JP6443883B2 - 多成分型有機溶剤系の下塗り塗料組成物及びこれを用いた補修塗装方法 - Google Patents
多成分型有機溶剤系の下塗り塗料組成物及びこれを用いた補修塗装方法 Download PDFInfo
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- JP6443883B2 JP6443883B2 JP2015068378A JP2015068378A JP6443883B2 JP 6443883 B2 JP6443883 B2 JP 6443883B2 JP 2015068378 A JP2015068378 A JP 2015068378A JP 2015068378 A JP2015068378 A JP 2015068378A JP 6443883 B2 JP6443883 B2 JP 6443883B2
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- 238000000576 coating method Methods 0.000 title claims description 87
- 239000000203 mixture Substances 0.000 title claims description 78
- 239000003960 organic solvent Substances 0.000 title claims description 36
- 239000011248 coating agent Substances 0.000 claims description 75
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- 239000000049 pigment Substances 0.000 claims description 51
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- 239000007787 solid Substances 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 17
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- 238000001035 drying Methods 0.000 claims description 13
- 239000000454 talc Substances 0.000 claims description 12
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- 239000004034 viscosity adjusting agent Substances 0.000 claims description 12
- 229920005906 polyester polyol Polymers 0.000 claims description 11
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- 239000004480 active ingredient Substances 0.000 claims description 3
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- 229910001209 Low-carbon steel Inorganic materials 0.000 description 3
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- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
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- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
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- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
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- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
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- XWKBMOUUGHARTI-UHFFFAOYSA-N tricalcium;diphosphite Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])[O-].[O-]P([O-])[O-] XWKBMOUUGHARTI-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
