JP6833331B2 - Al-Mg-Si based alloy plate - Google Patents

Al-Mg-Si based alloy plate Download PDF

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JP6833331B2
JP6833331B2 JP2016067350A JP2016067350A JP6833331B2 JP 6833331 B2 JP6833331 B2 JP 6833331B2 JP 2016067350 A JP2016067350 A JP 2016067350A JP 2016067350 A JP2016067350 A JP 2016067350A JP 6833331 B2 JP6833331 B2 JP 6833331B2
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眞二 籠重
眞二 籠重
和章 谷口
和章 谷口
西森 秀樹
秀樹 西森
智明 山ノ井
智明 山ノ井
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Showa Denko KK
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この発明は、Al−Mg―Si系合金板、特に熱伝導性、導電性、強度および加工性に優れた厚さ0.9mm未満のAl−Mg―Si系合金板に関する。 The present invention relates to an Al—Mg—Si based alloy plate, particularly an Al—Mg—Si based alloy plate having a thickness of less than 0.9 mm, which is excellent in thermal conductivity, conductivity, strength and workability.

薄型テレビ、パーソナルコンピューター用薄型モニター、ノートパソコン、タブレットパソコン、カーナビゲーションシステム、ポータブルナビゲーションシステム、スマートフォンや携帯電話等の携帯端末等の製品のシャーシ、メタルベースプリント基板、内部カバーのように発熱体を内蔵または装着する部材材料においては、速やかに放熱するための優れた熱伝導性、強度および加工性が求められる。 Flat-screen TVs, flat-screen monitors for personal computers, laptops, tablet computers, car navigation systems, portable navigation systems, chassis of products such as mobile terminals such as smartphones and mobile phones, metal-based printed boards, heating elements such as inner covers The member material to be built in or mounted is required to have excellent thermal conductivity, strength and workability for quick heat dissipation.

JIS1100、1050、1070等の純アルミニウム合金は熱伝導性に優れるが、強度が低い。高強材として用いられるJIS5052に等のAl−Mg合金(5000系合金)は、純アルミニウム系合金よりも熱伝導性および導電性が著しく劣る。 Pure aluminum alloys such as JIS1100, 1050, and 1070 have excellent thermal conductivity, but have low strength. Al-Mg alloys (5000 series alloys) such as JIS5052 used as high-strength materials are significantly inferior in thermal conductivity and conductivity to pure aluminum alloys.

これに対しAl−Mg−Si系合金(6000系合金)は、熱伝導性および導電性が良く時効硬化により強度向上を図ることができるため、Al−Mg―Si系合金を用いて、強度、熱伝導性、加工性に優れたアルミニウム合金圧延板を得る方法が検討されている。 On the other hand, the Al-Mg-Si-based alloy (6000-based alloy) has good thermal conductivity and conductivity, and the strength can be improved by aging curing. Therefore, the Al-Mg-Si-based alloy is used to increase the strength. A method for obtaining an aluminum alloy rolled plate having excellent thermal conductivity and workability is being studied.

例えば、特許文献1には、Mgを0.1〜0.34質量%、Siを0.2〜0.8質量%、Cuを0.22〜1.0質量%含有し、残部がAl及び不可避不純物からなり、Si/Mg含有量比が1.3以上であるAl−Mg―Si系合金を、半連続鋳造で厚さ250mm以上の鋳塊とし、400〜540℃の温度で予備加熱を経て熱間圧延、50〜85%の圧下率で冷間圧延を施した後、140〜280℃の温度で焼鈍をすることを特徴とする、Al−Mg−Si系合金圧延板の製造方法が開示されている。 For example, Patent Document 1 contains 0.1 to 0.34% by mass of Mg, 0.2 to 0.8% by mass of Si, 0.22 to 1.0% by mass of Cu, and the balance is Al and An Al-Mg-Si alloy composed of unavoidable impurities and having a Si / Mg content ratio of 1.3 or more is semi-continuously cast into an ingot having a thickness of 250 mm or more, and preheated at a temperature of 400 to 540 ° C. A method for producing an Al—Mg—Si alloy rolled plate, which comprises hot rolling, cold rolling at a rolling reduction of 50 to 85%, and then annealing at a temperature of 140 to 280 ° C. It is disclosed.

特許文献2には、Si:0.2〜1.5質量%、Mg:0.2〜1.5質量%、Fe:0.3質量%以下を含有し、さらに、Mn:0.02〜0.15質量%、Cr:0.02〜0.15%の1種または2種を含有するとともに、残部がAlおよび不可避不純物中のTiが0.2%以下に規制するか、もしくはこれにCu:0.01〜1質量%か希土類元素:0.01〜0.2質量%の1種または2種を含有する組成を有するアルミニウム合金版を連続鋳造圧延により作製し、その後冷間圧延し、次いで500〜570℃の溶体化処理を行い、続いてさらに冷間圧延率5〜40%で冷間圧延を行い、冷間圧延後150〜190℃未満に加熱する時効処理を行うことを特徴とする熱伝導性、強度および曲げ加工性に優れたアルミニウム板の製造方法が記載されている。 Patent Document 2 contains Si: 0.2 to 1.5% by mass, Mg: 0.2 to 1.5% by mass, Fe: 0.3% by mass or less, and Mn: 0.02 to 0.02 to It contains one or two kinds of 0.15% by mass and Cr: 0.02 to 0.15%, and the balance is Al and Ti in unavoidable impurities is regulated to 0.2% or less, or to this. An aluminum alloy plate having a composition containing 1 or 2 types of Cu: 0.01 to 1% by mass or rare earth element: 0.01 to 0.2% by mass is produced by continuous casting and rolling, and then cold-rolled. Then, solution treatment at 500 to 570 ° C. is performed, then cold rolling is further performed at a cold rolling rate of 5 to 40%, and after cold rolling, aging treatment is performed in which the material is heated to less than 150 to 190 ° C. A method for producing an aluminum plate having excellent thermal conductivity, strength and bending workability is described.

