記載の方法。
- 前記SOECユニットが、過剰の圧力からSOECユニットを保護するために前記CO2リサイクル流の下流に減圧弁を含む、請求項1に記載の方法。
- 前記SOECユニットが、SOECユニットに供給されたCO2の5〜99%をCOに転化する、請求項1〜4のいずれか一つに記載の方法。
- 前記SOECユニットが、SOECユニットに供給されたCO2の20〜60%をCOに転化する、請求項1〜5のいずれか一つに記載の方法。
- 前記第一の合成ガス流の圧力が2〜25Bar(g)である、請求項1〜6のいずれか一つに記載の方法。
- 前記第一の合成ガス流の圧力が15〜25Bar(g)である、請求項1〜7のいずれか一つに記載の方法。
- 前記CO2リサイクル流の圧力が0〜5Bar(g)である、請求項1〜8のいずれか一つに記載の方法。
- 前記合成ガス生成ステップが、水素化、脱流、予備改質及び改質を含む、請求項1〜9のいずれか一つに記載の方法。
- 前記CO精製ステップが、極低温または膜CO精製を含む、請求項1〜10のいずれか一つに記載の方法。
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DKPA201600122 | 2016-02-26 | ||
DKPA201600122 | 2016-02-26 | ||
PCT/EP2017/053765 WO2017144403A1 (en) | 2016-02-26 | 2017-02-20 | Carbon monoxide production process optimized by soec |
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JP6931354B2 true JP6931354B2 (ja) | 2021-09-01 |
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KR (1) | KR20180115746A (ja) |
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AU (1) | AU2017222158B2 (ja) |
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EA202191031A1 (ru) | 2018-10-15 | 2021-07-07 | Хальдор Топсёэ А/С | Способ получения синтез-газа |
WO2020092534A1 (en) * | 2018-10-30 | 2020-05-07 | Ohio University | Novel modular electrocatalytic processing for simultaneous conversion of carbon dioxide and wet shale gas |
DE102020000476A1 (de) | 2020-01-27 | 2021-07-29 | Linde Gmbh | Verfahren und Anlage zur Herstellung von Wasserstoff |
TWI734657B (zh) | 2021-01-15 | 2021-07-21 | 電聯運通股份有限公司 | 燃料電池能源循環利用系統 |
KR102600084B1 (ko) * | 2021-09-14 | 2023-11-09 | 두산에너빌리티 주식회사 | 천연가스 개질 시스템 및 공정 |
KR102584516B1 (ko) * | 2021-09-23 | 2023-10-04 | 삼성중공업 주식회사 | 이산화탄소 처리장치 |
CN114032563A (zh) * | 2021-11-30 | 2022-02-11 | 浙江工业大学 | 一种基于波浪能供电的海上固体氧化物电解池共电解系统 |
EP4349773A1 (de) * | 2022-10-05 | 2024-04-10 | Linde GmbH | Verfahren und anlage zur herstellung eines wasserstoffprodukts |
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US4861351A (en) * | 1987-09-16 | 1989-08-29 | Air Products And Chemicals, Inc. | Production of hydrogen and carbon monoxide |
JPH04200713A (ja) | 1990-11-30 | 1992-07-21 | Nippon Steel Corp | 高純度一酸化炭素製造方法 |
JP2000233918A (ja) | 1999-02-16 | 2000-08-29 | Mitsui Eng & Shipbuild Co Ltd | Coの製造方法 |
US6706770B2 (en) * | 2002-04-04 | 2004-03-16 | Air Products And Chemicals, Inc. | Co-production of hydrogen and methanol from steam reformate |
US7066984B2 (en) | 2003-09-25 | 2006-06-27 | The Boc Group, Inc. | High recovery carbon monoxide production process |
US7351275B2 (en) | 2004-12-21 | 2008-04-01 | The Boc Group, Inc. | Carbon monoxide production process |
US8075746B2 (en) | 2005-08-25 | 2011-12-13 | Ceramatec, Inc. | Electrochemical cell for production of synthesis gas using atmospheric air and water |
US7951283B2 (en) | 2006-07-31 | 2011-05-31 | Battelle Energy Alliance, Llc | High temperature electrolysis for syngas production |
