JP6262510B2 - 吸収性物品 - Google Patents
吸収性物品 Download PDFInfo
- Publication number
- JP6262510B2 JP6262510B2 JP2013250243A JP2013250243A JP6262510B2 JP 6262510 B2 JP6262510 B2 JP 6262510B2 JP 2013250243 A JP2013250243 A JP 2013250243A JP 2013250243 A JP2013250243 A JP 2013250243A JP 6262510 B2 JP6262510 B2 JP 6262510B2
- Authority
- JP
- Japan
- Prior art keywords
- fragrance
- absorbent
- sheet
- skin
- precursor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000002250 absorbent Substances 0.000 title claims description 206
- 230000002745 absorbent Effects 0.000 title claims description 205
- 239000003205 fragrance Substances 0.000 claims description 296
- 239000002243 precursor Substances 0.000 claims description 86
- 239000006096 absorbing agent Substances 0.000 claims description 50
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 41
- -1 silicate compound Chemical class 0.000 claims description 35
- 230000029142 excretion Effects 0.000 claims description 32
- 239000002304 perfume Substances 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 9
- 230000035699 permeability Effects 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 239000004615 ingredient Substances 0.000 claims description 6
- 239000012298 atmosphere Substances 0.000 claims description 5
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- 239000000835 fiber Substances 0.000 description 124
- 239000010410 layer Substances 0.000 description 123
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- 239000000126 substance Substances 0.000 description 11
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- 238000006243 chemical reaction Methods 0.000 description 9
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- FPCCDPXRNNVUOM-UHFFFAOYSA-N Hydroxycitronellol Chemical compound OCCC(C)CCCC(C)(C)O FPCCDPXRNNVUOM-UHFFFAOYSA-N 0.000 description 4
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- 238000009835 boiling Methods 0.000 description 4
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- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Chemical compound CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 description 4
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
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- 239000005770 Eugenol Substances 0.000 description 3
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 3
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- 206010027940 Mood altered Diseases 0.000 description 3