特許文献3には、Si:0.2〜0.8質量%、Mg:0.3〜1質量%、Fe:0.5質量%以下、Cu:0.5質量%以下を含有し、さらにTi:0.1質量%以下またはB:0.1質量%以下の少なくとも1種を含有し、残部Alおよび不可避不純物からなるか、もしくはさらに不純物としてのMnおよびCrが、Mn:0.1質量%以下、Cr:0.1質量%以下に規制されているAl−Mg−Si系合金鋳塊を、熱間圧延し、さらに冷間圧延する工程を含む合金板の製造方法であって、熱間圧延後で冷間圧延終了までの間に、200〜400℃で1時間以上保持することにより熱処理を行うことを特徴とするAl−Mg―Si系合金板の製造方法が示されている。 Patent Document 3 contains Si: 0.2 to 0.8% by mass, Mg: 0.3 to 1% by mass, Fe: 0.5% by mass or less, Cu: 0.5% by mass or less, and further. It contains at least one of Ti: 0.1% by mass or less or B: 0.1% by mass or less, and is composed of the balance Al and unavoidable impurities, or Mn and Cr as impurities are Mn: 0.1% by mass. % Or less, Cr: 0.1% by mass or less is a method for producing an alloy plate, which comprises a step of hot rolling an Al—Mg—Si based alloy ingot and further cold rolling. A method for producing an Al—Mg—Si based alloy plate, which comprises performing a heat treatment by holding at 200 to 400 ° C. for 1 hour or more after the inter-rolling until the end of the cold rolling is shown.

なお、特許文献3に記載のとおり、JIS1000系から7000系のアルミニウム合金においては、熱伝導率と導電率が良好な相関性を示し、優れた熱伝導性を有するアルミニウム合金板は優れた導電率を有し、放熱部材材料はもちろん導電部材材料として用いることができる。 As described in Patent Document 3, in the JIS1000 series to 7000 series aluminum alloys, the thermal conductivity and the conductivity show a good correlation, and the aluminum alloy plate having excellent thermal conductivity has excellent conductivity. Can be used as a conductive member material as well as a heat radiating member material.

特開2012−62517号公報Japanese Unexamined Patent Publication No. 2012-62517 特開2007−9262号公報Japanese Unexamined Patent Publication No. 2007-9262 特開2003−321755号公報Japanese Unexamined Patent Publication No. 2003-321755

上記のとおりAl−Mg―Si系合金板の改良がなされてきたが、アルミニウム合金部材材料を用いる製品の高性能化、小型化、薄型化に伴い、高い導電率と加工性に加え従来よりも更に高い強度を有することがAl−Mg−Si系合金板に求められているのに対し、上記特許文献1、特許文献2および特許文献3記載の方法では高い導電率と加工性を維持しつつ必要な強度を得ることが困難であり、比較的薄い厚さのAl−Mg―Si系合金板の改善検討も不十分であった。 As mentioned above, the Al-Mg-Si alloy plate has been improved, but with the improvement of high performance, miniaturization, and thinning of products using aluminum alloy member materials, in addition to high conductivity and workability, it is more than before. While the Al—Mg—Si alloy plate is required to have higher strength, the methods described in Patent Document 1, Patent Document 2 and Patent Document 3 maintain high conductivity and workability. It was difficult to obtain the required strength, and improvement studies on a relatively thin Al-Mg-Si alloy plate were insufficient.

本発明は、上述した技術背景に鑑み、高い導電率と良好な加工性を有しつつ更に高い強度を有する厚さ0.9mm未満のAl−Mg−Si系合金板を提供することを目的とする。 In view of the above-mentioned technical background, an object of the present invention is to provide an Al-Mg-Si based alloy plate having a thickness of less than 0.9 mm, which has high conductivity and good workability and further high strength. To do.

上記課題は、以下の手段によって解決される。
(1)化学組成が、Si:0.2〜0.8質量%、Mg:0.3〜1質量%、Fe:0.5質量%以下およびCu:0.5質量%以下を含有し、さらにTi:0.1質量%以下またはB:0.1質量%以下の少なくとも1種を含有し、残部Al及び不可避不純物からなり、引張強さが280MPa以上、導電率が54%IACS以上であり厚さが0.9mm未満のAl−Mg−Si系合金板。
(2)不純物としてのMn、Cr、およびZnが、それぞれ0.1質量%以下に規制されている前項1に記載のAl−Mg−Si系合金板。
(3)不純物としてのNi、V、Ga、Pb、Sn、BiおよびZrが、それぞれ0.05質量%以下に規制されている前項1または前項2に記載のAl−Mg−Si系合金板。
(4)不純物としてのAgが0.05質量%以下に規制されている前項1ないし前項3の何れか1項に記載のAl−Mg−Si系合金板。
(5)不純物としての希土類元素の合計含有量が0.1質量%以下に規制されている前項1ないし前項4の何れか1項に記載のAl−Mg−Si系合金板。
(6)引張強さTS(MPa)と0.2%耐力YS(MPa)の差(TS―YS)が0MPa以上30MPa以下である前項1ないし前項5の何れか1項に記載のAl−Mg−Si系合金板。
The above problem is solved by the following means.
(1) The chemical composition contains Si: 0.2 to 0.8% by mass, Mg: 0.3 to 1% by mass, Fe: 0.5% by mass or less, and Cu: 0.5% by mass or less. Further, it contains at least one of Ti: 0.1% by mass or less or B: 0.1% by mass or less, is composed of the balance Al and unavoidable impurities, has a tensile strength of 280 MPa or more, and a conductivity of 54% IACS or more. An Al-Mg-Si alloy plate with a thickness of less than 0.9 mm.
(2) The Al—Mg—Si based alloy plate according to item 1 above, wherein Mn, Cr, and Zn as impurities are each regulated to 0.1% by mass or less.
(3) The Al—Mg—Si alloy plate according to item 1 or 2, wherein Ni, V, Ga, Pb, Sn, Bi and Zr as impurities are regulated to 0.05% by mass or less, respectively.
(4) The Al—Mg—Si based alloy plate according to any one of Items 1 to 3 above, wherein Ag as an impurity is regulated to 0.05% by mass or less.
(5) The Al—Mg—Si alloy plate according to any one of the above items 1 to 4, wherein the total content of rare earth elements as impurities is regulated to 0.1% by mass or less.
(6) The Al-Mg according to any one of the above items 1 to 5, wherein the difference (TS-YS) between the tensile strength TS (MPa) and the 0.2% proof stress YS (MPa) is 0 MPa or more and 30 MPa or less. -Si based alloy plate.

前項(1)に記載の発明によれば、化学組成が、Si:0.2〜0.8質量%、Mg:0.3〜1質量%、Fe:0.5質量%以下およびCu:0.5質量%以下を含有し、さらにTi:0.1質量%以下またはB:0.1質量%以下の少なくとも1種を含有し、残部Al及び不可避不純物からなり、強度、熱伝導性、加工性に優れた厚さ0.9mm未満のAl−Mg−Si系合金板となしうる。 According to the invention described in the previous section (1), the chemical composition is Si: 0.2 to 0.8% by mass, Mg: 0.3 to 1% by mass, Fe: 0.5% by mass or less, and Cu: 0. It contains at least 1 type of Ti: 0.1% by mass or less or B: 0.1% by mass or less, and is composed of the balance Al and unavoidable impurities, and has strength, thermal conductivity, and processing. It can be an Al-Mg-Si based alloy plate having excellent properties and a thickness of less than 0.9 mm.

