JP6829243B2 - 洗浄製品 - Google Patents
洗浄製品 Download PDFInfo
- Publication number
- JP6829243B2 JP6829243B2 JP2018501942A JP2018501942A JP6829243B2 JP 6829243 B2 JP6829243 B2 JP 6829243B2 JP 2018501942 A JP2018501942 A JP 2018501942A JP 2018501942 A JP2018501942 A JP 2018501942A JP 6829243 B2 JP6829243 B2 JP 6829243B2
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- Prior art keywords
- composition
- surfactant
- weight
- ether
- glycol
- Prior art date
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- 238000004140 cleaning Methods 0.000 title claims description 34
- 239000000203 mixture Substances 0.000 claims description 136
- 239000004094 surface-active agent Substances 0.000 claims description 102
- -1 aliphatic alcohols Chemical class 0.000 claims description 65
- 239000000047 product Substances 0.000 claims description 59
- 150000001412 amines Chemical group 0.000 claims description 27
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 239000002904 solvent Substances 0.000 claims description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- 239000007921 spray Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 15
- 239000002736 nonionic surfactant Substances 0.000 claims description 15
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- 238000005507 spraying Methods 0.000 claims description 11
- 238000005406 washing Methods 0.000 claims description 11
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 10
- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical group CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000002280 amphoteric surfactant Substances 0.000 claims description 9
- 239000002738 chelating agent Substances 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 239000006254 rheological additive Substances 0.000 claims description 8
- 239000004210 ether based solvent Substances 0.000 claims description 7
- 238000005201 scrubbing Methods 0.000 claims description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 5
- 239000007859 condensation product Substances 0.000 claims description 4
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
- 229920005862 polyol Polymers 0.000 claims description 3
- 150000003077 polyols Chemical class 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims 1
- 239000004064 cosurfactant Substances 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 description 35
- 239000003945 anionic surfactant Substances 0.000 description 30
- 229910021653 sulphate ion Inorganic materials 0.000 description 30
- 229960003237 betaine Drugs 0.000 description 29
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 28
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 25
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 22
- 150000008051 alkyl sulfates Chemical class 0.000 description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- 125000004432 carbon atom Chemical group C* 0.000 description 15
- 239000003921 oil Substances 0.000 description 14
- 235000019198 oils Nutrition 0.000 description 14
- 150000003839 salts Chemical class 0.000 description 14
- 239000003599 detergent Substances 0.000 description 12
