JP6312692B2 - 水素吸蔵合金及び負極とこれらを用いたＮｉ金属水素化物電池 - Google Patents

水素吸蔵合金及び負極とこれらを用いたＮｉ金属水素化物電池 Download PDF

Info

Publication number
JP6312692B2
JP6312692B2 JP2015542737A JP2015542737A JP6312692B2 JP 6312692 B2 JP6312692 B2 JP 6312692B2 JP 2015542737 A JP2015542737 A JP 2015542737A JP 2015542737 A JP2015542737 A JP 2015542737A JP 6312692 B2 JP6312692 B2 JP 6312692B2
Authority
JP
Japan
Prior art keywords
alloy
phase
hydrogen storage
alloys
zrni
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2015542737A
Other languages
English (en)
Japanese (ja)
Other versions
JP2015537119A (ja
JP2015537119A5 (enExample
Inventor
クォ−ション ヤング、
クォ−ション ヤング、
タイヘイ オウチ、
タイヘイ オウチ、
ジーン ネイ、
ジーン ネイ、
Original Assignee
ビーエーエスエフ バッテリー マテリアルズ−オヴォニック
ビーエーエスエフ バッテリー マテリアルズ−オヴォニック
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ビーエーエスエフ バッテリー マテリアルズ−オヴォニック, ビーエーエスエフ バッテリー マテリアルズ−オヴォニック filed Critical ビーエーエスエフ バッテリー マテリアルズ−オヴォニック
Publication of JP2015537119A publication Critical patent/JP2015537119A/ja
Publication of JP2015537119A5 publication Critical patent/JP2015537119A5/ja
Application granted granted Critical
Publication of JP6312692B2 publication Critical patent/JP6312692B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/383—Hydrogen absorbing alloys
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C16/00—Alloys based on zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C19/00—Alloys based on nickel or cobalt
    • C22C19/03—Alloys based on nickel or cobalt based on nickel
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C30/00—Alloys containing less than 50% by weight of each constituent
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/24—Electrodes for alkaline accumulators
    • H01M4/242—Hydrogen storage electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/34—Gastight accumulators
    • H01M10/345—Gastight metal hydride accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Manufacturing & Machinery (AREA)
JP2015542737A 2012-11-16 2013-11-13 水素吸蔵合金及び負極とこれらを用いたＮｉ金属水素化物電池 Active JP6312692B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US13/694,299 2012-11-16
US13/694,299 US20140140885A1 (en) 2012-11-16 2012-11-16 Hydrogen storage alloy and negative electrode and Ni-metal hydride battery employing same
PCT/US2013/069797 WO2014078351A1 (en) 2012-11-16 2013-11-13 A hydrogen storage alloy and negative electrode and ni-metal hydride battery employing same

Publications (3)

Publication Number Publication Date
JP2015537119A JP2015537119A (ja) 2015-12-24
JP2015537119A5 JP2015537119A5 (enExample) 2016-06-16
JP6312692B2 true JP6312692B2 (ja) 2018-04-18

Family

ID=50728120

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2015542737A Active JP6312692B2 (ja) 2012-11-16 2013-11-13 水素吸蔵合金及び負極とこれらを用いたＮｉ金属水素化物電池

Country Status (5)

Country Link
US (2) US20140140885A1 (enExample)
EP (1) EP2920333A4 (enExample)
JP (1) JP6312692B2 (enExample)
CN (2) CN106953091A (enExample)
WO (1) WO2014078351A1 (enExample)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018511141A (ja) * 2015-02-11 2018-04-19 ビーエーエスエフ コーポレーション 水素吸蔵合金

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR920010422B1 (ko) * 1987-05-15 1992-11-27 마쯔시다덴기산교 가부시기가이샤 수소흡수저장전극 및 그 제조법
JPH0650633B2 (ja) * 1987-07-30 1994-06-29 松下電器産業株式会社 水素吸蔵電極
US5002730A (en) * 1989-07-24 1991-03-26 Energy Conversion Devices Preparation of vanadium rich hydrogen storage alloy materials
JPH05287422A (ja) * 1992-04-13 1993-11-02 Matsushita Electric Ind Co Ltd 水素吸蔵合金電極
JPH073365A (ja) * 1993-04-20 1995-01-06 Matsushita Electric Ind Co Ltd 水素吸蔵合金および水素吸蔵合金電極
US6682609B1 (en) * 1994-07-22 2004-01-27 Kabushiki Kaisha Toshiba Hydrogen absorbing alloy, method of surface modification of the alloy, negative electrode for battery and alkaline secondary battery
JPH09199121A (ja) * 1996-01-22 1997-07-31 Toshiba Corp 水素吸蔵合金及び二次電池
US5560752A (en) * 1994-08-17 1996-10-01 Lucent Technologies Inc. Process for activation of metal hydrides
JPH08134567A (ja) * 1994-11-11 1996-05-28 Shin Kobe Electric Mach Co Ltd 水素吸蔵合金及びアルカリ蓄電池用水素吸蔵合金電極
JPH08319529A (ja) * 1995-05-22 1996-12-03 Matsushita Electric Ind Co Ltd 水素吸蔵合金および水素吸蔵合金電極
CN1279637C (zh) * 1996-01-22 2006-10-11 东芝株式会社 储氢合金
JP3528599B2 (ja) * 1998-05-21 2004-05-17 トヨタ自動車株式会社 水素吸蔵合金
US6270719B1 (en) * 1999-04-12 2001-08-07 Ovonic Battery Company, Inc. Modified electrochemical hydrogen storage alloy having increased capacity, rate capability and catalytic activity
JP3931518B2 (ja) * 1999-07-08 2007-06-20 松下電器産業株式会社 ニッケル−水素二次電池
CN1162924C (zh) * 2001-05-11 2004-08-18 浙江大学 镍-金属氢化物(Ni-MH)二次电池
CN102683653A (zh) * 2011-03-09 2012-09-19 中国科学院长春应用化学研究所 复合贮氢合金及镍氢蓄电池
CN102738520B (zh) * 2011-04-14 2017-02-15 中国科学院长春应用化学研究所 镍氢蓄电池