前項(2)に記載の発明によれば、不純物としてのMn、Cr、およびZnが、それぞれ0.1質量%以下に規制されているから、強度、熱伝導性、加工性に優れた厚さ0.9mm未満のAl−Mg−Si系合金板となしうる。 According to the invention described in the previous section (2), since Mn, Cr, and Zn as impurities are each regulated to 0.1% by mass or less, the thickness is excellent in strength, thermal conductivity, and workability. It can be an Al-Mg-Si based alloy plate of less than 0.9 mm.

前項(3)に記載の発明によれば、不純物としてのNi、V、Ga、Pb、Sn、BiおよびZrが、それぞれ0.05質量%以下に規制されているから、強度、熱伝導性、加工性に優れたAl−Mg−Si系合金板となしうる。 According to the invention described in the previous section (3), Ni, V, Ga, Pb, Sn, Bi and Zr as impurities are regulated to 0.05% by mass or less, respectively, so that the strength and thermal conductivity are controlled. It can be an Al-Mg-Si based alloy plate with excellent workability.

前項(4)に記載の発明によれば、不純物としてのAgが0.05質量%以下に規制されているから、強度、熱伝導性、加工性に優れたAl−Mg−Si系合金板となしうる。 According to the invention described in the previous section (4), since Ag as an impurity is regulated to 0.05% by mass or less, the Al-Mg-Si alloy plate having excellent strength, thermal conductivity, and workability can be obtained. It can be done.

前項(5)に記載の発明によれば、不純物としての希土類元素の合計含有量が0.1質量%以下に規制されているから、強度、熱伝導性、加工性にAl−Mg−Si系合金板となしうる。 According to the invention described in the preceding paragraph (5), since the total content of rare earth elements as impurities is regulated to 0.1% by mass or less, the strength, thermal conductivity, and processability are based on Al-Mg-Si. It can be an alloy plate.

前項(6)に記載の発明によれば、引張強さおよび耐力の両方が強いAl−Mg−Si系合金板となしうる。 According to the invention described in the preceding paragraph (6), the Al-Mg-Si alloy plate having high tensile strength and proof stress can be obtained.

本願発明者は、熱間圧延、冷間圧延を順次施するAl−Mg−Si系合金板の製造方法において、熱間圧延上がりの合金板の表面温度を所定の温度以下とするとともに、熱間圧延終了後であって冷間圧延終了前に時効処理としての熱処理を施すことにより、高い導電率と良好な加工性を有しつつ更に高い強度を有するAl−Mg−Si系合金板が得られることを見出し本願の発明に至った。 In the method for producing an Al-Mg-Si based alloy plate in which hot rolling and cold rolling are sequentially performed, the inventor of the present application sets the surface temperature of the alloy plate after hot rolling to a predetermined temperature or lower and is hot. By performing heat treatment as an aging treatment after the end of rolling and before the end of cold rolling, an Al-Mg-Si based alloy plate having high conductivity and good workability and higher strength can be obtained. This led to the invention of the present application.

以下に、本願のAl−Mg−Si系合金板について詳細に説明する。 The Al—Mg—Si alloy plate of the present application will be described in detail below.

本願のAl−Mg−Si系合金組成において、各元素の添加目的および含有量の限定理由は下記のとおりである。 In the Al—Mg—Si based alloy composition of the present application, the purpose of adding each element and the reason for limiting the content are as follows.

MgおよびSiは強度の発現に必要な元素であり、それぞれの含有量はSi:0.2質量%以上0.8質量%以下、Mg:0.3質量%以上1質量%以下とする。Si含有量が0.2質量%未満あるいはMg含有量が0.3質量%未満では十分な強度を得ることができない。一方、Si含有量が0.8質量%、Mg含有量が1質量%を超えると、熱間圧延での圧延負荷が高くなって生産性が低下し、得られるアルミニウム合金板の成形加工性も悪くなる。Si含有量は0.2質量%以上0.6質量%以下が好ましく、更に0.32質量%以上0.60質量%以下が好ましい。Mg含有量は0.45質量%以上0.9質量%以下が好ましく、更に0.45質量%以上0.55質量%以下が好ましい。 Mg and Si are elements necessary for developing strength, and their respective contents are Si: 0.2% by mass or more and 0.8% by mass or less, and Mg: 0.3% by mass or more and 1% by mass or less. If the Si content is less than 0.2% by mass or the Mg content is less than 0.3% by mass, sufficient strength cannot be obtained. On the other hand, when the Si content exceeds 0.8% by mass and the Mg content exceeds 1% by mass, the rolling load in hot rolling increases, the productivity decreases, and the molding processability of the obtained aluminum alloy plate also increases. become worse. The Si content is preferably 0.2% by mass or more and 0.6% by mass or less, and more preferably 0.32% by mass or more and 0.60% by mass or less. The Mg content is preferably 0.45% by mass or more and 0.9% by mass or less, and more preferably 0.45% by mass or more and 0.55% by mass or less.

FeおよびCuは成形加工上必要な成分であるが、多量に含有すると耐食性が低下する。本願においてFe含有量およびCu含有量はそれぞれ0.5質量%以下に規制する。Fe含有量は0.35質量%以下に規制することが好ましく、更に0.1質量%以上0.25質量%以下であることが好ましい。Cu含有量は0.1質量%以下であることが好ましい。 Fe and Cu are necessary components for molding, but if they are contained in a large amount, the corrosion resistance is lowered. In the present application, the Fe content and the Cu content are each regulated to 0.5% by mass or less. The Fe content is preferably regulated to 0.35% by mass or less, and more preferably 0.1% by mass or more and 0.25% by mass or less. The Cu content is preferably 0.1% by mass or less.

TiおよびBは、合金をスラブに鋳造する際に結晶粒を微細化するとともに凝固割れを防止する効果がある。前記効果はTiまたはBの少なくとも1種の添加により得られ、両方を添加してもよい。しかしながら、多量に含有すると、晶出物がサイズの大きい晶出物が多く生成するため、製品の加工性や熱伝導性および導電率が低下する。Ti含有量は0.1質量以下が好ましく、更に0.005質量%以上0.05質量%以下が好ましい。 Ti and B have the effect of refining crystal grains and preventing solidification cracks when the alloy is cast into a slab. The effect is obtained by the addition of at least one of Ti or B, and both may be added. However, if it is contained in a large amount, a large amount of crystallized products having a large size are produced, so that the processability, thermal conductivity and conductivity of the product are lowered. The Ti content is preferably 0.1% by mass or less, more preferably 0.005% by mass or more and 0.05% by mass or less.

