JP6620086B2 - 光起電アレイ用の反射防止フィルム - Google Patents
光起電アレイ用の反射防止フィルム Download PDFInfo
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- JP6620086B2 JP6620086B2 JP2016504375A JP2016504375A JP6620086B2 JP 6620086 B2 JP6620086 B2 JP 6620086B2 JP 2016504375 A JP2016504375 A JP 2016504375A JP 2016504375 A JP2016504375 A JP 2016504375A JP 6620086 B2 JP6620086 B2 JP 6620086B2
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- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
- TVFJAZCVMOXQRK-UHFFFAOYSA-N ethenyl 7,7-dimethyloctanoate Chemical compound CC(C)(C)CCCCCC(=O)OC=C TVFJAZCVMOXQRK-UHFFFAOYSA-N 0.000 description 1
- AFSIMBWBBOJPJG-UHFFFAOYSA-N ethenyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC=C AFSIMBWBBOJPJG-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
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- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000005908 glyceryl ester group Chemical group 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical compound O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- RQAKESSLMFZVMC-UHFFFAOYSA-N n-ethenylacetamide Chemical compound CC(=O)NC=C RQAKESSLMFZVMC-UHFFFAOYSA-N 0.000 description 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000131 polyvinylidene Polymers 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000807 solvent casting Methods 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 125000004964 sulfoalkyl group Chemical group 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- KFAIYPBIFILLEZ-UHFFFAOYSA-N thallium(i) oxide Chemical compound [Tl]O[Tl] KFAIYPBIFILLEZ-UHFFFAOYSA-N 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/11—Anti-reflection coatings
- G02B1/111—Anti-reflection coatings using layers comprising organic materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0216—Coatings
- H01L31/02161—Coatings for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/02167—Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
- H01L31/02168—Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells the coatings being antireflective or having enhancing optical properties for the solar cells
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/10—Homopolymers or copolymers of propene
- C08J2423/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2433/08—Homopolymers or copolymers of acrylic acid esters
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
