CN110257677A - A kind of novel high thermal conductivity Al-Mg-Si alloy - Google Patents

A kind of novel high thermal conductivity Al-Mg-Si alloy Download PDF

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Publication number
CN110257677A
CN110257677A CN201910667939.6A CN201910667939A CN110257677A CN 110257677 A CN110257677 A CN 110257677A CN 201910667939 A CN201910667939 A CN 201910667939A CN 110257677 A CN110257677 A CN 110257677A
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China
Prior art keywords
alloy
thermal conductivity
high thermal
novel high
component
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CN201910667939.6A
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Chinese (zh)
Inventor
施国斌
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Jiangsu Weiteng Power Technology Co Ltd
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Jiangsu Weiteng Power Technology Co Ltd
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Priority to CN201910667939.6A priority Critical patent/CN110257677A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • C22C21/08Alloys based on aluminium with magnesium as the next major constituent with silicon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/02Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
    • H01B1/023Alloys based on aluminium

Abstract

The present invention discloses a kind of novel high thermal conductivity Al-Mg-Si alloy, it includes each component of following weight degree: Si 0.33~0.37%, Mg 0.52~0.56%, Impurity Fe≤0.15%, Cu≤0.01%, Zn≤0.05%, surplus are Al and other inevitable impurity elements;The mass percent of the total component of other inevitable impurity element total amount Zhan is≤0.03%.The novel high thermal conductivity Al-Mg-Si alloy component, further includes the B element for controlling V, Ti constituent content in alloy, and the 0.01~0.03% of the quality percentage of the total component of additional amount Zhan.It is≤0.002% that the content of V, Ti, which are controlled as the percentage of the total constituent mass of Zhan,.The present invention is the customized conductor material of bus duct, and conductivity, thermally conductive, tensile property etc. are above the national standard of T2 copper conductor, and its partial parameters technical performance reaches world lead level, and cost performance is high, has good application and economic value.