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Description
主剤成分(I)、ポリオール成分(II)と硬化剤成分(III)とを混合して得られる多成分型有機溶剤系の下塗り塗料組成物であって、
主剤成分(I)が、ラクトン変性アクリルポリオール(A1)、顔料組成物(B1)及び有機溶剤(C1)を含み、
ポリオール成分(II)が、アクリルポリオール(A2)、顔料組成物(B2)、有機溶剤(C2)及びポリエステルポリオール(D)を含み、硬化剤成分(III)がポリイソシアネート化合物を含むものであって
主剤成分(I)に含まれる顔料組成物(B1)がその成分の一部としてタルクを含み、タルクの含有量がラクトン変性アクリルポリオール(A1)固形分100質量部を基準として、61〜250質量部にあり、
顔料組成物(B1)の含有量がアクリルポリオール(A1)固形分100質量部を基準として50〜500質量部の範囲内、
顔料組成物(B2)の含有量が、ポリオール成分(II)に含まれる樹脂の合計100質量部を基準として50〜250質量部の範囲内
にあることを特徴とする下塗り塗料組成物、該下塗り塗料組成物を用いた補修塗装方法に関する。
本発明において、後述のポリイソシアネート化合物と共にポリウレタン皮膜形成成分となりうるアクリルポリオール(A1)は、ラクトン変性されていることが特徴である。
本発明においては、主剤成分(I)に含まれる顔料組成物(B1)が、体質顔料としてタルクを含む。
クリルポリオール(A1)固形分100質量部を基準として61〜250質量部、好まし
くは100〜230質量部の範囲内にあることを特徴とする。
本発明において有機溶剤(C1)としては、例えば分子量が58〜220、特に72〜200の範囲内にある有機化合物を挙げることができ、塗料分野で公知のものを制限なく使用することができるが、例えば、エステル系有機溶剤及びケトン系有機溶剤から選ばれる少なくとも1種の有機溶剤を含むことが望ましい。
上記主剤成分(I)としては、ラクトン変性アクリルポリオール(A1)、顔料組成物(B1)及び有機溶剤(C1)に加えて、粘性調整剤、硬化触媒、セルロースアセテートブチレート及びその変性物、ポリエステル樹脂、アルキッド樹脂、ポリウレタン樹脂等のラクトン変性アクリルポリオール(A1)以外の改質用樹脂、顔料分散剤、表面調整剤、樹脂粒子などの塗料用添加剤を適宜配合することができる。
本発明の下塗り塗料組成物は、上記主剤成分(I)にポリオール成分(II)を塗装直前に混合する。ポリオール成分(II)を混合することによって、各成分の貯蔵安定性は良好である上、本発明の下塗り塗料組成物による下塗り塗膜形成工程と、次工程である上塗り着色塗料組成物塗装工程をウェット・オン・ウェットで塗装したり、研磨工程を省略或いは短縮したとしても、仕上がり外観に優れた塗膜を形成する効果がある。
(メタ)アクリロイル基含有モノマーとしてはアクリルポリオール(A1)の説明で例示した化合物に加え、ラクトン変性ヒドロキシアルキル(メタ)アクリレート等を挙げることができる。また、アクリルポリオール(A2)は、アクリルポリオール(A1)の説明で列記した如き他の重合性不飽和モノマーを共重合成分とするものであることができる。
本発明においてポリイソシアネート化合物(D)としては、イソシアネート基を1分子中に2個以上有するポリイソシアネート化合物である。その具体例としては、例えばヘキサメチレンジイソシアネート、トリメチルヘキサメチレンジイソシアネ−ト、イソフォロンジイソシアネート、水添キシリレンジイソシアネート、キシリレンジイソシアネート、メタ−テトラメチルキシリレンシジイソシアネート、トリレンジイソシアネート、4,4´−ジフェニルメタンジイソシアネート、リジンジイソシアネ−ト等のポリイソシアネート化合物、またはこれらポリイソシアネートと多価アルコール、低分子量ポリエステル樹脂もしくは水等との付加物、あるいは上記した如き各ポリイソシアネート同志の環化重合体、更にはイソシアネート・ビウレット体等が挙げられ、これらは1種用いても良いし2種以上組み合わせて用いても良い。
本発明において硬化剤成分(III)としては、上記ポリイソシアネート化合物(D)を含むものであり、有機溶剤;粘性調整剤、硬化触媒、表面調整剤等の塗料用添加剤を必要に応じて配合することができる。
本発明においては、主剤成分(I)及びポリオール成分(II)に含まれる水酸基1当量に対し、硬化剤成分(III)中のイソシアネート基が0.5〜3.0当量、好ましくは0.7〜2.5の割合になるように配合することが適している。
実施例1
