A kind of hypoeutectic Al-Mg2The rotten and thinning method of Si alloy
Technical field
The invention belongs to aluminium alloy castings and melting technique field, in particular to a kind of hypoeutectic Al-Mg2The change of Si alloy
Matter and thinning method.
Background technique
In traditional Al-Si-Mg alloy, Mg2Si is to be heat-treated disperse educt by solid gas coupling as the second phase
Reinforced Al-matrix body.In recent years, Mg is directly precipitated from molten aluminum2Si phase and the Al-Mg formed2Si alloy, this is in hypereutectic composition
Also referred to as in-situ authigenic Mg2The composite material of Si/Al, the extensive concern by domestic and foreign scholars.This material and traditional
Al-Si-Mg alloy is compared, amount containing Mg and Mg2Si phase volume fraction is higher, has higher specific stiffness, specific strength and wearability
Equal excellent performances, the Novel lightweight material as fields such as space flight and aviation and automobiles have wider application prospect.However,
The Mg being precipitated under as cast condition2Si compares coarse, nascent Mg2Si is in dendritic crystalline coarse, with holes, and eutectic Mg2Si is then in coarse
Chinese character shape, netted, rodlike and sheet, seriously isolate Al matrix, stress are caused to be concentrated, and form formation of crack, deteriorate the power of alloy
Learn performance.In addition, for the Al-Mg of hypoeutectic ingredient2Si alloy is organized by primary α-Al and Mg2Si+ α-Al eutectic phase group
At wherein pattern of the primary α-Al under as cast condition is that coarse branch is crystalline, is macroscopically column crystal, leads to alloy mechanical property
With the decline of the casting characters such as feeding, crack resistance.
In recent years, people using various processes for example mechanical alloying, hot extrusion, rolling, heat treatment, quickly solidification and
Metamorphism treatment etc. controls Mg2The size and pattern of Si phase.In these methods, Metamorphism treatment has easy to operate, at low cost, change
The advantages that matter significant effect, is increased by the way that P, La, Nd, Y, Sr, Na, Ni, Zr and B iso-metamorphism agent element are added into alloy melt
Add Mg2The nucleation rate of Si phase or the growth pattern for changing crystal, and then can effectively refine Mg2Si phase improves the mechanics of alloy
Performance.
Up to now, people are to hypereutectic Al-Mg2Si alloy, that is, in-situ authigenic Mg2The Metamorphism treatment of Si/Al composite material
Etc. processes have conducted extensive research, and to hypoeutectic Al-Mg2The research of Si alloy is rarely reported.With hypereutectic Al-Mg2Si
Alloy is compared, hypoeutectic Al-Mg2The plasticity and toughness of Si alloy are more preferable, have more excellent comprehensive mechanical property, it is contemplated that have
Wider application.On condition that coarse Chinese character shape, netted and sheet eutectic Mg2Si phase is effectively refined.Together
When refine primary α-Al dendrite, so that alloy mechanical property and casting character is further improved.
At present for hypoeutectic Al-Mg2The research of Si alloy is rarely reported.The Li et al. people of University Of Tianjin is to hypoeutectic Al-
10Mg2Si alloy carries out 520 DEG C × 6h solid solution and the ageing treatment of 200 DEG C subsequent × 6h, being total in alloy after discovery processing
Brilliant Mg2The rodlike of Si Xiang Youchang is changed into short threadiness and spherical, and tensile strength is increased to 234.6 MPa by 186 MPa,
See Journal of Alloys and Compounds, 2016,663 (5): 15-19.Their research is also shown that hypoeutectic
Al-10Mg2Corrosion resistance of the Si alloy in 3.5 wt.% NaCl solutions is also improved, and sees Materials
Characterization, 2016, 122(12):142-147.Lee of material science research institute, South Korea et al. pairs
AlMg5Si2Mn diecasting alloys do cold-rolling treatment before Homogenization Treatments, make coarse eutectic Mg interconnected2Si phase is crushed
At tiny fragment, so that the mechanical property of alloy be made to be effectively improved, Materials Science and is seen
Engineering A, 2017, 685(8):244-252.Although these methods being capable of refining eutectic Mg2Si improves alloy force
Learn, the performances such as corrosion-resistant, but there are processes more, complex process and it is at high cost the disadvantages of.Therefore, there is an urgent need to research and develop both
It is easy and economical, it is suitable for hypoeutectic Al-Mg2Alterant, fining agent and the rotten, thinning method of Si alloy.
