KR102096761B1 - 금속 착물 - Google Patents
금속 착물 Download PDFInfo
- Publication number
- KR102096761B1 KR102096761B1 KR1020157007284A KR20157007284A KR102096761B1 KR 102096761 B1 KR102096761 B1 KR 102096761B1 KR 1020157007284 A KR1020157007284 A KR 1020157007284A KR 20157007284 A KR20157007284 A KR 20157007284A KR 102096761 B1 KR102096761 B1 KR 102096761B1
- Authority
- KR
- South Korea
- Prior art keywords
- group
- nitrogen
- optionally substituted
- membered
- metallosalenate complex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2217—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
- C08F4/80—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/02—Aliphatic polycarbonates
- C08G64/0208—Aliphatic polycarbonates saturated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/32—General preparatory processes using carbon dioxide
- C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261693000P | 2012-08-24 | 2012-08-24 | |
| US61/693,000 | 2012-08-24 | ||
| PCT/US2013/056102 WO2014031811A1 (en) | 2012-08-24 | 2013-08-22 | Metal complexes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20150046252A KR20150046252A (ko) | 2015-04-29 |
| KR102096761B1 true KR102096761B1 (ko) | 2020-04-03 |
Family
ID=50150376
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020157007284A Active KR102096761B1 (ko) | 2012-08-24 | 2013-08-22 | 금속 착물 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US9771388B2 (https=) |
| EP (1) | EP2888271B1 (https=) |
| JP (2) | JP6313305B2 (https=) |
| KR (1) | KR102096761B1 (https=) |
| CN (1) | CN104781268B (https=) |
| ES (1) | ES2761880T3 (https=) |
| WO (1) | WO2014031811A1 (https=) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102128706B1 (ko) | 2008-08-22 | 2020-07-02 | 사우디 아람코 테크놀로지스 컴퍼니 | 촉매 및 중합체 합성방법 |
| EP2707353B1 (en) | 2011-05-13 | 2021-03-31 | Novomer, Inc. | Carbonylation catalysts and method |
| KR102024510B1 (ko) | 2011-07-18 | 2019-11-14 | 사우디 아람코 테크놀로지스 컴퍼니 | 금속 착체 |
| WO2013067460A1 (en) | 2011-11-04 | 2013-05-10 | Novomer, Inc. | Metal complexes for the copolymerization of carbon dioxide and epoxides |
| US9403861B2 (en) | 2011-12-11 | 2016-08-02 | Novomer, Inc. | Salen complexes with dianionic counterions |
| EP2888271B1 (en) | 2012-08-24 | 2019-11-06 | Saudi Aramco Technologies Company | Metal complexes |
| WO2019126221A1 (en) | 2017-12-22 | 2019-06-27 | Saudi Aramco Technologies Company | Catalysts for polycarbonate production |
| JP2021522355A (ja) | 2018-04-18 | 2021-08-30 | サウジ アラムコ テクノロジーズ カンパニー | ポリ(アルキレンカーボネート)ポリマーの末端基異性化 |
| WO2020028606A1 (en) | 2018-08-02 | 2020-02-06 | Saudi Aramco Technologies Company | Sustainable polymer compositions and methods |
| MA53727A (fr) | 2018-09-24 | 2021-12-29 | Saudi Aramco Tech Co | Copolymères séquencés de polycarbonate et procédés associés |
| TWI906317B (zh) | 2020-06-24 | 2025-12-01 | 沙烏地阿拉伯商沙烏地阿美科技公司 | 多元醇組合物及方法 |
| WO2022153149A1 (en) | 2021-01-12 | 2022-07-21 | Saudi Aramco Technologies Company | Continuous manufacturing of polyol |
| US12195576B2 (en) | 2021-06-23 | 2025-01-14 | Saudi Aramco Technologies Company | Polyol compositions and methods |
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| DE69128528T2 (de) | 1990-03-21 | 1998-07-30 | Res Corp Technologies Inc | Chirale katalysatoren und dadurch katalysierte epoxydierungsreaktionen |
| US5637739A (en) | 1990-03-21 | 1997-06-10 | Research Corporation Technologies, Inc. | Chiral catalysts and catalytic epoxidation catalyzed thereby |
| US5696109A (en) | 1992-12-07 | 1997-12-09 | Eukarion, Inc. | Synthetic catalytic free radical scavengers useful as antioxidants for prevention and therapy of disease |
