JP6280505B2 - シリコーンエポキシエーテル組成物、それを製造する方法およびその使用 - Google Patents
シリコーンエポキシエーテル組成物、それを製造する方法およびその使用 Download PDFInfo
- Publication number
- JP6280505B2 JP6280505B2 JP2014552292A JP2014552292A JP6280505B2 JP 6280505 B2 JP6280505 B2 JP 6280505B2 JP 2014552292 A JP2014552292 A JP 2014552292A JP 2014552292 A JP2014552292 A JP 2014552292A JP 6280505 B2 JP6280505 B2 JP 6280505B2
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- composition
- compound
- electrolyte solvent
- lithium
- combination
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- 239000000203 mixture Substances 0.000 title claims description 86
- 239000004593 Epoxy Substances 0.000 title description 38
- 229920001296 polysiloxane Polymers 0.000 title description 35
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 title description 18
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000002904 solvent Substances 0.000 claims description 56
- 229920000570 polyether Polymers 0.000 claims description 47
- 239000003792 electrolyte Substances 0.000 claims description 46
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 38
- 150000001875 compounds Chemical class 0.000 claims description 35
- 125000005910 alkyl carbonate group Chemical group 0.000 claims description 27
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 20
- 229910003002 lithium salt Inorganic materials 0.000 claims description 20
- 159000000002 lithium salts Chemical class 0.000 claims description 20
- 229910052710 silicon Inorganic materials 0.000 claims description 20
- 239000010703 silicon Substances 0.000 claims description 20
- 229910013870 LiPF 6 Inorganic materials 0.000 claims description 15
- -1 LiCF 3 SO 3 Inorganic materials 0.000 claims description 12
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 claims description 12
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 7
- 229910052744 lithium Inorganic materials 0.000 claims description 7
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 claims description 5
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 claims description 3
- 229910013684 LiClO 4 Inorganic materials 0.000 claims description 3
- 229910015015 LiAsF 6 Inorganic materials 0.000 claims description 2
- 229910013063 LiBF 4 Inorganic materials 0.000 claims description 2
- 229910013528 LiN(SO2 CF3)2 Inorganic materials 0.000 claims description 2
- 150000004653 carbonic acids Chemical class 0.000 claims 1
- 230000003381 solubilizing effect Effects 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 description 21
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 20
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 20
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 14
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 14
- 229910001416 lithium ion Inorganic materials 0.000 description 14
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 11
- 150000003254 radicals Chemical class 0.000 description 11
- 125000005842 heteroatom Chemical group 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- 229910003473 lithium bis(trifluoromethanesulfonyl)imide Inorganic materials 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 229910013188 LiBOB Inorganic materials 0.000 description 6
- 125000000524 functional group Chemical group 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical group C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229910004283 SiO 4 Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003990 capacitor Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- RCNRJBWHLARWRP-UHFFFAOYSA-N ethenyl-[ethenyl(dimethyl)silyl]oxy-dimethylsilane;platinum Chemical compound [Pt].C=C[Si](C)(C)O[Si](C)(C)C=C RCNRJBWHLARWRP-UHFFFAOYSA-N 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 2
- 125000000466 oxiranyl group Chemical group 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 150000001723 carbon free-radicals Chemical class 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- YGHUUVGIRWMJGE-UHFFFAOYSA-N chlorodimethylsilane Chemical compound C[SiH](C)Cl YGHUUVGIRWMJGE-UHFFFAOYSA-N 0.000 description 1
- ZXPDYFSTVHQQOI-UHFFFAOYSA-N diethoxysilane Chemical compound CCO[SiH2]OCC ZXPDYFSTVHQQOI-UHFFFAOYSA-N 0.000 description 1
- 125000001891 dimethoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000010416 ion conductor Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/58—Liquid electrolytes
- H01G11/60—Liquid electrolytes characterised by the solvent
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/54—Electrolytes
- H01G11/58—Liquid electrolytes
- H01G11/64—Liquid electrolytes characterised by additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/04—Cells with aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0028—Organic electrolyte characterised by the solvent
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Dispersion Chemistry (AREA)
- Secondary Cells (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261584961P | 2012-01-10 | 2012-01-10 | |
| US61/584,961 | 2012-01-10 | ||
| PCT/US2013/020983 WO2013106537A2 (en) | 2012-01-10 | 2013-01-10 | Silicone epoxy ether compositions, methods for making same and uses therefor |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015513170A JP2015513170A (ja) | 2015-04-30 |
