JP6441332B2 - ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 - Google Patents
ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 Download PDFInfo
- Publication number
- JP6441332B2 JP6441332B2 JP2016524204A JP2016524204A JP6441332B2 JP 6441332 B2 JP6441332 B2 JP 6441332B2 JP 2016524204 A JP2016524204 A JP 2016524204A JP 2016524204 A JP2016524204 A JP 2016524204A JP 6441332 B2 JP6441332 B2 JP 6441332B2
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- JP
- Japan
- Prior art keywords
- alpha
- independently
- olefin
- mmol
- hydrocarbyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Crystallography & Structural Chemistry (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361840624P | 2013-06-28 | 2013-06-28 | |
| US61/840,624 | 2013-06-28 | ||
| PCT/US2014/044374 WO2014210333A1 (en) | 2013-06-28 | 2014-06-26 | Molecular weight control of polyolefins using halogenated bis-phenylphenoxy catalysts |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018217837A Division JP6813556B2 (ja) | 2013-06-28 | 2018-11-21 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2016524024A JP2016524024A (ja) | 2016-08-12 |
| JP2016524024A5 JP2016524024A5 (cg-RX-API-DMAC7.html) | 2017-08-24 |
| JP6441332B2 true JP6441332B2 (ja) | 2018-12-19 |
Family
ID=51211353
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016524204A Active JP6441332B2 (ja) | 2013-06-28 | 2014-06-26 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
| JP2018217837A Active JP6813556B2 (ja) | 2013-06-28 | 2018-11-21 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018217837A Active JP6813556B2 (ja) | 2013-06-28 | 2018-11-21 | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US9605098B2 (cg-RX-API-DMAC7.html) |
| EP (2) | EP3925989A1 (cg-RX-API-DMAC7.html) |
| JP (2) | JP6441332B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR102218415B1 (cg-RX-API-DMAC7.html) |
| CN (2) | CN105283474A (cg-RX-API-DMAC7.html) |
| BR (1) | BR112015030912B1 (cg-RX-API-DMAC7.html) |
| ES (1) | ES2934177T3 (cg-RX-API-DMAC7.html) |
| SG (2) | SG11201510689SA (cg-RX-API-DMAC7.html) |
| WO (1) | WO2014210333A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG11201503581PA (en) | 2012-12-27 | 2015-06-29 | Dow Global Technologies Llc | Catalyst systems for olefin polymerization |
| KR20150103082A (ko) * | 2012-12-27 | 2015-09-09 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌계 중합체를 제조하기 위한 중합 방법 |
| ES2720207T3 (es) | 2012-12-27 | 2019-07-18 | Dow Global Technologies Llc | Un proceso de polimerización para producir polímeros a base de etileno |
| JP6441332B2 (ja) * | 2013-06-28 | 2018-12-19 | ダウ グローバル テクノロジーズ エルエルシー | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
| CN106459288B (zh) * | 2014-06-30 | 2020-06-09 | 陶氏环球技术有限责任公司 | 烯烃聚合方法 |
| WO2016014749A1 (en) * | 2014-07-24 | 2016-01-28 | Dow Global Technologies Llc | Bis-biphenylphenoxy catalysts for polymerization of low molecular weight ethylene-based polymers |
| US11041027B2 (en) | 2015-06-30 | 2021-06-22 | Dow Global Technologies Llc | Polymerization process for producing ethylene based polymers |
| KR102588244B1 (ko) | 2015-06-30 | 2023-10-12 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌계 폴리머를 제조하는 중합 방법 |
| KR102589562B1 (ko) | 2015-09-30 | 2023-10-16 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌계 폴리머를 제조하기 위한 중합 방법 |
| BR112018006183B1 (pt) | 2015-09-30 | 2022-06-14 | Dow Global Technologies Llc | Pró-catalisador e processo de polimerização |
| KR102423018B1 (ko) | 2016-07-29 | 2022-07-21 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합을 위한 실릴-가교 비스-바이페닐-페녹시 촉매 |
| KR102631009B1 (ko) * | 2017-03-15 | 2024-01-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 다중-블록 공중합체 형성을 위한 촉매 시스템 |
| KR102533900B1 (ko) | 2017-03-31 | 2023-05-18 | 다우 글로벌 테크놀로지스 엘엘씨 | 올레핀 중합을 위한 게르마늄-브릿지된 비스-바이페닐-페녹시 촉매 |
| ES2988640T3 (es) | 2017-03-31 | 2024-11-21 | Dow Global Technologies Llc | Catalizadores de bis-bifenil-fenoxilo para la polimerización de olefinas |