固形分55%のアクリル樹脂溶液(注1)30部に、酢酸ブチル6部、メチルイソブチルケトン4部、顔料分散剤1.5部、チタン白16.2部、タルク30部、硫酸バリウム11部、酸化亜鉛5.5部、ジブチル錫ジラウレート0.1部、アミド系増粘剤(脂肪酸アマイド、アミド系粘性調整剤、有効成分20%)0.8部を順次配合し混合・攪拌し、30分間分散処理をし、主剤成分を得た。該主剤成分(I)に、下記ポリオール成分(II)(注2)を50部、硬化剤成分(III)としてポリイソシアネート化合物(「スミジュールN3390EA」、商品名、住化バイエルウレタン社製)を20部使用直前に混合し下塗用塗料組成物(A−1)を得た。
反応容器に、酢酸ブチル52部を仕込み、攪拌しながら110℃まで昇温し、スチレン15部、メチルメタクリレート10部、メタクリル酸n−ブチル10部、メタクリル酸t−ブチル20部、メタクリル酸2−エチルヘキシル19部、メタクリル酸2−ヒドロキシエチル15部、プラクセルFA−2D(商品名、ダイセル化学社製、カプロラクトンとヒドロキシエチルアクリレートの反応物):10部、アクリル酸1部からなるモノマー及び重合開始剤のモノマー混合物を110℃以下で滴下用ポンプを利用して3時間かけて一定速度で滴下した。滴下終了後60分間110℃に保ち、攪拌を続けた。その後、追加触媒としてアゾビスイソブチロニトリル0.5部を酢酸ブチル7部に溶解させたものを60分間かけて一定速度で滴下した。そして滴下終了後60分間110℃に保持し、反応を終了した。得られた水酸基含有アクリル樹脂溶液は、不揮発分55%、均一な黄色透明溶液であり、樹脂の重量平均分子量は14000、水酸基価は81mgKOH/gであった。
(注2)ポリオール成分(II)
攪拌混合容器に、下記配合にて各成分を仕込み、攪拌混合してポリオール成分(II)を得た。
55%アクリル樹脂溶液(注3) 30部
70%ポリエステルポリオール樹脂溶液(注4) 30部
セルロースアセテートブチレート(注5) 40部
二酸化チタン 110部
酢酸ブチル 250部
ジブチル錫ジラウレート 0.05部
(注3)アクリル樹脂溶液(2)
反応容器に、酢酸ブチル52部を仕込み、攪拌しながら110℃まで昇温し、スチレン10部、メチルメタクリレート10部、n−ブチルメタクリレート5部、i−ブチルメタクリレート60部、メタクリル酸1部、2−ヒドロキシエチルメタクリレート14部及びアゾビスイソブチロニトリル2.3部からなるモノマー及び重合開始剤のモノマー混合物を110℃以下で滴下用ポンプを利用して3時間かけて一定速度で滴下した。滴下終了後60分間110℃に保ち、攪拌を続けた。その後、追加触媒としてアゾビスイソブチロニトリル0.5部を酢酸ブチル7部に溶解させたものを60分間かけて一定速度で滴下した。そして滴下終了後60分間110℃に保持し、反応を終了した。得られた水酸基含有アクリル樹脂溶液は、不揮発分55%、均一な黄色透明溶液であり、樹脂の重量平均分子量は18000、水酸基価は60mgKOH/gであった。
反応器に下記成分を仕込み加熱し、3時間かけて160℃から230℃まで昇温させた。
ヘキサヒドロ無水フタル酸 26.7部
アジピン酸 28部
ネオペンチルグリコ−ル 5.3部
1,6−ヘキサンジオ−ル 40部
これを230℃で1時間保ち、生成した縮合水を精留塔を用いて留去させ、酸価が2以下になったところで120℃まで冷却した後、酢酸ブチルで不揮発分70%となるよう希釈し、ポリエステルポリオール溶液を得た。樹脂の重量平均分子量は20,000、水酸価は55mgKOH/gであった。
実施例2〜6及び比較例1〜5
上記実施例1において、表1記載の配合組成とする以外は実施例1と同様にして各下塗用塗料組成物(A−2)〜(A−12)を得た。
(*)仕上がり外観
300×100×0.8mmの軟鋼板に、「LUCポリパテ」(関西ペイント社製、不飽和ポリエステルパテ)をヘラにて厚さ約2mmとなるように盛り付け、20℃で60分間乾燥させた後、該塗面をP120空研ぎペーパーで表面をならすように研磨してから、該塗面上に実施例及び比較例で得られた各下塗用塗料組成物をプライマーサーフェーサーとして、希釈シンナーで塗装時固形分50%となるように調製し、乾燥膜厚で約50μmとなるようにスプレー塗装した後、20℃で10分放置した未硬化の塗膜上に、レタンPGハイブリッドエコ#202サンメタリックベース(商品名、1液型自動車補修用上塗メタリック塗料 関西ペイント社製)を乾燥膜厚として15μmになるようにエアスプレーにて塗装した。塗装後室温にて5分間放置した未硬化の塗膜上に、レタンPGエコHX(Q)クリヤー(商品名、自動車補修用2液型トップクリヤー塗料 関西ペイント社製)を乾燥膜厚として40μmとなるようにエアスプレーにて塗装した。室温にて10分間放置後に熱風循環式乾燥炉を使用して60℃で20分間加熱して、試験板を得た。その後各試験塗板の外観をスカシ方向(斜め方向)から観察し、下記評価基準にて評価した。
◎:ツヤ感、塗面平滑性が非常に良好であり、吸い込み、プラサフ跡がいずれも認められない、
○:ツヤ感、塗面平滑性が良好であり、吸い込み、プラサフ跡がいずれも認められない、