Up to now there is not yet there is refinement hypoeutectic Al-Mg2The report of Si alloy primary α-Al dendrite.For casting
Al-Si alloy mainly refines primary α-Al dendrite by adding fining agent into alloy melt.Currently used fining agent has
The intermediate alloys such as Al-Ti, Al-B, Al-Ti-B, Al-Ti-C, Al-Zr and KBF4、K2TiF6, TiC and K2ZrF6Etc. single or multiple
Close salt.The Ti class fining agent such as Al-Ti, Al -5Ti -1B and Al-Ti-C is suitable for the aluminium silicon of fine aluminium and silicon content less than 1.5%
Alloy is not obvious the hypoeutectic cast aluminium-silicon alloy thinning effect of silicon content >=5%, this is because (Ti1-x Six )Al3
The generation of compound reduces the Al as raw core agent3Ti and TiB2Amount.Studies have shown that the B class such as Al-3B, Al -3Ti -3B is thin
Agent has preferable thinning effect to the hypoeutectic cast aluminium-silicon alloy of silicon content > 4%, but B is easily reacted with alterant element Sr,
Generate SrB6, consume Sr and B.For Al-Mg2Si alloy, due to wherein contain higher Mg amount, Refining Elements be easier to Mg and
Alterant element etc. forms non-raw nuclear compound, weakens rotten and thinning effect or causes the generation of casting flaw.Iranian Teheran
Fakhraei of university et al. discovery, excessive B or Zr is added in Al-20Mg alloy can generate stomata, lead to alloy tensile
Materials & Design, 2014,56 (4): 557-564 are shown in the reduction of performance.
Summary of the invention
It is of the existing technology the purpose of the present invention is overcoming the problems, such as, provide that a kind of rotten, thinning effect is good, fade resistance
Good, strong applicability, metal mold, sand mold be all suitable for, the hypoeutectic Al-Mg of simple production process2The rotten and refinement side of Si alloy
Method.
The technical solution of the invention is as follows:
(1) %Mg of 4-12.5wt. containing mass percent is pressed2Hypoeutectic Al-the Mg of Si phase2Si alloying ingredient, wherein Mg adds
Dosage are as follows: the scaling loss amount of calculation amount+10 ~ 30%;
(2) it after pure Al, the aluminium silicon intermediate alloy prepared step (1) is cleaned and dried, is put into the graphite crucible of resistance furnace,
It is heated in resistance furnace, until completely melted, at 720 DEG C, by aluminium foil package, 300 DEG C of the preheating of pure Mg block of 300 DEG C of preheating
Graphite bell jar indentation melt in, until fusing, stand 5min;
(3) carbon trichloride that will account for melt quality 0.05 ~ 0.2% is obtained with graphite bell jar indentation step (2) for preheating 300 DEG C
To melt in, carry out refining degasification, at a temperature of 670 DEG C ~ 780 DEG C stir 1 ~ 5 min, remove the dross of bath surface, obtain
Melt after to refining;
(4) Bi particle is added under conditions of temperature is 670 DEG C ~ 730 DEG C to the melt that step (3) obtains, stands 1 ~ 3
Min obtains the melt that Bi content is 0.1-0.6wt. % mass percent;
(5) Al-10Zr intermediate alloy is added under conditions of temperature is 720 DEG C ~ 800 DEG C to the melt that step (4) obtains
Or compound containing Zr, 5 ~ 15min is stood, after its fusing, 2 ~ 5 min of stirring melt is uniformly distributed Zr, obtains Zr content and is
The melt of 0.05-0.2wt. % mass percent;
(6) refining treatment is carried out to the melt that step (5) obtains by step (3), will be melted at being 700 DEG C ~ 780 DEG C in temperature
Body is poured into casting mold, becomes casting or slab.