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 11
- 238000004851 dishwashing Methods 0.000 description 10
- 239000000243 solution Substances 0.000 description 9
- 238000005187 foaming Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 238000007046 ethoxylation reaction Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- LGGDNCSJIIYYPQ-UHFFFAOYSA-N 2-propylhexyl hydrogen sulfate Chemical compound CCCCC(CCC)COS(=O)(=O)O LGGDNCSJIIYYPQ-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 5
- OGMZKEIKYQBMGV-UHFFFAOYSA-N 2-butylheptyl hydrogen sulfate Chemical compound CCCCCC(CCCC)COS(=O)(=O)O OGMZKEIKYQBMGV-UHFFFAOYSA-N 0.000 description 5
- MHGOKSLTIUHUBF-UHFFFAOYSA-N 2-ethylhexyl sulfate Chemical compound CCCCC(CC)COS(O)(=O)=O MHGOKSLTIUHUBF-UHFFFAOYSA-N 0.000 description 5
- JMZXMGPMDJQBBW-UHFFFAOYSA-N 2-ethylpentyl hydrogen sulfate Chemical compound CCCC(CC)COS(=O)(=O)O JMZXMGPMDJQBBW-UHFFFAOYSA-N 0.000 description 5
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000006260 foam Substances 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 239000008399 tap water Substances 0.000 description 5
- 235000020679 tap water Nutrition 0.000 description 5
- NYMDCNMMCYRUHJ-UHFFFAOYSA-N 2-methylhexyl hydrogen sulfate Chemical compound CCCCC(C)COS(O)(=O)=O NYMDCNMMCYRUHJ-UHFFFAOYSA-N 0.000 description 4
- WYKCDPOYDNPTDY-UHFFFAOYSA-N 2-propylpentyl hydrogen sulfate Chemical compound CCCC(CCC)COS(O)(=O)=O WYKCDPOYDNPTDY-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 125000003545 alkoxy group Chemical group 0.000 description 4
- 150000007942 carboxylates Chemical class 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 229940067739 octyl sulfate Drugs 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- UZZYXUGECOQHPU-UHFFFAOYSA-N sulfuric acid monooctyl ester Natural products CCCCCCCCOS(O)(=O)=O UZZYXUGECOQHPU-UHFFFAOYSA-N 0.000 description 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 3
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 3
- GZMAAYIALGURDQ-UHFFFAOYSA-N 2-(2-hexoxyethoxy)ethanol Chemical compound CCCCCCOCCOCCO GZMAAYIALGURDQ-UHFFFAOYSA-N 0.000 description 3
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 description 3
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 3
- MHGOKSLTIUHUBF-UHFFFAOYSA-M 2-ethylhexyl sulfate(1-) Chemical compound CCCCC(CC)COS([O-])(=O)=O MHGOKSLTIUHUBF-UHFFFAOYSA-M 0.000 description 3
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 description 3
- OGHBROIESUOXPS-UHFFFAOYSA-N 2-methylheptyl hydrogen sulfate Chemical compound CCCCCC(C)COS(=O)(=O)O OGHBROIESUOXPS-UHFFFAOYSA-N 0.000 description 3
- JHFUZSMOUCNESD-UHFFFAOYSA-N 2-methylpentyl hydrogen sulfate Chemical compound CCCC(C)COS(O)(=O)=O JHFUZSMOUCNESD-UHFFFAOYSA-N 0.000 description 3
- AZCDQDTUJXPCQV-UHFFFAOYSA-N 2-pentylheptyl hydrogen sulfate Chemical compound CCCCCC(CCCCC)COS(O)(=O)=O AZCDQDTUJXPCQV-UHFFFAOYSA-N 0.000 description 3
- QUKARJXWKHASOI-UHFFFAOYSA-N 3-ethylhexyl hydrogen sulfate Chemical compound CCCC(CC)CCOS(=O)(=O)O QUKARJXWKHASOI-UHFFFAOYSA-N 0.000 description 3
- KKJHMEFPSGZBID-UHFFFAOYSA-N 3-methylhexyl hydrogen sulfate Chemical compound CCCC(C)CCOS(=O)(=O)O KKJHMEFPSGZBID-UHFFFAOYSA-N 0.000 description 3