- GLZPCOQZEFWAFX-JXMROGBWSA-N Nerol Natural products CC(C)=CCC\C(C)=C\CO GLZPCOQZEFWAFX-JXMROGBWSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 229940121375 antifungal agent Drugs 0.000 description 3
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
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- 229940113087 geraniol Drugs 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000007510 mood change Effects 0.000 description 3
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 2
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- CRDAMVZIKSXKFV-FBXUGWQNSA-N (2-cis,6-cis)-farnesol Chemical compound CC(C)=CCC\C(C)=C/CC\C(C)=C/CO CRDAMVZIKSXKFV-FBXUGWQNSA-N 0.000 description 2
- 239000000260 (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol Substances 0.000 description 2
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- KHWTYGFHPHRQMP-UHFFFAOYSA-N (4-propan-2-ylcyclohexyl)methanol Chemical compound CC(C)C1CCC(CO)CC1 KHWTYGFHPHRQMP-UHFFFAOYSA-N 0.000 description 2
- 239000001306 (7E,9E,11E,13E)-pentadeca-7,9,11,13-tetraen-1-ol Substances 0.000 description 2
- ZCHHRLHTBGRGOT-SNAWJCMRSA-N (E)-hex-2-en-1-ol Chemical compound CCC\C=C\CO ZCHHRLHTBGRGOT-SNAWJCMRSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 2
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 2
- RNLHVODSMDJCBR-SOFGYWHQSA-N (e)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol Chemical compound CC(O)C(C)\C=C\C1CC=C(C)C1(C)C RNLHVODSMDJCBR-SOFGYWHQSA-N 0.000 description 2
- BVDMQAQCEBGIJR-UHFFFAOYSA-N 1-(2,2,6-trimethylcyclohexyl)hexan-3-ol Chemical compound CCCC(O)CCC1C(C)CCCC1(C)C BVDMQAQCEBGIJR-UHFFFAOYSA-N 0.000 description 2
- NEHPIUGJDUWSRR-UHFFFAOYSA-N 1-(4-propan-2-ylcyclohexyl)ethanol Chemical compound CC(C)C1CCC(C(C)O)CC1 NEHPIUGJDUWSRR-UHFFFAOYSA-N 0.000 description 2
- OLQJQHSAWMFDJE-UHFFFAOYSA-N 2-(hydroxymethyl)-2-nitropropane-1,3-diol Chemical compound OCC(CO)(CO)[N+]([O-])=O OLQJQHSAWMFDJE-UHFFFAOYSA-N 0.000 description 2
- HUHGPYXAVBJSJV-UHFFFAOYSA-N 2-[3,5-bis(2-hydroxyethyl)-1,3,5-triazinan-1-yl]ethanol Chemical compound OCCN1CN(CCO)CN(CCO)C1 HUHGPYXAVBJSJV-UHFFFAOYSA-N 0.000 description 2
- OZAJZOFSMFJAEB-UHFFFAOYSA-N 2-cyclohexyl-3,3,4-trimethylpentan-2-ol Chemical compound CC(C)C(C)(C)C(C)(O)C1CCCCC1 OZAJZOFSMFJAEB-UHFFFAOYSA-N 0.000 description 2
- KHQDWCKZXLWDNM-UHFFFAOYSA-N 2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol Chemical compound CCC(CO)=CCC1CC=C(C)C1(C)C KHQDWCKZXLWDNM-UHFFFAOYSA-N 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 2
- BDCFWIDZNLCTMF-UHFFFAOYSA-N 2-phenylpropan-2-ol Chemical compound CC(C)(O)C1=CC=CC=C1 BDCFWIDZNLCTMF-UHFFFAOYSA-N 0.000 description 2