Bi described in step (4) is added with form of pure metal.
Zr described in step (5) is added with intermediate alloy or compound form.
Casting mold described in step (6) is the metal mold and other casting molds of 250 DEG C of sand mold or preheating.
The advantages of technical solution of the present invention, is mainly reflected in:
1, using Bi pure metal particles as alterant, can effectively go bad hypoeutectic Al-Mg2Mg in Si alloy2Si phase,
In hypoeutectic Al-Mg2After adding suitable Bi in Si alloy, eutectic Mg is changed significantly2The pattern and size of Si, Mg2Si phase
Tiny graininess, threadiness are changed by coarse Chinese character shape, netted and sheet, and primary α-Al phase volume fraction increases,
There is apparent stigma of degeneracy and effect, solubility of the Bi in Al is extremely low, when the melt of hypoeutectic and eutectic composition reaches altogether
When brilliant reflecting point, is easily adsorbing and assembling the eutectic Mg being formerly precipitated2The growth interface forward position of Si phase, in eutectic growth constantly
Block eutectic Mg2The original twin step of Si, and a large amount of new re-entrant angle twins are constantly inspired, make eutectic Mg2Si Branching Ratio does not go bad
Want much more frequent, moreover, twin density significantly increases so that eutectic Mg2Si growth characteristics are changed by original anisotropy
For isotropism, then, eutectic Mg2The mode of Si limited and thick sheet development from rotten preceding branch is sharp to become a large amount of frequent branches
Fibrous growth, final eutectic Mg2The pattern and size of Si have the change of matter;In addition, Bi is in liquid-solid boundary forward position
Enrichment causes constitutional supercooling, is greatly lowered the balance crystallization temperature of liquid at the forward position of interface, thus reduces liquid phase
Practical degree of supercooling, reduces the speed of growth of eutectic structure, to reach refining eutectic Mg2The purpose of Si.
2, using Al-Zr intermediate alloy or compound containing Zr to hypoeutectic Al-Mg2Primary α-Al Phase in Si alloy has
Significant refining effect, in hypoeutectic Al-Mg2After adding suitable Zr in Si alloy, Primary α-Al Phase is changed significantly
Pattern and size make it be changed into tiny equiax crystal by coarse columnar dendrite, and Zr is raw in conjunction with the Al in alloy melt
At ZrAl3Phase.ZrAl3Mutually close with the lattice constant of Primary α-Al Phase, mismatch between the two is only 0.925%, according to different
Matter forming core is theoretical, and mismatch is smaller, and the interatomic binding force of the two is stronger, easier in its substrate forming core, therefore, ZrAl3It can
Using the heterogeneous forming core core as primary α-Al, to refine Primary α-Al Phase.
3, to different content Mg2Hypoeutectic Al-the Mg of Si2Si alloy all has excellent rotten, thinning effect, expands
The application range of such alloy.
4, Bi alterant and Zr fining agent all have long-term effect, go bad, thinning effect, insensitive to cooling velocity, are applicable in
In the various casting production process such as metal mold, sand mold, die casting, since Bi is in eutectic Mg2The absorption in Si phase growth interface forward position is simultaneously
Coherent condition influenced by cooling velocity it is smaller, therefore Bi be added melt in, be either cast in metal mold, or in sand mold
In, eutectic Mg2Si can be refined effectively, i.e. Bi is in hypoeutectic Al-Mg2To eutectic Mg in Si alloy2The rotten effect of Si phase
Fruit is influenced smaller by cooling velocity;In addition, since bismuth with oxygen is not susceptible to chemically react, therefore in melt long-term heat preservation, casting
In the process, it is unlikely to be burnt, it is ensured that melt mesometamorphism eutectic Mg2The residual quantity of the minimum Bi of Si, so that the modification effect of Bi has
There is long-term effect.
