JP6695725B2 - Al-Mg-Si alloy plate - Google Patents

Al-Mg-Si alloy plate Download PDF

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JP6695725B2
JP6695725B2 JP2016067348A JP2016067348A JP6695725B2 JP 6695725 B2 JP6695725 B2 JP 6695725B2 JP 2016067348 A JP2016067348 A JP 2016067348A JP 2016067348 A JP2016067348 A JP 2016067348A JP 6695725 B2 JP6695725 B2 JP 6695725B2
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眞二 籠重
眞二 籠重
和章 谷口
和章 谷口
西森 秀樹
秀樹 西森
智明 山ノ井
智明 山ノ井
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Showa Denko KK
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Description

この発明は、Al−Mg―Si系合金板、特に熱伝導性、導電性、強度および加工性に優れた厚さ0.9mm以上のAl−Mg―Si系合金板に関する。   The present invention relates to an Al-Mg-Si alloy plate, and more particularly to an Al-Mg-Si alloy plate having a thickness of 0.9 mm or more, which is excellent in thermal conductivity, conductivity, strength and workability.

薄型テレビ、パーソナルコンピューター用薄型モニター、ノートパソコン、タブレットパソコン、カーナビゲーションシステム、ポータブルナビゲーションシステム、スマートフォンや携帯電話等の携帯端末等の製品のシャーシ、メタルベースプリント基板、内部カバーのように発熱体を内蔵または装着する部材材料においては、速やかに放熱するための優れた熱伝導性、強度および加工性が求められる。   Heat generating elements such as flat panel TVs, flat panel monitors for personal computers, laptops, tablet computers, car navigation systems, portable navigation systems, chassis of products such as mobile terminals such as smartphones and mobile phones, metal base printed circuit boards, and internal covers. The material of the member to be built in or mounted is required to have excellent thermal conductivity, strength and workability for prompt heat dissipation.

JIS1100、1050、1070等の純アルミニウム合金は熱伝導性に優れるが、強度が低い。高強材として用いられるJIS5052に等のAl−Mg合金(5000系合金)は、純アルミニウム系合金よりも熱伝導性および導電性が著しく劣る。   Pure aluminum alloys such as JIS 1100, 1050, and 1070 have excellent thermal conductivity but low strength. An Al-Mg alloy (5000 series alloy) such as JIS 5052 used as a high strength material is significantly inferior in thermal conductivity and conductivity to a pure aluminum series alloy.

これに対しAl−Mg−Si系合金(6000系合金)は、熱伝導性および導電性が良く時効硬化により強度向上を図ることができるため、Al−Mg―Si系合金を用いて強度、熱伝導性、加工性に優れたアルミニウム合金板を得る方法が検討されている。   On the other hand, the Al-Mg-Si alloy (6000 alloy) has good thermal conductivity and conductivity and can be improved in strength by age hardening. A method for obtaining an aluminum alloy plate excellent in conductivity and workability has been studied.

例えば、特許文献1には、Mgを0.1〜0.34質量%、Siを0.2〜0.8質量%、Cuを0.22〜1.0質量%含有し、残部がAl及び不可避不純物からなり、Si/Mg含有量比が1.3以上であるAl−Mg―Si系合金を、半連続鋳造で厚さ250mm以上の鋳塊とし、400〜540℃の温度で予備加熱を経て熱間圧延、50〜85%の圧下率で冷間圧延を施した後、140〜280℃の温度で焼鈍をすることを特徴とする、Al−Mg−Si系合金圧延板の製造方法が開示されている。   For example, in patent document 1, 0.1-0.34 mass% of Mg, 0.2-0.8 mass% of Si, 0.22-1.0 mass% of Cu are contained, and the balance contains Al and An Al-Mg-Si based alloy, which consists of unavoidable impurities and has a Si / Mg content ratio of 1.3 or more, is semi-continuously cast into an ingot having a thickness of 250 mm or more, and preheated at a temperature of 400 to 540 ° C. After that, hot rolling, cold rolling at a reduction rate of 50 to 85%, and then annealing at a temperature of 140 to 280 ° C. are performed, and a method for producing an Al—Mg—Si alloy rolled sheet is provided. It is disclosed.

特許文献2には、Si:0.2〜1.5質量%、Mg:0.2〜1.5質量%、Fe:0.3質量%以下を含有し、さらに、Mn:0.02〜0.15質量%、Cr:0.02〜0.15%の1種または2種を含有するとともに、残部がAlおよび不可避不純物中のTiが0.2%以下に規制するか、もしくはこれにCu:0.01〜1質量%か希土類元素:0.01〜0.2質量%の1種または2種を含有する組成を有するアルミニウム合金版を連続鋳造圧延により作製し、その後冷間圧延し、次いで500〜570℃の溶体化処理を行い、続いてさらに冷間圧延率5〜40%で冷間圧延を行い、冷間圧延後150〜190℃未満に加熱する時効処理を行うことを特徴とする熱伝導性、強度および曲げ加工性に優れたアルミニウム板の製造方法が記載されている。   Patent Document 2 contains Si: 0.2 to 1.5% by mass, Mg: 0.2 to 1.5% by mass, Fe: 0.3% by mass or less, and Mn: 0.02 to 0.02% by mass. 0.15 mass%, Cr: 0.02 to 0.15% of 1 type or 2 types, and the balance regulates Al and Ti in unavoidable impurities to 0.2% or less, or Cu: 0.01 to 1 mass% or rare earth element: 0.01 to 0.2 mass% An aluminum alloy plate having a composition containing one or two is produced by continuous casting and rolling, and then cold rolling. Then, a solution treatment at 500 to 570 ° C. is performed, a cold rolling is further performed at a cold rolling ratio of 5 to 40%, and an aging treatment of heating to 150 to less than 190 ° C. is performed after the cold rolling. And a method for producing an aluminum plate having excellent heat conductivity, strength and bending workability.