- YODQEQPJFXCNCG-UHFFFAOYSA-N 3-methylpentyl hydrogen sulfate Chemical compound CCC(C)CCOS(O)(=O)=O YODQEQPJFXCNCG-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- OQKPJZKUIATTMD-UHFFFAOYSA-N CCCCCC(CC)COS(O)(=O)=O Chemical compound CCCCCC(CC)COS(O)(=O)=O OQKPJZKUIATTMD-UHFFFAOYSA-N 0.000 description 3
- HDJRJUZJPOXXGL-UHFFFAOYSA-N CCCCCC(CCC)COS(O)(=O)=O Chemical compound CCCCCC(CCC)COS(O)(=O)=O HDJRJUZJPOXXGL-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- 235000010493 xanthan gum Nutrition 0.000 description 3
- 239000000230 xanthan gum Substances 0.000 description 3
- 229940082509 xanthan gum Drugs 0.000 description 3
- MWGRRMQNSQNFID-UHFFFAOYSA-N 1-(2-methylpropoxy)propan-2-ol Chemical compound CC(C)COCC(C)O MWGRRMQNSQNFID-UHFFFAOYSA-N 0.000 description 2
- BWPAALSUQKGDBR-UHFFFAOYSA-N 1-hexoxypropan-2-ol Chemical compound CCCCCCOCC(C)O BWPAALSUQKGDBR-UHFFFAOYSA-N 0.000 description 2
- MQVBKQCAXKLACB-UHFFFAOYSA-N 1-pentoxypropan-2-ol Chemical compound CCCCCOCC(C)O MQVBKQCAXKLACB-UHFFFAOYSA-N 0.000 description 2
- FENFUOGYJVOCRY-UHFFFAOYSA-N 1-propoxypropan-2-ol Chemical compound CCCOCC(C)O FENFUOGYJVOCRY-UHFFFAOYSA-N 0.000 description 2
- TTWHRLANJSQOAT-UHFFFAOYSA-N 2-(2-hexoxypropoxy)propan-1-ol Chemical compound CCCCCCOC(C)COC(C)CO TTWHRLANJSQOAT-UHFFFAOYSA-N 0.000 description 2
- QRLZJWCPSKLFKP-UHFFFAOYSA-N 2-(2-pentoxypropoxy)propan-1-ol Chemical compound CCCCCOC(C)COC(C)CO QRLZJWCPSKLFKP-UHFFFAOYSA-N 0.000 description 2
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 description 2
- WFMPPNQMYUMGFY-UHFFFAOYSA-N 2-(4-methylpentoxy)ethanol Chemical compound CC(C)CCCOCCO WFMPPNQMYUMGFY-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- RGICCULPCWNRAB-UHFFFAOYSA-N 2-[2-(2-hexoxyethoxy)ethoxy]ethanol Chemical compound CCCCCCOCCOCCOCCO RGICCULPCWNRAB-UHFFFAOYSA-N 0.000 description 2
- LYJYPLBZBGLWJW-UHFFFAOYSA-N 2-[2-(2-methylpropoxy)propoxy]propan-1-ol Chemical compound CC(C)COC(C)COC(C)CO LYJYPLBZBGLWJW-UHFFFAOYSA-N 0.000 description 2
- RPIUXDISLQFSAP-UHFFFAOYSA-N 2-[2-(2-pentoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCCOC(C)COC(C)COC(C)CO RPIUXDISLQFSAP-UHFFFAOYSA-N 0.000 description 2
- BYCBBQDYILWALL-UHFFFAOYSA-N 2-[2-(3-methylbutoxy)propoxy]propan-1-ol Chemical compound CC(C)CCOC(C)COC(C)CO BYCBBQDYILWALL-UHFFFAOYSA-N 0.000 description 2
- VAUZVHMWNUHESY-UHFFFAOYSA-N 2-[2-[2-(2-methylpropoxy)propoxy]propoxy]propan-1-ol Chemical compound CC(C)COC(C)COC(C)COC(C)CO VAUZVHMWNUHESY-UHFFFAOYSA-N 0.000 description 2
- LQPRGDBTQROLLJ-UHFFFAOYSA-N 2-[2-[2-(3-methylbutoxy)propoxy]propoxy]propan-1-ol Chemical compound CC(C)CCOC(C)COC(C)COC(C)CO LQPRGDBTQROLLJ-UHFFFAOYSA-N 0.000 description 2
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 2
- LFUZYDIVPWPMEY-UHFFFAOYSA-N 2-butylhexyl hydrogen sulfate Chemical compound CCCCC(CCCC)COS(O)(=O)=O LFUZYDIVPWPMEY-UHFFFAOYSA-N 0.000 description 2
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 2
- BNEHLDVYGUHBEC-UHFFFAOYSA-N 2-pentyloctyl hydrogen sulfate Chemical compound CCCCCCC(CCCCC)COS(=O)(=O)O BNEHLDVYGUHBEC-UHFFFAOYSA-N 0.000 description 2