5, Bi alterant and Zr fining agent also have many advantages, such as easily operated, low in cost and safety and environmental protection.
Detailed description of the invention
Fig. 1 is that 100 times of bottom dies do not refine, go bad %Mg containing 10wt.2Hypoeutectic Al-the Mg of Si phase2Si microstructure of the alloy
Micro-organization chart;
Fig. 2 is that 500 times of bottom dies do not refine, go bad %Mg containing 10wt.2Hypoeutectic Al-the Mg of Si phase2Si microstructure of the alloy
Micro-organization chart;
Fig. 3 is 100 times of bottom die 0.13%Zr refinements, the rotten %Mg containing 10wt. of 0.41%Bi2The hypoeutectic Al-of Si phase
Mg2Si microstructure of the alloy micro-organization chart;
Fig. 4 is 500 times of bottom die 0.13%Zr refinements, the rotten %Mg containing 10wt. of 0.41%Bi2The hypoeutectic Al-of Si phase
Mg2Si microstructure of the alloy micro-organization chart;
Fig. 5 is that 100 times of bottom dies do not refine, go bad %Mg containing 4wt.2Hypoeutectic Al-the Mg of Si phase2Si microstructure of the alloy is aobvious
Micro-assembly robot figure;
Fig. 6 is that 500 times of bottom dies do not refine, go bad %Mg containing 4wt.2Hypoeutectic Al-the Mg of Si phase2Si microstructure of the alloy is aobvious
Micro-assembly robot figure;
Fig. 7 is 100 times of bottom die 0.09%Zr refinements, the rotten %Mg containing 4wt. of 0.1%Bi2The hypoeutectic Al-of Si phase
Mg2Si microstructure of the alloy micro-organization chart;
Fig. 8 is 500 times of bottom die 0.09%Zr refinements, the rotten %Mg containing 4wt. of 0.1%Bi2The hypoeutectic Al-of Si phase
Mg2Si microstructure of the alloy micro-organization chart;
Fig. 9 is that 100 times of bottom dies do not refine, go bad %Mg containing 12.5wt.2Hypoeutectic Al-the Mg of Si phase2Si alloy gold
Phase micro-organization chart;
Figure 10 is that 500 times of bottom dies do not refine, go bad %Mg containing 12.5wt.2Hypoeutectic Al-the Mg of Si phase2Si alloy gold
Phase micro-organization chart;
Figure 11 is 100 times of bottom die 0.2%Zr refinements, the rotten %Mg containing 12.5wt. of 0.36%Bi2The hypoeutectic of Si phase
Al-Mg2Si microstructure of the alloy micro-organization chart;
Figure 12 is 500 times of bottom die 0.2%Zr refinements, the rotten %Mg containing 12.5wt. of 0.36%Bi2The hypoeutectic of Si phase
Al-Mg2Si microstructure of the alloy micro-organization chart;
Figure 13 is that 100 times of lower sand molds do not refine, go bad %Mg containing 10wt.2Hypoeutectic Al-the Mg of Si phase2Si microstructure of the alloy is aobvious
Micro-assembly robot figure;
Figure 14 is that 500 times of lower sand molds do not refine, go bad %Mg containing 10wt.2Hypoeutectic Al-the Mg of Si phase2Si microstructure of the alloy is aobvious
Micro-assembly robot figure;
Figure 15 is 100 times of lower sand mold 0.17Zr refinements, the rotten %Mg containing 10wt. of 0.6%Bi2Hypoeutectic Al-the Mg of Si phase2Si
Microstructure of the alloy micro-organization chart;
Figure 16 is 500 times of lower sand mold 0.17Zr refinements, the rotten %Mg containing 10wt. of 0.6%Bi2Hypoeutectic Al-the Mg of Si phase2Si
Microstructure of the alloy micro-organization chart;
Figure 17 is the not rotten %Mg containing 13.5wt. of 500 times of bottom dies2Hypoeutectic Al-the Mg of Si phase2Si microstructure of the alloy is aobvious
