JP6788588B2 - 糖から乳酸及び２−ヒドロキシ−３−ブテン酸又はα−ヒドロキシメチオニン類似体のエステルを製造する方法 - Google Patents

糖から乳酸及び２−ヒドロキシ−３−ブテン酸又はα−ヒドロキシメチオニン類似体のエステルを製造する方法 Download PDF

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JP6788588B2
JP6788588B2 JP2017528450A JP2017528450A JP6788588B2 JP 6788588 B2 JP6788588 B2 JP 6788588B2 JP 2017528450 A JP2017528450 A JP 2017528450A JP 2017528450 A JP2017528450 A JP 2017528450A JP 6788588 B2 JP6788588 B2 JP 6788588B2
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lewis acid
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サダバ・スビリ・イランツ
ターニング・エスペン
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ハルドール・トプサー・アクチエゼルスカベット
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/18—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/26—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/57—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being further substituted by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C323/58—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being further substituted by nitrogen atoms, not being part of nitro or nitroso groups with amino groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/44—Preparation of carboxylic acid esters by oxidation-reduction of aldehydes, e.g. Tishchenko reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/475—Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
    • C07C69/675—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids of saturated hydroxy-carboxylic acids
    • C07C69/68—Lactic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
    • C07C69/732—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids of unsaturated hydroxy carboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00033—Continuous processes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP2017528450A 2014-11-28 2015-11-12 糖から乳酸及び２−ヒドロキシ−３−ブテン酸又はα−ヒドロキシメチオニン類似体のエステルを製造する方法 Active JP6788588B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP14195485 2014-11-28
EP14195485.9 2014-11-28
DKPA201500288 2015-05-13
DKPA201500288 2015-05-13
PCT/EP2015/076399 WO2016083137A1 (en) 2014-11-28 2015-11-12 Process for preparing esters of lactic acid, and 2-hydroxy-3-butenoic acid or alfa-hydroxy methionine analogues from sugars

Related Child Applications (1)

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JP2020070960A Division JP6826225B2 (ja) 2014-11-28 2020-04-10 糖から乳酸及び２−ヒドロキシ−３−ブテン酸又はα−ヒドロキシメチオニン類似体のエステルを製造する方法

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JP6788588B2 true JP6788588B2 (ja) 2020-11-25

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JP2020070960A Expired - Fee Related JP6826225B2 (ja) 2014-11-28 2020-04-10 糖から乳酸及び２−ヒドロキシ−３−ブテン酸又はα−ヒドロキシメチオニン類似体のエステルを製造する方法

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US (3) US10100007B2 (enExample)
EP (2) EP3224234B1 (enExample)
JP (2) JP6788588B2 (enExample)
KR (1) KR102475064B1 (enExample)
CN (2) CN107001253B (enExample)
AU (1) AU2015352840B2 (enExample)
BR (1) BR112017011304B1 (enExample)
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HU (2) HUE046852T2 (enExample)
MX (2) MX2017006538A (enExample)
MY (1) MY194486A (enExample)
PL (2) PL3461806T3 (enExample)
RU (2) RU2710014C2 (enExample)
SG (2) SG10201810447YA (enExample)
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Publication number Priority date Publication date Assignee Title
HUE046852T2 (hu) 2014-11-28 2020-03-30 Haldor Topsoe As Eljárás tejsav és 2-hidroxi-3-buténsav észtereinek elõállítására cukrokból
BR112017020877B1 (pt) 2015-04-30 2020-12-08 Haldor Topsøe A/S processo para a preparação de um análogo de a-hidróxi metionina e derivados do mesmo a partir de açúcares
US10526308B2 (en) 2016-05-04 2020-01-07 Haldor Topsøe A/S Adipate-type compounds and a process of preparing it
CN106349060B (zh) * 2016-08-26 2020-06-12 上海交通大学 一种路易斯酸催化转化碳水化合物制备乳酸烷基酯的方法
CN109289909B (zh) * 2018-10-16 2021-03-19 郑州大学 一种催化复杂糖转化制备乳酸酯的催化剂
AU2020343325A1 (en) * 2019-09-06 2022-03-03 Kemin Industries, Inc. Processes for the preparation of alpha-hydroxy esters by esterification of alpha-hydroxy acids
CN111905802B (zh) * 2020-06-15 2022-01-18 厦门大学 一种使用钼-碱金属/碱土金属修饰的路易斯酸催化剂制乳酸酯的方法
CN113831238B (zh) * 2020-06-24 2024-05-03 中国石油化工股份有限公司 一种催化转化碳水化合物制备乳酸甲酯的方法
CN116272945B (zh) * 2023-01-16 2024-12-31 山东理工大学 酸碱碳基催化剂的制备方法及应用

