JP6664552B2 - 感熱記録材料 - Google Patents
感熱記録材料 Download PDFInfo
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- JP6664552B2 JP6664552B2 JP2019530385A JP2019530385A JP6664552B2 JP 6664552 B2 JP6664552 B2 JP 6664552B2 JP 2019530385 A JP2019530385 A JP 2019530385A JP 2019530385 A JP2019530385 A JP 2019530385A JP 6664552 B2 JP6664552 B2 JP 6664552B2
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- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical class C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- BDIFKMOUQSYRRD-UHFFFAOYSA-N diphenyl hexanedioate Chemical compound C=1C=CC=CC=1OC(=O)CCCCC(=O)OC1=CC=CC=C1 BDIFKMOUQSYRRD-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- ZJOLCKGSXLIVAA-UHFFFAOYSA-N ethene;octadecanamide Chemical compound C=C.CCCCCCCCCCCCCCCCCC(N)=O.CCCCCCCCCCCCCCCCCC(N)=O ZJOLCKGSXLIVAA-UHFFFAOYSA-N 0.000 description 1
- PKVPQUVCBXSQNS-UHFFFAOYSA-N ethyl 4-[(4-ethoxycarbonylphenyl)sulfamoylcarbamoylamino]benzoate Chemical compound C(C)OC(=O)C1=CC=C(C=C1)NC(=O)NS(=O)(=O)NC1=CC=C(C=C1)C(=O)OCC PKVPQUVCBXSQNS-UHFFFAOYSA-N 0.000 description 1
- OYQYHJRSHHYEIG-UHFFFAOYSA-N ethyl carbamate;urea Chemical compound NC(N)=O.CCOC(N)=O OYQYHJRSHHYEIG-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000000155 isotopic effect Effects 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- RQAQWBFHPMSXKR-UHFFFAOYSA-N n-(4-chlorophenyl)-3-(phosphonooxy)naphthalene-2-carboxamide Chemical compound OP(O)(=O)OC1=CC2=CC=CC=C2C=C1C(=O)NC1=CC=C(Cl)C=C1 RQAQWBFHPMSXKR-UHFFFAOYSA-N 0.000 description 1
- DJWFNQUDPJTSAD-UHFFFAOYSA-N n-octadecyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCCNC(=O)CCCCCCCCCCCCCCCCC DJWFNQUDPJTSAD-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- GJNDMSSZEBNLPU-UHFFFAOYSA-N octadecylurea Chemical compound CCCCCCCCCCCCCCCCCCNC(N)=O GJNDMSSZEBNLPU-UHFFFAOYSA-N 0.000 description 1
- WGOROJDSDNILMB-UHFFFAOYSA-N octatriacontanediamide Chemical compound NC(=O)CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC(N)=O WGOROJDSDNILMB-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 102000054765 polymorphisms of proteins Human genes 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- WKEDVNSFRWHDNR-UHFFFAOYSA-N salicylanilide Chemical compound OC1=CC=CC=C1C(=O)NC1=CC=CC=C1 WKEDVNSFRWHDNR-UHFFFAOYSA-N 0.000 description 1
- 229950000975 salicylanilide Drugs 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- 238000007651 thermal printing Methods 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/323—Organic colour formers, e.g. leuco dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/333—Colour developing components therefor, e.g. acidic compounds