特許文献3には、Si:0.2〜0.8質量%、Mg:0.3〜1質量%、Fe:0.5質量%以下、Cu:0.5質量%以下を含有し、さらにTi:0.1質量%以下またはB:0.1質量%以下の少なくとも1種を含有し、残部Alおよび不可避不純物からなるか、もしくはさらに不純物としてのMnおよびCrが、Mn:0.1質量%以下、Cr:0.1質量%以下に規制されているAl−Mg−Si系合金鋳塊を、熱間圧延し、さらに冷間圧延する工程を含む合金板の製造方法であって、熱間圧延後で冷間圧延終了までの間に、200〜400℃で1時間以上保持することにより熱処理を行うことを特徴とするAl−Mg―Si系合金板の製造方法が示されている。   Patent Document 3 contains Si: 0.2 to 0.8% by mass, Mg: 0.3 to 1% by mass, Fe: 0.5% by mass or less, and Cu: 0.5% by mass or less, and Ti: 0.1% by mass or less or B: 0.1% by mass or less, and the balance Al and unavoidable impurities, or Mn and Cr as impurities are Mn: 0.1% by mass. %, Cr: 0.1% by mass or less of an Al-Mg-Si alloy ingot, which is regulated to not more than 0.1% by mass, is a method for manufacturing an alloy sheet, which includes a step of hot rolling and further cold rolling. It shows a method for producing an Al-Mg-Si alloy plate, which is characterized by performing heat treatment by holding at 200 to 400 ° C for 1 hour or more between hot rolling and completion of cold rolling.

なお、特許文献3に記載のとおり、JIS1000系から7000系のアルミニウム合金においては、熱伝導率と導電率が良好な相関性を示し、優れた熱伝導性を有するアルミニウム合金板は優れた導電率を有し、放熱部材材料はもちろん導電部材材料として用いることができる。   As described in Patent Document 3, in the JIS 1000 to 7000 aluminum alloys, the thermal conductivity and the electrical conductivity show a good correlation, and an aluminum alloy plate having excellent thermal conductivity has an excellent electrical conductivity. And can be used as a conductive member material as well as a heat dissipation member material.

特開2012−62517号公報JP 2012-62517 A 特開2007−9262号公報JP, 2007-9262, A 特開2003−321755号公報JP, 2003-321755, A

上記のとおりAl−Mg―Si系合金板の改良がなされてきたが、アルミニウム合金部材材料を用いる製品の高性能化に伴い、高い導電率と加工性に加え従来よりも更に高い強度を有することがAl−Mg−Si系合金板に求められているのに対し、特許文献1記載のAl−Mg−Si系合金板は比較的導電率が高いものの引張強度が低く、上記特許文献1、特許文献2および特許文献3記載の方法では高い導電率と加工性を維持しつつ必要な強度を得ることが困難であった。   As described above, the Al-Mg-Si alloy plate has been improved, but with the higher performance of products using aluminum alloy member materials, in addition to high electrical conductivity and workability, it has higher strength than before. Is required for the Al-Mg-Si alloy plate, whereas the Al-Mg-Si alloy plate described in Patent Document 1 has relatively high conductivity but low tensile strength. With the methods described in Document 2 and Patent Document 3, it was difficult to obtain the required strength while maintaining high conductivity and workability.

先行技術文献において、比較的板厚が厚い実施例に着目すると、特許文献1では最終板厚1mmおよび1.5mmのAl−Mg−Si系合金圧延板の実施例が示されているが、発明例の引張強度220N/mm(MPa)は未満である。一方、引用文献2では、板厚1.0mm前後の実施例において引張試験強さが320MPaを超える実施があるが導電率は低く、時効時の温度を高くすると導電率は改善するものの引張試験強さが低下している。 In the prior art document, focusing on an example having a relatively large plate thickness, Patent Document 1 shows an example of an Al—Mg—Si alloy rolling plate having a final plate thickness of 1 mm and 1.5 mm. The tensile strength of the example is 220 N / mm 2 (MPa) is less than. On the other hand, in Cited Document 2, the tensile test strength exceeds 320 MPa in Examples with a plate thickness of around 1.0 mm, but the conductivity is low, and the conductivity improves when the temperature during aging is increased, but the tensile test strength is higher. Is decreasing.

本発明は、上述した技術背景に鑑み、高い導電率と良好な加工性を有しつつ更に高い強度を有する厚さ0.9mm以上のAl−Mg−Si系合金板を提供することを目的とする。   In view of the above technical background, the present invention has an object to provide an Al-Mg-Si alloy plate having a thickness of 0.9 mm or more, which has high electrical conductivity and good workability, and further has high strength. To do.

上記課題は、以下の手段によって解決される。
(1)化学組成が、Si:0.2〜0.8質量%、Mg:0.3〜1質量%、Fe:0.5質量%以下およびCu:0.5質量%以下を含有し、さらにTi:0.1質量%以下またはB:0.1質量%以下の少なくとも1種を含有し、残部Al及び不可避不純物からなり、引張強さが280MPa以上、導電率が54%IACS以上であり厚さが0.9mm以上のAl−Mg−Si系合金板。
(2)不純物としてのMn、Cr、およびZnが、それぞれ0.1質量%以下に規制されている前項1に記載のAl−Mg−Si系合金板。
(3)不純物としてのNi、V、Ga、Pb、Sn、BiおよびZrが、それぞれ0.05質量%以下に規制されている前項1または前項2に記載のAl−Mg−Si系合金板。
(4)不純物としてのAgが0.05質量%以下に規制されている前項1ないし前項3の何れか1項に記載のAl−Mg−Si系合金板。
(5)不純物としての希土類元素の合計含有量が0.1質量%以下に規制されている前項1ないし前項4の何れか1項に記載のAl−Mg−Si系合金板。
(6)0.2%耐力が230MPa以上である前項1ないし前項5の何れか1項に記載のAl−Mg−Si系合金板。
(7)引張強さが285MPa以上である前項1ないし前項6の何れか1項に記載のAl−Mg−Si系合金板。
The above problem can be solved by the following means.
(1) The chemical composition contains Si: 0.2 to 0.8% by mass, Mg: 0.3 to 1% by mass, Fe: 0.5% by mass or less and Cu: 0.5% by mass or less, Further, at least one of Ti: 0.1% by mass or less or B: 0.1% by mass or less is contained, the balance is Al and unavoidable impurities, the tensile strength is 280 MPa or more, and the conductivity is 54% IACS or more. An Al-Mg-Si alloy plate having a thickness of 0.9 mm or more.
(2) The Al-Mg-Si-based alloy plate according to the above item 1, wherein Mn, Cr, and Zn as impurities are regulated to 0.1% by mass or less, respectively.
(3) The Al-Mg-Si based alloy plate according to the above 1 or 2, wherein Ni, V, Ga, Pb, Sn, Bi and Zr as impurities are regulated to 0.05% by mass or less, respectively.
(4) The Al-Mg-Si alloy plate according to any one of the preceding items 1 to 3, in which Ag as an impurity is regulated to 0.05% by mass or less.
(5) The Al-Mg-Si alloy plate according to any one of the preceding items 1 to 4, wherein the total content of rare earth elements as impurities is regulated to 0.1% by mass or less.
(6) The Al-Mg-Si alloy plate according to any one of the preceding items 1 to 5, which has a 0.2% proof stress of 230 MPa or more.
(7) The Al—Mg—Si alloy plate according to any one of the items 1 to 6, which has a tensile strength of 285 MPa or more.