| US6030917A (en) | 1996-07-23 | 2000-02-29 | Symyx Technologies, Inc. | Combinatorial synthesis and analysis of organometallic compounds and catalysts |
| US5665890A (en) | 1995-03-14 | 1997-09-09 | President And Fellows Of Harvard College | Stereoselective ring opening reactions |
| WO1998004538A1 (en) | 1996-07-26 | 1998-02-05 | Princeton University | Catalytic oxygenation of hydrocarbons by metalloporphyrin and metallosalen complexes |
| TWI246520B (en) | 1997-04-25 | 2006-01-01 | Mitsui Chemicals Inc | Processes for olefin polymerization |
| US6130340A (en) | 1998-01-13 | 2000-10-10 | President And Fellows Of Harvard College | Asymmetric cycloaddition reactions |
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| US6639087B2 (en) | 2001-08-22 | 2003-10-28 | Rhodia Pharma Solutions Inc. | Kinetic resolution method |
| DE10235316A1 (de) | 2002-08-01 | 2004-02-12 | Basf Ag | Katalysator und Verfahren zur Carbonylierung von Oxiranen |
| US7304172B2 (en) * | 2004-10-08 | 2007-12-04 | Cornell Research Foundation, Inc. | Polycarbonates made using highly selective catalysts |
| KR100724550B1 (ko) | 2004-12-16 | 2007-06-04 | 주식회사 엘지화학 | 이중 금속 아연 착화합물과 이를 촉매로 사용한폴리카보네이트의 제조 방법 |
| WO2006099162A2 (en) | 2005-03-14 | 2006-09-21 | Georgia Tech Research Corporation | Polymeric salen compounds and methods thereof |
| US7399822B2 (en) | 2005-06-21 | 2008-07-15 | Cornell Research Foundation, Inc. | Isotactic specific catalyst for direct production of highly isotactic poly (propylene oxide) or highly isotactic poly (butylene oxide) |
| GB0607096D0 (en) | 2006-04-07 | 2006-05-17 | Imp Innovations Ltd | Compound |
| US8232267B2 (en) | 2006-10-06 | 2012-07-31 | The Trustees Of Princeton University | Porphyrin catalysts and methods of use thereof |
| GB0708016D0 (en) | 2007-04-25 | 2007-06-06 | Univ Newcastle | Synthesis of cyclic carbonates |
| EP2573126B1 (en) | 2007-05-04 | 2014-09-24 | SK Innovation Co. Ltd. | A process for producing polycarbonates and a coordination complex used therefor |
| WO2008150033A1 (ja) | 2007-06-08 | 2008-12-11 | The University Of Tokyo | エポキシドと二酸化炭素との立体選択的交互共重合 |
| EP2096132A1 (en) | 2008-02-26 | 2009-09-02 | Total Petrochemicals Research Feluy | Monomers issued from renewable resources and process for polymerising them |
| BRPI0908982B8 (pt) | 2008-03-07 | 2018-08-07 | Univ Newcastle | síntese de carbonatos cíclicos |
| CN104193980B (zh) | 2008-05-09 | 2018-11-13 | 康奈尔大学 | 环氧乙烷与二氧化碳的聚合物 |
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| KR102128706B1 (ko) | 2008-08-22 | 2020-07-02 | 사우디 아람코 테크놀로지스 컴퍼니 | 촉매 및 중합체 합성방법 |
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| EP2609090A4 (en) | 2010-08-28 | 2013-12-25 | Novomer Inc | AMMONIC ACID ANHYDRIDE FROM ETHYLENE OXIDE |
| KR101805648B1 (ko) | 2010-09-14 | 2017-12-14 | 사우디 아람코 테크놀로지스 컴퍼니 | 중합체 합성용의 촉매 및 방법 |
| KR101963568B1 (ko) | 2010-09-22 | 2019-07-31 | 사우디 아람코 테크놀로지스 컴퍼니 | 치환된 살리실알데하이드 유도체의 합성 |
| EP3584265B1 (en) | 2010-11-23 | 2023-03-15 | Saudi Aramco Technologies Company | Polycarbonate polyol compositions |
| US8952104B2 (en) | 2011-01-06 | 2015-02-10 | Novomer, Inc. | Polymer compositions and methods |
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| HUE036462T2 (hu) | 2011-05-09 | 2018-07-30 | Saudi Aramco Tech Co | Polimer készítmények és eljárások |
| EP2707353B1 (en) | 2011-05-13 | 2021-03-31 | Novomer, Inc. | Carbonylation catalysts and method |
| KR102024510B1 (ko) | 2011-07-18 | 2019-11-14 | 사우디 아람코 테크놀로지스 컴퍼니 | 금속 착체 |
| IN2014CN01299A (https=) | 2011-07-25 | 2015-04-24 | Novomer Inc | |
| KR20190059988A (ko) | 2011-08-08 | 2019-05-31 | 사우디 아람코 테크놀로지스 컴퍼니 | 폴리머 합성용 촉매 및 방법 |
