JP6313305B2 - 金属錯体 - Google Patents

金属錯体 Download PDF

Info

Publication number
JP6313305B2
JP6313305B2 JP2015528642A JP2015528642A JP6313305B2 JP 6313305 B2 JP6313305 B2 JP 6313305B2 JP 2015528642 A JP2015528642 A JP 2015528642A JP 2015528642 A JP2015528642 A JP 2015528642A JP 6313305 B2 JP6313305 B2 JP 6313305B2
Authority
JP
Japan
Prior art keywords
group
optionally substituted
membered
nitrogen
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2015528642A
Other languages
English (en)
Japanese (ja)
Other versions
JP2015535809A (ja
JP2015535809A5 (https=
Inventor
ガブリエル ジョブ，
ガブリエル ジョブ，
スコット ディー． アレン，
スコット ディー． アレン，
クリストファー シモノー，
クリストファー シモノー，
ロナルド バレンテ，
ロナルド バレンテ，
ジェイ ジェイ． ファーマ—，
ジェイ ジェイ． ファーマ―，
Original Assignee
サウジ アラムコ テクノロジーズ カンパニー
サウジ アラムコ テクノロジーズ カンパニー
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by サウジ アラムコ テクノロジーズ カンパニー, サウジ アラムコ テクノロジーズ カンパニー filed Critical サウジ アラムコ テクノロジーズ カンパニー
Publication of JP2015535809A publication Critical patent/JP2015535809A/ja
Publication of JP2015535809A5 publication Critical patent/JP2015535809A5/ja
Application granted granted Critical
Publication of JP6313305B2 publication Critical patent/JP6313305B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06—Cobalt compounds
    • C07F15/065—Cobalt compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2217—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/80—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/02—Aliphatic polycarbonates
    • C08G64/0208—Aliphatic polycarbonates saturated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/32—General preparatory processes using carbon dioxide
    • C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2015528642A 2012-08-24 2013-08-22 金属錯体 Active JP6313305B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261693000P 2012-08-24 2012-08-24
US61/693,000 2012-08-24
PCT/US2013/056102 WO2014031811A1 (en) 2012-08-24 2013-08-22 Metal complexes

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2018004171A Division JP2018052995A (ja) 2012-08-24 2018-01-15 金属錯体

Publications (3)

Publication Number Publication Date
JP2015535809A JP2015535809A (ja) 2015-12-17
JP2015535809A5 JP2015535809A5 (https=) 2016-09-29
JP6313305B2 true JP6313305B2 (ja) 2018-04-18

Family

ID=50150376

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2015528642A Active JP6313305B2 (ja) 2012-08-24 2013-08-22 金属錯体
JP2018004171A Withdrawn JP2018052995A (ja) 2012-08-24 2018-01-15 金属錯体

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2018004171A Withdrawn JP2018052995A (ja) 2012-08-24 2018-01-15 金属錯体

Country Status (7)

Country Link
US (2) US9771388B2 (https=)
EP (1) EP2888271B1 (https=)
JP (2) JP6313305B2 (https=)
KR (1) KR102096761B1 (https=)
CN (1) CN104781268B (https=)
ES (1) ES2761880T3 (https=)
WO (1) WO2014031811A1 (https=)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102128706B1 (ko) 2008-08-22 2020-07-02 사우디 아람코 테크놀로지스 컴퍼니 촉매 및 중합체 합성방법
EP2707353B1 (en) 2011-05-13 2021-03-31 Novomer, Inc. Carbonylation catalysts and method
KR102024510B1 (ko) 2011-07-18 2019-11-14 사우디 아람코 테크놀로지스 컴퍼니 금속 착체
WO2013067460A1 (en) 2011-11-04 2013-05-10 Novomer, Inc. Metal complexes for the copolymerization of carbon dioxide and epoxides
US9403861B2 (en) 2011-12-11 2016-08-02 Novomer, Inc. Salen complexes with dianionic counterions
EP2888271B1 (en) 2012-08-24 2019-11-06 Saudi Aramco Technologies Company Metal complexes
WO2019126221A1 (en) 2017-12-22 2019-06-27 Saudi Aramco Technologies Company Catalysts for polycarbonate production
JP2021522355A (ja) 2018-04-18 2021-08-30 サウジ アラムコ テクノロジーズ カンパニー ポリ（アルキレンカーボネート）ポリマーの末端基異性化
WO2020028606A1 (en) 2018-08-02 2020-02-06 Saudi Aramco Technologies Company Sustainable polymer compositions and methods
MA53727A (fr) 2018-09-24 2021-12-29 Saudi Aramco Tech Co Copolymères séquencés de polycarbonate et procédés associés
TWI906317B (zh) 2020-06-24 2025-12-01 沙烏地阿拉伯商沙烏地阿美科技公司 多元醇組合物及方法
WO2022153149A1 (en) 2021-01-12 2022-07-21 Saudi Aramco Technologies Company Continuous manufacturing of polyol
US12195576B2 (en) 2021-06-23 2025-01-14 Saudi Aramco Technologies Company Polyol compositions and methods