- WSSCXWYOZFNUEE-UHFFFAOYSA-N 3-ethylheptyl hydrogen sulfate Chemical compound CCCCC(CC)CCOS(=O)(=O)O WSSCXWYOZFNUEE-UHFFFAOYSA-N 0.000 description 2
- WJPHIZMTXNBRTQ-UHFFFAOYSA-N 3-ethylpentyl hydrogen sulfate Chemical compound CCC(CC)CCOS(O)(=O)=O WJPHIZMTXNBRTQ-UHFFFAOYSA-N 0.000 description 2
- LCCQOBVYRYCTJW-UHFFFAOYSA-N 3-propyloctyl hydrogen sulfate Chemical compound CCCCCC(CCC)CCOS(=O)(=O)O LCCQOBVYRYCTJW-UHFFFAOYSA-N 0.000 description 2
- SATHPVQTSSUFFW-UHFFFAOYSA-N 4-[6-[(3,5-dihydroxy-4-methoxyoxan-2-yl)oxymethyl]-3,5-dihydroxy-4-methoxyoxan-2-yl]oxy-2-(hydroxymethyl)-6-methyloxane-3,5-diol Chemical compound OC1C(OC)C(O)COC1OCC1C(O)C(OC)C(O)C(OC2C(C(CO)OC(C)C2O)O)O1 SATHPVQTSSUFFW-UHFFFAOYSA-N 0.000 description 2
- BCEQKAQCUWUNML-UHFFFAOYSA-N 4-hydroxybenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC=C(O)C(C(O)=O)=C1 BCEQKAQCUWUNML-UHFFFAOYSA-N 0.000 description 2
- OMYMWDFOOFWXCW-UHFFFAOYSA-N 4-methyl-1-(4-methylpentoxy)pentane Chemical compound CC(C)CCCOCCCC(C)C OMYMWDFOOFWXCW-UHFFFAOYSA-N 0.000 description 2
- 239000001904 Arabinogalactan Substances 0.000 description 2
- 229920000189 Arabinogalactan Polymers 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 244000205754 Colocasia esculenta Species 0.000 description 2
- 235000006481 Colocasia esculenta Nutrition 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 235000019312 arabinogalactan Nutrition 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 238000001595 flow curve Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- IPYWELFAZHBWIY-UHFFFAOYSA-N heptan-2-yl hydrogen sulfate Chemical compound CCCCCC(C)OS(O)(=O)=O IPYWELFAZHBWIY-UHFFFAOYSA-N 0.000 description 2
- PEDMDDPAVNTCLH-UHFFFAOYSA-N heptan-3-yl hydrogen sulfate Chemical compound CCCCC(CC)OS(O)(=O)=O PEDMDDPAVNTCLH-UHFFFAOYSA-N 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- LFLCNBLTOXIVOQ-UHFFFAOYSA-N hydron;octan-3-yl sulfate Chemical compound CCCCCC(CC)OS(O)(=O)=O LFLCNBLTOXIVOQ-UHFFFAOYSA-N 0.000 description 2
- 125000001165 hydrophobic group Chemical group 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- OAYBNDVKGPIONW-UHFFFAOYSA-N nonan-4-yl hydrogen sulfate Chemical compound S(OC(CCC)CCCCC)(O)(=O)=O OAYBNDVKGPIONW-UHFFFAOYSA-N 0.000 description 2
- NSTCTYHTRJDLSF-UHFFFAOYSA-N octan-2-yl hydrogen sulfate Chemical compound CCCCCCC(C)OS(O)(=O)=O NSTCTYHTRJDLSF-UHFFFAOYSA-N 0.000 description 2
- VFONGPORGRTFEM-UHFFFAOYSA-N octan-4-yl hydrogen sulfate Chemical compound CCCCC(CCC)OS(O)(=O)=O VFONGPORGRTFEM-UHFFFAOYSA-N 0.000 description 2
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 2
- 239000004006 olive oil Substances 0.000 description 2
- 235000008390 olive oil Nutrition 0.000 description 2
- 230000002085 persistent effect Effects 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- ACPZHTKFHKYNGA-UHFFFAOYSA-N undecan-6-yl hydrogen sulfate Chemical compound CCCCCC(OS(O)(=O)=O)CCCCC ACPZHTKFHKYNGA-UHFFFAOYSA-N 0.000 description 2
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- PESIOFOMBVLTPT-UHFFFAOYSA-N COCC(OCC(OCC(C)OCCCCC)C)C Chemical compound COCC(OCC(OCC(C)OCCCCC)C)C PESIOFOMBVLTPT-UHFFFAOYSA-N 0.000 description 1
