JP6820318B2 - 微結晶性セルロース熱分解生成物吸着剤並びにこれを作製及び使用する方法 - Google Patents
微結晶性セルロース熱分解生成物吸着剤並びにこれを作製及び使用する方法 Download PDFInfo
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- JP6820318B2 JP6820318B2 JP2018509847A JP2018509847A JP6820318B2 JP 6820318 B2 JP6820318 B2 JP 6820318B2 JP 2018509847 A JP2018509847 A JP 2018509847A JP 2018509847 A JP2018509847 A JP 2018509847A JP 6820318 B2 JP6820318 B2 JP 6820318B2
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
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Description
「MICROCRYSTALLINE CELLULOSE PYROLYZATE ADSORBENT AND GAS SUPPLY PACKAGES COMPRISING SAME」について2016年8月22日にEdward A.Sturmらの名前で出願された米国特許仮出願第62/208663号の米国特許法第119条の利益が本明細書により主張される。米国特許仮出願第62/208663号の開示は、これにより全ての目的のために出典明示によりその全文が本明細書に援用される。
天然トウモロコシデンプンの供給を得、この供給物から採取したデンプンのサンプルを秤量し、実験室の空気炉で195℃に加熱して、そのような前駆体材料を乾燥させ、安定化させた。次に、乾燥したデンプンを600℃の管炉内で窒素流下で熱分解した。冷却後、トウモロコシデンプン由来の炭素熱分解生成物のN2 BET表面積を、Micromeritics ASAP 2420 Porosimeterを使用して、578m2/gと測定した。
工業用トウモロコシデンプン由来のマルトデキストリンの供給を得た。マルトデキストリンのサンプルを秤量し、実験室の空気炉で加熱して、235℃の温度でサンプルを乾燥させ、安定化させた。乾燥したマルトデキストリンを、次に600℃の温度の管路中、窒素気流下で熱分解した。冷却後、Micromeritics ASAP 2420 Porosimeterを使用して、トウモロコシデンプン由来のマルトデキストリン炭素をN2 BET表面積について分析した。465m2/グラムの表面積が決定された。
実施例2で考察されるトウモロコシデンプン由来のマルトデキストリンと混合した、実施例1で考察される天然のトウモロコシデンプンを様々な比で組み合わせる円筒形のタブレットを、28から338MPa(〜4050psiから49,000psi)の間の圧縮条件下で形成して、プリフォームタブレットを得た。タブレットを秤量し、測定し、いくつかの方法で強度及びその他の重要な物理的特性について評価した。
デンプン由来の炭素のサンプルを、三フッ化ホウ素吸着容量の試験のために数個選択した。この大型の平らな分子は微孔性炭素においてスリット状の多孔性の良好な評価を提供するためである。全てのデンプン由来の炭素サンプルを、600℃の温度の管路中、窒素気流下で熱分解した。次に、各々を600℃から1000℃の間の温度でCO2中で酸化的に活性化させ、表面積を増加させて1000平方メートル/グラムよりも大きくした。
セルロース系並びに非セルロース系前駆体材料を吸着剤として有用な炭素熱分解生成物材料の形成について評価した。微結晶性セルロースは、前駆体材料として糖類、デンプン、キチン、キトサン、ペクチン、及びマルトデキストリンと共に評価した。この試みで考えられる微結晶性セルロース材料には、Acros Organics(サーモフィッシャーサイエンティフィック、http://www.acros.com)、及び微結晶性セルロース−Ultra Pure Powder(アビセル(登録商標)PH−101、シグマ−アルドリッチ Co.,LLC)、から商業的に入手可能な、結晶の大きさが約50μmの無水セルロース微結晶性粉末が含まれた。