Family Cites Families (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69128528T2 (de) 1990-03-21 1998-07-30 Res Corp Technologies Inc Chirale katalysatoren und dadurch katalysierte epoxydierungsreaktionen
US5637739A (en) 1990-03-21 1997-06-10 Research Corporation Technologies, Inc. Chiral catalysts and catalytic epoxidation catalyzed thereby
US5696109A (en) 1992-12-07 1997-12-09 Eukarion, Inc. Synthetic catalytic free radical scavengers useful as antioxidants for prevention and therapy of disease
US6030917A (en) 1996-07-23 2000-02-29 Symyx Technologies, Inc. Combinatorial synthesis and analysis of organometallic compounds and catalysts
US5665890A (en) 1995-03-14 1997-09-09 President And Fellows Of Harvard College Stereoselective ring opening reactions
WO1998004538A1 (en) 1996-07-26 1998-02-05 Princeton University Catalytic oxygenation of hydrocarbons by metalloporphyrin and metallosalen complexes
TWI246520B (en) 1997-04-25 2006-01-01 Mitsui Chemicals Inc Processes for olefin polymerization
US6130340A (en) 1998-01-13 2000-10-10 President And Fellows Of Harvard College Asymmetric cycloaddition reactions
US6521561B1 (en) 1998-05-01 2003-02-18 President And Fellows Of Harvard College Main-group metal based asymmetric catalysts and applications thereof
KR100342659B1 (en) 2000-12-15 2002-07-04 Rstech Co Ltd Chiral polymer salene catalyst and process for preparing chiral compounds from racemic epoxide using the same
US6884750B2 (en) 2001-06-27 2005-04-26 Rs Tech Corp. Chiral salen catalyst and methods for the preparation of chiral compounds from racemic epoxides by using new catalyst
US6639087B2 (en) 2001-08-22 2003-10-28 Rhodia Pharma Solutions Inc. Kinetic resolution method
DE10235316A1 (de) 2002-08-01 2004-02-12 Basf Ag Katalysator und Verfahren zur Carbonylierung von Oxiranen
US7304172B2 (en) * 2004-10-08 2007-12-04 Cornell Research Foundation, Inc. Polycarbonates made using highly selective catalysts
KR100724550B1 (ko) 2004-12-16 2007-06-04 주식회사 엘지화학 이중 금속 아연 착화합물과 이를 촉매로 사용한폴리카보네이트의 제조 방법
WO2006099162A2 (en) 2005-03-14 2006-09-21 Georgia Tech Research Corporation Polymeric salen compounds and methods thereof
US7399822B2 (en) 2005-06-21 2008-07-15 Cornell Research Foundation, Inc. Isotactic specific catalyst for direct production of highly isotactic poly (propylene oxide) or highly isotactic poly (butylene oxide)
GB0607096D0 (en) 2006-04-07 2006-05-17 Imp Innovations Ltd Compound
US8232267B2 (en) 2006-10-06 2012-07-31 The Trustees Of Princeton University Porphyrin catalysts and methods of use thereof
GB0708016D0 (en) 2007-04-25 2007-06-06 Univ Newcastle Synthesis of cyclic carbonates
EP2573126B1 (en) 2007-05-04 2014-09-24 SK Innovation Co. Ltd. A process for producing polycarbonates and a coordination complex used therefor
WO2008150033A1 (ja) 2007-06-08 2008-12-11 The University Of Tokyo エポキシドと二酸化炭素との立体選択的交互共重合
EP2096132A1 (en) 2008-02-26 2009-09-02 Total Petrochemicals Research Feluy Monomers issued from renewable resources and process for polymerising them
BRPI0908982B8 (pt) 2008-03-07 2018-08-07 Univ Newcastle síntese de carbonatos cíclicos
CN104193980B (zh) 2008-05-09 2018-11-13 康奈尔大学 环氧乙烷与二氧化碳的聚合物