- DLTWBMHADAJAAZ-UHFFFAOYSA-N 2-tert-butylcyclohexan-1-ol Chemical compound CC(C)(C)C1CCCCC1O DLTWBMHADAJAAZ-UHFFFAOYSA-N 0.000 description 2
- QZFSNJAQFWEXEA-UHFFFAOYSA-N 3,3-dimethyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol Chemical compound CC(O)C(C)(C)C=CC1CC=C(C)C1(C)C QZFSNJAQFWEXEA-UHFFFAOYSA-N 0.000 description 2
- NGYMOTOXXHCHOC-UHFFFAOYSA-N 3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol Chemical compound CC(O)C(C)CCC1CC=C(C)C1(C)C NGYMOTOXXHCHOC-UHFFFAOYSA-N 0.000 description 2
- INIOTLARNNSXAE-UHFFFAOYSA-N 4,8-dimethyl-2-propan-2-ylidene-3,3a,4,5,6,8a-hexahydro-1h-azulen-6-ol Chemical compound CC1CC(O)C=C(C)C2CC(=C(C)C)CC12 INIOTLARNNSXAE-UHFFFAOYSA-N 0.000 description 2
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Description
測定対象物である吸収体を水平な場所にシワや折れ曲がりがないように静置し、5cN/cm2の荷重下での厚みを測定する。本発明における厚みの測定には、厚み計 PEACOCK DIAL UPRIGHT GAUGES R5-C(OZAKI MFG.CO.LTD.製)を用いた。このとき、厚み計の先端部と測定対象物における測定部分との間に、平面視円形状又は正方形状のプレート(厚さ5mm程度のアクリル板)を配置して、荷重が5cN/cm2となるようにプレートの大きさを調整する。
香料前駆体含有領域の面積S1は、好ましくは0.002m2以上、更に好ましくは0.003m2以上、そして、排泄物の吸収性の観点から、好ましくは0.04m2以下、更に好ましくは0.03m2以下、より具体的には、好ましくは0.002〜0.04m2、更に好ましくは0.003〜0.03m2である。
香料含有領域の面積S2は、好ましくは0.001m2以上、更に好ましくは0.002m2以上、そして、排泄物の吸収性の観点から、好ましくは0.03m2以下、更に好ましくは0.02m2以下、より具体的には、好ましくは0.001〜0.03m2、更に好ましくは0.002〜0.02m2である。
香料前駆体の、吸収体単位面積当たりの含有量(坪量)P1は、好ましくは3mg/m2以上、更に好ましくは5mg/m2以上、そして、好ましくは1000mg/m2以下、更に好ましくは500mg/m2以下、より具体的には、好ましくは3〜1000mg/m2、更に好ましくは5〜500mg/m2である。
香料の単位面積当たりの含有量(坪量)P2は、好ましくは1mg/m2以上、更に好ましくは3mg/m2以上、そして、好ましくは500mg/m2以下、更に好ましくは100mg/m2以下、より具体的には、好ましくは1〜500mg/m2、更に好ましくは3〜100mg/m2である。
吸収性物品(ナプキン1)における吸収容量1g当たりの、香料の含有量(坪量)P2’は、好ましくは0.1mg/g以上、更に好ましくは0.2mg/g以上、そして、好ましくは1mg/g以下、更に好ましくは0.6mg/g以下、より具体的には、好ましくは0.1〜1mg/g、更に好ましくは0.2〜0.6mg/gである。
吸収性物品における吸収容量は、以下のようにして測定される。
測定対象の吸収性物品における吸収体に対して、高吸水性樹脂の吸水試験法であるJIS K 7223−1996に準拠して吸収容量の測定を行う。吸収性物品(ナプキン1)から吸収体を取り出し、25℃に調温した生理食塩水(0.9質量%塩化ナトリウム水)に全体が浸かるように浸漬させる。浸漬開始から10分後に吸収体を生理食塩水から取り出し、遠心脱水器(コクサン(株)、型式130c特型)を用いて脱水する。脱水条件は800rpm×5分とする。脱水後、試料の質量を測定し、次式に従って遠心保持量(単位:g/g)を算出し、その算出値を当該吸収性物品の吸収容量とする。次式中、各質量はg単位である。
遠心保持量=(遠心脱水後の吸収体の質量−吸水前の吸収体の質量)/吸水前の吸収体の質量
測定は5回行い、上下各1点の値を除外し、残る3点の平均値を測定値とした。尚、測定は23±2℃、湿度50±5%で行い、測定の前には試料である吸収体を測定と同じ環境で24時間以上保存する。
・工程2:前記ウェブをエアスルー方式の熱風処理に付して前記熱伸長性の芯鞘繊維の交点を熱融着させると共に、該熱伸長性の芯鞘繊維を熱伸長させないか又は再度の熱伸長の余地を残した状態で該熱伸長性の芯鞘繊維を伸長させてなる上層不織布を形成する。
・工程3:前記上層不織布の形成とは別に、潜在捲縮性繊維を原料として用いてカード法で下層ウェブを形成し、前記上層不織布と該下層ウェブとを重ね合わせて、両者を複数の接合部によって接合して積層ウェブを得る。
・工程4:前記積層ウェブをエアスルー方式の熱風処理に付して、前記下層ウェブに含まれる前記潜在捲縮性繊維を捲縮させるとともに、前記上層不織布中の前記熱伸長性の芯鞘繊維を熱伸長させる。