Micro-assembly robot figure;
Figure 18 is the rotten %Mg containing 13.5wt. of 500 times of bottom die 0.44%Bi2Hypoeutectic Al-the Mg of Si phase2Si alloy gold
Phase micro-organization chart;
Figure 19 is the rotten %Mg containing 10wt. of 500 times of bottom die 0.06%Bi2Hypoeutectic Al-the Mg of Si phase2Si microstructure of the alloy
Micro-organization chart;
Figure 20 is the rotten %Mg containing 10wt. of 500 times of bottom die 0.87%Bi2Hypoeutectic Al-the Mg of Si phase2Si microstructure of the alloy
Micro-organization chart;
Figure 21 is that 100 times of bottom die 0.02%Zr refine %Mg containing 10wt.2Hypoeutectic Al-the Mg of Si phase2Si microstructure of the alloy
Micro-organization chart;
Figure 22 is 500 times of bottom die 0.64%Zr refinements, the rotten %Mg containing 10wt. of 0.47% Bi2The hypoeutectic of Si phase
Al-Mg2Si microstructure of the alloy micro-organization chart;
Figure 23 is the load-deformation curve of alloy.
Specific embodiment
The present invention is for hypoeutectic Al-Mg2Si alloy is applicable in, including be added various alloy elements, it is additional and
The case where interior raw reinforced phase, following implementation of the present invention be intended merely to it is detailed for example, but the invention is not limited to
Following implementation, various modifications and replacement under all core of the invention technical conditions, all belongs to the scope of the present invention it
It is interior.
Below to hypoeutectic Al-Mg of the present invention2Si alloying component, alterant, fining agent and melting and founder
Skill condition is illustrated:
Alloying component: Al-Mg of the present invention2Mg in Si alloy2The ingredient of Si is limited to 4 ~ 12.5wt. %, Al-Mg2Si is
The eutectic alloy that eutectic point is 13.9%, eutectic Mg in alloy2Si phase is hardening constituent, quantity, pattern, size and distribution pair
Its Effect on Mechanical Properties is very big, works as Mg2When Si < 4wt. %, Mg2Si phasor is low, and alloy strength is too low;Work as Mg2Si=13.9wt.
%(eutectic composition) and 12.5wt. % < Mg2The nearly eutectic composition of Si < 13.9wt. %() when, our experiments demonstrated that, although Bi
The a small amount of block-like nascent Mg occurred under as cast condition can be eliminated2Si phase, but to eutectic Mg2The modification effect of Si phase is unobvious, sees figure
17, Figure 18;Mg2Si is within the scope of 4 ~ 12.5wt. %, with Mg2The increase of Si amount, alloy strength, hardness increase, plasticity, toughness
Reduce;In practical application, Mg can be reasonably selected according to the requirement of workpiece mechanical property2The quantity of Si phase, so that it is determined that final
Alloying component.
Alterant: Bi alterant is to Al-Mg2Mg in Si alloy2The modification effect of Si phase depends primarily on the content of Bi, melts
There is best modification effect, as Bi content < 0.1% in melt, Mg when Bi content is 0.1 ~ 0.6% in body2Although Si phase Chinese character
Shape disappears, and threadiness occurs, but there are still numerous strips, sheet, show rotten deficiency, see Figure 19;As Bi in melt
When content > 0.6%, Mg2Si phase is most of still to be not fibrous, but part strip, sheet occurs, showed denaturalization phenomenon, and saw
Figure 20.