US7858729B2 (en) 2008-05-29 2010-12-28 Novomer, Inc. Methods of controlling molecular weight distribution of polymers and compositions thereof
CA2727959A1 (en) 2008-07-30 2010-02-04 Sk Energy, Co., Ltd. Novel coordination complexes and process of producing polycarbonate by copolymerization of carbon dioxide and epoxide using the same as catalyst
KR102128706B1 (ko) 2008-08-22 2020-07-02 사우디 아람코 테크놀로지스 컴퍼니 촉매 및 중합체 합성방법
CN103333330A (zh) 2008-09-08 2013-10-02 诺沃梅尔公司 聚碳酸酯多元醇组合物和方法
WO2010033703A1 (en) 2008-09-17 2010-03-25 Novomer, Inc. Purification of polycarbonates
CA2639870A1 (en) 2008-09-29 2010-03-29 Nova Chemicals Corporation Trimerization
US8580911B2 (en) 2008-11-01 2013-11-12 Novomer, Inc. Polycarbonate block copolymers
CN101412809B (zh) * 2008-11-28 2011-04-27 大连理工大学 用于合成聚碳酸酯的单活性点催化剂
GB0904654D0 (en) * 2009-03-18 2009-04-29 Univ Newcastle Synthesis of cyclic carbonates
KR101221404B1 (ko) 2009-06-18 2013-01-11 아주대학교산학협력단 이산화탄소/에폭사이드 공중합 촉매 시스템
CN102665406B (zh) 2009-12-24 2016-03-09 诺沃梅尔公司 合成多环胍化合物的方法
KR101503745B1 (ko) 2010-02-25 2015-03-19 에스케이이노베이션 주식회사 나이트레이트 음이온의 이산화탄소/에폭사이드 공중합 촉매 시스템
WO2011163133A1 (en) 2010-06-20 2011-12-29 Novomer, Inc. Aliphatic polycarbonates
KR101983006B1 (ko) 2010-08-27 2019-05-29 사우디 아람코 테크놀로지스 컴퍼니 중합체 조성물 및 방법
EP2609090A4 (en) 2010-08-28 2013-12-25 Novomer Inc AMMONIC ACID ANHYDRIDE FROM ETHYLENE OXIDE
KR101805648B1 (ko) 2010-09-14 2017-12-14 사우디 아람코 테크놀로지스 컴퍼니 중합체 합성용의 촉매 및 방법
KR101963568B1 (ko) 2010-09-22 2019-07-31 사우디 아람코 테크놀로지스 컴퍼니 치환된 살리실알데하이드 유도체의 합성
EP3584265B1 (en) 2010-11-23 2023-03-15 Saudi Aramco Technologies Company Polycarbonate polyol compositions
US8952104B2 (en) 2011-01-06 2015-02-10 Novomer, Inc. Polymer compositions and methods
CN103687584B (zh) * 2011-01-28 2016-03-30 罗地亚管理公司 表现出低眼刺激潜能的个人清洁体系
HUE036462T2 (hu) 2011-05-09 2018-07-30 Saudi Aramco Tech Co Polimer készítmények és eljárások
EP2707353B1 (en) 2011-05-13 2021-03-31 Novomer, Inc. Carbonylation catalysts and method
KR102024510B1 (ko) 2011-07-18 2019-11-14 사우디 아람코 테크놀로지스 컴퍼니 금속 착체
IN2014CN01299A (https=) 2011-07-25 2015-04-24 Novomer Inc
KR20190059988A (ko) 2011-08-08 2019-05-31 사우디 아람코 테크놀로지스 컴퍼니 폴리머 합성용 촉매 및 방법
GB201115565D0 (en) 2011-09-08 2011-10-26 Imp Innovations Ltd Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent
WO2013055747A1 (en) 2011-10-10 2013-04-18 Novomer, Inc. Methods to produce alkylated polycyclic guanidine compounds
WO2013067460A1 (en) 2011-11-04 2013-05-10 Novomer, Inc. Metal complexes for the copolymerization of carbon dioxide and epoxides
US9403861B2 (en) 2011-12-11 2016-08-02 Novomer, Inc. Salen complexes with dianionic counterions
WO2013096602A1 (en) 2011-12-20 2013-06-27 Novomer, Inc. Methods for polymer synthesis
CN102558199B (zh) * 2011-12-31 2014-10-22 中国科学院长春应用化学研究所 四齿席夫碱金属配合物、金属卟啉配合物和制备聚碳酸酯的方法
WO2013138161A1 (en) 2012-03-12 2013-09-19 Novomer, Inc. Polymer compositions and methods
EP2838954B1 (en) 2012-04-16 2024-09-18 Saudi Aramco Technologies Company Adhesive compositions and methods
US20140024795A1 (en) 2012-04-25 2014-01-23 Novomer, Inc. Aliphatic polycarbonate polyols containing silyl groups
JP6527080B2 (ja) 2012-05-24 2019-06-05 サウジ アラムコ テクノロジーズ カンパニー ポリカーボネートポリオール組成物および方法
EP2888271B1 (en) 2012-08-24 2019-11-06 Saudi Aramco Technologies Company Metal complexes

