DK3224234T3 - Proces til fremstilling af estere af mælkesyre og 2-hydroxy-3-butensyre fra sukre - Google Patents

Proces til fremstilling af estere af mælkesyre og 2-hydroxy-3-butensyre fra sukre Download PDF

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Publication number
DK3224234T3
DK3224234T3 DK15793830T DK15793830T DK3224234T3 DK 3224234 T3 DK3224234 T3 DK 3224234T3 DK 15793830 T DK15793830 T DK 15793830T DK 15793830 T DK15793830 T DK 15793830T DK 3224234 T3 DK3224234 T3 DK 3224234T3
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Prior art keywords
sugar
hydroxy
esters
preparation
acid
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DK15793830T
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English (en)
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Zubiri Irantzu Sadaba
Esben Taarning
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Haldor Topsoe As
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/08Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/14Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/18Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/26Separation; Purification; Stabilisation; Use of additives
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/57Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being further substituted by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C323/58Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being further substituted by nitrogen atoms, not being part of nitro or nitroso groups with amino groups bound to the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/44Preparation of carboxylic acid esters by oxidation-reduction of aldehydes, e.g. Tishchenko reaction
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/475Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/48Separation; Purification; Stabilisation; Use of additives
    • C07C67/62Use of additives, e.g. for stabilisation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/67Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
    • C07C69/675Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids of saturated hydroxy-carboxylic acids
    • C07C69/68Lactic acid esters
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/73Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
    • C07C69/732Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids of unsaturated hydroxy carboxylic acids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00027Process aspects
    • B01J2219/00033Continuous processes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DK15793830T 2014-11-28 2015-11-12 Proces til fremstilling af estere af mælkesyre og 2-hydroxy-3-butensyre fra sukre DK3224234T3 (da)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14195485 2014-11-28
DKPA201500288 2015-05-13
PCT/EP2015/076399 WO2016083137A1 (en) 2014-11-28 2015-11-12 Process for preparing esters of lactic acid, and 2-hydroxy-3-butenoic acid or alfa-hydroxy methionine analogues from sugars

Publications (1)

Publication Number Publication Date
DK3224234T3 true DK3224234T3 (da) 2019-10-28

Family

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Family Applications (2)

Application Number Title Priority Date Filing Date
DK15793830T DK3224234T3 (da) 2014-11-28 2015-11-12 Proces til fremstilling af estere af mælkesyre og 2-hydroxy-3-butensyre fra sukre
DK18204431.3T DK3461806T3 (da) 2014-11-28 2015-11-12 Fremgangsmåde til fremstilling af alfa-hydroxymethionin-analoger ud fra sukker

Family Applications After (1)

Application Number Title Priority Date Filing Date
DK18204431.3T DK3461806T3 (da) 2014-11-28 2015-11-12 Fremgangsmåde til fremstilling af alfa-hydroxymethionin-analoger ud fra sukker

Country Status (19)

Country Link
US (3) US10100007B2 (da)
EP (2) EP3224234B1 (da)
JP (2) JP6788588B2 (da)
KR (1) KR102475064B1 (da)
CN (2) CN109942466B (da)
AU (1) AU2015352840B2 (da)
BR (1) BR112017011304B1 (da)
CA (1) CA2968906C (da)
CU (1) CU24499B1 (da)
DK (2) DK3224234T3 (da)
ES (2) ES2748690T3 (da)
HU (2) HUE051552T2 (da)
MX (2) MX2017006538A (da)
MY (1) MY194486A (da)
PL (2) PL3224234T3 (da)
RU (2) RU2710014C2 (da)
SG (2) SG11201704329UA (da)
WO (1) WO2016083137A1 (da)
ZA (1) ZA201703204B (da)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2017006538A (es) 2014-11-28 2017-08-09 Topsoe Haldor As Proceso para preparar esteres de acido lactico y acido 2-hidroxi-3-butenoico o analogos de alfa-hidroxi-metionina a partir de azucares.
MX2017012457A (es) 2015-04-30 2018-01-30 Topsoe Haldor As Un proceso para la preparacion de analogos alfa-hidroxilados de metionina a partir de azucares y derivados de los mismos.
TWI712584B (zh) 2016-05-04 2020-12-11 丹麥商托普索公司 新穎己二酯類化合物及其製備方法
CN106349060B (zh) * 2016-08-26 2020-06-12 上海交通大学 一种路易斯酸催化转化碳水化合物制备乳酸烷基酯的方法
CN109289909B (zh) * 2018-10-16 2021-03-19 郑州大学 一种催化复杂糖转化制备乳酸酯的催化剂
EP4025561A4 (en) * 2019-09-06 2024-01-31 Kemin Industries, Inc. METHOD FOR PRODUCING ALPHA-HYDROXYESTERS BY ESTERIFICATION OF ALPHA-HYDROXY ACIDS
CN111905802B (zh) * 2020-06-15 2022-01-18 厦门大学 一种使用钼-碱金属/碱土金属修饰的路易斯酸催化剂制乳酸酯的方法
CN113831238B (zh) * 2020-06-24 2024-05-03 中国石油化工股份有限公司 一种催化转化碳水化合物制备乳酸甲酯的方法
CN116272945A (zh) * 2023-01-16 2023-06-23 山东理工大学 酸碱碳基催化剂的制备方法及应用