Fining agent: Zr fining agent is to Al-Mg2The thinning effect of Primary α-Al Phase depends primarily on containing for Zr in Si alloy
Amount, i.e., as the heterogeneous forming core core ZrAl of primary α-Al3Production quantity number, melt Zr content be 0.05 ~ 0.2% when have
There is best thinning effect, as Zr content < 0.05% in melt, the ZrAl that is formed in melt3Very little, Primary α-Al Phase forming core position
It sets less, α-Al is still dendrite, shows the deficiency of refinement, sees Figure 21;As Zr content > 0.2% in melt, not but not increase
Strong thinning effect, excessive Zr easily form ZrBi two-spot compound or Al-Zr-Bi ternary compound with alterant Bi instead, disappear
The Bi atom in melt is consumed, rotten deficiency is caused, although forming some fibre shape Mg2Si phase, but most of is still strip, piece
Shape is shown in Figure 22.
Smelting technology: Al-Mg2Si series alloy amount containing Mg is higher, and the present invention is smelting technology under atmosphere, protects without gas
Shield or melting under vacuum, but answer the scaling loss of strict control Mg, measure are as follows: 300 DEG C of preheating Mg blocks, and being wrapped up with aluminium foil, with pre-
In the graphite bell jar indentation melt of 300 DEG C of heat, until fusing, is added Bi later, after stirring slightly, i.e. closed among addition Al-Zr
Gold, it is therefore an objective to avoid MAG block under high temperature from directly contacting with the oxygen in air, shorten the fusing of magnesium and the soaking time of melt, make
The scaling loss amount of magnesium is controlled 10 ~ 30%, i.e. fusible in addition molten aluminum because the fusing point of pure Bi is low, without standing, but in Al-10Zr
Between alloy relative melting points it is high, standing is needed after addition 5 ~ 15 minutes, and after its fusing, 2 ~ 5 min of stirring melt divides Zr uniformly
Cloth.
Embodiment 1:
1, hypoeutectic Al-Mg is prepared using Al-15Si intermediate alloy, pure Al and pure Mg2Si alloy, wherein Mg and Si are pressed
10.wt %Mg2The ratio of Si is added, the additive amount of Mg are as follows: the scaling loss amount of calculation amount+10%, surplus are pure Al;
2, it after pure Al, the aluminium silicon intermediate alloy prepared step 1 is cleaned and dried, is put into the graphite crucible of resistance furnace,
Pure Al and Al-15Si intermediate alloy is heated in resistance furnace, until completely melted, at 720 DEG C, by aluminium foil package, preheating 300
DEG C pure Mg block with preheat 300 DEG C graphite bell jar indentation melt in, until fusing, stand 5min;
3, the melt for obtaining the graphite bell jar indentation step 2 that the carbon trichloride for accounting for melt quality 0.1% preheats 300 DEG C
In, refining degasification is carried out, stirs 3min at a temperature of 740 DEG C, removes the dross of bath surface, the melt after being refined;
4, pure metal Bi particle is added at a temperature of 710 DEG C into melt to the melt that step 3 obtains, stands 2 min, obtains
It is the melt of 0.41wt. % mass percent to Bi content;
5, Al-10Zr intermediate alloy is added under conditions of temperature is 750 DEG C to the melt that step 4 obtains, stood
10min, after its fusing, 3 min of stirring melt is uniformly distributed Zr, and obtaining Zr content is 0.13wt. % mass percent
Melt;
6, the melt for obtaining the graphite bell jar indentation step 5 that the carbon trichloride for accounting for melt quality 0.05% preheats 300 DEG C
In, refining degasification is carried out, is stirred at a temperature of 740 DEG C, after refining, skimming, the gold of 250 DEG C of preheating is poured at a temperature of 740 DEG C
In genotype, become casting.
Specific modification effect is shown in Fig. 1, Fig. 2, Fig. 3 and Fig. 4, and the Primary α-Al Phase being not added in Bi, Zr alloy is coarse
Dendrite is shown in Fig. 1, Mg2Si phase is coarse Chinese character, lath-shaped, sees Fig. 2;Add Primary α-Al Phase after Bi, Zr in alloy by
Coarse branch is crystalline to be changed into tiny equiaxed dendrite shape, sees Fig. 3, Mg2Si phase becomes threadiness and minimal amount of tiny item
Shape is shown in Fig. 4;The wax-anti dispersant of alloy is respectively 214.37MPa and 2.01% before refining, being rotten, after refining, being rotten
279.44MPa and 7.02% is respectively increased, sees Figure 23.