| WO2019067280A1 (en) | 2017-09-29 | 2019-04-04 | Dow Global Technologies Llc | BIS-PHENYL-PHENOXY-POLYOLEFIN CATALYSTS HAVING ALKOXY OR AMIDO-TYPE LIGAND ON METAL FOR ENHANCED SOLUBILITY |
| SG11202002719VA (en) | 2017-09-29 | 2020-04-29 | Dow Global Technologies Llc | Bis-phenyl-phenoxy polyolefin catalysts having a methylenetrialkylsilicon ligand on the metal for improved solubility |
| US11066489B2 (en) | 2017-09-29 | 2021-07-20 | Dow Global Technologies Llc | Bis-phenyl-phenoxy polyolefin catalysts having two methylenetrialkylsilicon ligands on the metal for improved solubility |
| KR102100142B1 (ko) * | 2017-12-21 | 2020-04-14 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 금속-리간드 착체, 이를 포함하는 에틸렌계 중합용 촉매 조성물 및 이를 이용한 에틸렌계 중합체의 제조방법 |
| WO2019191098A1 (en) * | 2018-03-30 | 2019-10-03 | Dow Global Technologies Llc | Olefin polymerization activators |
| CN111918717B (zh) * | 2018-03-30 | 2024-04-09 | 陶氏环球技术有限责任公司 | 烯烃聚合活化剂 |
| CN112585172B (zh) | 2018-08-30 | 2023-05-23 | 陶氏环球技术有限责任公司 | 具有两个蒽基配体的双苯基苯氧基聚烯烃主催化剂 |
| CN113423742B (zh) * | 2019-02-12 | 2023-05-05 | 埃克森美孚化学专利公司 | 双(芳基酚盐)路易斯碱催化剂及其方法 |
| KR20220097897A (ko) | 2019-11-04 | 2022-07-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 티타늄 바이페닐페놀 중합 촉매 |
| JP7730316B2 (ja) | 2019-11-04 | 2025-08-27 | ダウ グローバル テクノロジーズ エルエルシー | ビフェニルフェノール重合触媒 |
| MX2022005288A (es) | 2019-11-04 | 2022-05-24 | Dow Global Technologies Llc | Sistemas catalizadores bimodales. |
| CN115023445B (zh) * | 2019-12-19 | 2025-03-14 | 陶氏环球技术有限责任公司 | 气相联苯酚聚合催化剂 |
| EP4097151B1 (en) | 2020-01-31 | 2025-08-06 | Dow Global Technologies LLC | Group iii and lanthanide bis-phenyl-phenoxy metal-ligand complexes |
| JP2024500603A (ja) * | 2020-12-28 | 2024-01-10 | サビック エスケー ネクスレン カンパニー プライヴェート リミテッド | 金属-リガンド錯体、これを含むエチレン系重合体製造用の触媒組成物およびこれを用いたエチレン系重合体の製造方法 |
| KR20230155453A (ko) * | 2021-02-15 | 2023-11-10 | 다우 글로벌 테크놀로지스 엘엘씨 | 역상 공단량체 분포를 갖는 폴리(에틸렌-코-1-알켄) 공중합체의 제조 방법 |
| CN116848157A (zh) * | 2021-02-15 | 2023-10-03 | 陶氏环球技术有限责任公司 | 具有改进的动力学诱导时间的联苯酚聚合催化剂 |
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| ES2720207T3 (es) | 2012-12-27 | 2019-07-18 | Dow Global Technologies Llc | Un proceso de polimerización para producir polímeros a base de etileno |
| JP6441332B2 (ja) * | 2013-06-28 | 2018-12-19 | ダウ グローバル テクノロジーズ エルエルシー | ハロゲン化ビス−フェニルフェノキシ触媒を使用するポリオレフィンの分子量制御 |
| KR102173912B1 (ko) | 2013-06-28 | 2020-11-05 | 다우 글로벌 테크놀로지스 엘엘씨 | 초분지된 에틸렌계 올리고머 |
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| CN105722913B (zh) | 2013-09-25 | 2018-03-16 | 三菱化学株式会社 | 软质氯乙烯系树脂组合物、成形体、电线包覆材及经包覆的电线 |
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2014
- 2014-06-26 JP JP2016524204A patent/JP6441332B2/ja active Active
- 2014-06-26 EP EP21183736.4A patent/EP3925989A1/en active Pending
- 2014-06-26 WO PCT/US2014/044374 patent/WO2014210333A1/en not_active Ceased
- 2014-06-26 ES ES14741484T patent/ES2934177T3/es active Active
- 2014-06-26 SG SG11201510689SA patent/SG11201510689SA/en unknown
- 2014-06-26 SG SG10201802443VA patent/SG10201802443VA/en unknown
- 2014-06-26 EP EP14741484.1A patent/EP3013871B1/en active Active
- 2014-06-26 CN CN201480033642.XA patent/CN105283474A/zh active Pending
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| BR112015030912B1 (pt) | 2021-08-03 |
| JP2016524024A (ja) | 2016-08-12 |
| WO2014210333A1 (en) | 2014-12-31 |
| CN105283474A (zh) | 2016-01-27 |
| US20170158790A1 (en) | 2017-06-08 |
| EP3013871B1 (en) | 2022-10-19 |
| JP6813556B2 (ja) | 2021-01-13 |
| KR20160037890A (ko) | 2016-04-06 |
| ES2934177T3 (es) | 2023-02-17 |
| CN113201084A (zh) | 2021-08-03 |
| JP2019049003A (ja) | 2019-03-28 |
| SG11201510689SA (en) | 2016-01-28 |
| US20160108156A1 (en) | 2016-04-21 |
| BR112015030912A2 (pt) | 2017-07-25 |
| SG10201802443VA (en) | 2018-05-30 |
| KR102218415B1 (ko) | 2021-02-22 |
| US10144791B2 (en) | 2018-12-04 |
| EP3925989A1 (en) | 2021-12-22 |
| BR112015030912A8 (pt) | 2020-01-28 |
| EP3013871A1 (en) | 2016-05-04 |
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