US8138380B2 (en) | 2007-07-13 | 2012-03-20 | University Of Southern California | Electrolysis of carbon dioxide in aqueous media to carbon monoxide and hydrogen for production of methanol |
US8366902B2 (en) * | 2008-03-24 | 2013-02-05 | Battelle Energy Alliance, Llc | Methods and systems for producing syngas |
US8182771B2 (en) * | 2009-04-22 | 2012-05-22 | General Electric Company | Method and apparatus for substitute natural gas generation |
CN103140606A (zh) | 2010-07-09 | 2013-06-05 | 赫多特普索化工设备公司 | 将沼气转化为富含甲烷的气体的方法 |
US20120228150A1 (en) | 2011-03-08 | 2012-09-13 | Kang Bruce S | Co2 decomposition via oxygen deficient ferrite electrodes using solid oxide electrolyser cell |
FR2982272B1 (fr) * | 2011-11-04 | 2014-03-07 | Commissariat Energie Atomique | Procede de conversion thermochimique d'une charge carbonee en gaz de synthese contenant majoritairement h2 et co |
TWI500820B (zh) * | 2012-03-05 | 2015-09-21 | 製造高純度一氧化碳之設備 | |
US9664385B2 (en) * | 2012-09-17 | 2017-05-30 | Phillips 66 Company | Process for enabling carbon-capture from existing combustion processes |
CN104919023B (zh) * | 2013-01-04 | 2016-08-24 | 沙特阿拉伯石油公司 | 利用太阳辐射通过合成气制备单元将二氧化碳转化为烃类燃料 |
US9631284B2 (en) * | 2013-03-15 | 2017-04-25 | Colorado School Of Mines | Electrochemical device for syngas and liquid fuels production |
DK2989233T3 (da) | 2013-03-26 | 2020-10-12 | Haldor Topsoe As | Fremgangsmåde til fremstilling af carbonmonoxid (CO) ud fra carbondioxid (CO2) i en fastoxidelektrolysecelle |
FR3009308B1 (fr) | 2013-08-01 | 2015-09-11 | Commissariat Energie Atomique | Procede de conversion thermochimique d'une charge carbonee en gaz de synthese contenant majoritairement h2 et co. |
EP2873939B1 (en) * | 2013-11-19 | 2019-02-27 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process and apparatus for the production of CO and CO2 |
EA031571B1 (ru) * | 2013-12-12 | 2019-01-31 | Хальдор Топсёэ А/С | Способ получения синтез-газа |
ES2804677T3 (es) | 2014-06-11 | 2021-02-09 | Haldor Topsoe As | Un proceso para la producción segura de fosgeno |
KR101599918B1 (ko) | 2014-06-25 | 2016-03-28 | 울산과학기술원 | 합성가스 생성 시스템 |
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AU2017222158B2 (en) | 2021-04-15 |
CN108698820A (zh) | 2018-10-23 |
ES2769176T3 (es) | 2020-06-24 |
TW201741233A (zh) | 2017-12-01 |
DK3419929T3 (da) | 2020-03-02 |
JP2019507718A (ja) | 2019-03-22 |
WO2017144403A1 (en) | 2017-08-31 |
CN108698820B (zh) | 2021-10-26 |
EP3419929A1 (en) | 2019-01-02 |
US20210179436A1 (en) | 2021-06-17 |
EP3419929B1 (en) | 2019-11-27 |
AU2017222158A1 (en) | 2018-08-23 |
TWI730056B (zh) | 2021-06-11 |
US11401165B2 (en) | 2022-08-02 |
KR20180115746A (ko) | 2018-10-23 |
CA3013415A1 (en) | 2017-08-31 |
CA3013415C (en) | 2024-01-23 |
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