また、B含有量は0.1質量%以下が好ましく、特に0.06質量%以下が好ましい。 The B content is preferably 0.1% by mass or less, and particularly preferably 0.06% by mass or less.

また、合金元素には種々の不純物元素が不可避的に含有されるが、MnおよびCrは伝導性および導電性を低下させ、Znは含有量が多くなると合金材の耐食性を低下させるため少ないことが好ましい。不純物としてのMn、Cr、およびZnのそれぞれの含有量は0.1質量%以下が好ましく、更に0.05質量%以下が好ましい。 Further, although various impurity elements are inevitably contained in the alloy element, Mn and Cr reduce the conductivity and conductivity, and the amount of Zn is small because the corrosion resistance of the alloy material is lowered as the content is increased. preferable. The content of each of Mn, Cr, and Zn as impurities is preferably 0.1% by mass or less, and more preferably 0.05% by mass or less.

上記以外のその他の不純物元素としては、Ni、V、Ga、Pb、Sn、Bi、Zr、Ag、希土類等が挙げられるが、これらに限定されるものではなく、これらその他の不純物元素のうち希土類以外は個々の元素の含有量として0.05質量%以下であることが好ましい。上記その他の不純物元素のうち希土類は、1種または複数種の元素が含まれていてもよく、ミッシュメタルの状態で含まれている鋳造用原料に由来するものでも良いが、希土類元素の合計含有量は0.1質量%以下であることが好ましく、更に0.05質量%以下であることが好ましい。 Examples of other impurity elements other than the above include, but are not limited to, Ni, V, Ga, Pb, Sn, Bi, Zr, Ag, rare earths, etc., and among these other impurity elements, rare earths Other than the above, the content of each element is preferably 0.05% by mass or less. Among the above other impurity elements, the rare earth element may contain one or more kinds of elements, or may be derived from a casting raw material contained in the state of mischmetal, but contains the total amount of rare earth elements. The amount is preferably 0.1% by mass or less, and more preferably 0.05% by mass or less.

次に、本願規定のAl−Mg―Si系合金板を得るための処理工程について記述する。 Next, a processing step for obtaining the Al—Mg—Si based alloy plate specified in the present application will be described.

常法にて溶解成分調整し、Al−Mg―Si系合金鋳塊を得る。得られた合金鋳塊に熱間圧延前加熱より前の工程として均質化処理を施すことが好ましい。 The dissolution component is adjusted by a conventional method to obtain an Al—Mg—Si based alloy ingot. It is preferable that the obtained alloy ingot is homogenized as a step prior to heating before hot rolling.

前記均質化処理は、500℃以上で行うことが好ましい。 The homogenization treatment is preferably performed at 500 ° C. or higher.

前記熱間圧延前加熱はAl−Mg―Si系合金鋳塊中に晶出物およびMg、Siを固溶させ均一な組織とするために実施するが、温度が高すぎると鋳塊中で部分的な融解が起こる可能性があるため、450℃以上580℃以下で行うことが好ましく、特に500℃以上580℃以下で行うことが好ましい。 The heating before hot rolling is carried out in order to solid-solve the crystals, Mg and Si in the Al—Mg—Si alloy ingot to form a uniform structure, but if the temperature is too high, the part in the ingot is partially heated. It is preferable to carry out the process at 450 ° C. or higher and 580 ° C. or lower, and particularly preferably at 500 ° C. or higher and 580 ° C. or lower.

Al−Mg―Si系合金鋳塊に均質化処理を行った後冷却し、熱間圧延前加熱を行っても良いし、均質化処理と熱間圧延前加熱を連続して行っても良く、前記均質化処理および熱間圧延前加熱の好ましい温度範囲にて均質化処理と熱間圧延前加熱を兼ねて同じ温度で加熱しても良い。 The Al—Mg—Si alloy ingot may be homogenized and then cooled and preheated before hot rolling, or homogenized and preheated before hot rolling may be continuously performed. In the preferable temperature range of the homogenization treatment and the pre-hot rolling heating, the homogenization treatment and the pre-hot rolling heating may be combined and heated at the same temperature.

鋳造後熱間圧延前加熱前に鋳塊の表面近傍の不純物層を除去する為に鋳塊に面削を施すことが好ましい。面削は鋳造後均質化処理前であっても良いし、均質化処理後熱間圧延前加熱前であってもよい。 After casting, before hot rolling, before heating, it is preferable to face-cut the ingot in order to remove the impurity layer near the surface of the ingot. The face cutting may be performed after casting and before homogenization treatment, or after homogenization treatment and before hot rolling and before heating.

熱間圧延前加熱後のAl−Mg―Si系合金鋳塊に熱間圧延を施す。 Before hot rolling Hot rolling is performed on the Al—Mg—Si alloy ingot after heating.

熱間圧延は粗熱間圧延と仕上げ熱間圧延からなり、粗熱間圧延機を用い複数のパスからなる粗熱間圧延を行った後、粗熱間圧延機とは異なる仕上げ熱間圧延機を用いて仕上げ熱間圧延を行う。なお、本願において、粗熱間圧延機での最終パスを熱間圧延の最終パスとする場合は、仕上げ熱間圧延を省略することができる。 Hot rolling consists of rough hot rolling and finishing hot rolling. After performing rough hot rolling consisting of multiple passes using a rough hot rolling machine, a finishing hot rolling machine different from the rough hot rolling machine Is used for finishing hot rolling. In the present application, when the final pass in the rough hot rolling mill is the final pass for hot rolling, the finishing hot rolling can be omitted.

本願において、仕上げ熱間圧延は、上下一組のワークロールもしくは二組以上のワークロールが連続して設置された圧延機を用いて1方向からAl−Mg―Si系合金板を導入し1回のパスで実施される。 In the present application, finish hot rolling is performed once by introducing an Al-Mg—Si alloy plate from one direction using a rolling mill in which one set of upper and lower work rolls or two or more sets of work rolls are continuously installed. It is carried out with the pass of.

冷間圧延をコイルで実施する場合には、仕上げ熱間圧延後のAl−Mg―Si系合金板を巻き取り装置で巻き取って熱延コイルとすればよい。仕上げ熱間圧延を省略し、粗熱間圧延の最終パスを熱間圧延の最終パスとする場合は、粗熱間圧延の後、Al−Mg―Si系合金板を巻き取り装置にて巻き取って熱延コイルとしてもよい。 When cold rolling is carried out with a coil, the Al—Mg—Si based alloy plate after finishing hot rolling may be wound by a winding device to form a hot-rolled coil. When the final hot rolling is omitted and the final pass of the rough hot rolling is the final pass of the hot rolling, the Al—Mg—Si alloy plate is wound by a winding device after the rough hot rolling. It may be a hot-rolled coil.