前項(1)に記載の発明によれば、化学組成が、Si:0.2〜0.8質量%、Mg:0.3〜1質量%、Fe:0.5質量%以下およびCu:0.5質量%以下を含有し、さらにTi:0.1質量%以下またはB:0.1質量%以下の少なくとも1種を含有し、残部Al及び不可避不純物からなり、強度、熱伝導性、加工性に優れた厚さ0.9mm以上のAl−Mg−Si系合金板となしうる。   According to the invention described in the above item (1), the chemical composition is Si: 0.2 to 0.8 mass%, Mg: 0.3 to 1 mass%, Fe: 0.5 mass% or less, and Cu: 0. 0.5% by mass or less, Ti: 0.1% by mass or less or B: 0.1% by mass or less, and the balance Al and unavoidable impurities, strength, thermal conductivity, and processing. An Al-Mg-Si alloy plate having a thickness of 0.9 mm or more, which has excellent properties, can be formed.

前項(2)に記載の発明によれば、不純物としてのMn、Cr、およびZnが、それぞれ0.1質量%以下に規制されているから、強度、熱伝導性、加工性に優れた厚さ0.9mm以上のAl−Mg−Si系合金板となしうる。   According to the invention described in the above item (2), Mn, Cr, and Zn as impurities are regulated to 0.1% by mass or less, respectively, so that the thickness is excellent in strength, thermal conductivity, and workability. It can be an Al-Mg-Si based alloy plate of 0.9 mm or more.

前項(3)に記載の発明によれば、不純物としてのNi、V、Ga、Pb、Sn、BiおよびZrが、それぞれ0.05質量%以下に規制されているから、強度、熱伝導性、加工性に優れたAl−Mg−Si系合金板となしうる。   According to the invention described in the above paragraph (3), since Ni, V, Ga, Pb, Sn, Bi and Zr as impurities are regulated to 0.05% by mass or less respectively, strength, thermal conductivity, It can be an Al-Mg-Si alloy plate having excellent workability.

前項(4)に記載の発明によれば、不純物としてのAgが0.05質量%以下に規制されているから、強度、熱伝導性、加工性に優れたAl−Mg−Si系合金板となしうる。   According to the invention described in the above item (4), since Ag as an impurity is regulated to 0.05% by mass or less, an Al-Mg-Si alloy plate excellent in strength, thermal conductivity and workability is obtained. You can do it.

前項(5)に記載の発明によれば、不純物としての希土類元素の合計含有量が0.1質量%以下に規制されているから、強度、熱伝導性、加工性にAl−Mg−Si系合金板となしうる。   According to the invention described in the above paragraph (5), the total content of rare earth elements as impurities is regulated to 0.1% by mass or less, so that the Al-Mg-Si-based alloy has high strength, thermal conductivity and workability. It can be an alloy plate.

前項(6)に記載の発明によれば、耐力が強いAl−Mg−Si系合金板となしうる。   According to the invention described in the above item (6), an Al-Mg-Si alloy plate having a high yield strength can be obtained.

前項(7)に記載の発明によれば、さらに耐力が強いAl−Mg−Si系合金板となしうる。   According to the invention described in the above item (7), an Al-Mg-Si alloy plate having a higher yield strength can be obtained.

本願発明者は、熱間圧延、冷間圧延を順次施するAl−Mg−Si系合金板の製造方法において、熱間圧延上がりの合金板の表面温度を所定の温度以下とするとともに、熱間圧延終了後であって冷間圧延終了前に時効処理としての熱処理を施すことにより、高い導電率と良好な加工性を有しつつ更に高い強度を有するAl−Mg−Si系合金板が得られることを見出し本願の発明に至った。   In the method for producing an Al-Mg-Si alloy sheet in which hot rolling and cold rolling are sequentially performed, the inventor of the present application sets the surface temperature of the alloy sheet just after hot rolling to a predetermined temperature or less and hot rolling. By performing a heat treatment as an aging treatment after the completion of rolling and before the completion of cold rolling, an Al-Mg-Si alloy plate having high electrical conductivity and good workability as well as higher strength can be obtained. This has led to the invention of the present application.

以下に、本願のAl−Mg−Si系合金板について詳細に説明する。   Hereinafter, the Al-Mg-Si alloy plate of the present application will be described in detail.

本願のAl−Mg−Si系合金組成において、各元素の添加目的および含有量の限定理由は下記のとおりである。   In the Al—Mg—Si alloy composition of the present application, the purpose of adding each element and the reasons for limiting the content are as follows.

MgおよびSiは強度の発現に必要な元素であり、それぞれの含有量はSi:0.2質量%以上0.8質量%以下、Mg:0.3質量%以上1質量%以下とする。Si含有量が0.2質量%未満あるいはMg含有量が0.3質量%未満では十分な強度を得ることができない。一方、Si含有量が0.8質量%、Mg含有量が1質量%を超えると、熱間圧延での圧延負荷が高くなって生産性が低下し、得られるアルミニウム合金板の成形加工性も悪くなる。Si含有量は0.2質量%以上0.6質量%以下が好ましく、更に0.32質量%以上0.60質量%以下が好ましい。Mg含有量は0.45質量%以上0.9質量%以下が好ましく、更に0.45質量%以上0.55質量%以下が好ましい。   Mg and Si are elements necessary for developing strength, and the respective contents are Si: 0.2 mass% or more and 0.8 mass% or less, and Mg: 0.3 mass% or more and 1 mass% or less. If the Si content is less than 0.2 mass% or the Mg content is less than 0.3 mass%, sufficient strength cannot be obtained. On the other hand, when the Si content exceeds 0.8 mass% and the Mg content exceeds 1 mass%, the rolling load in the hot rolling increases, the productivity decreases, and the formability of the obtained aluminum alloy sheet also increases. become worse. The Si content is preferably 0.2% by mass or more and 0.6% by mass or less, and more preferably 0.32% by mass or more and 0.60% by mass or less. The Mg content is preferably 0.45 mass% or more and 0.9 mass% or less, and more preferably 0.45 mass% or more and 0.55 mass% or less.

FeおよびCuは成形加工上必要な成分であるが、多量に含有すると耐食性が低下する。本願においてFe含有量およびCu含有量はそれぞれ0.5質量%以下に規制する。Fe含有量は0.35質量%以下に規制することが好ましく、更に0.1質量%以上0.25質量%以下であることが好ましい。Cu含有量は0.1質量%以下であることが好ましい。   Fe and Cu are components necessary for molding, but if they are contained in a large amount, the corrosion resistance decreases. In the present application, the Fe content and the Cu content are regulated to 0.5 mass% or less. The Fe content is preferably regulated to 0.35% by mass or less, and more preferably 0.1% by mass or more and 0.25% by mass or less. The Cu content is preferably 0.1% by mass or less.