| GB201115565D0 (en) | 2011-09-08 | 2011-10-26 | Imp Innovations Ltd | Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent |
| WO2013055747A1 (en) | 2011-10-10 | 2013-04-18 | Novomer, Inc. | Methods to produce alkylated polycyclic guanidine compounds |
| WO2013067460A1 (en) | 2011-11-04 | 2013-05-10 | Novomer, Inc. | Metal complexes for the copolymerization of carbon dioxide and epoxides |
| US9403861B2 (en) | 2011-12-11 | 2016-08-02 | Novomer, Inc. | Salen complexes with dianionic counterions |
| WO2013096602A1 (en) | 2011-12-20 | 2013-06-27 | Novomer, Inc. | Methods for polymer synthesis |
| CN102558199B (zh) * | 2011-12-31 | 2014-10-22 | 中国科学院长春应用化学研究所 | 四齿席夫碱金属配合物、金属卟啉配合物和制备聚碳酸酯的方法 |
| WO2013138161A1 (en) | 2012-03-12 | 2013-09-19 | Novomer, Inc. | Polymer compositions and methods |
| EP2838954B1 (en) | 2012-04-16 | 2024-09-18 | Saudi Aramco Technologies Company | Adhesive compositions and methods |
| US20140024795A1 (en) | 2012-04-25 | 2014-01-23 | Novomer, Inc. | Aliphatic polycarbonate polyols containing silyl groups |
| JP6527080B2 (ja) | 2012-05-24 | 2019-06-05 | サウジ アラムコ テクノロジーズ カンパニー | ポリカーボネートポリオール組成物および方法 |
| EP2888271B1 (en) | 2012-08-24 | 2019-11-06 | Saudi Aramco Technologies Company | Metal complexes |
-
2013
- 2013-08-22 EP EP13830629.5A patent/EP2888271B1/en active Active
- 2013-08-22 US US14/422,780 patent/US9771388B2/en active Active
- 2013-08-22 KR KR1020157007284A patent/KR102096761B1/ko active Active
- 2013-08-22 CN CN201380053750.9A patent/CN104781268B/zh active Active
- 2013-08-22 WO PCT/US2013/056102 patent/WO2014031811A1/en not_active Ceased
- 2013-08-22 ES ES13830629T patent/ES2761880T3/es active Active
- 2013-08-22 JP JP2015528642A patent/JP6313305B2/ja active Active
-
2017
- 2017-08-22 US US15/683,496 patent/US20170349616A1/en not_active Abandoned
-
2018
- 2018-01-15 JP JP2018004171A patent/JP2018052995A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| US9771388B2 (en) | 2017-09-26 |
| EP2888271A1 (en) | 2015-07-01 |
| JP2018052995A (ja) | 2018-04-05 |
| CN104781268B (zh) | 2019-05-21 |
| CN104781268A (zh) | 2015-07-15 |
| JP2015535809A (ja) | 2015-12-17 |
| US20150232496A1 (en) | 2015-08-20 |
| WO2014031811A1 (en) | 2014-02-27 |
| KR20150046252A (ko) | 2015-04-29 |
| ES2761880T3 (es) | 2020-05-21 |
| EP2888271A4 (en) | 2016-05-04 |
| US20170349616A1 (en) | 2017-12-07 |
| JP6313305B2 (ja) | 2018-04-18 |
| EP2888271B1 (en) | 2019-11-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
St.27 status event code: A-0-1-A10-A15-nap-PA0105 |
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| P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
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| P13-X000 | Application amended |
St.27 status event code: A-2-2-P10-P13-nap-X000 |
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| PG1501 | Laying open of application |
St.27 status event code: A-1-1-Q10-Q12-nap-PG1501 |
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| R18-X000 | Changes to party contact information recorded |
St.27 status event code: A-3-3-R10-R18-oth-X000 |
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| R18-X000 | Changes to party contact information recorded |
St.27 status event code: A-3-3-R10-R18-oth-X000 |
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| N231 | Notification of change of applicant | ||
| PN2301 | Change of applicant |
St.27 status event code: A-3-3-R10-R13-asn-PN2301 St.27 status event code: A-3-3-R10-R11-asn-PN2301 |
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| P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
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| P13-X000 | Application amended |
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