JP6430410B2 - ガス透過膜を含むリチウム二次電池 - Google Patents
ガス透過膜を含むリチウム二次電池 Download PDFInfo
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- JP6430410B2 JP6430410B2 JP2015560127A JP2015560127A JP6430410B2 JP 6430410 B2 JP6430410 B2 JP 6430410B2 JP 2015560127 A JP2015560127 A JP 2015560127A JP 2015560127 A JP2015560127 A JP 2015560127A JP 6430410 B2 JP6430410 B2 JP 6430410B2
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- gas permeable
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- battery
- permeable membrane
- secondary battery
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- 239000006260 foam Substances 0.000 description 1
- BLBBMBKUUHYSMI-UHFFFAOYSA-N furan-2,3,4,5-tetrol Chemical compound OC=1OC(O)=C(O)C=1O BLBBMBKUUHYSMI-UHFFFAOYSA-N 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- PVADDRMAFCOOPC-UHFFFAOYSA-N germanium monoxide Inorganic materials [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 230000010220 ion permeability Effects 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 239000001989 lithium alloy Substances 0.000 description 1
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 1
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Inorganic materials [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 description 1
- 229910002102 lithium manganese oxide Inorganic materials 0.000 description 1
- QEXMICRJPVUPSN-UHFFFAOYSA-N lithium manganese(2+) oxygen(2-) Chemical class [O-2].[Mn+2].[Li+] QEXMICRJPVUPSN-UHFFFAOYSA-N 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 1
- VROAXDSNYPAOBJ-UHFFFAOYSA-N lithium;oxido(oxo)nickel Chemical compound [Li+].[O-][Ni]=O VROAXDSNYPAOBJ-UHFFFAOYSA-N 0.000 description 1
- URIIGZKXFBNRAU-UHFFFAOYSA-N lithium;oxonickel Chemical compound [Li].[Ni]=O URIIGZKXFBNRAU-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229940017219 methyl propionate Drugs 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 150000005181 nitrobenzenes Chemical class 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 229910021470 non-graphitizable carbon Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000001008 quinone-imine dye Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 238000010532 solid phase synthesis reaction Methods 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 239000006234 thermal black Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
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Description
電解質と、
電極積層体と、
前記電解質及び前記電極積層体を内蔵する空間部と、前記空間部を取り囲んでいる密封部とを含む電池ケースと、
ガス透過膜と、
を含んでいてもよい。
1つ以上の正極、1つ以上の負極、及び1つ以上の分離膜を含み、正極、分離膜、負極が、正極と負極との間に分離膜が介在するように積層されている積層構造を含む電極積層体と、
電解質と、
を含むことを特徴とするリチウム二次電池を提供する。
LixMyMn2−yO4−zAz (1)
上記式中、
0.9≦x≦1.2、0<y<2、0≦z<0.2であり、
Mは、Al、Mg、Ni、Co、Fe、Cr、V、Ti、Cu、B、Ca、Zn、Zr、Nb、Mo、Sr、Sb、W、Ti及びBiからなる群から選択される1つ以上の元素であり、
