KR102096761B1 - 금속 착물 - Google Patents

금속 착물 Download PDF

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Publication number
KR102096761B1
KR102096761B1 KR1020157007284A KR20157007284A KR102096761B1 KR 102096761 B1 KR102096761 B1 KR 102096761B1 KR 1020157007284 A KR1020157007284 A KR 1020157007284A KR 20157007284 A KR20157007284 A KR 20157007284A KR 102096761 B1 KR102096761 B1 KR 102096761B1
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group
nitrogen
optionally substituted
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metallosalenate complex
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KR20150046252A (ko
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가브리엘 잡
스캇 디. 앨런
크리스토퍼 시모노
로날드 발렌티
제이 제이. 파머
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사우디 아람코 테크놀로지스 컴퍼니
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06Cobalt compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06Cobalt compounds
    • C07F15/065Cobalt compounds without a metal-carbon linkage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2204Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208Oxygen, e.g. acetylacetonates
    • B01J31/2217At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/80Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/02Aliphatic polycarbonates
    • C08G64/0208Aliphatic polycarbonates saturated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20General preparatory processes
    • C08G64/32General preparatory processes using carbon dioxide
    • C08G64/34General preparatory processes using carbon dioxide and cyclic ethers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14Other (co) polymerisation, e.g. of lactides or epoxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/845Cobalt

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020157007284A 2012-08-24 2013-08-22 금속 착물 Active KR102096761B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261693000P 2012-08-24 2012-08-24
US61/693,000 2012-08-24
PCT/US2013/056102 WO2014031811A1 (en) 2012-08-24 2013-08-22 Metal complexes

Publications (2)

Publication Number Publication Date
KR20150046252A KR20150046252A (ko) 2015-04-29
KR102096761B1 true KR102096761B1 (ko) 2020-04-03

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Country Status (7)

Country Link
US (2) US9771388B2 (https=)
EP (1) EP2888271B1 (https=)
JP (2) JP6313305B2 (https=)
KR (1) KR102096761B1 (https=)
CN (1) CN104781268B (https=)
ES (1) ES2761880T3 (https=)
WO (1) WO2014031811A1 (https=)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102128706B1 (ko) 2008-08-22 2020-07-02 사우디 아람코 테크놀로지스 컴퍼니 촉매 및 중합체 합성방법
EP2707353B1 (en) 2011-05-13 2021-03-31 Novomer, Inc. Carbonylation catalysts and method
KR102024510B1 (ko) 2011-07-18 2019-11-14 사우디 아람코 테크놀로지스 컴퍼니 금속 착체
WO2013067460A1 (en) 2011-11-04 2013-05-10 Novomer, Inc. Metal complexes for the copolymerization of carbon dioxide and epoxides
US9403861B2 (en) 2011-12-11 2016-08-02 Novomer, Inc. Salen complexes with dianionic counterions
EP2888271B1 (en) 2012-08-24 2019-11-06 Saudi Aramco Technologies Company Metal complexes
WO2019126221A1 (en) 2017-12-22 2019-06-27 Saudi Aramco Technologies Company Catalysts for polycarbonate production
JP2021522355A (ja) 2018-04-18 2021-08-30 サウジ アラムコ テクノロジーズ カンパニー ポリ(アルキレンカーボネート)ポリマーの末端基異性化
WO2020028606A1 (en) 2018-08-02 2020-02-06 Saudi Aramco Technologies Company Sustainable polymer compositions and methods
MA53727A (fr) 2018-09-24 2021-12-29 Saudi Aramco Tech Co Copolymères séquencés de polycarbonate et procédés associés
TWI906317B (zh) 2020-06-24 2025-12-01 沙烏地阿拉伯商沙烏地阿美科技公司 多元醇組合物及方法
WO2022153149A1 (en) 2021-01-12 2022-07-21 Saudi Aramco Technologies Company Continuous manufacturing of polyol
US12195576B2 (en) 2021-06-23 2025-01-14 Saudi Aramco Technologies Company Polyol compositions and methods