TiおよびBは、合金をスラブに鋳造する際に結晶粒を微細化するとともに凝固割れを防止する効果がある。前記効果はTiまたはBの少なくとも1種の添加により得られ、両方を添加してもよい。しかしながら、多量に含有すると、晶出物がサイズの大きい晶出物が多く生成するため、製品の加工性や熱伝導性および導電率が低下する。Ti含有量は0.1質量以下が好ましく、更に0.005質量%以上0.05質量%以下が好ましい。   Ti and B have the effect of refining the crystal grains and preventing solidification cracking when the alloy is cast into a slab. The above effect is obtained by adding at least one of Ti and B, and both may be added. However, when contained in a large amount, many crystallized substances having large size are generated, and thus the workability, thermal conductivity and electrical conductivity of the product are lowered. The Ti content is preferably 0.1 mass% or less, more preferably 0.005 mass% or more and 0.05 mass% or less.

また、B含有量は0.1質量%以下が好ましく、特に0.06質量%以下が好ましい。   Further, the B content is preferably 0.1% by mass or less, and particularly preferably 0.06% by mass or less.

また、合金元素には種々の不純物元素が不可避的に含有されるが、MnおよびCrは伝導性および導電性を低下させ、Znは含有量が多くなると合金材の耐食性を低下させるため少ないことが好ましい。不純物としてのMn、Cr、およびZnのそれぞれの含有量は0.1質量%以下が好ましく、更に0.05質量%以下が好ましい。   Further, although various impurity elements are unavoidably contained in the alloy element, Mn and Cr decrease conductivity and conductivity, and Zn is less contained as the content increases, because the corrosion resistance of the alloy material decreases. preferable. The content of each of Mn, Cr, and Zn as impurities is preferably 0.1% by mass or less, and more preferably 0.05% by mass or less.

上記以外のその他の不純物元素としては、Ni、V、Ga、Pb、Sn、Bi、Zr、Ag、希土類等が挙げられるが、これらに限定されるものではなく、これらその他の不純物元素のうち希土類以外は個々の元素の含有量として0.05質量%以下であることが好ましい。上記その他の不純物元素のうち希土類は、1種または複数種の元素が含まれていてもよく、ミッシュメタルの状態で含まれている鋳造用原料に由来するものでも良いが、希土類元素の合計含有量は0.1質量%以下であることが好ましく、更に0.05質量%以下であることが好ましい。   Other impurity elements other than the above include Ni, V, Ga, Pb, Sn, Bi, Zr, Ag, and rare earth elements, but are not limited to these, and rare earth elements among these other impurity elements are included. Other than the above, the content of each element is preferably 0.05% by mass or less. Among the above-mentioned other impurity elements, the rare earth element may contain one or more kinds of elements, and may be derived from the casting raw material contained in the state of misch metal, but the total content of rare earth elements The amount is preferably 0.1% by mass or less, more preferably 0.05% by mass or less.

次に、本願規定のAl−Mg―Si系合金材を得るための処理工程について記述する。   Next, the processing steps for obtaining the Al-Mg-Si based alloy material specified in the present application will be described.

常法にて溶解成分調整し、Al−Mg―Si系合金鋳塊を得る。得られた合金鋳塊に熱 間圧延前加熱より前の工程として均質化処理を施すことが好ましい。   The melting components are adjusted by a conventional method to obtain an Al-Mg-Si alloy ingot. It is preferable to subject the obtained alloy ingot to homogenization treatment as a step prior to heating before hot rolling.

前記均質化処理は、500℃以上で行うことが好ましい。   The homogenization treatment is preferably performed at 500 ° C. or higher.

前記熱間圧延前加熱はAl−Mg―Si系合金鋳塊中に晶出物およびMg、Siを固溶させ均一な組織とするために実施するが、温度が高すぎると鋳塊中で部分的な融解が起こる可能性があるため、450℃以上580℃以下で行うことが好ましく、特に500℃以上580℃以下で行うことが好ましい。   The pre-hot-rolling heating is carried out in order to form a uniform structure by solid solution of crystallized substances and Mg and Si in the Al-Mg-Si alloy ingot, but if the temperature is too high, it will partially occur in the ingot. It is preferable that the heating is performed at 450 ° C. or higher and 580 ° C. or lower, and particularly 500 ° C. or higher and 580 ° C. or lower, because the melting may occur.

Al−Mg―Si系合金鋳塊に均質化処理を行った後冷却し、熱間圧延前加熱を行っても良いし、均質化処理と熱間圧延前加熱を連続して行っても良く、前記均質化処理および熱間圧延前加熱の好ましい温度範囲にて均質化処理と熱間圧延前加熱を兼ねて同じ温度で加熱しても良い。   The Al-Mg-Si alloy ingot may be homogenized and then cooled, and may be heated before hot rolling, or may be continuously homogenized and heated before hot rolling. The homogenization treatment and the pre-hot rolling heating may be performed at the same temperature in a preferable temperature range of the homogenization treatment and the hot rolling pre-heating.

鋳造後熱間圧延前加熱前に鋳塊の表面近傍の不純物層を除去する為に鋳塊に面削を施すことが好ましい。面削は鋳造後均質化処理前であっても良いし、均質化処理後熱間圧延前加熱前であってもよい。   After casting, before hot rolling and before heating, it is preferable to chamfer the ingot to remove an impurity layer near the surface of the ingot. The chamfering may be performed after casting and before homogenization treatment, or after homogenization treatment and before heating before hot rolling.

熱間圧延前加熱後のAl−Mg―Si系合金鋳塊に熱間圧延を施す。   Hot rolling is performed on the Al-Mg-Si alloy ingot after heating before hot rolling.

熱間圧延は粗熱間圧延と仕上げ熱間圧延からなり、粗熱間圧延機を用い複数のパスからなる粗熱間圧延を行った後、粗熱間圧延機とは異なる仕上げ熱間圧延機を用いて仕上げ熱間圧延を行う。なお、本願において、粗熱間圧延機での最終パスを熱間圧延の最終パスとする場合は、仕上げ熱間圧延を省略することができる。   Hot rolling consists of rough hot rolling and finish hot rolling.After performing rough hot rolling consisting of multiple passes using a rough hot rolling mill, a finish hot rolling mill different from the rough hot rolling mill is used. Is used for finish hot rolling. In the present application, when the final pass of the rough hot rolling mill is the final pass of hot rolling, finishing hot rolling can be omitted.