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- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Sustainable Energy (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Surface Treatment Of Optical Elements (AREA)
Description
プレートは、溶融押出プロセスによって、ニートポリマー樹脂のペレットから調製される。Leistritz押出機内で、200〜225℃の範囲のバレル温度で溶融処理されたプロピレン樹脂((Huntsman Reyen、RI=1.49、Tg−10℃、Tm173℃)。この溶融複合では続いて、ペレット化、真空オーブン内で60℃での乾燥、221〜236℃の温度での出射成形が行われた。出射成形によって得られる試験プレートは、以下の寸法を有する:66.9mm×66.9mm×1.5mm。それらのプレートは、ASTM D 10003−00(透明なプラスチックの曇り度及び視感透過率の標準試験方法)及びASTM E 313−00(機器で測定された色座標から黄色さ及び白さインデックスを計算するための標準的な技法)によって評価された。データは以下の表Iに示される。
プレートは、溶融押出プロセスによって、GRIN粒子とポリマー樹脂の混合物から調製される。以下で概説される重合プロセスによって調製された、及び組成物:p((ベンジルアクリレート/ALMA=76/4)//MMA/EA=16/4)のGRIN粒子(RI=1.56〜1.49であり、粒子サイズ直径は0.75μmである)は、ポリプロピレン樹脂(Huntsman Reyen、RI=1.49)と乾燥ブレンドされ、それに続いて、Leistritz押出機内で200〜225℃の範囲のバレル温度で溶融複合された。溶融複合は特別なスクリーンパック配置、80/120/300/120/80メッシュを使用して、GRIN粒子の最終分散物を生成した。この溶融複合では続いて、ペレット化、真空オーブン内において60℃での乾燥、及び221〜236℃の温度での出射成形が行われた。出射成形によって得られる試験プレートは、以下の寸法を有する:66.9mm×66.9mm×1.5mm。それらのプレートは、ASTM D 10003−00(透明なプラスチックの曇り度及び視感透過率の標準試験方法)及びASTM E 313−00(機器で測定された色座標から黄色さ及び白さインデックスを計算するための標準的な技法)によって評価された。データは以下の表Iに示される。
プレートは、溶融押出プロセスによって、GRIN粒子とポリマー樹脂の混合物から調製される。以下で概説される重合プロセスによって調製された、及び組成物:p((ベンジルアクリレート/ALMA=76/4)//スチレン=20)のGRIN粒子(RI=1.56〜1.59であり、粒子サイズ直径は0.80μmである)は、ポリプロピレン樹脂(Huntsman Reyen、RI=1.49)と乾燥ブレンドされ、それに続いて、Leistritz押出機内で200〜225℃の範囲のバレル温度で溶融複合された。溶融複合は特別なスクリーンパック配置、80/120/300/120/80メッシュを使用して、GRIN粒子の最終分散物を生成した。この溶融複合では続いて、ペレット化、真空オーブン内において60℃での乾燥、及び221〜236℃の温度での出射成形が行われた。出射成形によって得られる試験プレートは、以下の寸法を有する:66.9mm×66.9mm×1.5mm。それらのプレートは、ASTM D 10003−00(透明なプラスチックの曇り度及び視感透過率の標準試験方法)及びASTM E 313−00(機器で測定された色座標から黄色さ及び白さインデックスを計算するための標準的な技法)によって評価された。データは以下の表IIに示される。
本実施例は、直径0.25μmの架橋ポリマープレシードの調製して、水分散液内でより大きなシード粒子を作製するのを示す。以下の混合物A〜Cは脱イオン水で調製された。
本実施例では、実施例8のエマルションのプレシード粒子は、n−ブチルアクリレート,スチレン、及び1−ヘキサンチオールを用いて直径0.56μmまで成長する。以下の混合物A2〜G2は脱イオン水で調製された。
本実施例では、段階Iにおいて、実施例9のエマルション内の粒子は膨張させられ、n−ブチルアクリレート、及びアリメタクリレートを使用して、5μmの直径の発散レンズを形成し、その後、段階IIにおいて、メチルメタクリレート及びエチルアクリレートの共重合が行われた。以下の混合物A3〜G3は脱イオン水で調製された。
本実施例では、実施例9のエマルション内の粒子が膨張させられ、メチルメタクリレート及びアリメタクリレートを使用して5μmの直径の収束レンズを形成する。以下の混合物A3〜C3はイオン水で調製された。
YIは黄色さインデックスである(ASTM E 313−00に従って測定された)。
曇り度はASTM D 10003−00に従って測定された。
Claims (8)
- (a)0.75〜15μmの平均粒子直径、ここで前記平均粒子直径はCoulter
カウンターを用いて測定される粒子サイズ分布の中央値として定義される、及び(b)前
記粒子の中心から表面まで連続的に変化する屈折率を有するポリマー粒子であって、表面
より高い屈折率を中心に有するポリマー粒子と、ポリオレフィンを含む連続ポリマー相と
を含むフィルムであって、ナトリウムD線の589.29nmの波長を有する光を用いて
測定された前記ポリマー粒子の表面の平均屈折率と、ナトリウムD線の589.29nm
の波長を有する光を用いて測定した前記連続ポリマー相の平均屈折率の間の差が0.02以下である、前記フィルム。 - 前記平均粒子直径が1.5〜10μmである、請求項1に記載の前記フィルム。
- 前記ポリマー粒子が1.45〜1.53の屈折率を有する、請求項1に記載の前記フィルム。