△:ツヤ感、塗面平滑性がやや不良であり、吸い込み、プラサフ跡がいずれも認められない、
×:ツヤ感、塗面平滑性が不良であり、吸い込み、プラサフ跡のいずれかが認められる。
300×100×0.8mmの軟鋼板に、上記実施例及び比較例で得られた各下塗り塗料組成物を乾燥膜厚が60μmとなるようにスプレー塗装した後、20℃、60分乾燥させた硬化塗膜上に、レタンPGハイブリッドエコ#202サンメタリックベース(商品名、1液型自動車補修用上塗塗料 関西ペイント社製)を乾燥膜厚として15μmになるようにエアスプレーにて塗装した。塗装後室温にて5分間放置した未硬化の塗膜上に、レタンPGエコHX(Q)クリヤー(商品名、自動車補修用2液型トップクリヤー塗料 関西ペイント社製)を乾燥膜厚として40μmとなるようにエアスプレーにて塗装した。室温にて10分間放置後に熱風循環式乾燥炉を使用して60℃で20分間加熱して、試験板を得た。この試験塗板について、JIS K 5600に準拠した碁盤目試験を行った。具体的には、塗膜上に縦横に2mmの間隔で碁盤目状に素材に達する100個の切れ目を入れ、密着力(120gf/10mm)の接着テープを貼りつける。そしてこの接着テープを瞬時に剥ぎ取り、剥離して接着テープに付着した塗膜片の数量を調べて下記の基準にて評価した。
○:下塗り塗膜とメタリックベース塗膜の間で剥離なし、
△:下塗り塗膜とメタリックベース塗膜の間で剥離数10%未満、
×:下塗り塗膜とメタリックベース塗膜の間で剥離数10%以上。
仕上がり外観で得られた各試験塗板作成時の白黒隠蔽紙が隠蔽するときの膜厚を測定した。
◎:30μm以下、
○:30〜50μm、
△:50〜80μm、
×:80μm以上。
(*)耐タレ性
22×45cmの大きさの軟鋼板の長尺側の端部から3cmの部分に、直径5mmのポンチ孔を、2cm間隔で21個一列状に設けたものを被塗物とし、これに各下塗り用塗料組成物を25℃の条件下で長尺方向に膜厚勾配をつけて塗装し、該塗装板をほぼ垂直に立てて、塗板の温度を60℃に保った状態となるように20分間強制乾燥して耐タレ性試験用の試験塗板を得た。得られた各試験塗板のポンチ孔下端部から2mmの塗膜のタレが観察される位置を調べ、該位置の膜厚(タレ限界膜厚(μm))を測定することにより、耐タレ性の評価を行なった。タレ限界膜厚が大きいほど耐タレ性は良好であることを示す。
◎:タレ限界膜厚が200μm以上、
〇:タレ限界膜厚が150μm以上で且つ200μm未満、
△:タレ限界膜厚が100μm以上で且つ150μm未満、
×;タレ限界膜厚が100μm未満。
Claims (7)
- 主剤成分(I)、ポリオール成分(II)と硬化剤成分(III)とを混合して得られる多成分型有機溶剤系の下塗り塗料組成物であって、
主剤成分(I)が、ラクトン変性アクリルポリオール(A1)、顔料組成物(B1)及び有機溶剤(C1)を含み、
ポリオール成分(II)が、アクリルポリオール(A2)、顔料組成物(B2)、有機溶剤(C2)及びポリエステルポリオール(D)を含み、硬化剤成分(III)がポリイソシアネート化合物を含むものであって
主剤成分(I)に含まれる顔料組成物(B1)がその成分の一部としてタルクを含み、タルクの含有量がラクトン変性アクリルポリオール(A1)固形分100質量部を基準として、61〜250質量部にあり、
顔料組成物(B1)の含有量がアクリルポリオール(A1)固形分100質量部を基準として50〜500質量部の範囲内、
顔料組成物(B2)の含有量が、ポリオール成分(II)に含まれる樹脂の合計100質量部を基準として50〜250質量部の範囲内
にあることを特徴とする下塗り塗料組成物。 - 顔料組成物(B1)が、防錆顔料をさらに含む請求項1に記載の下塗り塗料組成物。
- 主剤成分(I)が、さらにアミド系粘性調整剤を含むものであり、該アミド系粘性調整剤の有効成分の量がラクトン変性アクリルポリオール(A1)固形分100質量部を基準として0.1〜15質量部の範囲内にある請求項1又は2に記載の下塗り塗料組成物。
- ポリオール成分(II)が、さらにセルロース誘導体を含む請求項1ないし3のいずれか1項に記載の下塗り塗料組成物。
- 請求項1ないし4のいずれか1項に記載の下塗り塗料組成物を下地塗装に用いた補修塗装方法。
- パテ塗布がされていてもよい補修部位に、請求項1ないし4のいずれか1項に記載の下塗り塗料組成物を塗装し、該下塗り塗料組成物による塗膜が未硬化の状態で上塗り着色塗料組成物を塗装する工程を含むことを特徴とする補修塗装方法。
- パテ塗布がされていてもよい補修部位に、請求項1ないし4のいずれか1項に記載の下塗り塗料組成物を塗装し、該下塗り塗料組成物による塗膜が未硬化の状態で上塗り着色塗料組成物を塗装し、該上塗り着色塗料組成物が未硬化の状態でトップクリヤー塗料を塗装し、乾燥させる工程を含むことを特徴とする補修塗装方法。
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