Family Cites Families (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69128528T2 (de) 1990-03-21 1998-07-30 Res Corp Technologies Inc Chirale katalysatoren und dadurch katalysierte epoxydierungsreaktionen
US5637739A (en) 1990-03-21 1997-06-10 Research Corporation Technologies, Inc. Chiral catalysts and catalytic epoxidation catalyzed thereby
US5696109A (en) 1992-12-07 1997-12-09 Eukarion, Inc. Synthetic catalytic free radical scavengers useful as antioxidants for prevention and therapy of disease
US6030917A (en) 1996-07-23 2000-02-29 Symyx Technologies, Inc. Combinatorial synthesis and analysis of organometallic compounds and catalysts
US5665890A (en) 1995-03-14 1997-09-09 President And Fellows Of Harvard College Stereoselective ring opening reactions
WO1998004538A1 (en) 1996-07-26 1998-02-05 Princeton University Catalytic oxygenation of hydrocarbons by metalloporphyrin and metallosalen complexes
TWI246520B (en) 1997-04-25 2006-01-01 Mitsui Chemicals Inc Processes for olefin polymerization
US6130340A (en) 1998-01-13 2000-10-10 President And Fellows Of Harvard College Asymmetric cycloaddition reactions
US6521561B1 (en) 1998-05-01 2003-02-18 President And Fellows Of Harvard College Main-group metal based asymmetric catalysts and applications thereof
KR100342659B1 (en) 2000-12-15 2002-07-04 Rstech Co Ltd Chiral polymer salene catalyst and process for preparing chiral compounds from racemic epoxide using the same
US6884750B2 (en) 2001-06-27 2005-04-26 Rs Tech Corp. Chiral salen catalyst and methods for the preparation of chiral compounds from racemic epoxides by using new catalyst
US6639087B2 (en) 2001-08-22 2003-10-28 Rhodia Pharma Solutions Inc. Kinetic resolution method
DE10235316A1 (de) 2002-08-01 2004-02-12 Basf Ag Katalysator und Verfahren zur Carbonylierung von Oxiranen
US7304172B2 (en) * 2004-10-08 2007-12-04 Cornell Research Foundation, Inc. Polycarbonates made using highly selective catalysts
KR100724550B1 (ko) 2004-12-16 2007-06-04 주식회사 엘지화학 이중 금속 아연 착화합물과 이를 촉매로 사용한폴리카보네이트의 제조 방법
WO2006099162A2 (en) 2005-03-14 2006-09-21 Georgia Tech Research Corporation Polymeric salen compounds and methods thereof
US7399822B2 (en) 2005-06-21 2008-07-15 Cornell Research Foundation, Inc. Isotactic specific catalyst for direct production of highly isotactic poly (propylene oxide) or highly isotactic poly (butylene oxide)
GB0607096D0 (en) 2006-04-07 2006-05-17 Imp Innovations Ltd Compound
US8232267B2 (en) 2006-10-06 2012-07-31 The Trustees Of Princeton University Porphyrin catalysts and methods of use thereof
GB0708016D0 (en) 2007-04-25 2007-06-06 Univ Newcastle Synthesis of cyclic carbonates
EP2573126B1 (en) 2007-05-04 2014-09-24 SK Innovation Co. Ltd. A process for producing polycarbonates and a coordination complex used therefor
WO2008150033A1 (ja) 2007-06-08 2008-12-11 The University Of Tokyo エポキシドと二酸化炭素との立体選択的交互共重合
EP2096132A1 (en) 2008-02-26 2009-09-02 Total Petrochemicals Research Feluy Monomers issued from renewable resources and process for polymerising them
BRPI0908982B8 (pt) 2008-03-07 2018-08-07 Univ Newcastle síntese de carbonatos cíclicos
CN104193980B (zh) 2008-05-09 2018-11-13 康奈尔大学 环氧乙烷与二氧化碳的聚合物
US7858729B2 (en) 2008-05-29 2010-12-28 Novomer, Inc. Methods of controlling molecular weight distribution of polymers and compositions thereof
CA2727959A1 (en) 2008-07-30 2010-02-04 Sk Energy, Co., Ltd. Novel coordination complexes and process of producing polycarbonate by copolymerization of carbon dioxide and epoxide using the same as catalyst