- KPYFXOXAXYRXEU-UHFFFAOYSA-N COCCOCCOCCCC(C)C Chemical compound COCCOCCOCCCC(C)C KPYFXOXAXYRXEU-UHFFFAOYSA-N 0.000 description 1
- JZCDWLWHPFQNGA-UHFFFAOYSA-N COCCOCCOCCOCCCC(C)C Chemical compound COCCOCCOCCOCCCC(C)C JZCDWLWHPFQNGA-UHFFFAOYSA-N 0.000 description 1
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- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
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- 239000004471 Glycine Substances 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
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- 229920002907 Guar gum Polymers 0.000 description 1
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- JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical compound OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 1
- XHFWUECSNJWBJU-UHFFFAOYSA-N N-(docosanoyl)ethanolamine Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)NCCO XHFWUECSNJWBJU-UHFFFAOYSA-N 0.000 description 1
- 240000007817 Olea europaea Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 102100030093 Probable ATP-dependent RNA helicase DHX37 Human genes 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Chemical class 0.000 description 1
- 241000934878 Sterculia Species 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000002386 air freshener Substances 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229960004203 carnitine Drugs 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
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- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000006165 cyclic alkyl group Chemical group 0.000 description 1
- KAELECMSVUTZTD-UHFFFAOYSA-N decan-4-yl hydrogen sulfate Chemical compound CCCCCCC(CCC)OS(O)(=O)=O KAELECMSVUTZTD-UHFFFAOYSA-N 0.000 description 1
- FKIFMTDDBRLCRS-UHFFFAOYSA-N decan-5-yl hydrogen sulfate Chemical compound CCCCCC(OS(O)(=O)=O)CCCC FKIFMTDDBRLCRS-UHFFFAOYSA-N 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- BZCOSCNPHJNQBP-OWOJBTEDSA-N dihydroxyfumaric acid Chemical compound OC(=O)C(\O)=C(/O)C(O)=O BZCOSCNPHJNQBP-OWOJBTEDSA-N 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- YBRJOFRRFFDCEO-UHFFFAOYSA-N dodecan-6-yl hydrogen sulfate Chemical compound CCCCCCC(OS(O)(=O)=O)CCCCC YBRJOFRRFFDCEO-UHFFFAOYSA-N 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-M dodecyl sulfate Chemical compound CCCCCCCCCCCCOS([O-])(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-M 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229920000591 gum Polymers 0.000 description 1
- OXRNUVLSQFDCAE-UHFFFAOYSA-N heptan-4-yl hydrogen sulfate Chemical compound CCCC(CCC)OS(O)(=O)=O OXRNUVLSQFDCAE-UHFFFAOYSA-N 0.000 description 1
- HCMQBEUVAMJCAY-UHFFFAOYSA-N hexan-2-yl hydrogen sulfate Chemical compound CCCCC(C)OS(O)(=O)=O HCMQBEUVAMJCAY-UHFFFAOYSA-N 0.000 description 1
- GAXDOQHCRWDOFF-UHFFFAOYSA-N hexan-3-yl hydrogen sulfate Chemical compound CCCC(CC)OS(O)(=O)=O GAXDOQHCRWDOFF-UHFFFAOYSA-N 0.000 description 1
- IDUWTCGPAPTSFB-UHFFFAOYSA-N hexyl hydrogen sulfate Chemical compound CCCCCCOS(O)(=O)=O IDUWTCGPAPTSFB-UHFFFAOYSA-N 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 229940116335 lauramide Drugs 0.000 description 1