粗熱間圧延では、溶体化処理に準じてMgおよびSiが固溶された状態を保持した後、粗熱間圧延のパスによるAl−Mg―Si系合金板の冷却、もしくは粗熱間圧延のパス後とパス後の強制冷却による温度降下により焼き入れの効果を得ことができる。 In rough hot rolling, after the state in which Mg and Si are solid-melted is maintained according to the solution heat treatment, the Al-Mg—Si alloy plate is cooled by the rough hot rolling pass, or the rough hot rolling is performed. The effect of quenching can be obtained by the temperature drop after the pass and due to the forced cooling after the pass.

本願において粗熱間圧延の複数のパスのうち、パス直前のAl−Mg―Si系合金板の表面温度が350℃以上470℃以下でありパスによるAl−Mg―Si系合金板の冷却、もしくはパスとパス後の強制冷却による平均冷却速度が50℃/分以上であるパスを制御パスと呼ぶ。制御パス直前のAl−Mg―Si系合金板の表面温度を350℃以上470℃以下としたのは、350℃未満では粗熱間圧延における急冷による焼き入れの効果が小さく、470℃より高い温度ではパス上がりのAl−Mg―Si系合金板の急冷が困難であるからである。 In the present application, among the plurality of passes of rough hot rolling, the surface temperature of the Al—Mg—Si alloy plate immediately before the pass is 350 ° C. or higher and 470 ° C. or lower, and the Al—Mg—Si alloy plate is cooled by the pass, or A pass and a pass in which the average cooling rate by forced cooling after the pass is 50 ° C./min or more is called a control pass. The surface temperature of the Al-Mg-Si alloy plate immediately before the control pass was set to 350 ° C or higher and 470 ° C or lower because the effect of quenching by quenching in rough hot rolling is small below 350 ° C and the temperature is higher than 470 ° C. This is because it is difficult to quench the Al-Mg-Si alloy plate after passing.

上記平均冷却速度は制御パスにおいて強制冷却を行わない場合は制御パスの開始から終了まで、制御パス後に強制冷却を行う場合は制御パスの開始から強制冷却の終了までのAl−Mg―Si系合金板の温度降下(℃)を要した時間(分)で除した値とする。 The average cooling rate is the Al-Mg—Si alloy from the start to the end of the control path when forced cooling is not performed in the control path, and from the start to the end of forced cooling when forced cooling is performed after the control pass. It shall be the value obtained by dividing the temperature drop (° C) of the plate by the required time (minutes).

制御パス後の強制冷却は、Al−Mg―Si系合金板を圧延しながら圧延後の部位に対し順次実施してもよいし、Al−Mg―Si系合金板全体を圧延した後実施してもよい。強制冷却の方法は限定されないが、水冷であっても空冷であってもよいし、クーラントを利用してもよい。 The forced cooling after the control pass may be sequentially performed on the rolled portion while rolling the Al—Mg—Si alloy plate, or after rolling the entire Al—Mg—Si alloy plate. May be good. The method of forced cooling is not limited, but water cooling, air cooling, or coolant may be used.

前記制御パスは少なくとも1回実施することが好ましく、複数回実施しても良い。制御パスを複数回実施する場合、各々の制御パスについてパス後に強制冷却を行うか否かを選択できる。パス直前Al−Mg―Si系合金板の表面温度が470〜350℃であって冷却速度が50℃/分以上であれば制御パスは複数回実施することができるが、1回の制御パスでAl−Mg―Si系合金板の温度を350℃未満に降下させることにより効率よく効果的に焼き入れを行うことができる。 The control pass is preferably performed at least once, and may be performed a plurality of times. When the control path is executed a plurality of times, it is possible to select whether or not to perform forced cooling after the control path for each control path. Immediately before the pass If the surface temperature of the Al-Mg—Si alloy plate is 470 to 350 ° C and the cooling rate is 50 ° C / min or more, the control pass can be performed multiple times, but one control pass is required. By lowering the temperature of the Al—Mg—Si based alloy plate to less than 350 ° C., quenching can be performed efficiently and effectively.

本願において、粗熱間圧延の最終パス後に強制冷却を行わない場合は、熱間圧延の最終パス直後のAl−Mg―Si系合金板の表面温度を粗熱間圧延上がり温度とし、粗熱間圧延の最終パス後に強制冷却を行う場合は、強制冷却終了直後のAl−Mg―Si系合金板の表面温度を粗熱間圧延上がり温度とする。 In the present application, when forced cooling is not performed after the final pass of the rough hot rolling, the surface temperature of the Al—Mg—Si based alloy plate immediately after the final pass of the hot rolling is set as the rough hot rolling rising temperature, and the rough hot rolling. When forced cooling is performed after the final pass of rolling, the surface temperature of the Al—Mg—Si based alloy plate immediately after the completion of forced cooling is set as the crude hot rolling rise temperature.

本願において仕上げ熱間圧延を実施する場合は仕上げ熱間圧延の終了、仕上げ熱間圧延を実施しない場合は粗熱間圧延の最終パスの終了をもって熱間圧延の終了とし、熱間圧延終了直後のAl−Mg―Si系合金板の表面温度は170℃以下とすることが好ましい。熱間圧延終了直後の合金板の温度を170℃以下とすることにより有効な焼き入れ効果が得られ、その後の熱処理時により時効硬化するとともに導電率が向上する。 In the present application, when the finish hot rolling is carried out, the finish hot rolling is completed, and when the finish hot rolling is not carried out, the end of the final pass of the rough hot rolling is regarded as the end of the hot rolling, and immediately after the end of the hot rolling. The surface temperature of the Al—Mg—Si based alloy plate is preferably 170 ° C. or lower. An effective quenching effect can be obtained by setting the temperature of the alloy plate immediately after the completion of hot rolling to 170 ° C. or lower, and then age hardening and conductivity are improved by the subsequent heat treatment.

熱間圧延終了直後のAl−Mg―Si系合金板の表面温度が高すぎると、焼き入れの効果が不足し、熱間圧延終了後冷間圧延終了前に熱処理を実施しても強度の向上が不十分となる。熱間圧延終了直後のAl−Mg―Si系合金板の表面温度は150℃以下が更に好ましく、特に130℃以下が好ましい。 If the surface temperature of the Al-Mg-Si alloy plate immediately after the end of hot rolling is too high, the effect of quenching will be insufficient, and the strength will be improved even if heat treatment is performed after the end of hot rolling and before the end of cold rolling. Is insufficient. The surface temperature of the Al—Mg—Si alloy plate immediately after the completion of hot rolling is more preferably 150 ° C. or lower, and particularly preferably 130 ° C. or lower.

