JP6452296B2 - アレルゲン低減化組成物 - Google Patents
アレルゲン低減化組成物 Download PDFInfo
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- JP6452296B2 JP6452296B2 JP2014057432A JP2014057432A JP6452296B2 JP 6452296 B2 JP6452296 B2 JP 6452296B2 JP 2014057432 A JP2014057432 A JP 2014057432A JP 2014057432 A JP2014057432 A JP 2014057432A JP 6452296 B2 JP6452296 B2 JP 6452296B2
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- Prior art keywords
- allergen
- acid
- allergens
- zinc
- water
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- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Description
2−エチルヘキサン酸亜鉛としてオクトライフZNS(住化エンビロサイエンス株式会社製)を用い、エタノールに溶解して2%のエタノール溶液とした。
オクトライフZNS(住化エンビロサイエンス株式会社製)10%、溶剤としてエチルヘキシルジグリコールを80%、乳化剤としてサニマールSF−T(日本乳化剤株式会社製)5%およびニューカルゲンCP−120(竹本油脂株式会社製)5%を添加し、10%乳剤とした。
オクチル酸(田岡化学株式会社製の2−エチルヘキサン酸)7gをイオン交換水約30gに混合し、撹拌しながら10%水酸化ナトリウム水溶液を20g添加した。さらに硫酸銅五水和物(和光純薬工業株式会社製)を12.5g添加し、撹拌しながら100〜135℃に加熱した。生成した青色沈殿をろ別し、水洗後に乾燥させて2−エチルヘキサン酸銅を得た。この2−エチルヘキサン酸銅をエタノールに溶解し、2%の溶液とした。
実施例3で得られた2-エチルヘキサン酸銅を10%、溶剤としてエチルヘキシルジグリコールを77%、乳化剤としてニューカルゲンD−220K(竹本油脂株式会社製)8%およびニューカルゲンCP−120(竹本油脂株式会社製)5%を添加し、10%乳剤とした。
2−エチルヘキサン酸ジルコニウムとしてオクトライフZr12%(住化エンビロサイエンス株式会社製)83%、乳化剤としてニューカルゲン1105H(竹本油脂株式会社製)3.5%およびニューカルゲン1105L(竹本油脂株式会社製)3.5%を添加し、10%乳剤とした。
2−エチルヘキサン酸(田岡化学株式会社製オクチル酸)7gをイオン交換水約30gに混合し、撹拌しながら10%水酸化ナトリウム水溶液を20g添加した。さらに硫酸第二セリウム(和光純薬工業株式会社製)を5.1g添加し、撹拌しながら100℃に加熱した。生成した淡黄色油状液体を分離し、2−エチルヘキサン酸セリウムを得た。この2−エチルヘキサン酸セリウムをエタノールに溶解し、2%の溶液とした。
ネオデカン酸(シェル株式会社製バーサチック酸)340gに撹拌しながら亜鉛華(東栄化工株式会社製の酸化亜鉛)を170g添加した。さらに撹拌しながらイオン交換水150gを添加し、徐々に加熱しながら温度を130℃まで上昇させた。加熱を継続して水分を揮発させ、ネオデカン酸亜鉛を得た。このネオデカン酸亜鉛をエタノールに溶解し、2%の溶液とした。
ヘキサン酸(和光純薬工業株式会社製)6gをイオン交換水30gに混合し、撹拌しながら10%水酸化ナトリウム水溶液を20g添加した。さらに硫酸銅五水和物(和光純薬工業株式会社製)を12.5g添加し、撹拌しながら100〜130℃に加熱した。生成した青色沈殿をろ別し、水洗後に乾燥させてヘキサン酸銅を得た。このヘキサン酸銅をエタノールに溶解し、2%の溶液とした。