- 229940094506 lauryl betaine Drugs 0.000 description 1
- IZWSFJTYBVKZNK-UHFFFAOYSA-N lauryl sulfobetaine Chemical compound CCCCCCCCCCCC[N+](C)(C)CCCS([O-])(=O)=O IZWSFJTYBVKZNK-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229940098895 maleic acid Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QEALYLRSRQDCRA-UHFFFAOYSA-N myristamide Chemical compound CCCCCCCCCCCCCC(N)=O QEALYLRSRQDCRA-UHFFFAOYSA-N 0.000 description 1
- HTBSGBIWKJSAGD-UHFFFAOYSA-N n,n-dimethylpropan-1-amine oxide Chemical class CCC[N+](C)(C)[O-] HTBSGBIWKJSAGD-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- ZNJWLEVJPURVCW-UHFFFAOYSA-N nonan-2-yl hydrogen sulfate Chemical compound CCCCCCCC(C)OS(O)(=O)=O ZNJWLEVJPURVCW-UHFFFAOYSA-N 0.000 description 1
- CUPBXUHYSKADLO-UHFFFAOYSA-N nonan-5-yl hydrogen sulfate Chemical compound CCCCC(OS(O)(=O)=O)CCCC CUPBXUHYSKADLO-UHFFFAOYSA-N 0.000 description 1
- WHSXTWFYRGOBGO-UHFFFAOYSA-N o-cresotic acid Natural products CC1=CC=CC(C(O)=O)=C1O WHSXTWFYRGOBGO-UHFFFAOYSA-N 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- GWOHECWKODFSHY-UHFFFAOYSA-N pentan-2-yl hydrogen sulfate Chemical compound CCCC(C)OS(O)(=O)=O GWOHECWKODFSHY-UHFFFAOYSA-N 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-K pentetate(3-) Chemical compound OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O QPCDCPDFJACHGM-UHFFFAOYSA-K 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical class NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Chemical class 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical compound CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- HKBPKZKQWGHQFA-UHFFFAOYSA-N tridecan-7-yl hydrogen sulfate Chemical compound CCCCCCC(OS(O)(=O)=O)CCCCCC HKBPKZKQWGHQFA-UHFFFAOYSA-N 0.000 description 1
- OLMHEIZIBLXNIJ-UHFFFAOYSA-N undecan-5-yl hydrogen sulfate Chemical compound S(=O)(=O)(O)OC(CCCC)CCCCCC OLMHEIZIBLXNIJ-UHFFFAOYSA-N 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/003—Cleaning involving contact with foam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0043—For use with aerosol devices
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/046—Insoluble free body dispenser
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
Description
i)組成物の少なくとも5重量%、好ましくは6重量%〜15重量%の界面活性剤系であって、
ii)両性界面活性剤、双極性界面活性剤、及びその混合物から選択される、界面活性剤系の60重量%〜90重量%の主界面活性剤であって、好ましくはアミンオキシド、ベタイン、及びその混合物から選択される主界面活性剤、及び
iii)非イオン性界面活性剤、アニオン性界面活性剤、及びその混合物から選択される、界面活性剤系の10〜40重量%の補助界面活性剤、を含む界面活性剤系と、
iv)式1:R1O(R2O)nR3、及び式2:R4O(R5O)nR6、のグリコールエーテル、及びその組み合わせからなる群から選択されるグリコールエーテル溶剤とを含み、
式中、
R1は直鎖若しくは分岐状C4、C5、若しくはC6アルキル又は置換若しくは非置換フェニルであり、R2はエチル又はイソプロピルであり、R3は水素又はメチルであり、nは1、2、又は3であり、
R4はn−プロピル又はイソプロピルであり、R5はイソプロピルであり、R6は水素又はメチルであり、nは1、2、又は3であり。
i)組成物の約4〜約10重量%、好ましくは約5〜約8重量%のアミンオキシド界面活性剤と、
ii)組成物の約1〜約5重量%の非イオン性界面活性剤と、
iii)組成物の3重量%〜8重量%、好ましくは約4〜約7重量%のグリコールエーテル溶剤、好ましくはジプロピレングリコールn−ブチルエーテルと、を含む。
a)任意選択的に、汚れた食器を事前に湿らせる工程と、
b)洗浄組成物を汚れた食器に噴射する工程と、
c)任意選択的に、汚れた食器に水を一定時間加える工程と、
d)任意選択的に食器をこすり洗いする工程と、
e)食器をすすぐ工程と、を有す方法が提供される。
洗剤組成物は好ましくは手洗い用食器洗浄組成物であり、好ましくは液状である。
予備アルカリ度=0.1NのHCLの容積(mL)×0.1(等量/L)×NaOHの等量重量(g/等量)×10