なお、粗熱間圧延の後仕上げ熱間圧延を行う場合は、仕上げ熱間圧延のパスによる焼き入れ効果を得るために、仕上げ熱間圧延直前のAl−Mg―Si系合金板の表面温度は280℃以下であることが好ましい。 When performing hot rolling after rough hot rolling, the surface temperature of the Al-Mg—Si alloy plate immediately before hot rolling is set in order to obtain the quenching effect due to the pass of hot rolling. It is preferably 280 ° C. or lower.

また、仕上げ熱間圧延を行わず粗熱間圧延の最終パスが制御パスではない場合も同様に、粗熱間圧延最終パス直前のAl−Mg―Si系合金板の表面温度は280℃以下が好ましい。 Similarly, when the final pass of rough hot rolling is not the control pass without finish hot rolling, the surface temperature of the Al—Mg—Si alloy plate immediately before the final pass of rough hot rolling is 280 ° C or lower. preferable.

一方、仕上げ熱間圧延を行わず粗熱間圧延の最終パスが制御パスである場合、制御パスが熱間圧延の最終パスとなるので、熱間圧延の最終パス直前のAl−Mg―Si系合金板の表面温度が470〜350℃であって圧延もしくは圧延と圧延後の強制冷却により冷却速度が50℃/分以上の冷却速度で合金板の表面温度が170℃以下となるように制御パスを実施する。 On the other hand, when the final pass of rough hot rolling is the control pass without performing finish hot rolling, the control pass is the final pass of hot rolling, so the Al-Mg-Si system immediately before the final pass of hot rolling. Control path so that the surface temperature of the alloy plate is 470 to 350 ° C and the surface temperature of the alloy plate is 170 ° C or less at a cooling rate of 50 ° C / min or more by rolling or forced cooling after rolling and rolling. To carry out.

熱間圧延終了後冷間圧延終了前のAl−Mg―Si系合金板に熱処理を施し、時効硬化させるとともに導電率を向上させる。 After the completion of hot rolling, the Al—Mg—Si alloy plate before the completion of cold rolling is heat-treated to be age-hardened and the conductivity is improved.

本願において熱間圧延終了後冷間圧延終了前のAl−Mg―Si系合金板への熱処理は時効硬化および導電率向上の効果を得るために120℃以上200℃未満の温度で実施する。前記熱処理の温度は130℃以上190℃以下が好ましく、更に140℃以上180℃以下が好ましい。 In the present application, the heat treatment of the Al—Mg—Si alloy plate after the completion of hot rolling and before the completion of cold rolling is carried out at a temperature of 120 ° C. or higher and lower than 200 ° C. in order to obtain the effects of age hardening and conductivity improvement. The temperature of the heat treatment is preferably 130 ° C. or higher and 190 ° C. or lower, and more preferably 140 ° C. or higher and 180 ° C. or lower.

前記熱間圧延終了後冷間圧延終了前において120℃以上200℃未満の温度で実施するAl−Mg―Si系合金板の熱処理の時間は特に限定されないが、時効硬化および導電率向上の効果が得られるように所定の温度で時間を調節すればよく、例えば、1〜12時間の範囲で時間を調節して熱処理を実施すればよい。 The heat treatment time of the Al—Mg—Si alloy plate carried out at a temperature of 120 ° C. or higher and lower than 200 ° C. after the completion of the hot rolling and before the completion of the cold rolling is not particularly limited, but the effects of aging hardening and improvement of conductivity can be obtained. The time may be adjusted at a predetermined temperature so as to be obtained, and for example, the heat treatment may be performed by adjusting the time in the range of 1 to 12 hours.

前記熱処理の後、冷間圧延を実施することにより加工硬化し強度が更に向上する。 After the heat treatment, cold rolling is performed to work harden and further improve the strength.

前記熱処理は時効硬化させたAl−Mg―Si系合金板の冷間圧延による強度向上効果を高めるため、熱間圧延終了後冷間圧延開始前に実施することが好ましい。 The heat treatment is preferably carried out after the completion of hot rolling and before the start of cold rolling in order to enhance the effect of improving the strength of the age-hardened Al—Mg—Si alloy plate by cold rolling.

前記熱処理後の冷間圧延により所定の厚さのAl−Mg―Si系合金板とする。熱処理後の冷間圧延は強度向上と加工性の改善の為60%以上の圧延率で実施されることが好ましい。熱処理後の冷間圧延によるAl−Mg―Si系合金板の圧延率は更に70%以上が好ましく、特に80%以上が好ましい。 After the heat treatment, cold rolling is performed to obtain an Al—Mg—Si based alloy plate having a predetermined thickness. Cold rolling after the heat treatment is preferably carried out at a rolling ratio of 60% or more in order to improve the strength and workability. The rolling ratio of the Al—Mg—Si alloy plate by cold rolling after the heat treatment is more preferably 70% or more, and particularly preferably 80% or more.

冷間圧延後のAl−Mg―Si系合金板に必要に応じて洗浄を実施しても良い。 If necessary, the Al—Mg—Si alloy plate after cold rolling may be washed.

Al−Mg―Si系合金板の加工性を更に重視する場合は冷間圧延後に最終焼鈍を実施しても良い。最終焼鈍はAl−Mg―Si系合金板の強度が低くなりすぎないようにする為に180℃以下で実施することが好ましく、更に160℃以下、特に140℃以下で実施することが好ましい。 When the workability of the Al—Mg—Si alloy plate is more important, final annealing may be performed after cold rolling. The final annealing is preferably carried out at 180 ° C. or lower, and more preferably 160 ° C. or lower, particularly 140 ° C. or lower, in order to prevent the strength of the Al—Mg—Si alloy plate from becoming too low.

前記180℃以下の温度で実施するAl−Mg―Si系合金板の最終焼鈍の時間は必要な加工性および強度が得られるよう調節すればよく、例えば、1〜10時間の範囲で最終焼鈍の温度により選択すれば良い。 The final annealing time of the Al—Mg—Si alloy plate carried out at a temperature of 180 ° C. or lower may be adjusted so as to obtain the required workability and strength. For example, the final annealing is performed in the range of 1 to 10 hours. It may be selected according to the temperature.

なお、本願のAl−Mg―Si系合金板の製造はコイルで行ってもよく、単板で行ってもよい。また、冷間圧延より後の任意の工程で合金板を切断し切断後の工程を単板で行ってもよいし、用途に応じスリットし条にしても良い。 The Al—Mg—Si alloy plate of the present application may be produced by a coil or a single plate. Further, the alloy plate may be cut in an arbitrary step after cold rolling, and the step after cutting may be performed on a single plate, or slits may be formed depending on the application.