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US4792620A (en) * 1983-10-14 1988-12-20 Bp Chemicals Limited Carbonylation catalysts
US4933161A (en) 1987-02-04 1990-06-12 Exxon Research And Engineering Company Tin substitution into zeolite frameworks
US5973200A (en) * 1997-01-23 1999-10-26 Novus International, Inc. Process for the preparation of 2-hydroxy-4-(methylthio) butanoic acid or methionine by mercaptan addition
DE10140202A1 (de) 2001-08-16 2003-03-06 Bayer Ag Vanadium-Imido-Phosphoraniminato für die Olefinpolymerisation
DE102005003990A1 (de) * 2005-01-28 2006-08-03 Degussa Ag Herstellung von 3-(Alkylthio)propanal
ES2401537T3 (es) * 2008-11-11 2013-04-22 Haldor Topsoe A/S Preparación catalizada por zeolita de compuestos de ácidos alfa-hidroxicarboxílicos y ésteres de los mismos
FR2938535B1 (fr) 2008-11-20 2012-08-17 Arkema France Procede de fabrication de methylmercaptopropionaldehyde et de methionine a partir de matieres renouvelables
WO2010113964A1 (ja) * 2009-04-03 2010-10-07 三菱瓦斯化学株式会社 α－ヒドロキシカルボン酸エステルの製造方法
TWI630197B (zh) 2013-02-27 2018-07-21 丹麥商哈爾德杜薩公司 從包含低分子量羰基化合物之組成物移除甲醛的方法
DK3036040T3 (en) 2013-08-20 2018-01-08 Haldor Topsoe As A process for converting sugars into lactic acid and 2-hydroxy-3-butenoic acid or esters thereof comprising a metal silicate material and a metal ion.
HUE046852T2 (hu) 2014-11-28 2020-03-30 Haldor Topsoe As Eljárás tejsav és 2-hidroxi-3-buténsav észtereinek elõállítására cukrokból

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ES2813341T3 (es) 2021-03-23
CU20170072A7 (es) 2017-10-05
CA2968906A1 (en) 2016-06-02
US20190062271A1 (en) 2019-02-28
SG11201704329UA (en) 2017-06-29
DK3224234T3 (da) 2019-10-28
DK3461806T3 (da) 2020-09-28
BR112017011304A2 (pt) 2018-07-10
PL3461806T3 (pl) 2021-02-08
CN109942466B (zh) 2021-08-27
US20170334844A1 (en) 2017-11-23
RU2017122603A3 (enExample) 2019-05-31
CN107001253B (zh) 2019-03-12
PL3224234T3 (pl) 2020-03-31
US10343986B2 (en) 2019-07-09
CN109942466A (zh) 2019-06-28
WO2016083137A9 (en) 2016-08-25
HUE046852T2 (hu) 2020-03-30
CN107001253A (zh) 2017-08-01
US10100007B2 (en) 2018-10-16
JP2020125313A (ja) 2020-08-20
MX2017006538A (es) 2017-08-09
JP6826225B2 (ja) 2021-02-03
CU24499B1 (es) 2021-02-04
WO2016083137A1 (en) 2016-06-02
EP3224234B1 (en) 2019-08-14
EP3461806B1 (en) 2020-08-05
CA2968906C (en) 2023-09-12
ZA201703204B (en) 2019-10-30
RU2019131408A (ru) 2019-10-29
BR112017011304B1 (pt) 2020-04-14
NZ732280A (en) 2021-09-24
AU2015352840B2 (en) 2020-01-02
AU2015352840A1 (en) 2017-06-15
EP3224234A1 (en) 2017-10-04
JP2017537096A (ja) 2017-12-14
MY194486A (en) 2022-11-30
KR102475064B1 (ko) 2022-12-07
US10280136B2 (en) 2019-05-07
MX2020011677A (es) 2020-12-10
EP3461806A1 (en) 2019-04-03
ES2748690T3 (es) 2020-03-17
RU2017122603A (ru) 2018-12-29
RU2710014C2 (ru) 2019-12-24
HUE051552T2 (hu) 2021-03-29
SG10201810447YA (en) 2018-12-28
KR20170091107A (ko) 2017-08-08
US20190016674A1 (en) 2019-01-17

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