洗浄組成物は、好ましくは約5重量%〜約15重量%、より好ましくは約6重量%〜約14重量%、特に好ましくは約7重量%〜約12重量%の界面活性剤系を含む。界面活性剤系は、両性界面活性剤、双極性界面活性剤、及びその組み合わせからなる群から選択される主界面活性剤を含み、両性界面活性剤は好ましくはアミンオキシド界面活性剤を含む。界面活性剤系は、補助界面活性剤を含む。補助界面活性剤は好ましくは非イオン性界面活性剤、アニオン性界面活性剤系、及びその混合物からなる群から選択される。非イオン性界面活性剤が好ましい。
主界面活性剤は、両性界面活性剤、双極性界面活性剤、及びその組み合わせからなる群から選択される。
好ましくは、両性界面活性剤はアミンオキシドである。好ましいアミンオキシドは、アルキルジメチルアミンオキシド又はアルキルアミドプロピルジメチルアミンオキシド、より好ましくはアルキルジメチルアミンオキシド、及び特にココジメチルアミンオキシドである。アミンオキシドは、直鎖又は中等度分岐状アルキル基を有し得る。典型的な直鎖アミンオキシドとしては、C8〜18アルキル部分である1つのR1と、C1〜3アルキル基及びC1〜3ヒドロキシアルキル基からなる群から選択される2つのR2及びR3部分と、を含有する水溶性アミンオキシドが挙げられる。好ましくは、アミンオキシドは、式:R1−N(R2)(R3)O(式中、R1はC8〜18アルキルであり、R2及びR3はメチル、エチル、プロピル、イソプロピル、2−ヒドロキシエチル、2−ヒドロキシプロピル、及び3−ヒドロキシプロピルからなる群から選択される)により特徴付けられる。直鎖アミンオキシド系界面活性剤としては、具体的には、直鎖C10〜C18アルキルジメチルアミンオキシド及び直鎖C8〜C12アルコキシエチルジヒドロキシエチルアミンオキシドを挙げることができる。好ましいアミンオキシドとしては、直鎖C10、直鎖C10〜C12、及び直鎖C12〜C14アルキルジメチルアミンオキシドが挙げられる。本明細書で使用するとき、「中鎖分岐状(mid-branched)」とは、アミンオキシドが、炭素原子n1個を有する1つのアルキル部分を有し、このアルキル部分上の1つのアルキル分岐が炭素原子n2個を有することを意味する。アルキル分岐は、アルキル部分の窒素のα炭素に位置する。アミンオキシドにおけるこのタイプの分岐は、当該技術分野において、内部アミンオキシドとしても知られている。n1とn2の合計は、10〜24個の炭素原子、好ましくは12〜20個、より好ましくは10〜16個である。1つのアルキル部分と1つのアルキル分岐とが対称となるように、1つのアルキル部分の炭素原子数(n1)は、1つのアルキル分岐の炭素原子数(n2)とおよそ同じであるべきである。本明細書で使用するとき、「対称」は、本明細書で用いられる中分岐状アミンオキシドの少なくとも50重量%、より好ましくは少なくとも75重量%〜100重量%が、|n1〜n2|が5以下、好ましくは4、最も好ましくは0〜4の炭素原子であることを意味する。
他の好適な界面活性剤としては、好ましくはアルキルベタイン、アルキルアミドベタイン、アミダゾリニウムベタイン、スルホベタイン(INCIスルタイン)並びにホスホベタインなどのベタインのような双性イオン性界面活性剤が挙げられ、好ましくは次の式(I)に合致する。
R1−[CO−X(CH2)n]x−N+(R2)(R3)−(CH2)m−[CH(OH)−CH2]y−Y−
(I)
式中、
R1は飽和又は不飽和C6〜22アルキル残基であり、好ましくはC8〜18アルキル残基、特に飽和C10〜16アルキル残基、例えば、飽和C12〜14アルキル残基であり、
Xは、NH、NR4(C1〜4アルキル残基R4を有する)、O、又はSであり;
nは、1〜10の数、好ましくは2〜5、特に3であり、
xは0又は1、好ましくは1であり、
R2、R3は独立して、ヒドロキシエチル、好ましくはメチルなどの、ヒドロキシ置換される可能性のあるC1〜4アルキル残基であり、
mは1〜4の数、特に1、2又は3であり、
yは0又は1であり、
Yは、COO、SO3、OPO(OR5)O又はP(O)(OR5)Oであり、R5は水素原子H又はC1〜4アルキル残基である。
R1−N+(CH3)2−CH2COO−(Ia)
R1−CO−NH(CH2)3−N+(CH3)2−CH2COO−(Ib)
R1−N+(CH3)2−CH2CH(OH)CH2SO3−(Ic)
R1−CO−NH−(CH2)3−N+(CH3)2−CH2CH(OH)CH2SO3−(Id)、式中、R11は、式Iと同じ意味である。特に好ましいベタインは、カルボベタイン[式中、Y−=COO−]であり、特に式(Ia)及び(Ib)のカルボベタインであり、式(Ib)のアルキルアミドベタインが最も好ましい。
補助界面活性剤は、非イオン性界面活性剤、アニオン性界面活性剤、及びその混合物からなる群から選択される。
好適な非イオン性界面活性剤としては、脂肪族アルコールと1〜25モルのエチレンオキシドとの縮合生成物が挙げられる。脂肪族アルコールのアルキル鎖は、直鎖又は分岐鎖状、第1級又は第2級でよく、一般的に8〜22個の炭素原子を含有する。特に好ましいのは、10〜18個の炭素原子、好ましくは10〜15個の炭素原子を含有するアルキル基を有するアルコールと、アルコール1モル当たり2〜18モル、好ましくは2〜15モル、より好ましくは5〜12モルのエチレンオキシドとの縮合生成物である。極めて好ましい非イオン性界面活性剤は、ゲルベアルコールと、アルコール1モル当たり2〜18モル、好ましくは2〜15モル、より好ましくは5〜12モルのエチレンオキシドとの縮合生成物である。
サルフェートアニオン性界面活性剤は好ましくはアルコキシ化されたものであり、より好ましくは平均アルコキシ化度が約2〜約5、最も好ましくは平均アルコキシ化度が約3のアルコキシ化サルフェートアニオン性界面活性剤である。好ましくは、アルコキシ基はエトキシである。サルフェートアニオン性界面活性剤がサルフェートアニオン性界面活性剤の混合物であるとき、アルコキシ化度は混合物の全ての組成物の重量平均アルコキシ化度(重量平均アルコキシ化度)である。重量平均アルコキシ化度の計算において、アルコキシ化された基を有さない硫酸化アニオン性界面活性剤組成物の重量も含める必要がある。
式中、x1、x2、...は、混合物の各サルフェートアニオン性界面活性剤のグラム単位の重量であり、アルコキシ化度は、各サルフェートアニオン性界面活性剤のアルコキシ基の数である。
式中、x1、x2、...は、本発明の洗剤のアニオン性界面活性剤のための出発原料として使用したアルコールの全アルコール混合物中の各アルコールのグラム単位の重量である。重量平均分岐化度の計算において、分岐基を有さないアニオン性界面活性剤組成物の重量も含める必要がある。
この種のアニオン性界面活性剤は、しつこい油汚れに対する洗浄を実現することが確認されている。更に、アミンオキシド又はベタイン、特にアミンオキシド界面活性剤と組み合わせると優良な発泡性を示す。具体的には噴射直後の発泡が実現される。
本発明の組成物は、式1、式2のグリコールエーテルから選択されるグリコールエーテル溶剤を含む。
式1=R1O(R2O)nR3
式中、
R1は直鎖又は分岐状C4、C5又はC6アルキル、置換又は非置換フェニル、好ましくはn−ブチルであり(ここでは置換フェニルの1つとしてベンジルが挙げられる)、
R2はエチル又はイソプロピル、好ましくはイソプロピルであり、