Embodiment 2:
1, hypoeutectic Al-Mg is prepared using Al-15Si intermediate alloy, pure Al and pure Mg2Si alloy, wherein Mg and Si are pressed
4.wt %Mg2The ratio of Si is added, the additive amount of Mg are as follows: the scaling loss amount of calculation amount+20%, surplus are pure Al;
2, it after pure Al, the aluminium silicon intermediate alloy prepared step 1 is cleaned and dried, is put into the graphite crucible of resistance furnace,
Pure Al and Al-15Si intermediate alloy is heated in resistance furnace, until completely melted, at 720 DEG C, by aluminium foil package, preheating 300
DEG C pure Mg block with preheat 300 DEG C graphite bell jar indentation melt in, until fusing, stand 5min;
3, the melt for obtaining the graphite bell jar indentation step 2 that the carbon trichloride for accounting for melt quality 0.05% preheats 300 DEG C
In, refining degasification is carried out, stirs 1min at a temperature of 780 DEG C, removes the dross of bath surface, the melt after being refined;
4, pure metal Bi particle is added at a temperature of 730 DEG C into melt to the melt that step 3 obtains, stands 3 min, obtains
It is the melt of 0. 1wt. % mass percent to Bi content;
5, Al-10Zr intermediate alloy is added under conditions of temperature is 800 DEG C to the melt that step 4 obtains, stands 5min,
After its fusing, 2 min of stirring melt is uniformly distributed Zr, obtains the melt that Zr content is 0.09wt. % mass percent;
6, the melt for obtaining the graphite bell jar indentation step 5 that the carbon trichloride for accounting for melt quality 0.2% preheats 300 DEG C
In, refining degasification is carried out, is stirred at a temperature of 780 DEG C, after refining, skimming, the gold of 250 DEG C of preheating is poured at a temperature of 780 DEG C
In genotype, become casting.
Specific modification effect is shown in Fig. 5, Fig. 6, Fig. 7 and Fig. 8, and the Primary α-Al Phase being not added in Bi, Zr alloy is coarse
Dendrite is shown in Fig. 5, Mg2Si phase is coarse Chinese character, lath-shaped, sees Fig. 6;Add Primary α-Al Phase after Bi, Zr in alloy by
Coarse branch is crystalline to be changed into tiny equiaxed dendrite shape, sees Fig. 7, Mg2Si phase becomes threadiness and minimal amount of tiny item
Shape is shown in Fig. 8;The wax-anti dispersant of alloy is respectively 214.37MPa and 2.01% before refining, being rotten, after refining, being rotten
255.67MPa and 9.25% is respectively increased, sees Figure 23.
Embodiment 3:
1, hypoeutectic Al-Mg is prepared using Al-15Si intermediate alloy, pure Al and pure Mg2Si alloy, wherein Mg and Si are pressed
12.5wt %Mg2The ratio of Si is added, the additive amount of Mg are as follows: the scaling loss amount of calculation amount+30%, surplus are pure Al;
2, it after pure Al, the aluminium silicon intermediate alloy prepared step 1 is cleaned and dried, is put into the graphite crucible of resistance furnace,
Pure Al and Al-15Si intermediate alloy is heated in resistance furnace, until completely melted, at 720 DEG C, by aluminium foil package, preheating 300
DEG C pure Mg block with preheat 300 DEG C graphite bell jar indentation melt in, until fusing, stand 5min;
3, the melt for obtaining the graphite bell jar indentation step 2 that the carbon trichloride for accounting for melt quality 0.2% preheats 300 DEG C
In, refining degasification is carried out, stirs 5min at a temperature of 670 DEG C, removes the dross of bath surface, the melt after being refined;
4, pure metal Bi particle is added at a temperature of 730 DEG C into melt to the melt that step 3 obtains, stands 1 min, obtains
It is the melt of 0.36wt. % mass percent to Bi content;
5, compound containing Zr is added under conditions of temperature is 720 DEG C to the melt that step 4 obtains, 15min is stood, to it
After fusing, 5 min of stirring melt is uniformly distributed Zr, obtains the melt that Zr content is 0.2wt. % mass percent;
6, the melt for obtaining the graphite bell jar indentation step 5 that the carbon trichloride for accounting for melt quality 0.1% preheats 300 DEG C
In, refining degasification is carried out, is stirred at a temperature of 700 DEG C, after refining, skimming, the gold of 250 DEG C of preheating is poured at a temperature of 700 DEG C
In genotype, become casting.