本願において、仕上げ熱間圧延は、上下一組のワークロールもしくは二組以上のワークロールが連続して設置された圧延機を用いて1方向からAl−Mg―Si系合金板を導入し1回のパスで実施される。   In the present application, the finish hot rolling is performed once by introducing an Al—Mg—Si alloy plate from one direction using a rolling machine in which one set of upper and lower work rolls or two or more sets of work rolls are continuously installed. Will take place on the path.

冷間圧延をコイルで実施する場合には、仕上げ熱間圧延後のAl−Mg―Si系合金板を巻き取り装置で巻き取って熱延コイルとすればよい。仕上げ熱間圧延を省略し、粗熱間圧延の最終パスを熱間圧延の最終パスとする場合は、粗熱間圧延の後、Al−Mg―Si系合金板を巻き取り装置にて巻き取って熱延コイルとしてもよい。   When cold rolling is performed with a coil, the Al—Mg—Si alloy plate after the finish hot rolling may be wound with a winding device to form a hot rolled coil. When omitting the finish hot rolling and making the final pass of the rough hot rolling the final pass of the hot rolling, after the rough hot rolling, the Al-Mg-Si alloy plate is wound by the winding device. It may be a hot rolled coil.

粗熱間圧延では、溶体化処理に準じてMgおよびSiが固溶された状態を保持した後、粗熱間圧延のパスによるAl−Mg―Si系合金板の冷却、もしくは粗熱間圧延のパス後とパス後の強制冷却による温度降下により焼き入れの効果を得ことができる。   In the rough hot rolling, after keeping the state in which Mg and Si are solid-solved in accordance with the solution heat treatment, cooling of the Al-Mg-Si alloy plate by the path of the rough hot rolling or the rough hot rolling is performed. The effect of quenching can be obtained by the temperature drop due to the forced cooling after the pass and after the pass.

本願において粗熱間圧延の複数のパスのうち、パス直前のAl−Mg―Si系合金板の表面温度が350℃以上470℃以下でありパスによるAl−Mg―Si系合金板の冷却、もしくはパスとパス後の強制冷却による平均冷却速度が50℃/分以上であるパスを制御パスと呼ぶ。制御パス直前のAl−Mg―Si系合金板の表面温度を350℃以上470℃以下としたのは、350℃未満では粗熱間圧延における急冷による焼き入れの効果が小さく、470℃より高い温度ではパス上がりのAl−Mg―Si系合金板の急冷が困難であるからである。   In the present application, among a plurality of passes of rough hot rolling, the surface temperature of the Al—Mg—Si alloy plate immediately before the pass is 350 ° C. or higher and 470 ° C. or lower, and the Al—Mg—Si alloy plate is cooled by the pass, or A pass having an average cooling rate of 50 ° C./minute or more by passing and forced cooling after passing is called a control pass. The surface temperature of the Al-Mg-Si alloy plate immediately before the control pass is set to 350 ° C or more and 470 ° C or less because the effect of quenching by quenching in the rough hot rolling is small below 350 ° C and the temperature is higher than 470 ° C. This is because it is difficult to rapidly cool the Al-Mg-Si alloy plate after passing.

上記平均冷却速度は制御パスにおいて強制冷却を行わない場合は制御パスの開始から終了まで、制御パス後に強制冷却を行う場合は制御パスの開始から強制冷却の終了までのAl−Mg―Si系合金板の温度降下(℃)を要した時間(分)で除した値とする。   The above average cooling rate is an Al-Mg-Si alloy from the start to the end of the control path when the forced cooling is not performed in the control path, and from the start of the control path to the end of the forced cooling when the forced cooling is performed after the control path. The value is obtained by dividing the temperature drop (° C) of the plate by the time (minutes) required.

制御パス後の強制冷却は、Al−Mg―Si系合金板を圧延しながら圧延後の部位に対し順次実施してもよいし、Al−Mg―Si系合金板全体を圧延した後実施してもよい。強制冷却の方法は限定されないが、水冷であっても空冷であってもよいし、クーラントを利用してもよい。   The forced cooling after the control pass may be sequentially performed on the rolled portion while rolling the Al-Mg-Si alloy sheet, or may be performed after rolling the entire Al-Mg-Si alloy sheet. Good. The method of forced cooling is not limited, but water cooling or air cooling may be used, or a coolant may be used.

前記制御パスは少なくとも1回実施することが好ましく、複数回実施しても良い。制御パスを複数回実施する場合、各々の制御パスについてパス後に強制冷却を行うか否かを選択できる。パス直前Al−Mg―Si系合金板の表面温度が470〜350℃であって冷却速度が50℃/分以上であれば制御パスは複数回実施することができるが、1回の制御パスでAl−Mg―Si系合金板の温度を350℃未満に降下させることにより効率よく効果的に焼き入れを行うことができる。   The control pass is preferably performed at least once, and may be performed multiple times. When the control pass is performed a plurality of times, whether or not the forced cooling is performed after the pass can be selected for each control pass. Immediately before the pass, if the surface temperature of the Al-Mg-Si alloy plate is 470 to 350 ° C and the cooling rate is 50 ° C / min or more, the control pass can be performed plural times, but one control pass is required. By lowering the temperature of the Al-Mg-Si alloy plate to below 350 ° C, quenching can be performed efficiently and effectively.

本願において、粗熱間圧延の最終パス後に強制冷却を行わない場合は、熱間圧延の最終パス直後のAl−Mg―Si系合金板の表面温度を粗熱間圧延上がり温度とし、粗熱間圧延の最終パス後に強制冷却を行う場合は、強制冷却終了直後のAl−Mg―Si系合金板の表面温度を粗熱間圧延上がり温度とする。   In the present application, when forced cooling is not performed after the final pass of the rough hot rolling, the surface temperature of the Al-Mg-Si alloy sheet immediately after the final pass of the hot rolling is set as the rough hot rolling rising temperature, and When forced cooling is performed after the final pass of rolling, the surface temperature of the Al—Mg—Si alloy plate immediately after the termination of forced cooling is taken as the rough hot rolling finish temperature.