Aは、−1または−2価の1つ以上のアニオンである。
(1−x)LiM’O2−yAy −xLi2MnO3−y’Ay’ (2)
上記式中、
M’は、MnaMbであり、
Mは、Ni、Ti、Co、Al、Cu、Fe、Mg、B、Cr、Zr、Zn及び第2周期の遷移金属からなる群から選択される1つ以上であり、
Aは、PO4、BO3、CO3、F及びNO3のアニオンからなる群から選択される1つ以上であり、
0<x<1、0<y≦0.02、0<y’≦0.02、0.5≦a≦1.0、0≦b≦0.5、a+b=1である。
バインダーを溶媒に分散または溶解させてバインダー溶液を製造する過程と、
前記バインダー溶液と電極活物質及び導電材を混合して電極スラリーを製造する過程と、
前記電極スラリーを集電体上にコーティングする過程と、
電極を乾燥する過程と、
電極を一定の厚さに圧縮する過程とを含む。
LixMyMn2−yO4−zAz (1)
上記式中、0.9≦x≦1.2、0<y<2、0≦z<0.2であり、
Mは、Al、Mg、Ni、Co、Fe、Cr、V、Ti、Cu、B、Ca、Zn、Zr、Nb、Mo、Sr、Sb、W、Ti及びBiからなる群から選択される1つ以上の元素であり、
Aは、−1または−2価の1つ以上のアニオンである。
LixNiyMn2−yO4 (2)
上記式中、0.9≦x≦1.2、0.4≦y≦0.5である。
LiaM’bO4−cAc (3)
上記式中、M’は、Ti、Sn、Cu、Pb、Sb、Zn、Fe、In、Al及びZrからなる群から選択される1つ以上の元素であり、
a及びbは、0.1≦a≦4、0.2≦b≦4の範囲においてM’の酸化数(oxidation number)に応じて決定され、
cは、0≦c<0.2の範囲において酸化数に応じて決定され、
Aは、−1または−2価の1つ以上のアニオンである。
LiaTibO4 (4)
上記式中、0.5≦a≦3、1≦b≦2.5である。
前記デバイスは、具体的に、携帯電話、携帯用コンピュータ、スマートフォン、スマートパッド、ネットブック、LEV(Light Electronic Vehicle)、電気自動車、ハイブリッド電気自動車、プラグインハイブリッド電気自動車、及び電力貯蔵装置からなる群から選択されてもよい。
図1を参照すると、リチウム二次電池10は、電極積層体100、電池ケース200、ガス透過膜300、及び電解質(図示せず)からなっている。電池ケース200は、空間部210と密封部220を含んでおり、電極積層体100は空間部210に内蔵されている。ガス透過膜300は、電極積層体100と密封部220との間に設けられている。したがって、電極積層体100から発生したガスは、ガス透過膜300に排出された後、密封部220を通して電池の外部に排出され得る。一方、電解質はガス透過膜300を通過できないので、電解質が漏出することを防止することができる。
図2を参照すると、電池ケース20は、第1ケース21及び第2ケース22からなっている。第2ケース22は、第1ケース21から延びている構造となっている。
20 電池ケース
20A 内部シーラント層
20B バリア層
20C 外部被覆層
20D 気孔
21 第1ケース
22 第2ケース
100 電極積層体
200 電池ケース
210 空間部
220 密封部
300 ガス透過膜
Claims (7)
- 電解質と、
電極積層体と、
前記電解質及び前記電極積層体を内蔵する空間部と、前記空間部を取り囲んでいる密封部とを含む電池ケースと、
第1のガス透過膜及び第2のガス透過膜と、
を含み、
前記電池ケースは、第1ケースと、前記第1ケースと結合して電池ケースを密封する第2ケースとを含み、
前記第1のガス透過膜は、前記空間部に設置され、
前記第1及び第2のガス透過膜は、液体非透過性であり、
前記第1及び第2のガス透過膜は、気孔の大きさが2.0Å以上〜10Å以下の範囲内であり、
前記第1のガス透過膜は、垂直断面視で前記電極積層体と密封部との間に設置され、
前記第1のガス透過膜は、垂直断面視で空間部を分割するように前記第1ケースと前記第2ケースとの間に配置され、
前記第2のガス透過膜は前記密封部を貫通し、
前記第2のガス透過膜は、前記第1ケースと前記第2ケースとの接合面に介在し、
前記第1及び第2のガス透過膜は、酸素(O 2 )及び二酸化炭素(CO 2 )を選択的に透過する選択的ガス透過膜であることを特徴とする、リチウム二次電池。 - 前記第1及び第2のガス透過膜はポリエチレンテレフタレート(PET)からなることを特徴とする、請求項1に記載のリチウム二次電池。
- 正極活物質として、下記化学式(1)で表される化合物及び下記化学式(2)で表される化合物から選択された1つ以上のリチウム遷移金属酸化物を含んでいることを特徴とする、請求項1に記載のリチウム二次電池。
LixMyMn2−yO4−zAz (1)
上記式中、
0.9≦x≦1.2、0<y<2、0≦z<0.2であり、
Mは、Al、Mg、Ni、Co、Fe、Cr、V、Ti、Cu、B、Ca、Zn、Zr、Nb、Mo、Sr、Sb、W、Ti及びBiからなる群から選択される1つ以上の元素であり、
Aは、−1または−2価の1つ以上のアニオンである。
(1−x)LiM’O2−yAy −xLi2MnO3−y’Ay’ (2) 上記式中、
M’は、MnaMbであり、
Mは、Ni、Ti、Co、Al、Cu、Fe、Mg、B、Cr、Zr、Zn及び第2周期の遷移金属からなる群から選択される1つ以上であり、
Aは、PO4、BO3、CO3、F及びNO3のアニオンからなる群から選択される1つ以上であり、
0<x<1、0<y≦0.02、0<y’≦0.02、0.5≦a≦1.0、0≦b≦0.5、a+b=1である。 - 負極活物質として、炭素系物質及び/又はSiを含むことを特徴とする、請求項3に記載のリチウム二次電池。
- 前記リチウム二次電池は、リチウムイオン電池、リチウムイオンポリマー電池、またはリチウムポリマー電池であることを特徴とする、請求項3に記載のリチウム二次電池。
- 請求項1に記載のリチウム二次電池を含むことを特徴とする電池パック。
- 請求項6に記載の電池パックをエネルギー源として使用するデバイス。
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