| JP2015513170A5 JP2015513170A5 (enExample) | 2016-02-25 |
| JP6280505B2 true JP6280505B2 (ja) | 2018-02-14 |
Family
ID=48782077
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014552292A Active JP6280505B2 (ja) | 2012-01-10 | 2013-01-10 | シリコーンエポキシエーテル組成物、それを製造する方法およびその使用 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9923243B2 (enExample) |
| EP (1) | EP2803107B1 (enExample) |
| JP (1) | JP6280505B2 (enExample) |
| KR (1) | KR102085867B1 (enExample) |
| CN (1) | CN104919635B (enExample) |
| CA (1) | CA2863274A1 (enExample) |
| WO (1) | WO2013106537A2 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10809054B2 (en) | 2016-03-11 | 2020-10-20 | Chuo Hatsujo Kabushiki Kaisha | Device, method, and program for measuring shape of spiral spring |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3035545B1 (fr) * | 2015-04-21 | 2019-09-13 | Rhodia Operations | Electrolyte polymere et dispositifs electrochimiques le comprenant |
| CN106785032B (zh) * | 2017-03-17 | 2019-08-09 | 北京工业大学 | 一种锂离子电池用聚合物电解质及制备方法 |
| CN111293364B (zh) * | 2018-12-10 | 2021-03-30 | 张家港市国泰华荣化工新材料有限公司 | 一种非水电解液及锂离子电池 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0885913B1 (en) | 1996-12-09 | 2003-04-16 | Daiso Co., Ltd. | Copolyether and solid polymer electrolyte |
| EP1159332A1 (en) | 1999-03-11 | 2001-12-05 | Wisconsin Alumni Research Foundation | Polysiloxane polymers with multiple oligooxyethylene side chains |
| JP2001118578A (ja) | 1999-10-19 | 2001-04-27 | Ngk Insulators Ltd | リチウム二次電池及びその製造方法 |
| WO2001036206A1 (en) | 1999-11-12 | 2001-05-25 | Fargo Electronics, Inc. | Thermal printhead compensation |
| US6956083B2 (en) * | 2001-05-31 | 2005-10-18 | The Regents Of The University Of California | Single ion conductor cross-linked polymeric networks |
| JP3953922B2 (ja) | 2001-10-18 | 2007-08-08 | 日東電工株式会社 | 反射防止フィルム、光学素子および表示装置 |
| US6858351B2 (en) * | 2001-11-07 | 2005-02-22 | Daiso Co., Ltd. | Polyethylene oxide-based electrolyte containing silicon compound |
| JP4269648B2 (ja) * | 2001-11-07 | 2009-05-27 | ダイソー株式会社 | 電解質組成物および電池 |
| US7695860B2 (en) | 2002-03-22 | 2010-04-13 | Quallion Llc | Nonaqueous liquid electrolyte |
| US6887619B2 (en) | 2002-04-22 | 2005-05-03 | Quallion Llc | Cross-linked polysiloxanes |
| JP4537035B2 (ja) * | 2003-01-09 | 2010-09-01 | 三星エスディアイ株式会社 | 非水電解液及びリチウム二次電池 |
| JP4632399B2 (ja) | 2003-01-09 | 2011-02-16 | 信越化学工業株式会社 | 高純度ポリエーテルシリコーン |
| US7351501B2 (en) | 2003-01-09 | 2008-04-01 | Samsung Sdi Co., Ltd | Electrolyte for rechargeable lithium battery and rechargeable lithium battery comprising same |
| US7588859B1 (en) | 2004-02-11 | 2009-09-15 | Bookeun Oh | Electrolyte for use in electrochemical devices |
| US20050106470A1 (en) | 2003-01-22 | 2005-05-19 | Yoon Sang Y. | Battery having electrolyte including one or more additives |
| US20060035154A1 (en) | 2003-09-10 | 2006-02-16 | West Robert C | Electrochemical device having an electrolyte that includes a tetrasiloxane |
| US20050170254A1 (en) | 2004-02-04 | 2005-08-04 | West Robert C. | Electrochemical device having electrolyte including disiloxane |
| US7473491B1 (en) | 2003-09-15 | 2009-01-06 | Quallion Llc | Electrolyte for electrochemical cell |
| US7466539B2 (en) | 2005-09-30 | 2008-12-16 | Wisconsin Alumni Research Foundation | Electrochemical double-layer capacitor using organosilicon electrolytes |
| KR101451802B1 (ko) * | 2007-07-31 | 2014-10-16 | 삼성에스디아이 주식회사 | 글리시딜 에테르계 화합물을 채용한 유기전해액 및 리튬전지 |
| WO2010037138A2 (en) * | 2008-09-29 | 2010-04-01 | Akermin, Inc. | Direct alcohol anion fuel cell with biocathode |
| CN102074736B (zh) * | 2010-06-07 | 2012-09-05 | 中国科学院广州能源研究所 | 含聚醚链有机硅胺电解质材料及其在锂电池电解液中的应用 |
| US9005808B2 (en) * | 2011-03-01 | 2015-04-14 | Uchicago Argonne, Llc | Electrode materials for rechargeable batteries |
-
2013
- 2013-01-10 CN CN201380005009.5A patent/CN104919635B/zh active Active
- 2013-01-10 KR KR1020147022440A patent/KR102085867B1/ko active Active
- 2013-01-10 WO PCT/US2013/020983 patent/WO2013106537A2/en not_active Ceased
- 2013-01-10 JP JP2014552292A patent/JP6280505B2/ja active Active
- 2013-01-10 EP EP13735575.6A patent/EP2803107B1/en active Active
- 2013-01-10 US US14/371,491 patent/US9923243B2/en active Active
- 2013-01-10 CA CA2863274A patent/CA2863274A1/en not_active Abandoned
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10809054B2 (en) | 2016-03-11 | 2020-10-20 | Chuo Hatsujo Kabushiki Kaisha | Device, method, and program for measuring shape of spiral spring |
Also Published As
| Publication number | Publication date |
|---|---|
| KR102085867B1 (ko) | 2020-03-06 |
| JP2015513170A (ja) | 2015-04-30 |
| EP2803107B1 (en) | 2018-07-25 |
| CN104919635B (zh) | 2017-06-23 |
| CA2863274A1 (en) | 2013-07-18 |
| US9923243B2 (en) | 2018-03-20 |
| EP2803107A2 (en) | 2014-11-19 |
| US20150050560A1 (en) | 2015-02-19 |
| CN104919635A (zh) | 2015-09-16 |
| KR20140116922A (ko) | 2014-10-06 |
| WO2013106537A2 (en) | 2013-07-18 |
| EP2803107A4 (en) | 2015-12-16 |
| WO2013106537A3 (en) | 2015-01-29 |
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