上記の製造方法によれば、高い導電率を得つつ、強度を向上させることができ、高強度であるにも関わらず加工性も優れた厚さ0.9mm未満のAl−Mg―Si系合金板が得られる。 According to the above manufacturing method, the strength can be improved while obtaining high conductivity, and the Al-Mg—Si alloy having a thickness of less than 0.9 mm, which has excellent workability despite its high strength. A board is obtained.

本願のAl−Mg―Si系合金板の導電率は54%IACS以上、引張強さは280MPa以上と規定する。引張強さは285MPa以上が好ましく、290MPa以上が更に好ましい。本願のAl−Mg―Si系合金板の引張強さTS(MPa)と0.2%耐力YS(MPa)の差(TS―YS)は0MPa以上30MPa以下であることが好ましく、TS―YSは更に0MPa以上20MPa以下であることが好ましい。 The Al-Mg—Si alloy plate of the present application is defined to have a conductivity of 54% IACS or more and a tensile strength of 280 MPa or more. The tensile strength is preferably 285 MPa or more, and more preferably 290 MPa or more. The difference (TS-YS) between the tensile strength TS (MPa) and the 0.2% proof stress YS (MPa) of the Al-Mg—Si alloy plate of the present application is preferably 0 MPa or more and 30 MPa or less, and TS-YS is Further, it is preferably 0 MPa or more and 20 MPa or less.

以下に本発明の実施例および比較例を示す。 Examples and comparative examples of the present invention are shown below.

表1に示す化学組成の異なるアルミニウム合金スラブをDC鋳造法により得た。 Aluminum alloy slabs having different chemical compositions shown in Table 1 were obtained by a DC casting method.

[実施例1]
表1の化学組成番号1のアルミニウム合金スラブに面削を施した。次に、面削後の合金スラブに対し加熱炉中で570℃3hの均質化処理を実施した後、同じ炉中で温度を変化させ540℃4hの熱間圧延前加熱を実施した。熱間圧延前加熱後540℃のスラブを加熱炉中から取り出し、粗熱間圧延を開始した。粗熱間圧延中の合金板の厚さが25mmとなった後、パス直前の合金板温度451℃から平均冷却速度80℃/分にて、粗熱間圧延の最終パスを実施し、粗熱間圧延上がり温度222℃厚さ12mmの合金板とした。なお、粗熱間圧延の最終パスでは、圧延しながら合金板を移動させ、圧延後の合金板の部位に対し順次上下から水を合金板に噴霧する水冷による強制冷却を実施した。
[Example 1]
The aluminum alloy slab having the chemical composition No. 1 in Table 1 was face-cut. Next, the alloy slab after face cutting was subjected to a homogenization treatment at 570 ° C. for 3 hours in a heating furnace, and then the temperature was changed in the same furnace to perform hot rolling preheating at 540 ° C. for 4 hours. Before hot rolling After heating, the slab at 540 ° C. was taken out from the heating furnace, and rough hot rolling was started. After the thickness of the alloy plate during rough hot rolling is 25 mm, the final pass of rough hot rolling is carried out from the alloy plate temperature of 451 ° C just before the pass to an average cooling rate of 80 ° C / min. An alloy plate having a rise temperature of 222 ° C. and a thickness of 12 mm was used. In the final pass of rough hot rolling, the alloy plate was moved while rolling, and forced cooling was performed by water cooling by sequentially spraying water on the alloy plate from above and below on the rolled alloy plate portion.

粗熱間圧延の後、合金板に仕上げ熱間圧延直前温度220℃から仕上げ熱間圧延を実施し、厚さ7.0mmの合金板を得た。仕上げ熱間圧延直後の合金板の温度は111℃であった。仕上げ熱間圧延後の合金板に170℃5hの熱処理を施した後、圧延率98%の冷間圧延を実施し、製品板厚0.15mmのアルミニウム合金板を得た。 After the rough hot rolling, the alloy plate was subjected to the finish hot rolling from the temperature immediately before the finish hot rolling at 220 ° C. to obtain an alloy plate having a thickness of 7.0 mm. The temperature of the alloy plate immediately after hot rolling was 111 ° C. After the alloy plate after the finish hot rolling was heat-treated at 170 ° C. for 5 hours, cold rolling with a rolling ratio of 98% was carried out to obtain an aluminum alloy plate having a product plate thickness of 0.15 mm.

Figure 0006833331
Figure 0006833331

[実施例2〜42、比較例1〜6]
表1に記載のアルミニウム合金スラブに面削を施した後、表2〜表6に記載の条件で、処理を施し、アルミニウム合金板を得た。なお、実施例1と同様に全ての実施例および比較例において均質化処理と熱間圧延前加熱は同じ炉で連続して実施し、粗熱間圧延最終パス後の強制冷却は、圧延しながら合金板を移動させ圧延後の合金板の部位に対し順次上下から水を合金板に噴霧する水冷または粗熱間圧延最終パス完了後に送風冷却する空冷のどちらかを選択した。また、一部の実施例では冷間圧延後に最終焼鈍を実施した。
[Examples 2-42, Comparative Examples 1-6]
The aluminum alloy slabs shown in Table 1 were surface-cut and then treated under the conditions shown in Tables 2 to 6 to obtain an aluminum alloy plate. As in Example 1, in all Examples and Comparative Examples, the homogenization treatment and the pre-hot rolling heating were continuously performed in the same furnace, and the forced cooling after the final pass of the rough hot rolling was performed while rolling. Either water cooling, in which the alloy plate was moved and water was sequentially sprayed onto the alloy plate from above and below on the portion of the rolled alloy plate, or air cooling, in which air cooling was performed after the final pass of rough hot rolling was completed, was selected. In some examples, final annealing was performed after cold rolling.

実施例15では、粗熱間圧延の最終パスを熱間圧延の最終パスとし、仕上げ熱間圧延を実施しなかった。 In Example 15, the final pass of the rough hot rolling was set as the final pass of the hot rolling, and the finishing hot rolling was not carried out.

比較例1および比較例2では、冷間圧延の途中に550℃1分の熱処理を施した後5℃/秒以上の速度での冷却を行う溶体化処理を実施した。比較例1および比較例2において、冷間圧延率は溶体化処理後の冷間圧延の合計圧延率であり、溶体化処理後の冷間圧延は、溶体化処理後の合金材の厚さからの冷間圧延率が30%となるように実施した。 In Comparative Example 1 and Comparative Example 2, a solution treatment was carried out in which heat treatment was performed at 550 ° C. for 1 minute during cold rolling and then cooling was performed at a speed of 5 ° C./sec or higher. In Comparative Example 1 and Comparative Example 2, the cold rolling ratio is the total rolling ratio of the cold rolling after the solution treatment, and the cold rolling after the solution treatment is based on the thickness of the alloy material after the solution treatment. The cold rolling ratio of the above was 30%.