本願において仕上げ熱間圧延を実施する場合は仕上げ熱間圧延の終了、仕上げ熱間圧延を実施しない場合は粗熱間圧延の最終パスの終了をもって熱間圧延の終了とし、熱間圧延終了直後のAl−Mg―Si系合金板の表面温度は170℃以下とすることが好ましい。熱間圧延終了直後の合金板の温度を170℃以下とすることにより有効な焼き入れ効果が得られ、その後の熱処理時により時効硬化するとともに導電率が向上する。   When finishing hot rolling is carried out in the present application, finishing hot rolling is finished, and when finishing hot rolling is not carried out, hot rolling is finished at the end of the final pass of rough hot rolling, and immediately after finishing hot rolling. The surface temperature of the Al-Mg-Si alloy plate is preferably 170 ° C or lower. By setting the temperature of the alloy sheet immediately after hot rolling to 170 ° C. or lower, an effective quenching effect can be obtained, and age hardening occurs and electrical conductivity is improved by the subsequent heat treatment.

熱間圧延終了直後のAl−Mg―Si系合金板の表面温度が高すぎると、焼き入れの効果が不足し、熱間圧延終了後冷間圧延終了前に熱処理を実施しても強度の向上が不十分となる。熱間圧延終了直後のアルミニウム板の表面温度は150℃以下が更に好ましく、特に130℃以下が好ましい。   If the surface temperature of the Al-Mg-Si alloy plate immediately after the hot rolling is too high, the effect of quenching will be insufficient, and the strength will be improved even if heat treatment is performed after the hot rolling and before the cold rolling. Is insufficient. The surface temperature of the aluminum plate immediately after hot rolling is more preferably 150 ° C or lower, and particularly preferably 130 ° C or lower.

なお、粗熱間圧延の後仕上げ熱間圧延を行う場合は、仕上げ熱間圧延のパスによる焼き入れ効果を得るために、仕上げ熱間圧延直前のAl−Mg―Si系合金板の表面温度は280℃以下であることが好ましい。   When performing finish hot rolling after rough hot rolling, the surface temperature of the Al-Mg-Si alloy plate immediately before finish hot rolling is set to obtain the quenching effect by the pass of finish hot rolling. It is preferably 280 ° C or lower.

また、仕上げ熱間圧延を行わず粗熱間圧延の最終パスが制御パスではない場合も同様に、粗熱間圧延最終パス直前のAl−Mg―Si系合金板の表面温度は280℃以下が好ましい。   Similarly, when finishing hot rolling is not performed and the final pass of rough hot rolling is not the control pass, the surface temperature of the Al—Mg—Si alloy plate immediately before the final pass of rough hot rolling is 280 ° C. or lower. preferable.

一方、仕上げ熱間圧延を行わず粗熱間圧延の最終パスが制御パスである場合、制御パスが熱間圧延の最終パスとなるので、熱間圧延の最終パス直前のAl−Mg―Si系合金板の表面温度が470〜350℃であって圧延もしくは圧延と圧延後の強制冷却により冷却速度が50℃/分以上の冷却速度で合金板の表面温度が170℃以下となるように制御パスを実施する。   On the other hand, when the final pass of rough hot rolling is the control pass without performing finish hot rolling, the control pass is the final pass of hot rolling. Therefore, the Al--Mg--Si system immediately before the final pass of hot rolling is used. The surface temperature of the alloy plate is 470 to 350 ° C, and a control path is set so that the surface temperature of the alloy plate becomes 170 ° C or less at a cooling rate of 50 ° C / min or more by rolling or rolling and forced cooling after rolling. Carry out.

熱間圧延終了後冷間圧延終了前のAl−Mg―Si系合金板に熱処理を施し、時効硬化させるとともに導電率を向上させる。   After finishing the hot rolling and before finishing the cold rolling, the Al—Mg—Si alloy plate is heat-treated to age-harden and improve the conductivity.

本願において熱間圧延終了後冷間圧延終了前のAl−Mg―Si系合金板への熱処理は時効硬化および導電率向上の効果を得るために120℃以上200℃未満の温度で実施する。前記熱処理の温度は130℃以上190℃以下が好ましく、更に140℃以上180℃以下が好ましい。   In the present application, the heat treatment of the Al—Mg—Si alloy plate after the completion of hot rolling and before the completion of cold rolling is performed at a temperature of 120 ° C. or higher and lower than 200 ° C. in order to obtain the effects of age hardening and conductivity improvement. The temperature of the heat treatment is preferably 130 ° C or higher and 190 ° C or lower, more preferably 140 ° C or higher and 180 ° C or lower.

前記熱間圧延終了後冷間圧延終了前において120℃以上200℃未満の温度で実施するAl−Mg―Si系合金板の熱処理の時間は特に限定されないが、時効硬化および導電率向上の効果が得られるように所定の温度で時間を調節すればよく、例えば、1〜12時間の範囲で時間を調節して熱処理を実施すればよい。   The time for heat treatment of the Al-Mg-Si alloy plate to be carried out at a temperature of 120 ° C or higher and lower than 200 ° C after the end of hot rolling and before the end of cold rolling is not particularly limited, but the effects of age hardening and conductivity improvement can be obtained. The time may be adjusted at a predetermined temperature so as to obtain the heat treatment, and for example, the heat treatment may be performed by adjusting the time in the range of 1 to 12 hours.

前記熱処理の後、冷間圧延を実施することにより加工硬化し強度が更に向上する。   After the heat treatment, cold rolling is performed to work-harden and further improve the strength.

前記熱処理は時効硬化させたAl−Mg―Si系合金板の冷間圧延による強度向上効果を高めるため、熱間圧延終了後冷間圧延開始前に実施することが好ましい。   The heat treatment is preferably performed after the end of hot rolling and before the start of cold rolling in order to enhance the strength improving effect of the age-hardened Al-Mg-Si alloy plate by cold rolling.

前記熱処理後の冷間圧延により所定の厚さのAl−Mg―Si系合金板とする。熱処理後の冷間圧延は強度向上と加工性の改善の為50%以上の圧延率で実施されることが好ましい。熱処理後の冷間圧延によるAl−Mg―Si系合金板の圧延率は更に60%以上が好ましく、特に70%以上が好ましい。   After the heat treatment, cold rolling is performed to obtain an Al-Mg-Si alloy plate having a predetermined thickness. Cold rolling after heat treatment is preferably carried out at a rolling rate of 50% or more in order to improve strength and workability. The rolling rate of the Al-Mg-Si alloy plate by cold rolling after the heat treatment is more preferably 60% or more, and particularly preferably 70% or more.

冷間圧延後のAl−Mg―Si系合金板に必要に応じて洗浄を実施しても良い。   The Al—Mg—Si alloy plate after cold rolling may be washed as necessary.