ラウリン酸亜鉛(和光純薬工業株式会社製)10g、ポイズ520(花王株式会社製)2.5g、ニューカルゲンCP−80(竹本油脂株式会社製)2.5gをイオン交換水85gに添加し、直径1mmのガラス製ビーズを用いて湿式粉砕を行い、30メッシュの金網でビーズを取り除き、ラウリン酸亜鉛の10%フロアブル剤を調製した。
アジピン酸(和光純薬工業株式会社製)7.3gをイオン交換水20gに混合し、撹拌しながら10%水酸化ナトリウム水溶液を38g添加しアジピン酸を溶解した。60℃に加熱し、さらに塩化亜鉛(和光純薬工業株式会社製)6.8gを撹拌しながら添加した。生成した白色沈殿をろ別し、水洗後に乾燥させてアジピン酸亜鉛を得た。このアジピン酸亜鉛をニューカルゲンCP−120(竹本油脂株式会社製)の2%水溶液に分散させ、2%の分散液を調製した。
2−エチルヘキサン酸(田岡化学株式会社製オクチル酸)2gをイオン交換水約30gに溶解し、10%水酸化ナトリウム水溶液を添加して中和し、さらにイオン交換水を添加して2%の水溶液とした。
塩化セリウム七水和物(和光純薬工業株式会社製)をイオン交換水に溶解し、2%水溶液とした。
ステアリン酸亜鉛(和光純薬工業株式会社製)10g、ポイズ520(花王株式会社製)3g、ニューカルゲンCP−80(竹本油脂株式会社製)3gをイオン交換水84gに添加し、直径1mmのガラス製ビーズを用いて湿式粉砕を行い、30メッシュの金網でビーズを取り除き、ステアリン酸亜鉛の10%フロアブル剤を調製した。
酢酸亜鉛(和光純薬工業株式会社製)をイオン交換水に溶解し、2%水溶液とした。
アレルゲン低減化組成物によるダニアレルゲンの低減化効果の測定
ダニアレルゲンDer f2を含有する、タンパク質量として約900ng/1mL{リン酸緩衝液(pH7.2)}のアレルゲン液1mLに対し、実施例1〜10(実施例2、4、5,9についてはあらかじめ水で5倍に希釈した液を使用)、比較例1〜4(比較例3についてはあらかじめ水で5倍に希釈した液を使用)と対照として蒸留水をそれぞれ100μL反応させた。これら試料について Der f2酵素免疫測定法(ELISA)のサンドイッチ法にてダニアレルゲン低減化効果の測定を行った。まず、リン酸緩衝液(pH7.4)で2μg/mLに希釈した抗Der f2 モノクローナル抗体15E11を、F16 MAXISORP NUNC−IMMUNO MODULEプレート(NUNC社製)の1ウェルあたり100μLずつ添加し、4℃にて3日以上感作させた。感作後、液を捨て、ブロッキング試薬{1重量%牛血清アルブミン+リン酸緩衝液(pH7.2)}を1ウェルあたり200μLずつ添加し、37℃、60分間反応させた。反応後、リン酸緩衝液(pH7.2)にてプレートを洗浄した。
アレルゲン低減化組成物によるスギ花粉アレルゲンの低減化効果の測定
スギ花粉アレルゲンCry j1として約12.5ng/1mL{リン酸緩衝液(pH7.2)}のアレルゲン液1mLに対し、実施例1〜10(実施例2、4、5,9についてはあらかじめ水で5倍に希釈した液を使用)、比較例1〜4(比較例3についてはあらかじめ水で5倍に希釈した液を使用)と対照として蒸留水をそれぞれ100μL反応させた。これら試料についてCry j1酵素免疫測定法(ELISA)のサンドイッチ法にてスギ花粉アレルゲン低減化効果の測定を行った。まず、リン酸緩衝液(pH7.4、0.1重量%NaN3含有)で2μg/mLに希釈したCry j1 モノクローナル抗体013を、F16 MAXISORP NUNC−IMMUNO MODULEプレート(NUNC社製)の1ウェルあたり100μLずつ添加し、4℃にて1日以上感作させた。感作後、液を捨て、ブロッキング試薬{1重量%牛血清アルブミン+リン酸緩衝液(pH7.2、0.1重量%NaN3含有)}を1ウェルあたり200μLずつ添加し、37℃、60分間反応させた。反応後、リン酸緩衝液{pH7.2、0.1重量%ポリオキシエチレン(20)ソルビタンモノラウレート含有}にてプレートを洗浄した。