Family Cites Families (11)

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US4792620A (en) * 1983-10-14 1988-12-20 Bp Chemicals Limited Carbonylation catalysts
US4933161A (en) 1987-02-04 1990-06-12 Exxon Research And Engineering Company Tin substitution into zeolite frameworks
US5973200A (en) * 1997-01-23 1999-10-26 Novus International, Inc. Process for the preparation of 2-hydroxy-4-(methylthio) butanoic acid or methionine by mercaptan addition
DE10140202A1 (de) 2001-08-16 2003-03-06 Bayer Ag Vanadium-Imido-Phosphoraniminato für die Olefinpolymerisation
DE102005003990A1 (de) * 2005-01-28 2006-08-03 Degussa Ag Herstellung von 3-(Alkylthio)propanal
DK2184270T3 (da) * 2008-11-11 2013-04-15 Haldor Topsoe As Zeolit-katalyseret fremstilling af alpha-hydroxy carboxylsyreforbindelser og estere deraf
FR2938535B1 (fr) * 2008-11-20 2012-08-17 Arkema France Procede de fabrication de methylmercaptopropionaldehyde et de methionine a partir de matieres renouvelables
US8759566B2 (en) * 2009-04-03 2014-06-24 Mitsubishi Gas Chemical Company, Inc. Method for producing α-hydroxycarboxylic acid ester
TWI630197B (zh) 2013-02-27 2018-07-21 丹麥商哈爾德杜薩公司 從包含低分子量羰基化合物之組成物移除甲醛的方法
JP6431913B2 (ja) 2013-08-20 2018-11-28 ハルドール・トプサー・アクチエゼルスカベット メタロシリケート材料及び金属イオンを含む乳酸及び2−ヒドロキシ−3−ブテン酸又はそれらのエステルの糖への転化方法
MX2017006538A (es) 2014-11-28 2017-08-09 Topsoe Haldor As Proceso para preparar esteres de acido lactico y acido 2-hidroxi-3-butenoico o analogos de alfa-hidroxi-metionina a partir de azucares.

Also Published As

Publication number Publication date
PL3224234T3 (pl) 2020-03-31
BR112017011304B1 (pt) 2020-04-14
EP3224234A1 (en) 2017-10-04
RU2017122603A (ru) 2018-12-29
JP6788588B2 (ja) 2020-11-25
CN107001253A (zh) 2017-08-01
CU24499B1 (es) 2021-02-04
HUE046852T2 (hu) 2020-03-30
US10100007B2 (en) 2018-10-16
RU2017122603A3 (da) 2019-05-31
ES2813341T3 (es) 2021-03-23
KR102475064B1 (ko) 2022-12-07
PL3461806T3 (pl) 2021-02-08
EP3461806A1 (en) 2019-04-03
NZ732280A (en) 2021-09-24
CN109942466A (zh) 2019-06-28
US20170334844A1 (en) 2017-11-23
AU2015352840A1 (en) 2017-06-15
SG10201810447YA (en) 2018-12-28
CN109942466B (zh) 2021-08-27
CA2968906C (en) 2023-09-12
US20190016674A1 (en) 2019-01-17
EP3224234B1 (en) 2019-08-14
JP2020125313A (ja) 2020-08-20
MX2017006538A (es) 2017-08-09
JP6826225B2 (ja) 2021-02-03
US10280136B2 (en) 2019-05-07
BR112017011304A2 (pt) 2018-07-10
JP2017537096A (ja) 2017-12-14
AU2015352840B2 (en) 2020-01-02
DK3461806T3 (da) 2020-09-28
SG11201704329UA (en) 2017-06-29
WO2016083137A1 (en) 2016-06-02
ES2748690T3 (es) 2020-03-17
ZA201703204B (en) 2019-10-30
CN107001253B (zh) 2019-03-12
WO2016083137A9 (en) 2016-08-25
CA2968906A1 (en) 2016-06-02
HUE051552T2 (hu) 2021-03-29
RU2019131408A (ru) 2019-10-29
US10343986B2 (en) 2019-07-09
EP3461806B1 (en) 2020-08-05
US20190062271A1 (en) 2019-02-28
RU2710014C2 (ru) 2019-12-24
CU20170072A7 (es) 2017-10-05
MY194486A (en) 2022-11-30
MX2020011677A (es) 2020-12-10
KR20170091107A (ko) 2017-08-08

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