Al−Mg―Si系合金板の加工性を更に重視する場合は冷間圧延後に最終焼鈍を実施しても良い。最終焼鈍はAl−Mg―Si系合金板の強度が低くなりすぎないようにする為に180℃以下で実施することが好ましく、更に160℃以下、特に140℃以下で実施することが好ましい。   When the workability of the Al-Mg-Si alloy plate is further emphasized, final annealing may be performed after cold rolling. The final annealing is preferably performed at 180 ° C. or lower, more preferably 160 ° C. or lower, and particularly preferably 140 ° C. or lower to prevent the strength of the Al—Mg—Si alloy plate from becoming too low.

前記180℃以下の温度で実施するAl−Mg―Si系合金板の最終焼鈍の時間は必要な加工性および強度が得られるよう調節すればよく、例えば、1〜10時間の範囲で最終焼鈍の温度により選択すれば良い。   The time for the final annealing of the Al-Mg-Si alloy plate performed at a temperature of 180 ° C or lower may be adjusted so that the required workability and strength can be obtained. For example, the final annealing is performed in the range of 1 to 10 hours. It may be selected according to the temperature.

なお、本願のAl−Mg―Si系合金板の製造はコイルで行ってもよく、単板で行ってもよい。また、冷間圧延より後の任意の工程で合金板を切断し切断後の工程を単板で行ってもよいし、用途に応じスリットし条にしても良い。   The Al—Mg—Si alloy plate of the present invention may be manufactured using a coil or a single plate. Further, the alloy sheet may be cut in any step after the cold rolling and the step after cutting may be performed as a single sheet, or slits may be formed depending on the application.

上記の製造方法によれば、高い導電率を得つつ、強度を向上させることができ、高強度であるにも関わらず加工性も優れた厚さ0.9mm以上のAl−Mg―Si系合金板が得られる。   According to the above-mentioned manufacturing method, it is possible to improve the strength while obtaining high conductivity, and the Al-Mg-Si alloy having a thickness of 0.9 mm or more, which has high strength and excellent workability. A board is obtained.

本願のAl−Mg―Si系合金板の導電率は54%IACS以上、引張強さは280MPa以上と規定する。引張強さは285MPa以上が好ましく、290MPa以上が更に好ましい。本願のAl−Mg―Si系合金板の0.2%耐力は、230MPa以上が好ましく、更に240MPa以上が好ましく、特に250MPa以上が好ましい。   The Al—Mg—Si alloy plate of the present application has a conductivity of 54% IACS or more and a tensile strength of 280 MPa or more. The tensile strength is preferably 285 MPa or more, more preferably 290 MPa or more. The 0.2% proof stress of the Al-Mg-Si alloy plate of the present application is preferably 230 MPa or more, more preferably 240 MPa or more, and particularly preferably 250 MPa or more.

以下に本発明の実施例および比較例を示す。   Examples and comparative examples of the present invention will be shown below.

表1に示す化学組成の異なるアルミニウム合金スラブをDC鋳造法により得た。   Aluminum alloy slabs having different chemical compositions shown in Table 1 were obtained by the DC casting method.

[実施例1]
表1の化学組成番号1のアルミニウム合金スラブに面削を施した。次に、面削後の合金スラブに対し加熱炉中で570℃3hの均質化処理を実施した後、同じ炉中で温度を変化させ540℃4hの熱間圧延前加熱を実施した。熱間圧延前加熱後540℃のスラブを加熱炉中から取り出し、粗熱間圧延を開始した。粗熱間圧延中の合金板の厚さが25mmとなった後、パス直前の合金板温度451℃から平均冷却速度80℃/分にて、粗熱間圧延の最終パスを実施し、粗熱間圧延上がり温度222℃厚さ12mmの合金板とした。なお、粗熱間圧延の最終パスでは、圧延しながら合金板を移動させ、圧延後の合金板の部位に対し順次上下から水を合金板に噴霧する水冷による強制冷却を実施した。
[Example 1]
The aluminum alloy slab having the chemical composition number 1 in Table 1 was chamfered. Next, the alloy slab after the chamfering was subjected to homogenizing treatment at 570 ° C. for 3 hours in a heating furnace, and then temperature was changed in the same furnace to perform heating before hot rolling at 540 ° C. for 4 hours. After heating before hot rolling, the slab at 540 ° C. was taken out of the heating furnace, and rough hot rolling was started. After the thickness of the alloy plate during the rough hot rolling reaches 25 mm, the final pass of the rough hot rolling is performed at an average cooling rate of 80 ° C./min from the alloy plate temperature of 451 ° C. immediately before the pass to perform the rough heat rolling. An alloy plate having a hot rolling finish temperature of 222 ° C. and a thickness of 12 mm was prepared. In the final pass of the rough hot rolling, the alloy plate was moved while rolling, and forced cooling was performed by water cooling, in which water was sprayed onto the alloy plate sequentially from the top and bottom of the rolled alloy plate.

粗熱間圧延の後、合金板に仕上げ熱間圧延直前温度220℃から仕上げ熱間圧延を実施し、厚さ7.0mmの合金板を得た。仕上げ熱間圧延直後の合金板の温度は111℃であった。仕上げ熱間圧延後の合金板に170℃5hの熱処理を施した後、圧延率87%の冷間圧延を実施し、製品板厚0.9mmのアルミニウム合金板を得た。   After the rough hot rolling, the alloy sheet was subjected to finish hot rolling from a temperature of 220 ° C. immediately before finish hot rolling to obtain an alloy sheet having a thickness of 7.0 mm. The temperature of the alloy sheet immediately after the finish hot rolling was 111 ° C. The alloy sheet after the finish hot rolling was heat-treated at 170 ° C. for 5 hours, and then cold rolled at a rolling rate of 87% to obtain an aluminum alloy sheet having a product sheet thickness of 0.9 mm.

Figure 0006695725
Figure 0006695725

[実施例2〜38、比較例1〜6]
表1に記載のアルミニウム合金スラブに面削を施した後、表2〜表6に記載の条件で、処理を施し、アルミニウム合金板を得た。なお、実施例1と同様に全ての実施例および比較例において均質化処理と熱間圧延前加熱は同じ炉で連続して実施し、粗熱間圧延最終パス後の強制冷却は、圧延しながら合金板を移動させ圧延後の合金板の部位に対し順次上下から水を合金板に噴霧する水冷または粗熱間圧延最終パス完了後に送風冷却する空冷のどちらかを選択した。また、一部の実施例では冷間圧延後に最終焼鈍を実施した。
[Examples 2-38, Comparative Examples 1-6]
The aluminum alloy slabs shown in Table 1 were chamfered, and then treated under the conditions shown in Tables 2 to 6 to obtain aluminum alloy plates. As in Example 1, homogenization treatment and heating before hot rolling were continuously performed in the same furnace in all Examples and Comparative Examples, and forced cooling after the final pass of rough hot rolling was performed while rolling. Either water cooling in which the alloy plate was moved and sprayed with water from the top and bottom of the alloy plate after rolling was sequentially selected, or air cooling in which air cooling was performed after completion of the final pass of the rough hot rolling was selected. Further, in some examples, final annealing was performed after cold rolling.