溝部27(凹部)の坪量は、好ましくは10g/m2以上、更に好ましくは15g/m2以上、そして、好ましくは70g/m2以下、更に好ましくは50g/m2以下、より具体的には、好ましくは10〜70g/m2、更に好ましくは15〜50g/m2である。
肌対向面を形成する表面シート、非肌対向面を形成する裏面シート、及び両シート間に介在された吸収体を具備し、着用時に着用者の排泄部に対向配置される排泄部対向部を有する吸収性物品であって、
前記排泄部対向部に2種の香料成分を含み、そのうちの1種は、大気圧下で香気成分を大気中に蒸散し得る香料であり、他の1種は、水分と接触することによって香気成分を放出する香料前駆体であり、
前記香料と前記香料前駆体とは、前記吸収性物品の平面視において重なっている吸収性物品。
<2>
前記吸収性物品の厚み方向において、前記香料前駆体は前記香料よりも着用者の肌に近い部位に設けられている前記<1>記載の吸収性物品。
<3>
前記吸収体は、着用者の肌に近い側に位置する上層と、着用者の肌から遠い側に位置する下層とを有し、該上層に前記香料前駆体、該下層に前記香料がそれぞれ含まれている前記<2>記載の吸収性物品。
前記表面シートと前記吸収体との間に中間シートが介在され、該中間シートに前記香料前駆体、該吸収体に前記香料がそれぞれ含まれている前記<2>記載の吸収性物品。
<5>
前記中間シートは紙又は不織布である前記<4>記載の吸収性物品。
<6>
前記香料前駆体は、前記一般式(1)又は(2)で表されるケイ酸エステル化合物である前記<1>〜<5>の何れか1つに記載の吸収性物品。
前記表面シートの肌対向面側が凹凸形状をなしている前記<1>〜<6>の何れか1つに吸収性物品。
<8>
前記表面シートの凹凸形状を構成する凹部は、エンボス加工によって形成されている前記<7>記載の吸収性物品。
<9>
前記表面シートの凹凸形状を構成する凸部は中実である前記<7>又は<8>記載の吸収性物品。
<10>
前記表面シートの凹凸形状を構成する凸部は中空である前記<7>又は<8>記載の吸収性物品。
<11>
前記表面シートの凹凸形状を構成する凸部は、縦方向に延びる畝部、該凹凸形状を構成する凹部は、縦方向に延びる凹部であり、該凹部と該凸部とが横方向に交互に配されて畝溝構造を形成している前記<7>〜<10>の何れか1つに記載の吸収性物品。
前記裏面シートは透湿性を有する前記<1>〜<11>の何れか1つに記載の吸収性物品。<13>
前記香料前駆体の含有領域の面積は、前記香料の含有領域の面積に比して大きい前記<1>〜<12>の何れか1つに記載の吸収性物品。
<14>
前記吸収体において、前記香料前駆体を含む前記上層に、該上層を厚み方向に貫通するスリット状の開口部が設けられている前記<3>〜<13>の何れか1つに記載の吸収性物品。
前記吸収体は、該吸収体の外形を形成する主吸収体と、該主吸収体の一部に重ねて配され且つ該主吸収体より小型の補助吸収体とを有している前記<3>〜<14>の何れか1つに記載の吸収性物品。
<16>
前記排泄部対向部より着用者の腹側に配される前方部、及び該排泄部対向部よりも着用者の背側に配される後方部を有し、
前記主吸収体は、平面視において角が丸みを帯びた略矩形形状で且つ前記前方部から前記排泄部対向部を経て前記後方部に亘って延びる1枚の吸収性シートからなり、
前記補助吸収体は、平面視において略矩形形状であり、前記排泄部対向部からその近傍の前記後方部に亘って配されている前記<15>記載の吸収性物品。
<17>
前記主吸収体は、1枚の吸収性シートを折り畳んで複数層の構造としたものである前記<15>又は<16>記載の吸収性物品。
前記吸収体における前記ケイ酸エステル化合物の含有量は0.25〜40g/m2である前記<6>〜<16>の何れか1つに記載の吸収性物品。
<19>
前記吸収性物品が生理用ナプキンである前記<1>〜<18>の何れか1つに記載の吸収性物品。
<20>
前記生理用ナプキンの縦方向の全長が30cm以上である前記<19>記載の吸収性物品。
2 表面シート
21 凸部
22 凹部
23A,23C 第1繊維層
24A,24C 第2繊維層
26 畝部(凸部)
27 溝部(凹部)
3 裏面シート
4 吸収体
40 主吸収体
41 補助吸収体
401,402 吸収性シート
42 中高部
5 吸収性本体
7 ウイング部
8 後方フラップ部
9 中間シート
A 前方部
B 排泄部対向部
C 後方部
X 縦方向
Y 横方向
Claims (6)
- 肌対向面を形成する表面シート、非肌対向面を形成する裏面シート、及び両シート間に介在された吸収体を具備し、着用時に着用者の排泄部に対向配置される排泄部対向部を有する吸収性物品であって、
前記排泄部対向部に2種の香料成分を含み、そのうちの1種は、大気圧下で香気成分を大気中に蒸散し得る香料であり、他の1種は、水分と接触することによって香気成分を放出する香料前駆体であり、
前記香料由来の香気と前記香料前駆体由来の香気とは異なっており、
前記香料と前記香料前駆体とは、前記吸収性物品の平面視において重なっており、
前記吸収性物品の厚み方向において、前記香料前駆体は前記香料よりも着用者の肌に近い部位に設けられている吸収性物品。 - 前記吸収体は、着用者の肌に近い側に位置する上層と、着用者の肌から遠い側に位置する下層とを有し、該上層に前記香料前駆体、該下層に前記香料がそれぞれ含まれている請求項1記載の吸収性物品。
- 前記表面シートと前記吸収体との間に中間シートが介在され、該中間シートに前記香料前駆体、該吸収体に前記香料がそれぞれ含まれている請求項1記載の吸収性物品。
- 前記表面シートの肌対向面側が凹凸形状をなしている請求項1〜4の何れか一項に吸収性物品。
- 前記裏面シートは透湿性を有する請求項1〜5の何れか一項に記載の吸収性物品。
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