- B41M5/3333—Non-macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/04—Direct thermal recording [DTR]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/38—Intermediate layers; Layers between substrate and imaging layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
- B41M2205/40—Cover layers; Layers separated from substrate by imaging layer; Protective layers; Layers applied before imaging
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/323—Organic colour formers, e.g. leuco dyes
- B41M5/327—Organic colour formers, e.g. leuco dyes with a lactone or lactam ring
- B41M5/3275—Fluoran compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
- B41M5/337—Additives; Binders
- B41M5/3372—Macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/426—Intermediate, backcoat, or covering layers characterised by inorganic compounds, e.g. metals, metal salts, metal complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
Description
・ ビスフェノールA(これは2,2−ビス(4−ヒドロキシフェニル)−プロパンである)および
・ ビスフェノールS(これは4,4′−ジヒドロキシジフェニルスルホンである)
として公知の成分は、公然の批判の中心にあり、したがって、しばしば、
・ BASF SE社のPergafest(登録商標)201(これはN−(4−メチルフェニルスルホニル)−N′−(3−(4−メチルフェニルスルホニルオキシ)フェニル)尿素である)、
・ D8(これは4−ヒドロキシ−4′−イソプロポキシジフェニルスルホンである)、
・ N−[2−(3−フェニルウレイド)フェニル]ベンゼンスルホンアミドおよび
・ N−{2−[(フェニルカルバモイル)アミノ]フェニル}ベンゼンスルホンアミドに置き換えられる。
i)支持基材と、
ii)感熱記録層と
を含み、感熱記録層は、発色剤と顕色剤混合物とを含み、かつ顕色剤混合物は、
a)式(I)
b)式(II)
ここで、式(I)の化合物は、IRスペクトルにおいて3401±20cm-1で吸収バンドを有する結晶形で存在し、
ここで、
i)式(I)の化合物と式(II)の化合物との質量比は、0.5:99.5〜35:65であるか、
または
ii)式(I)の化合物と式(II)の化合物との質量比は、99.5:0.5〜65:35である
感熱記録材料により解決される。
i)支持基材と、
ii)感熱記録層と
を含み、感熱記録層は、発色剤と顕色剤混合物とを含み、かつ顕色剤混合物は、
a)式(I)
b)式(II)
ここで、式(I)の化合物は、IRスペクトルにおいて3401±20cm-1で吸収バンドを有する結晶形で存在する、
感熱記録材料に関する。
i.支持基材を準備または製造し;
ii.本発明による感熱記録材料中に使用される式(I)の化合物と本発明による感熱記録材料中に使用される式(II)の化合物とを含む被覆組成物を準備または製造し;
iii.準備または製造した支持基材上へ準備または製造した被覆組成物を塗工し;
iv.塗工した被覆組成物を乾燥させて感熱記録層を形成すること
を含む感熱記録材料の製造方法に関する。
a)顔料を含む被覆組成物を準備または製造し;
b)支持基材上へ準備または製造した被覆組成物を塗工し;
c)塗工した被覆組成物を乾燥させて中間層を形成すること
をさらに含み、
ここで、方法工程a)〜c)は、方法工程ii.の前に実施され、かつ支持基材と感熱記録層との間に中間層が配置されている、方法が好ましい。中間層が形成される場合、本発明による方法の工程iii.において、準備または製造された被覆組成物の塗工は、形成された中間層上に行われ、準備または製造された支持基材上に直接は行われない。
A)被覆組成物を準備または製造し;
B)感熱記録層上へ準備または製造した被覆組成物を塗工し;
C)塗工した被覆組成物を乾燥させて保護層を形成すること
をさらに含み、
ここで、方法工程A)〜C)は、方法工程iv.の後に実施され、かつ保護層は感熱記録材料上に配置されている、方法が好ましい。
例1〜15および比較例1および2:
長網抄紙機で、支持基材として、通常の添加剤を通常の量で添加しながら、67g/m2の面積基準の質量を有する漂白しかつ粉砕した広葉樹および針葉樹パルプから紙匹を製造した。前側にロールブレード塗工機を用いて、顔料として中空顔料および焼成カオリン、結合剤としてスチレンブタジエンラテックスおよび共結合剤としてデンプンを含む、9g/m2の面積基準の質量を有する中間層を塗工し、慣用のように乾燥する。
例16〜30を、例1〜15と同様に実施した。しかしながら、中間層は、ロールブレード塗工機を用いて塗工するのではなく、ブレードで引いて中間層として輪郭塗工を行う。
本発明による例1〜15ならびに比較例1およびの感熱記録材料上の感熱印刷出力物の耐候性を測定技術的に記録するために、それぞれ試験されるべき感熱記録材料上に、白黒市松模様の感熱サンプル印刷出力物をPrintrex社(USA)のAtlantek 400型の機器を用いて作製し、ここで300dpiの解像度および16mJ/mm2の単位面積当たりのエネルギーを有するサーマルヘッドを使用した。