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得られた合金板の引張強さ、0.2%耐力、導電率、加工性を以下の方法により評価した。 The tensile strength, 0.2% proof stress, conductivity, and workability of the obtained alloy plate were evaluated by the following methods.

引張強さおよび0.2%耐力は、JIS5号試験片について、常温で常法により測定した。 Tensile strength and 0.2% proof stress were measured by a conventional method at room temperature for JIS No. 5 test pieces.

導電率は、国際的に採択された焼鈍標準軟銅(体積低効率1.7241×10−2μΩm)の導電率を100%IACSとしたときの相対値(%IACS)として求めた。 The conductivity was determined as internationally adopted have been annealed standard soft copper (volume resistivity 1.7241 × 10 -2 μΩm) relative value when the conductivity was set to 100% IACS of (% IACS).

加工性は、曲げ角度を90°、合金板の厚さが0.4mm以上の場合はそれぞれの合金板の板厚を曲げ内側半径、合金板の厚さが0.4mm未満の場合は曲げ内側半径を0として、JIS Z 2248金属材料曲げ試験方法の6.3 Vブロック法による曲げ試験を実施し、割れが発生しなかったものを○、割れが発生したものを×として評価した。 For workability, the bending angle is 90 °, the thickness of each alloy plate is bent inside radius when the thickness of the alloy plate is 0.4 mm or more, and the bending inside when the thickness of the alloy plate is less than 0.4 mm. A bending test was carried out by the 6.3 V block method of the JIS Z 2248 metal material bending test method with the radius set to 0, and those without cracks were evaluated as ◯, and those with cracks were evaluated as ×.

引張強さ、0.2%耐力、導電率、および加工性の評価結果を表7および表8に示す。 The evaluation results of tensile strength, 0.2% proof stress, conductivity, and workability are shown in Tables 7 and 8.

Figure 0006833331
Figure 0006833331

Figure 0006833331
Figure 0006833331

本願規定の化学組成、引張強さ、および導電率を満足する実施例記載のAl−Mg−Si系合金材は加工性も良好である。一方、冷間圧延の途中に溶体化処理を実施した比較例1および比較例2は導電率が本願実施に劣り、化学組成が本願規定範囲を満足しない比較例3〜比較例6は引張強さもしくは導電率の少なくともどちらかが実施例に劣り、加工性に劣るものもある。
The Al—Mg—Si based alloy material described in Examples, which satisfies the chemical composition, tensile strength, and conductivity specified in the present application, has good workability. On the other hand, Comparative Example 1 and Comparative Example 2 in which the solution treatment was carried out during the cold rolling were inferior in the conductivity of the present application, and the chemical composition did not satisfy the specified range of the present application. Comparative Examples 3 to 6 had tensile strength. Alternatively, at least one of the conductivitys is inferior to that of the examples, and some are inferior in processability.

Claims (6)

化学組成が、Si:0.2〜0.8質量%、Mg:0.3〜1質量%、Fe:0.5質量%以下およびCu:0.5質量%以下を含有し、さらにTi:0.1質量%以下またはB:0.1質量%以下の少なくとも1種を含有し、残部Al及び不可避不純物からなるAl−Mg−Si系合金鋳塊に対し、熱間圧延終了後冷間圧延終了前に120℃以上200℃未満の熱処理を実施し、熱処理後の冷間圧延を60%以上の圧下率で実施することを特徴とする、引張強さが280MPa以上、導電率が54%IACS以上であり厚さ0.9mm未満のAl−Mg−Si系合金板の製造方法。 The chemical composition contains Si: 0.2 to 0.8% by mass, Mg: 0.3 to 1% by mass, Fe: 0.5% by mass or less, Cu: 0.5% by mass or less, and Ti: Cold rolling after completion of hot rolling on an Al—Mg—Si alloy ingot containing at least 0.1% by mass or B: 0.1% by mass or less and consisting of the balance Al and unavoidable impurities. The heat treatment is carried out at 120 ° C. or higher and lower than 200 ° C. before the end, and the cold rolling after the heat treatment is carried out at a rolling reduction of 60% or more. The tensile strength is 280 MPa or more and the conductivity is 54%. A method for producing an Al-Mg-Si based alloy plate having an IACS or more and a thickness of less than 0.9 mm. 前記Al−Mg−Si系合金鋳塊において、不可避不純物としてのMn、Cr、およびZnが、それぞれ0.1質量%以下に規制されている請求項1に記載のAl−Mg−Si系合金板の製造方法。 The Al-Mg-Si-based alloy plate according to claim 1, wherein in the Al-Mg-Si-based alloy ingot, Mn, Cr, and Zn as unavoidable impurities are each regulated to 0.1% by mass or less. Manufacturing method. 前記Al−Mg−Si系合金鋳塊において、不可避不純物としてのNi、V、Ga、Pb、Sn、Bi、およびZrが、それぞれ0.05質量%以下に規制されている請求項1または請求項2に記載のAl−Mg−Si系合金板の製造方法。 Claim 1 or claim that Ni, V, Ga, Pb, Sn, Bi, and Zr as unavoidable impurities are regulated to 0.05% by mass or less, respectively, in the Al—Mg—Si alloy ingot. 2. The method for producing an Al-Mg-Si based alloy plate according to 2. 前記Al−Mg−Si系合金鋳塊において、不可避不純物としてのAgが0.05質量%以下に規制されている請求項1ないし請求項3の何れか1項に記載のAl−Mg−Si系合金板の製造方法。 The Al-Mg-Si-based ingot according to any one of claims 1 to 3, wherein Ag as an unavoidable impurity is regulated to 0.05% by mass or less in the Al-Mg-Si-based alloy ingot. Manufacturing method of alloy plate. 前記Al−Mg−Si系合金鋳塊において、不可避不純物としての希土類元素の合計含有量が0.1質量%以下に規制されている請求項1ないし請求項4の何れか1項に記載のAl−Mg−Si系合金板の製造方法。 The Al according to any one of claims 1 to 4, wherein the total content of rare earth elements as unavoidable impurities in the Al—Mg—Si alloy ingot is regulated to 0.1% by mass or less. -Mg-Si based alloy plate manufacturing method. 前記Al−Mg−Si系合金板の引張強さTS(MPa)と0.2%耐力YS(MPa)の差(TS−YS)が0MPa以上30MPa以下である請求項1ないし請求項3の何れか1項に記載のAl−Mg−Si系合金板の製造方法。 Any of claims 1 to 3, wherein the difference (TS-YS) between the tensile strength TS (MPa) and the 0.2% proof stress YS (MPa) of the Al-Mg-Si alloy plate is 0 MPa or more and 30 MPa or less. The method for producing an Al-Mg-Si based alloy plate according to item 1.
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