KR102128706B1 (ko) 2008-08-22 2020-07-02 사우디 아람코 테크놀로지스 컴퍼니 촉매 및 중합체 합성방법
CN103333330A (zh) 2008-09-08 2013-10-02 诺沃梅尔公司 聚碳酸酯多元醇组合物和方法
WO2010033703A1 (en) 2008-09-17 2010-03-25 Novomer, Inc. Purification of polycarbonates
CA2639870A1 (en) 2008-09-29 2010-03-29 Nova Chemicals Corporation Trimerization
US8580911B2 (en) 2008-11-01 2013-11-12 Novomer, Inc. Polycarbonate block copolymers
CN101412809B (zh) * 2008-11-28 2011-04-27 大连理工大学 用于合成聚碳酸酯的单活性点催化剂
GB0904654D0 (en) * 2009-03-18 2009-04-29 Univ Newcastle Synthesis of cyclic carbonates
KR101221404B1 (ko) 2009-06-18 2013-01-11 아주대학교산학협력단 이산화탄소/에폭사이드 공중합 촉매 시스템
CN102665406B (zh) 2009-12-24 2016-03-09 诺沃梅尔公司 合成多环胍化合物的方法
KR101503745B1 (ko) 2010-02-25 2015-03-19 에스케이이노베이션 주식회사 나이트레이트 음이온의 이산화탄소/에폭사이드 공중합 촉매 시스템
WO2011163133A1 (en) 2010-06-20 2011-12-29 Novomer, Inc. Aliphatic polycarbonates
KR101983006B1 (ko) 2010-08-27 2019-05-29 사우디 아람코 테크놀로지스 컴퍼니 중합체 조성물 및 방법
EP2609090A4 (en) 2010-08-28 2013-12-25 Novomer Inc AMMONIC ACID ANHYDRIDE FROM ETHYLENE OXIDE
KR101805648B1 (ko) 2010-09-14 2017-12-14 사우디 아람코 테크놀로지스 컴퍼니 중합체 합성용의 촉매 및 방법
KR101963568B1 (ko) 2010-09-22 2019-07-31 사우디 아람코 테크놀로지스 컴퍼니 치환된 살리실알데하이드 유도체의 합성
EP3584265B1 (en) 2010-11-23 2023-03-15 Saudi Aramco Technologies Company Polycarbonate polyol compositions
US8952104B2 (en) 2011-01-06 2015-02-10 Novomer, Inc. Polymer compositions and methods
CN103687584B (zh) * 2011-01-28 2016-03-30 罗地亚管理公司 表现出低眼刺激潜能的个人清洁体系
HUE036462T2 (hu) 2011-05-09 2018-07-30 Saudi Aramco Tech Co Polimer készítmények és eljárások
EP2707353B1 (en) 2011-05-13 2021-03-31 Novomer, Inc. Carbonylation catalysts and method
KR102024510B1 (ko) 2011-07-18 2019-11-14 사우디 아람코 테크놀로지스 컴퍼니 금속 착체
IN2014CN01299A (https=) 2011-07-25 2015-04-24 Novomer Inc
KR20190059988A (ko) 2011-08-08 2019-05-31 사우디 아람코 테크놀로지스 컴퍼니 폴리머 합성용 촉매 및 방법
GB201115565D0 (en) 2011-09-08 2011-10-26 Imp Innovations Ltd Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent
WO2013055747A1 (en) 2011-10-10 2013-04-18 Novomer, Inc. Methods to produce alkylated polycyclic guanidine compounds
WO2013067460A1 (en) 2011-11-04 2013-05-10 Novomer, Inc. Metal complexes for the copolymerization of carbon dioxide and epoxides
US9403861B2 (en) 2011-12-11 2016-08-02 Novomer, Inc. Salen complexes with dianionic counterions
WO2013096602A1 (en) 2011-12-20 2013-06-27 Novomer, Inc. Methods for polymer synthesis
CN102558199B (zh) * 2011-12-31 2014-10-22 中国科学院长春应用化学研究所 四齿席夫碱金属配合物、金属卟啉配合物和制备聚碳酸酯的方法
WO2013138161A1 (en) 2012-03-12 2013-09-19 Novomer, Inc. Polymer compositions and methods
EP2838954B1 (en) 2012-04-16 2024-09-18 Saudi Aramco Technologies Company Adhesive compositions and methods
US20140024795A1 (en) 2012-04-25 2014-01-23 Novomer, Inc. Aliphatic polycarbonate polyols containing silyl groups
JP6527080B2 (ja) 2012-05-24 2019-06-05 サウジ アラムコ テクノロジーズ カンパニー ポリカーボネートポリオール組成物および方法
EP2888271B1 (en) 2012-08-24 2019-11-06 Saudi Aramco Technologies Company Metal complexes

Also Published As

Publication number Publication date
US9771388B2 (en) 2017-09-26
EP2888271A1 (en) 2015-07-01
JP2018052995A (ja) 2018-04-05
CN104781268B (zh) 2019-05-21
CN104781268A (zh) 2015-07-15
JP2015535809A (ja) 2015-12-17
US20150232496A1 (en) 2015-08-20
WO2014031811A1 (en) 2014-02-27
KR20150046252A (ko) 2015-04-29
ES2761880T3 (es) 2020-05-21
EP2888271A4 (en) 2016-05-04
US20170349616A1 (en) 2017-12-07
JP6313305B2 (ja) 2018-04-18
EP2888271B1 (en) 2019-11-06

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