本発明による例ならびに比較例の感熱記録材料上の感熱印刷出力物の、ラノリンに対する耐久性を測定技術的に記録するために、それぞれ試験されるべき感熱記録材料上に、白黒市松模様の感熱サンプル印刷出力物をPrintrex社(USA)のAtlantek 400型の機器を用いて作製し、ここで300dpiの解像度および16mJ/mm2の単位面積当たりのエネルギーを有するサーマルヘッドを使用した。
この試験を用いて、水および水溶液に対する、記録層上に作成された画像の耐久性を評価する。ATLANTEK Model 400 -Thermal Response Test Systemの印刷機を用いてエネルギーレベルMedium、段階10で作製された印刷面上に、蒸留水または選択された25%のエタノール水溶液1滴を施す。余剰の試験液体を、20分の作用時間後に、濾紙または綿布で拭き取り、引き続きこの試験紙を、室内気候(23℃、50%相対湿度)で24時間貯蔵する。それぞれの試験液体を施す前および貯蔵時間の経過の後に、濃度計のTECHKON(登録商標)SpectroDens Advanced分光濃度計を用いて印刷面の光学濃度ならびにその差を決定する。
市場で入手可能である、約158℃の融点を有する式(I)の化合物をエタノールから再結晶させる。約175℃の融点を有する式(I)の本発明により使用される化合物が得られる。式(I)の本発明により使用される化合物は、IRスペクトルにおいて、3401±20cm-1で吸収バンドを有する。
Claims (12)
- i)前記式(I)の化合物と前記式(II)の化合物との質量比が、0.5:99.5〜35:65であるか、
または
ii)前記式(I)の化合物と前記式(II)の化合物との質量比が、99.5:0.5〜65:35である、
請求項1記載の感熱記録材料。 - 前記式(I)の化合物と前記式(II)の化合物との質量比は、0.5:99.5〜99.5:0.5である、請求項1記載の感熱記録材料。
- 前記感熱記録層中の前記顕色剤混合物の割合は、前記感熱記録層の全固形分を基準として35〜15質量%である、請求項1から3までのいずれか1項記載の感熱記録材料。
- 前記感熱記録層の面積基準の質量は、1.5〜6g/m2の範囲内にある、請求項1から4までのいずれか1項記載の感熱記録材料。
- 前記支持基材と前記感熱記録層との間に配置された中間層をさらに含む、請求項1から5までのいずれか1項記載の感熱記録材料。
- 前記中間層は、顔料を含み、
前記顔料が、
a)有機顔料
および/または
b)無機顔料
である、請求項6記載の感熱記録材料。 - 前記感熱記録層が、完全にまたは部分的に保護層で覆われている、請求項1から7までのいずれか1項記載の感熱記録材料。
- 航空券、鉄道乗車券、乗船券、バス乗車券、賭博券、駐車券、ラベル、レシート、自己接着ラベル、医療用記録紙、ファックス用紙またはバーコードラベルとしての、請求項1から8までのいずれか1項記載の感熱記録材料の使用。
- 請求項1において定義された式(II)の化合物を顕色剤として含んでいる感熱記録材料の印刷画像の耐湿性を改善するための、請求項1において定義された式(I)の化合物の使用において、式(I)の化合物は、IRスペクトルにおいて3401±20cm-1で吸収バンドを有する結晶形で存在し、かつ前記式(I)の化合物と前記式(II)の化合物との質量比が、0.5:99.5〜35:65である、
前記使用。 - 請求項1において定義された式(I)の化合物を顕色剤として含んでいる感熱記録材料の印刷画像のラノリン耐久性を改善するための、請求項1において定義された式(II)の化合物の使用において、式(I)の化合物は、IRスペクトルにおいて3401±20cm-1で吸収バンドを有する結晶形で存在し、かつ前記式(I)の化合物と前記式(II)の化合物との質量比が、99.5:0.5〜65:35である、
前記使用。 - 少なくとも次の方法工程:
i.支持基材を準備または製造し;
ii.請求項1において定義された式(I)の化合物と請求項1において定義された式(II)の化合物とを含み、式(I)の化合物は、IRスペクトルにおいて3401±20cm-1で吸収バンドを有する結晶形で存在する、被覆組成物を準備または製造し;
iii.準備または製造した前記被覆組成物を塗工し;
iv.塗工した前記被覆組成物を乾燥させて感熱記録層を形成すること
を含む、感熱記録材料の製造方法。
Applications Claiming Priority (7)
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EP16192933.6A EP3305538A1 (de) | 2016-10-07 | 2016-10-07 | Wärmeempfindliches aufzeichnungsmaterial |
DE102016219569.7A DE102016219569A1 (de) | 2016-10-07 | 2016-10-07 | Wärmeempfindliches Aufzeichnungsmaterial |
EP16192933.6 | 2016-10-07 | ||
DE102016219567.0 | 2016-10-07 | ||
DE102016219567.0A DE102016219567A1 (de) | 2016-10-07 | 2016-10-07 | Wärmeempfindliches Aufzeichnungsmaterial |
DE102016219569.7 | 2016-10-07 | ||
PCT/EP2017/074879 WO2018065330A1 (de) | 2016-10-07 | 2017-09-29 | Wärmeempfindliches aufzeichnungsmaterial |
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US (1) | US10882348B2 (ja) |
EP (1) | EP3523134A1 (ja) |
JP (1) | JP6664552B2 (ja) |