Claims (8)
- 微結晶性セルロース材料の微孔質熱分解物を含む、セルロース前駆体材料の熱分解生成物及び1以上の非セルロース前駆体材料の熱分解生成物を含む、半導体製品、フラットパネルディスプレイ、及びソーラーパネルからなる群から選択される製品の製造のためのガスをその上に可逆的に吸着させる、セルロース系炭素吸着剤であって、
前記1以上の非セルロース前駆体材料が、糖類、サッカライド、デンプン及びマルトデキストリンから選択される1以上のセルロース以外の炭水化物から選択され、
前記セルロース前駆体材料が、前記セルロース前駆体材料及び非セルロース前駆体材料の総重量に基づいて、55から98重量%の濃度で存在する、セルロース系炭素吸着剤。 - 前記ガスが、(i)水素化物、(ii)ハロゲン化物、(iii)有機金属、(iv)水素、(v)二酸化炭素、(vi)一酸化炭素、(vii)メタン、(viii)天然ガス、(ix)エタン、(x)エチレン、(xi)プロパン、(xii)プロピレン、(xiii)ブタン、(xiv)ブチレン、及びこれらのガスの2以上の組合せからなる群から選択されるガスを含む、請求項1に記載のセルロース系炭素吸着剤。
- 前記ガスが(i)ホウ素含有ガス、(ii)ケイ素含有ガス、(iii)ゲルマニウム含有ガスからなる群から選択される同位体濃縮変異体、又はこれらのいずれかを、1以上の共流ガス、キャリアガス、及び希釈剤との組み合わせで含む、請求項1に記載のセルロース系炭素吸着剤。
- 前記微孔質熱分解物が、木材パルプ、おが屑、新聞印刷用紙、ヤシ殻、オリーブの種、モモの種、アンズ核、ビスコース、ビスコースレーヨン、コットン、コットンリンター、アルガンの殻、マカダミアナッツ殻、酢酸セルロース、バクテリアセルロース、リグニン、リンボクの種、クルミ殻、ナツメヤシの種、籾殻、コーヒーの実の皮、コーヒー滓、バガス、ソルガム雑穀藁、竹材、マンゴー核、アーモンド殻、トウモロコシ穂軸、サクランボの種、及びブドウ種子の1以上の熱分解生成物を含む、請求項1に記載のセルロース系炭素吸着剤。
- 以下の特性:
ASTM D2866の手順によって測定して0.5%未満の全灰含有量を有する;
片密度が0.55g/ccから1.30g/ccである;
嵩密度が0.5g/ccから1.3g/ccである;
前記吸着剤が結合剤を含まない;
N2 BET表面積が750から3000m2/グラムの範囲内である;
0.3nmから2.0nmの範囲のサイズを有するマイクロ孔が細孔容積の50%から90%又はそれ以上を有する;
メタン吸着容量が21℃及び35バールの圧力で140V/Vから220V/Vの範囲内である;及び
35バールと1バールとの間のメタン吸着作業/デルタ容量が75から125V/Vの範囲内である;
の1以上を特徴とする、請求項1に記載のセルロース系炭素吸着剤。 - (i)微結晶性セルロース熱分解生成物と、
(ii)(a)デンプン及び(b)マルトデキストリンのうちの少なくとも一つの熱分解生成物と
を含む、請求項1に記載の吸着剤。 - 2以上の異なるセルロース材料を含むセルロース前駆体材料の熱分解生成物を含む、請求項1に記載のセルロース系炭素吸着剤。
- ガス供給パッケージにおいて、ガスをその上に吸着させた状態で可逆的に保持し、前記ガス供給パッケージの分配条件下で容器から放出するためにガスを脱着するための、請求項1から7の何れか一項に記載のセルロース系炭素吸着剤を収容するガス貯蔵分配容器を含む、ガス供給パッケージ。
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US201562208663P | 2015-08-22 | 2015-08-22 | |
US62/208,663 | 2015-08-22 | ||
PCT/US2016/047880 WO2017035023A1 (en) | 2015-08-22 | 2016-08-19 | Microcrystalline cellulose pyrolyzate adsorbents and methods of making and using name |
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