Also Published As

Publication number Publication date
US9771388B2 (en) 2017-09-26
EP2888271A1 (en) 2015-07-01
JP2018052995A (ja) 2018-04-05
CN104781268B (zh) 2019-05-21
CN104781268A (zh) 2015-07-15
JP2015535809A (ja) 2015-12-17
US20150232496A1 (en) 2015-08-20
WO2014031811A1 (en) 2014-02-27
KR20150046252A (ko) 2015-04-29
ES2761880T3 (es) 2020-05-21
EP2888271A4 (en) 2016-05-04
KR102096761B1 (ko) 2020-04-03
US20170349616A1 (en) 2017-12-07
EP2888271B1 (en) 2019-11-06

Similar Documents

Publication Publication Date Title
JP6313305B2 (ja) 金属錯体
JP6110379B2 (ja) 金属錯体
JP2014522863A5 (https=)
CN103140482B (zh) 由环氧乙烷制备的丁二酸酐
JP6670011B2 (ja) 金属錯体の合成およびその使用
JP6847843B2 (ja) ポリプロピオラクトンの生成のためのプロセスおよびシステム
US9327280B2 (en) Catalytic carbonylation catalysts and methods
Liu et al. Bis (imino) aryl NCN pincer aluminum and zinc complexes: synthesis, characterization, and catalysis on l-Lactide polymerization
CN106232607A (zh) 环氧化物羰基化催化剂
KR20140106725A (ko) 폴리머 합성 방법
Jeon et al. CO 2/ethylene oxide copolymerization and ligand variation for a highly active salen–cobalt (iii) complex tethering 4 quaternary ammonium salts
Liu et al. Alternating ring-opening copolymerization of styrene oxide and maleic anhydride using asymmetrical bis-Schiff-base metal (III) catalysts
TWI614259B (zh) 雙金屬鎳錯合物、其製備方法及其用途
Li Copolymerization of Ethene and Functionalized Comonomers with Cationic α-Diimine Palladium Catalysts
Abbina Synthesis And Catalytic Studies Of Zinc Complexes Of Amido-Oxazolinate Ligands

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20160809

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20160809

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20170518

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20170525

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20170825

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20170825

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20170915

A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A711

Effective date: 20171211

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20180115

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20180124

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20180308

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20180322

R150 Certificate of patent or registration of utility model

Ref document number: 6313305

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250