Specific modification effect is shown in Fig. 9, Figure 10, Figure 11 and Figure 12, and the Primary α-Al Phase being not added in Bi, Zr alloy is coarse
Dendrite, see Fig. 9, Mg2Si phase is coarse Chinese character, lath-shaped, sees Figure 10;Primary α-Al after addition Bi, Zr in alloy
Mutually it is changed into tiny equiaxed dendrite shape by coarse branch is crystalline, sees Figure 11, Mg2Si phase becomes fibrous and minimal amount of thin
Small strip, is shown in Figure 12;The wax-anti dispersant of alloy is respectively 221.61MPa and 1.82% before refining, being rotten, and refinement becomes
287.76MPa and 6.81% are respectively increased after matter, sees Figure 23.
Embodiment 4:
1, hypoeutectic Al-Mg is prepared using Al-15Si intermediate alloy, pure Al and pure Mg2Si alloy, wherein Mg and Si are pressed
10.wt %Mg2The ratio of Si is added, the additive amount of Mg are as follows: the scaling loss amount of calculation amount+15%, surplus are pure Al;
2, it after pure Al, the aluminium silicon intermediate alloy prepared step 1 is cleaned and dried, is put into the graphite crucible of resistance furnace,
Pure Al and Al-15Si intermediate alloy is heated in resistance furnace, until completely melted, at 720 DEG C, by aluminium foil package, preheating 300
DEG C pure Mg block with preheat 300 DEG C graphite bell jar indentation melt in, until fusing, stand 5min;
3, the melt for obtaining the graphite bell jar indentation step 2 that the carbon trichloride for accounting for melt quality 0.2% preheats 300 DEG C
In, refining degasification is carried out, stirs 4min at a temperature of 750 DEG C, removes the dross of bath surface, the melt after being refined;
4, pure metal Bi particle is added at a temperature of 710 DEG C into melt to the melt that step 3 obtains, stands 3 min, obtains
It is the melt of 0.6wt. % mass percent to Bi content;
5, compound containing Zr is added under conditions of temperature is 760 DEG C to the melt that step 4 obtains, 12min is stood, to it
After fusing, 4 min of stirring melt is uniformly distributed Zr, obtains the melt that Zr content is 0.05wt. % mass percent;
6, the melt for obtaining the graphite bell jar indentation step 5 that the carbon trichloride for accounting for melt quality 0.05% preheats 300 DEG C
In, refining degasification is carried out, is stirred at a temperature of 730 DEG C, after refining, skimming, is poured into sand mold at a temperature of 730 DEG C.
Specific modification effect is shown in Figure 13, Figure 14, Figure 15 and Figure 16, compared with metal mold, under the conditions of sand mold, be not added with Bi,
Primary α-Al Phase in Zr alloy is dendrite, and more coarse, sees Figure 13, Mg2Si phase is coarse lath-shaped, sees Figure 14;
Primary α-Al Phase after addition Bi, Zr in alloy is changed into tiny equiaxed dendrite shape, sees Figure 15, Mg2Si phase becomes tiny
Strip is shown in Figure 16;The wax-anti dispersant of alloy is respectively 175.96MPa and 1.23% before refining, being rotten, and refinement is gone bad
After 244.69MPa and 3.83% is respectively increased, see Figure 23.