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CN109641472B (zh) | 2016-08-24 | 2021-07-27 | 日本曹达株式会社 | 记录材料及记录片材 |
WO2018139484A1 (ja) * | 2017-01-30 | 2018-08-02 | 日本曹達株式会社 | 記録材料及び記録シート |
DE102019132401B3 (de) * | 2019-11-28 | 2021-02-18 | Papierfabrik August Koehler Se | Polymorphe Formen von N-(4-((4-(3-Phenylureido)phenyl)sulfonyl)phenyl)benzosulfonamid |
EP3957488A1 (de) | 2020-08-19 | 2022-02-23 | Mitsubishi HiTec Paper Europe GmbH | Wärmeempfindliches aufzeichnungsmaterial sowie wärmeempfindliche aufzeichnungsschicht und beschichtungszusammensetzung zu seiner herstellung, entsprechende verwendungen und verfahren |
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GB9827569D0 (en) * | 1998-12-16 | 1999-02-10 | Ciba Geigy Ag | Heat sensitive recording material |
CN1443117A (zh) * | 2000-03-27 | 2003-09-17 | 西巴特殊化学品控股有限公司 | 热敏记录材料 |
FI110677B (fi) | 2001-10-12 | 2003-03-14 | Jujo Thermal Oy | Lämpöherkkä tallennusmateriaali |
JP2003276334A (ja) * | 2002-03-22 | 2003-09-30 | Ricoh Co Ltd | 感熱記録材料 |
JP4255300B2 (ja) * | 2003-03-24 | 2009-04-15 | 三菱製紙株式会社 | 感熱記録材料 |
DE102004004204A1 (de) | 2004-01-27 | 2005-08-11 | Mitsubishi Hitec Paper Bielefeld Gmbh | Wärmeempfindliches Aufzeichnungsmaterial |
JP2005262714A (ja) * | 2004-03-19 | 2005-09-29 | Mitsubishi Paper Mills Ltd | 感熱記録材料 |
JP6184325B2 (ja) * | 2011-10-31 | 2017-08-23 | 日本製紙株式会社 | フェノールスルホン酸アリールエステル、顕色剤および感熱記録材料 |
ES2765891T3 (es) | 2011-12-21 | 2020-06-11 | Ono Pharmaceutical Co | Derivados de piridinona y pirimidinona como inhibidores del factor XIa |
JP5887423B2 (ja) * | 2012-11-21 | 2016-03-16 | 日本曹達株式会社 | 非フェノール系化合物を用いた記録材料 |
US9034790B2 (en) | 2013-03-14 | 2015-05-19 | Appvion, Inc. | Thermally-responsive record material |
JP5967013B2 (ja) | 2013-05-10 | 2016-08-10 | 王子ホールディングス株式会社 | 感熱記録体 |
JP6187388B2 (ja) * | 2013-06-05 | 2017-08-30 | 王子ホールディングス株式会社 | 感熱記録体 |
CN105579241B (zh) * | 2013-10-04 | 2018-10-16 | 王子控股株式会社 | 热敏记录体 |
JP2015134428A (ja) * | 2014-01-16 | 2015-07-27 | 王子ホールディングス株式会社 | 感熱記録体 |
DE102014107567B3 (de) | 2014-05-28 | 2015-11-05 | Papierfabrik August Koehler Se | Wärmeempfindliches Aufzeichnungsmaterial |
KR101951584B1 (ko) | 2015-02-25 | 2019-02-22 | 닛뽕소다 가부시키가이샤 | N-(2-(3-페닐우레이도)페닐)벤젠술폰아미드의 결정형 및 그것을 사용한 기록 재료 |
DE102015104306B4 (de) | 2015-03-23 | 2018-05-03 | Papierfabrik August Koehler Se | Wärmeempfindliches Aufzeichnungsmaterial |
ES2684629T3 (es) | 2015-06-24 | 2018-10-03 | Mitsubishi Hitec Paper Europe Gmbh | Material de registro termosensible |
US10439502B2 (en) * | 2016-09-28 | 2019-10-08 | Texas Instruments Incorporated | Resonant rectifier circuit with capacitor sensing |
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