Description

A kind of novel high thermal conductivity Al-Mg-Si alloy
Technical field
The present invention relates to a kind of novel high thermal conductivity Al-Mg-Si alloys.
Technical background
Country low voltage bus bar groove market reaches its maturity and standardizes at present, and competition exceedes plus fierceness, in the large-scale weight of some countries In point engineering project, demand to product is in addition to requiring product specification high outer, there are also prior demand factor, including energy saving, Electrical Safety is reliable etc..But the current country has the bus duct manufacturing enterprise of high conductance energy conservation class almost without even if having It is only capable of reaching international standards: the part busway product produced such as Schneider company.
In general, the incorporation of alloying element can cause aluminium alloy impurity defect, move to free electron and generate resistance, meeting Reduce the thermal conductivity in alloy.Si and Mg is the essential element in Al-Mg-Si system alloy.Studies have shown that is smaller when Mg content When, the thermal conductivity of alloy is higher and intensity is slightly lower, and when Mg/Si mass is bigger, excessive Mg can not only weaken Mg2Si effect, And can be added in aluminum substrate, decline the thermal conductivity of alloy.When alloying element is become being dissolved state from precipitation state, thermal conductivity can be caused Rate becomes smaller.And when Si excess quantity is more, superfluous Si is solid-solution in aluminum substrate, is easy and Fe forms Al9Fe2Si phase, thermal conductivity It reduces.There is studies have shown that addition rare earth that alloy thermal conductivity can be made to improve again, and rare earth content adds less or adds will lead to alloy Conductivity decline.It is therefore desirable to be researched and developed for the novel high conductivity conductor material of bus duct, to meet the country The high demand of client.
Summary of the invention
For above-mentioned current domestic bus duct conductor materials demand situation, the present invention provides a kind of novel high thermal conductivity Al- Mg-Si alloy is the customized conductor material of bus duct, and conductivity, thermally conductive, tensile property etc. are above the state of T2 copper conductor Family's standard, and its partial parameters technical performance reaches world lead level.Specific technical solution is as follows:
A kind of novel high thermal conductivity Al-Mg-Si alloy comprising each component of following weight degree: Si 0.33~ 0.37%, 0.52~0.56% Mg, Impurity Fe≤0.15%, Cu≤0.01%, Zn≤0.05%, surplus be Al and it is other can not The impurity element avoided.
Novel high thermal conductivity Al-Mg-Si alloy above-mentioned, other inevitable impurity include Cr, Mn, V and/or Ti Element, the mass percent of the total component of other inevitable impurity element total amount Zhan are≤0.03.Preferably, described The mass percent of the total component of quality summation Zhan of two kinds of elements of Cr, Mn is≤0.005%.
Novel high thermal conductivity Al-Mg-Si alloy above-mentioned, further includes the B element for controlling V, Ti constituent content in alloy. Preferably, the 0.01~0.03% of the quality percentage of the total component of additional amount Zhan of the B element.Preferably, the content of described V, Ti Control is that the percentage of the total constituent mass of its quality summation Zhan is≤0.002%.
Novel high thermal conductivity Al-Mg-Si alloy above-mentioned, more specifically several formulas are as follows: by weight percentage:
It is formulated 1:Si 0.33~0.37%, Mg 0.52~0.56%, Fe 0.12%, Cr and/or Mn 0.005%, V and/or Ti 0.02%, Cu 0.01%, Zn 0.05%, B 0.03%, surplus are Al and other inevitable impurity elements.
It is formulated 2:Si 0.35%, Mg 0.55%, Fe 0.12%, Cr and/or Mn 0.005%, V and/or Ti 0.02%, Cu 0.01%, Zn 0.05%, B 0.03%, surplus are Al and other inevitable impurity elements.
Be formulated 3:Si 0.35%, Mg 0.56%, Fe 0.08%, Cr and/or Mn≤0.004%, Ti 0.01%, Cu≤ 0.001%, Zn 0.04%, B 0.011%, surplus are Al and other inevitable impurity elements.
Novel high thermal conductivity Al-Mg-Si alloy above-mentioned, the tensile strength of the novel high thermal conductivity Al-Mg-Si alloy >= 215MPa, 20 DEG C of conductivity >=56.6%IACS, webster hardness >=11,20 DEG C thermal coefficient >=220W/mK.
The beneficial effects of the present invention are:
The present invention is the customized conductor material of bus duct, and conductivity, thermally conductive, tensile property etc. are above the state of T2 copper conductor Family's standard, and its partial parameters technical performance reaches world lead level, and cost performance is high, has good application and economic valence Value.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with embodiment, to skill of the invention Art scheme is clearly and completely described.
Embodiment 1
A kind of novel high thermal conductivity Al-Mg-Si alloy, component be respectively as follows: by weight percentage Si 0.33%, Mg 0.52%, Fe 0.15%, Cr and/or Mn 0.005%, V and/or Ti 0.02%, Cu 0.01%, Zn 0.05%, B 0.03%, surplus be Al and Other inevitable impurity elements, other inevitable impurity element≤0.03%.Firstly, pressing above-mentioned matter in smelting furnace It measures percentage and aluminium ingot and alusil alloy is added, be heated to 700 DEG C of meltings, and deslagging agent is added and carries out deslagging agent;After slagging-off Molten aluminum is heated to 780 DEG C, and the other components in addition to aluminium are added in smelting furnace by above-mentioned percentage, continue to stir aluminium alloy 5 Minute;Then, then by aluminium alloy temperature control at 740 DEG C, fining agent is added and refining agent carries out refining treatment;After refining Aluminium alloy is stood 15 minutes, is removed the gred using inert gas deaeration at 680 DEG C, is being carried out stokehold constituent analysis, is being carried out after qualified Die casting obtains novel high thermal conductivity Al-Mg-Si alloy.
After the completion of die casting processing, the novel high thermal conductivity Al-Mg-Si alloy of acquisition is subjected to heat-conductive characteristic inspection, tension Intensity is 215MPa, 20 DEG C of conductivity 57.4%IACS, 11,20 DEG C of webster hardness position thermal coefficient 222.1W/mK.
Embodiment 2
A kind of novel high thermal conductivity Al-Mg-Si alloy, component be respectively as follows: by weight percentage Si 0.35%, Mg 0.55%, Fe 0.12%, Cr and/or Mn 0.005%, V and/or Ti 0.02%, Cu 0.01%, Zn 0.05%, B 0.03%, surplus be Al and Other inevitable impurity elements, other inevitable impurity element≤0.03%.Firstly, pressing above-mentioned matter in smelting furnace It measures percentage and aluminium ingot and alusil alloy is added, be heated to 750 DEG C of meltings, and deslagging agent is added and carries out deslagging agent;After slagging-off Molten aluminum is heated to 800 DEG C, and the other components in addition to aluminium are added in smelting furnace by above-mentioned percentage, continue to stir aluminium alloy 8 Minute;Then, then by aluminium alloy temperature control at 720 DEG C, fining agent is added and refining agent carries out refining treatment;After refining Aluminium alloy is stood 15 minutes, is removed the gred using inert gas deaeration at 700 DEG C, is being carried out stokehold constituent analysis, is being carried out after qualified Die casting obtains novel high thermal conductivity Al-Mg-Si alloy.
After the completion of die casting processing, the novel high thermal conductivity Al-Mg-Si alloy of acquisition is subjected to heat-conductive characteristic inspection, tension Intensity is 230MPa, 20 DEG C of conductivity 56.9%IACS, 12,20 DEG C of webster hardness position thermal coefficient 220.2W/mK.
Embodiment 3
A kind of novel high thermal conductivity Al-Mg-Si alloy, component be respectively as follows: by weight percentage Si 0.35%, Mg 0.56%, Fe 0.08%, Cr and/or Mn≤0.004%, Ti 0.01%, Cu≤0.001%, Zn 0.04%, B 0.02%, surplus be Al and Other inevitable impurity elements, other inevitable impurity element≤0.03%.Firstly, pressing above-mentioned matter in smelting furnace It measures percentage and aluminium ingot and alusil alloy is added, be heated to 760 DEG C of meltings, and deslagging agent is added and carries out deslagging agent;After slagging-off Molten aluminum is heated to 780 DEG C, and the other components in addition to aluminium are added in smelting furnace by above-mentioned percentage, continue to stir aluminium alloy 10 Minute;Then, then by aluminium alloy temperature control at 710 DEG C, fining agent is added and refining agent carries out refining treatment;After refining Aluminium alloy is stood 20 minutes, is removed the gred using inert gas deaeration at 710 DEG C, is being carried out stokehold constituent analysis, is being carried out after qualified Die casting obtains novel high thermal conductivity Al-Mg-Si alloy.
After the completion of die casting processing, the novel high thermal conductivity Al-Mg-Si alloy of acquisition is subjected to heat-conductive characteristic inspection, tension Intensity is 230MPa, 20 DEG C of conductivity 56.6%IACS, 13,20 DEG C of webster hardness position thermal coefficient 220.1W/mK.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive.Although in addition, it should be understood that originally Specification is described in terms of embodiments, but only includes not one technical solution, and this narrating mode of specification is only It is only for clarity that the skilled in the art should refer to the specification as a whole, the technical solution in embodiment can also To be properly combined, form other embodiments that can be understood by those skilled in the art.