- 前記ポリオレフィンが、2〜8個の炭素原子を有するアルケンのポリマーまたはコポリマーを含む、請求項1に記載の前記フィルム。
- (a)アクリルモノマーの少なくとも70重量%のポリマー残基(b)0.75〜15μmの平均粒子直径、ここで前記平均粒子直径はCoulterカウンターを用いて測定される粒子サイズ分布の中央値として定義される、及び(c)前記粒子の中心から表面まで連続的に変化する屈折率を有する、0.5〜15重量%のポリマー粒子であって、前記ポリマー粒子の前記中心の前記屈折率が1.52〜1.60であり、前記表面の前記屈折率が1.46〜1.52であるポリマー粒子;並びに、
2〜8個の炭素原子を有するアルケンのポリマーまたはコポリマーである、少なくとも85重量%のポリオレフィンを含む連続ポリマー相;
を含むフィルムであって、ナトリウムD線の589.29nmの波長を有する光を用いて測定された前記ポリマー粒子の表面の平均屈折率と、ナトリウムD線の589.29nmの波長を有する光を用いて測定した連続ポリマー相の平均屈折率の間の差が0.02以下である、前記フィルム。 - 前記連続ポリマー相が1〜12重量%の前記ポリマー粒子を含む、請求項1〜5のいずれか1項に記載の前記フィルム。
- 前記平均粒子直径が2〜8μmである、請求項6に記載の前記フィルム。
- 前記ポリマー粒子が、アクリルモノマー及びスチレンモノマーの少なくとも80%のポリマー残基を含む、請求項7に記載の前記フィルム。
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US61/804,895 | 2013-03-25 | ||
PCT/US2014/031438 WO2014160606A1 (en) | 2013-03-25 | 2014-03-21 | Anti-reflective film for photovoltaic arrays |
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JPH1121413A (ja) * | 1997-07-02 | 1999-01-26 | Kanegafuchi Chem Ind Co Ltd | シクロオレフィン系共重合体樹脂組成物及びその製造方法 |
JP3358520B2 (ja) * | 1997-12-09 | 2002-12-24 | 住友化学工業株式会社 | ポリオレフィン改質用微粒子 |
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JP4281785B2 (ja) | 2006-08-28 | 2009-06-17 | 住友化学株式会社 | 光拡散板 |
TWI386448B (zh) * | 2007-01-26 | 2013-02-21 | Rohm & Haas | 光散射組成物 |
TW200844174A (en) * | 2007-03-30 | 2008-11-16 | Jsr Corp | Particles for anti-glare film, process for producing the same, and a composition containing particles for anti-glare film |
JP2009073960A (ja) * | 2007-09-21 | 2009-04-09 | Sumitomo Chemical Co Ltd | 光学用フィルム |
US7768602B2 (en) | 2007-10-16 | 2010-08-03 | Rohm And Haas Company | Light diffusing article with GRIN lenses |
EP2431423A3 (en) * | 2010-09-21 | 2013-07-10 | Rohm and Haas Company | Anti-reflective coatings |
EP2431422A3 (en) * | 2010-09-21 | 2013-07-10 | Rohm and Haas Company | IR - reflecting compositions |
JP2014038180A (ja) * | 2012-08-15 | 2014-02-27 | Konica Minolta Inc | 光学フィルム、光学フィルムの製造方法、偏光板及び液晶表示装置 |
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JP2016516113A (ja) | 2016-06-02 |
BR112015019429A2 (pt) | 2017-07-18 |
MX2015013323A (es) | 2016-05-16 |
CN105051573B (zh) | 2017-07-07 |
TWI549829B (zh) | 2016-09-21 |
RU2662946C2 (ru) | 2018-07-31 |
WO2014160606A1 (en) | 2014-10-02 |
EP2941660A1 (en) | 2015-11-11 |
CN105051573A (zh) | 2015-11-11 |
US20160024263A1 (en) | 2016-01-28 |
EP2941660B1 (en) | 2022-09-07 |
TW201501942A (zh) | 2015-01-16 |
RU2015145601A (ru) | 2017-05-02 |
AR095055A1 (es) | 2015-09-16 |
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