Also Published As

Publication number Publication date
WO2014078351A1 (en) 2014-05-22
JP2015537119A (ja) 2015-12-24
US20140140885A1 (en) 2014-05-22
EP2920333A1 (en) 2015-09-23
US20160204429A1 (en) 2016-07-14
CN106953091A (zh) 2017-07-14
CN104903479A (zh) 2015-09-09
EP2920333A4 (en) 2016-11-16

Similar Documents

Publication Publication Date Title
Volodin et al. Study of hydrogen storage and electrochemical properties of AB2-type Ti0. 15Zr0. 85La0. 03Ni1. 2Mn0. 7V0. 12Fe0. 12 alloy
JP6747989B2 (ja) 改善活性及び高速性能を有する金属水素化物合金
Li et al. Annealing effects on structural and electrochemical properties of (LaPrNdZr) 0.83 Mg0. 17 (NiCoAlMn) 3.3 alloy
Férey et al. Elaboration and characterization of magnesium-substituted La5Ni19 hydride forming alloys as active materials for negative electrode in Ni-MH battery
Young et al. The effects of Al substitution on the phase abundance, structure and electrochemical performance of La0. 7Mg0. 3Ni2. 8Co0. 5− xAlx (x= 0, 0.1, 0.2) alloys
Young et al. Effects of La-addition to the structure, hydrogen storage, and electrochemical properties of C14 metal hydride alloys
US20160118654A1 (en) Bcc metal hydride alloys for electrochemical applications
Zhao et al. Characterization and improvement of electrochemical properties of Pr5Co19-type single-phase La0. 84Mg0. 16Ni3. 80 alloy
Young et al. Synergetic effects in electrochemical properties of ZrVxNi4. 5− x (x= 0.0, 0.1, 0.2, 0.3, 0.4, and 0.5) metal hydride alloys
Young et al. Effects of Zn-addition to C14 metal hydride alloys and comparisons to Si, Fe, Cu, Y, and Mo-additives
Liu et al. Effect of Pr on phase structure and cycling stability of La–Mg–Ni-based alloys with A2B7-and A5B19-type superlattice structures
Young et al. Improvement in− 40° C electrochemical properties of AB2 metal hydride alloy by silicon incorporation
Zhai et al. Influences of hydrogen-induced amorphization and annealing treatment on gaseous hydrogen storage properties of La1− xPrxMgNi3. 6Co0. 4 (x= 0–0.4) alloys
Nei et al. Effects of annealing on Zr8Ni19X2 (X= Ni, Mg, Al, Sc, V, Mn, Co, Sn, La, and Hf): Hydrogen storage and electrochemical properties
Young et al. Studies of copper as a modifier in C14-predominant AB2 metal hydride alloys
Young et al. The structure, hydrogen storage, and electrochemical properties of Fe-doped C14-predominating AB2 metal hydride alloys
Zhang et al. A study on structure and electrochemical properties of (La, Ce, Pr, Nd) 2MgNi9 hydrogen storage electrode alloys
WO2014210116A1 (en) Synergistic multiphase hydride alloy
Kong et al. Effects of rare-earth element additions to Laves phase-related body-centered-cubic solid solution metal hydride alloys: thermodynamic and electrochemical properties
Zhang et al. Effect of Co content on the structure and electrochemical properties of La1. 5Mg0. 5Ni7− xCox (x= 0, 1.2, 1.8) hydrogen storage alloys
Vivet et al. Effects of cobalt replacement by nickel, manganese, aluminium and iron on the crystallographic and electrochemical properties of AB5-type alloys
JP6906306B2 (ja) 再充電可能電池に使用される無秩序金属水素化物合金
JP2007291474A (ja) 水素吸蔵合金およびニッケル水素二次電池
Young et al. Improvement in the low-temperature performance of AB5 metal hydride alloys by Fe-addition
Li et al. Mechanism of distinct high rate dischargeability of La4MgNi19 electrode alloys prepared by casting and rapid quenching followed by annealing treatment

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20150716

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20160421

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20160421

RD03 Notification of appointment of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7423

Effective date: 20161107

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20161107

RD04 Notification of resignation of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7424

Effective date: 20161115

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20170328

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20170417

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20170714

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20171002

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20180126

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20180205

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20180312

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20180320

R150 Certificate of patent or registration of utility model

Ref document number: 6312692

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150