実施例9および比較例3を8cm×8cmのガラス板2枚に、塗布厚0.076mmのフィルムアプリケータを用いて塗布し、100℃の乾燥機で15分間、乾燥させた。このガラス板の1枚にダニアレルゲンDer f2を含有する、タンパク質量として約900ng/1mL{リン酸緩衝液(pH7.2)}のアレルゲン液1mLを載せ、直径0.3mm、長さ5mmのステンレス製の針金3本をスペーサーとして離して配置し、もう一枚のガラス板を処理面が合わさるように挟み、接触させた。1時間後のアレルゲン液について、Der f2酵素免疫測定法(ELISA)のサンドイッチ法にてダニアレルゲン濃度の測定を[試験例1]と同様の方法を用いて行った。結果を表3に示す。
実施例1をエタノールで20倍に希釈し、27cm×20cmのポリプロピレン製不織布(80g/m2)にスプレー処理し、5.5gを付着させ、110℃で乾燥させた。(加工量は2−エチルヘキサン酸亜鉛として0.1g/m2)。
実施例2を0.2g採り、イオン交換水で40gに希釈し、この液に27cm×20cmのポリプロピレン製不織布(80g/m2)を浸漬し、絞り率250%で処理後、110℃で乾燥させた。(加工量は2−エチルヘキサン酸亜鉛として0.1g/m2)。
実施例4を0.2g採りイオン交換水で40gに希釈し、この液に27cm×20cmのポリプロピレン製不織布(80g/m2)を浸漬し、絞り率250%で処理後、110℃で乾燥させた。(加工量は2−エチルヘキサン酸銅として0.1g/m2)。
比較例2を1.0g採り、イオン交換水で40gに希釈し、この液に27cm×20cmのポリプロピレン製不織布(80g/m2)を浸漬し、絞り率250%で処理後、110℃で乾燥させた。(加工量は塩化セリウムとして0.1g/m2)。
比較例4を1.0g採り、イオン交換水で40gに希釈し、この液に27cm×20cmのポリプロピレン製不織布(80g/m2)を浸漬し、絞り率250%で処理後、110℃で乾燥させた。(加工量は酢酸亜鉛として0.1g/m2)。
加工例1〜4の不織布を等分に切断し(13.5cm×20cm)、一方を4Lのイオン交換水に浸漬して30分間攪拌し、取り出して室温で風乾し水洗後の試料とした。
加工例1〜5の不織布および、これらの水洗を行った不織布を5cm×5cmに切り取り、チャック付きポリ袋に投入し、標準ダニアレルゲン懸濁液(アレルゲン量900ng/mL)1mLを加え、試料とアレルゲンを接触させた。1時間後にチャック付きポリ袋からアレルゲン液を搾り出し、遠心分離後のこれら試料について Der f2酵素免疫測定法(ELISA)のサンドイッチ法にてダニアレルゲン濃度の測定を[試験例1]と同様の方法を用いて行った。結果を表4に示す。
加工例1〜5の不織布および、これらの水洗を行った不織布を5cm×5cmに切り取り、チャック付きポリ袋に投入し、標準スギ花粉アレルゲン液(アレルゲン量 12.5ng/mL)1mLを加え、試料とアレルゲンを接触させた。1時間後にチャック付きポリ袋からアレルゲン液を搾り出し、遠心分離後のこれら試料について Cry j1酵素免疫測定法(ELISA)のサンドイッチ法にてスギ花粉アレルゲン濃度の測定を[試験例2]と同様の方法を用いて行った。結果を表5に示す。
Claims (2)
- 炭素数6〜12の、1価または2価のカルボン酸金属塩を含有するアレルゲン低減化組成物であって、当該金属は希土類金属、亜鉛、銅、およびジルコニウムの一種類以上から選択されるうち、該組成物が2−エチルヘキサン酸銅、および/または2−エチルヘキサン酸亜鉛であることを特徴とするダニアレルゲン用、またはスギ花粉アレルゲン用低減化組成物。
- 請求項1に記載のダニアレルゲン用、またはスギ花粉アレルゲン用低減化組成物を加工した不織布、繊維または繊維製品、建築用内装材。
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