R3は、水素又はメチルから選択され、好ましくは水素であり、
nは1、2、又は3、好ましくは1又は2である。
式2=R4O(R5O)nR6
式中、
R4はn−プロピル又はイソプロピル、好ましくはn−プロピルであり、
R5はイソプロピルであり、
R6は水素又はメチル、好ましくは水素であり、
nは1、2、又は3、好ましくは1又は2である。
本明細書の組成物は、キレート剤を組成物の総量の0.1重量%〜10%重量%、好ましくは0.2重量%〜5重量%、より好ましくは0.2重量%〜3重量%、最も好ましくは0.5重量%から1.5重量%の濃度で任意で更に含んでもよい。
本明細書の組成物は、ビルダー、好ましくはカルボン酸ビルダーを含んでもよい。本明細書で有用なカルボン酸塩としては、C1〜6の直鎖状の酸、又は少なくとも3個の炭素を含有する環状の酸が挙げられる。カルボン酸又はその塩の、直鎖若しくは環状炭素含有鎖は、水酸基、エステル基、エーテル基、1〜6個の、より好ましくは1〜4個の炭素原子を有する脂肪族基、及びこれらの組み合わせからなる群から選択される置換基で、置換されてもよい。
本発明の組成物は更に、レオロジー調整剤を含んでもよい。これにより製品が擬塑性流動が可能となる。好ましくは、レオロジー調整剤は、非結晶質ポリマーレオロジー調整剤である。ポリマーレオロジー調整剤は合成されたものあっても、自然由来のポリマーであってもよい。
ここでの組成物は、多数の任意成分を含んでもよい。当該成分としては、好ましくは塩化ナトリウムである無機塩、C2〜C4アルコール、C2〜C4ポリオール、ポリアルキレングリコール、ヒドロトロープ、及びこれらの組み合わせから選択される、レオロジー調整剤を含んでもよい。組成物は更に、pH調整及び/又は緩衝剤を含んでもよい。具体的には水酸化ナトリウムやモノエタノールアミンを含むアルカノールアミンや、重炭酸無機塩等である。組成物は、保存剤、UV安定剤、抗酸化剤、芳香剤、着色剤、及びその混合物から選択されるその他少量成分を更に含んでもよい。
製品の流動曲線を、レオメーター(TAインスツルメント製。型番DHR1))、ペルチェ同心円筒温度測定システム(TAインスツルメント製)、二重ギャップカップとローター(TAインスツルメント製)を使用して測定した。当該流動曲線処理は、調整工程と、20℃でのフローランピング工程とを含む。調整工程は、10s−1の剪断速度での30秒間の前剪断工程と、その後の120秒間の剪断を行わない平衡時間とを含む。フローランピング工程は、300秒間で対数剪断速度を0.001s−1から10000s−1まで上昇させることを含む。データフィルターを、使用器具の推奨される、20μNm(最小トルク値)に設定する。
スプレーディスペンサは、本発明の組成物を収容する筐体と、噴射手段とを有する。適切なディスペンサとしては、ハンドポンプ(「トリガー式」とも称する)装置、加圧缶装置、静電スプレー装置等が挙げられる。好ましくは、スプレーディスペンサは非加圧で、噴射手段はトリガー式噴射型であることが好ましい。好ましくは、スプレーディスペンサは非加圧で、噴射手段はトリガー式噴射型であることが好ましい。
Claims (17)
- スプレーディスペンサと、前記スプレーディスペンサに収納された噴射に適した洗浄組成物と、を有する洗浄製品であって、前記組成物は、
i)前記組成物の少なくとも5重量%の界面活性剤系であって、
ii)両性界面活性剤である、前記界面活性剤系の60重量%〜90重量%の主界面活性剤、及び
iii)非イオン性界面活性剤である、前記界面活性剤系の10〜40重量%の補助界面活性剤、を含み、前記両性界面活性剤はアミンオキシドであり、前記非イオン性界面活性剤は脂肪族アルコールとエチレンオキシドとの縮合生成物である、界面活性剤系と、
iv)式1:R1O(R2O)nR3、及び
式2:R4O(R5O)nR6、のグリコールエーテル、及びその組み合わせからなる群から選択されるグリコールエーテル溶剤と、を含み、
式中、
R1は直鎖又は分岐状C4、C5、又はC6アルキル或いは置換又は非置換フェニルであり、R2はエチレン又はイソプロピレンであり、R3は水素又はメチルであり、nは2、又は3であり、
R4はn−プロピル又はイソプロピルであり、R5はイソプロピレンであり、R6は水素又はメチルであり、nは2、又は3であり、
前記界面活性剤系と前記グリコールエーテル溶剤との重量比が5:1〜1:1である、製品。 - 前記主界面活性剤と前記補助界面活性剤とは、重量比が10:1〜2:1で存在する、請求項1に記載の製品。
- 前記組成物は、前記グリコールエーテル溶剤を前記組成物の1重量%〜7重量%で含む、請求項1又は2に記載の製品。
- 前記グリコールエーテル溶剤は、ジプロピレングリコールn−ブチルエーテルである、請求項1〜3のいずれか一項に記載の製品。
- 前記組成物は、20℃の蒸留水中にて10%溶液中で測定された場合、pHが8超であり、pH10の組成物100mL当たりのNaOHのグラム数で表現される予備アルカリ度が0.1〜1である、請求項1〜4のいずれか一項に記載の製品。
- 前記組成物は、pH10の組成物100mL当たりのNaOHのグラム数で表現される予備アルカリ度が0.1〜0.5である、請求項1〜5のいずれか一項に記載の製品。
- 前記組成物は、
i)前記組成物の4〜10重量%のアミンオキシド界面活性剤と、
ii)前記組成物の1〜5重量%の非イオン性界面活性剤と、
iii)前記組成物の3重量%〜8重量%のグリコールエーテル溶剤と、を含む、請求項1〜6のいずれか一項に記載の製品。 - 前記グリコールエーテルはジプロピレングリコールn−ブチルエーテルである、請求項7に記載の製品。
- 前記組成物はキレート剤を更に含む、請求項1〜8のいずれか一項に記載の製品。
- 前記組成物はビルダーを更に含む、請求項1〜9のいずれか一項に記載の製品。
- 前記組成物は重炭酸塩を更に含む、請求項1〜10のいずれか一項に記載の製品。
- 前記組成物はアルカノールアミンを更に含む、請求項1〜11のいずれか一項に記載の製品。
- 前記組成物は、C2〜C4アルコール、C2〜C4ポリオール、ポリアルキレングリコール、及びその混合物からなる群から選択される更なる溶剤を更に含む、請求項1〜12のいずれか一項に記載の製品。
- 前記組成物は、本明細書に記載の方法で20℃において測定した場合に、1〜20mPa sの高剪断粘度(10,000s−1)を有する、請求項1〜13のいずれか一項に記載の製品。
- 前記組成物は、本明細書に記載の方法で20℃において測定した場合、低剪断(100s−1)の高剪断粘度に対する比が、10:1〜1.5:1である、請求項14に記載の製品。
- 前記組成物はレオロジー調整剤を含む、請求項1〜15のいずれか一項に記載の製品。
- a)任意選択的に、前記汚れた食器を事前に湿らせる工程と、
b)前記洗浄組成物を前記汚れた食器に噴射する工程と、
c)任意選択的に、前記汚れた食器に水を一定時間加える工程と、
d)任意選択的に前記食器をこすり洗いする工程と、
e)前記食器をすすぐ工程と、を含む、請求項1〜16のいずれか一項に記載の製品を使用して、汚れた食器を洗う方法。
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