実施例13では、粗熱間圧延の最終パスを熱間圧延の最終パスとし、仕上げ熱間圧延を実施しなかった。   In Example 13, the final pass of rough hot rolling was set as the final pass of hot rolling, and finish hot rolling was not performed.

比較例1および比較例2では、冷間圧延の途中に550℃1分の熱処理を施した後5℃/秒以上の速度での冷却を行う溶体化処理を実施した。比較例1および比較例2において、冷間圧延率は溶体化処理後の冷間圧延の合計圧延率であり、溶体化処理後の冷間圧延は、溶体化処理後の合金材の厚さからの冷間圧延率が30%となるように実施した。   In Comparative Example 1 and Comparative Example 2, the solution treatment was performed by performing heat treatment at 550 ° C. for 1 minute during the cold rolling and then cooling at a rate of 5 ° C./sec or more. In Comparative Example 1 and Comparative Example 2, the cold rolling rate is the total rolling rate of the cold rolling after the solution treatment, and the cold rolling after the solution treatment is based on the thickness of the alloy material after the solution treatment. Was carried out so that the cold rolling rate was 30%.

Figure 0006695725
Figure 0006695725

Figure 0006695725
Figure 0006695725

Figure 0006695725
Figure 0006695725

Figure 0006695725
Figure 0006695725

Figure 0006695725
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得られた合金板の引張強さ、0.2%耐力、導電率、加工性を以下の方法により評価した。   The tensile strength, 0.2% proof stress, conductivity and workability of the obtained alloy plate were evaluated by the following methods.

引張強さおよび0.2%耐力は、JIS5号試験片について、常温で常法により測定した。   The tensile strength and the 0.2% proof stress of JIS No. 5 test piece were measured at room temperature by a conventional method.

導電率は、国際的に採択された焼鈍標準軟銅(体積低効率1.7241×10−2μΩm)の導電率を100%IACSとしたときの相対値(%IACS)として求めた。 The electrical conductivity was determined as a relative value (% IACS) when the electrical conductivity of internationally adopted annealing standard annealed copper (volume low efficiency 1.7241 × 10 −2 μΩm) was 100% IACS.

加工性は、曲げ角度を90°、それぞれの合金板の板厚を曲げ内側半径として、JIS Z 2248金属材料曲げ試験方法の6.3 Vブロック法による曲げ試験を実施し、割れが発生しなかったものを○、割れが発生したものを×として評価した。   As for workability, a bending angle was 90 °, a bending inner radius was the thickness of each alloy plate, and a bending test was performed by the 6.3 V block method of JIS Z 2248 metal material bending test method. The sample was evaluated as ◯ and the sample with cracks was evaluated as x.

引張強さ、0.2%耐力、導電率、および加工性の評価結果を表7および表8に示す。   The evaluation results of tensile strength, 0.2% proof stress, conductivity, and workability are shown in Tables 7 and 8.

Figure 0006695725
Figure 0006695725

Figure 0006695725
Figure 0006695725

本願規定の化学組成、引張強さ、および導電率を満足する実施例記載のAl−Mg−Si系合金材は加工性も良好である。一方、冷間圧延の途中に溶体化処理を実施した比較例1および比較例2は導電率が本願実施に劣り、化学組成が本願規定範囲を満足しない比較例3〜比較例6は引張強さもしくは導電率の少なくともどちらかが実施例に劣り、加工性に劣るものもある。
The Al—Mg—Si based alloy materials described in the examples which satisfy the chemical composition, tensile strength, and conductivity specified in the present application have good workability. On the other hand, in Comparative Example 1 and Comparative Example 2 in which the solution treatment was performed during the cold rolling, the conductivity was inferior to that in the present application, and the chemical compositions did not satisfy the specified range of the present invention. Alternatively, at least one of the conductivity is inferior to that in the example, and the workability is inferior.

Claims (6)

化学組成が、Si:0.2〜0.8質量%、Mg:0.3〜1質量%、Fe:0.5質量%以下およびCu:0.5質量%以下を含有し、さらにTi:0.1質量%以下またはB:0.1質量%以下の少なくとも1種を含有し、残部Al及び不可避不純物からなり、引張強さが285MPa以上、導電率が54%IACS以上であり厚さが0.9mm以上のAl−Mg−Si系合金板。 The chemical composition contains Si: 0.2 to 0.8% by mass, Mg: 0.3 to 1% by mass, Fe: 0.5% by mass or less and Cu: 0.5% by mass or less, and Ti: 0.1 mass% or less or B: 0.1 mass% or less of at least one, and the balance Al and unavoidable impurities, the tensile strength is 285 MPa or more, the conductivity is 54% IACS or more, and the thickness. Of 0.9 mm or more is an Al-Mg-Si alloy plate. 不純物としてのMn、Cr、およびZnが、それぞれ0.1質量%以下に規制されている請求項1に記載のAl−Mg−Si系合金板。   The Al-Mg-Si alloy plate according to claim 1, wherein Mn, Cr, and Zn as impurities are regulated to 0.1% by mass or less, respectively. 不純物としてのNi、V、Ga、Pb、Sn、BiおよびZrが、それぞれ0.05質量%以下に規制されている請求項1または請求項2に記載のAl−Mg−Si系合金板。   The Al-Mg-Si based alloy plate according to claim 1 or 2, wherein Ni, V, Ga, Pb, Sn, Bi and Zr as impurities are regulated to 0.05% by mass or less, respectively. 不純物としてのAgが0.05質量%以下に規制されている請求項1ないし請求項3の何れか1項に記載のAl−Mg−Si系合金板。   The Al-Mg-Si based alloy plate according to any one of claims 1 to 3, wherein Ag as an impurity is regulated to 0.05% by mass or less. 不純物としての希土類元素の合計含有量が0.1質量%以下に規制されている請求項1ないし請求項4の何れか1項に記載のAl−Mg−Si系合金板。   The Al-Mg-Si alloy plate according to any one of claims 1 to 4, wherein the total content of rare earth elements as impurities is regulated to 0.1% by mass or less. 0.2%耐力が230MPa以上である請求項1ないし請求項5の何れか1項に記載のAl−Mg−Si系合金板。   The Al-Mg-Si alloy plate according to any one of claims 1 to 5, which has a 0.2% proof stress of 230 MPa or more.
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