Claims (10)

1. a kind of novel high thermal conductivity Al-Mg-Si alloy, it is characterised in that: it includes each component of following weight degree: Si 0.33~0.37%, Mg 0.52~0.56%, Impurity Fe≤0.15%, Cu≤0.01%, Zn≤0.05%, surplus are Al and other inevitable impurity elements.
2. novel high thermal conductivity Al-Mg-Si alloy according to claim 1, it is characterised in that: described other inevitable Impurity includes Cr, Mn, V and/or Ti element, and the mass percents of other inevitable total components of total amount Zhan is≤ 0.03%。
3. novel high thermal conductivity Al-Mg-Si alloy according to claim 2, it is characterised in that: two kinds of elements of described Cr, Mn The total component of quality summation Zhan mass percent be≤0.005%.
4. novel high thermal conductivity Al-Mg-Si alloy according to claim 1, it is characterised in that: further include for controlling alloy The B element of middle V, Ti constituent content.
5. novel high thermal conductivity Al-Mg-Si alloy according to claim 4, it is characterised in that: the additional amount of the B element The 0.01~0.03% of the quality percentage of the total component of Zhan.
6. novel high thermal conductivity Al-Mg-Si alloy according to claim 4, it is characterised in that: the content of described V, Ti control Percentage for the total constituent mass of its quality summation Zhan is≤0.002%.
7. a kind of novel high thermal conductivity Al-Mg-Si alloy, it is characterised in that: it includes each component as following weight percent: Si 0.33~0.37%, Mg 0.52~0.56%, Fe 0.12%, Cr and/or Mn 0.005%, V and/or Ti 0.02%, Cu 0.01%, Zn 0.05%, B 0.03%, surplus are Al and other inevitable impurity elements.
8. a kind of novel high thermal conductivity Al-Mg-Si alloy, it is characterised in that: it includes each component as following weight percent: Si 0.35%, Mg 0.55%, Fe 0.12%, Cr and/or Mn 0.005%, V and/or Ti 0.02%, Cu 0.01%, Zn 0.05%, B 0.03%, surplus is Al and other inevitable impurity elements.
9. a kind of novel high thermal conductivity Al-Mg-Si alloy, it is characterised in that: it includes each component as following weight percent: Si 0.35%, Mg 0.56%, Fe 0.08%, Cr and/or Mn≤0.004%, Ti 0.01%, Cu≤0.001%, Zn 0.04%, B 0.011%, surplus is Al and other inevitable impurity elements.
10. according to claim 1, novel high thermal conductivity Al-Mg-Si alloy described in 7,8,9 any one, it is characterised in that: institute State tensile strength >=215MPa of novel high thermal conductivity Al-Mg-Si alloy, 20 DEG C of conductivity >=56.6%IACS, webster hardness >= 11,20 DEG C of thermal coefficient >=220W/mK.
CN201910667939.6A 2019-07-23 2019-07-23 A kind of novel high thermal conductivity Al-Mg-Si alloy Pending CN110257677A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4134460A1 (en) * 2021-08-12 2023-02-15 Shanghai XPT Technology Limited Aluminum alloy with preferred mechanical property and preferred electrical and thermal conductivity and related manufacturing method

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JP2002030368A (en) * 2000-07-17 2002-01-31 Furukawa Electric Co Ltd:The Heat sink made of aluminum alloy excellent in strength after brazing heating
CN1639373A (en) * 2002-03-01 2005-07-13 昭和电工株式会社 Process for producing Al-Mg-Si alloy plate, Al-Mg-Si alloy plate and Al-Mg-Si alloy material
CN103203596A (en) * 2013-03-27 2013-07-17 成都阳光铝制品有限公司 Aluminum alloy section production process for IT (information technology) industry
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4134460A1 (en) * 2021-08-12 2023-02-15 Shanghai XPT Technology Limited Aluminum alloy with preferred mechanical property and preferred electrical and thermal conductivity and related manufacturing method

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Application publication date: 20190920