JP6238932B2 - ヨウ素化合物吸着剤及びその製造方法並びにヨウ素化合物吸着剤を用いる放射性廃液の処理方法及び装置 - Google Patents

ヨウ素化合物吸着剤及びその製造方法並びにヨウ素化合物吸着剤を用いる放射性廃液の処理方法及び装置 Download PDF

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JP6238932B2
JP6238932B2 JP2015114113A JP2015114113A JP6238932B2 JP 6238932 B2 JP6238932 B2 JP 6238932B2 JP 2015114113 A JP2015114113 A JP 2015114113A JP 2015114113 A JP2015114113 A JP 2015114113A JP 6238932 B2 JP6238932 B2 JP 6238932B2
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iodine compound
compound adsorbent
iodine
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JP2017000909A (ja
JP2017000909A5 (enExample
Inventor
貴志 佐久間
貴志 佐久間
小松　誠
誠 小松
出水　丈志
丈志 出水
伊藤　智彦
智彦 伊藤
渋谷　徹
徹 渋谷
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Ebara Corp
Nihon Kaisui Co Ltd
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Ebara Corp
Nihon Kaisui Co Ltd
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Priority to US15/575,504 priority patent/US10388419B2/en
Priority to PCT/JP2016/066666 priority patent/WO2016195096A1/ja
Priority to CA2986717A priority patent/CA2986717C/en
Priority to CN201680032176.2A priority patent/CN107847902B/zh
Priority to EP16803527.7A priority patent/EP3305403A4/en
Publication of JP2017000909A publication Critical patent/JP2017000909A/ja
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    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • G21F9/06—Processing
    • G21F9/16—Processing by fixation in stable solid media
    • G21F9/167—Processing by fixation in stable solid media in polymeric matrix, e.g. resins, tars
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08—Selective adsorption, e.g. chromatography
    • B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
    • B01D15/36—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving ionic interaction, e.g. ion-exchange, ion-pair, ion-suppression or ion-exclusion
    • B01D15/361—Ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7003—A-type
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04—Treating liquids
    • G21F9/06—Processing
    • G21F9/12—Processing by absorption; by adsorption; by ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/10—Inorganic absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/006—Radioactive compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/20—Heavy metals or heavy metal compounds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • High Energy & Nuclear Physics (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Water Treatment By Sorption (AREA)
JP2015114113A 2015-06-04 2015-06-04 ヨウ素化合物吸着剤及びその製造方法並びにヨウ素化合物吸着剤を用いる放射性廃液の処理方法及び装置 Active JP6238932B2 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2015114113A JP6238932B2 (ja) 2015-06-04 2015-06-04 ヨウ素化合物吸着剤及びその製造方法並びにヨウ素化合物吸着剤を用いる放射性廃液の処理方法及び装置
PCT/JP2016/066666 WO2016195096A1 (ja) 2015-06-04 2016-06-03 ヨウ素化合物及び／又はアンチモンを吸着する吸着剤及びその製造方法並びに当該吸着剤を用いる放射性廃液の処理方法及び装置
CA2986717A CA2986717C (en) 2015-06-04 2016-06-03 Adsorbent for adsorbing iodine compounds and/or antimony, method for preparing said adsorbent, and method and apparatus for treating radioactive waste liquid by using said adsorbent
CN201680032176.2A CN107847902B (zh) 2015-06-04 2016-06-03 吸附碘化合物及/或锑的吸附剂及其制造方法以及使用该吸附剂的放射性废液的处理方法及装置
US15/575,504 US10388419B2 (en) 2015-06-04 2016-06-03 Adsorbent for adsorbing iodine compounds and/or antimony, method for preparing said adsorbent, and method and apparatus for treating radioactive waste liquid by using said absorbent
EP16803527.7A EP3305403A4 (en) 2015-06-04 2016-06-03 ADSORBENT FOR ADSORPTION OF IODINE AND / OR ANTIMONY COMPOUNDS, PROCESS FOR PREPARING SAID ADSORBENT, AND METHOD AND APPARATUS FOR TREATING RADIOACTIVE LIQUID WAST THROUGH SAID ADSORBENT

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US (1) US10388419B2 (enExample)
EP (1) EP3305403A4 (enExample)
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CN (1) CN107847902B (enExample)
CA (1) CA2986717C (enExample)
WO (1) WO2016195096A1 (enExample)

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CN110382442B (zh) * 2017-01-31 2022-04-01 三井金属矿业株式会社 成型体
JP7086524B2 (ja) * 2017-03-08 2022-06-20 株式会社荏原製作所 アルカリ土類金属イオン吸着剤及びその製造方法並びにアルカリ土類金属イオン含有液処理装置
CN110482641B (zh) * 2019-07-19 2022-02-11 南华大学 一种银附载多孔陶粒吸附材料在处理低浓度碘废水中的应用
US11143592B2 (en) 2019-08-23 2021-10-12 King Abdulaziz University Method of detecting antimony ions and method of removing antimony ions using a fluorescent nanocomposite
JP2023032407A (ja) * 2021-08-27 2023-03-09 東ソー株式会社 ヨウ化物イオン吸着材及びその製造方法
US12562289B2 (en) * 2023-01-20 2026-02-24 Abilene Christian University Fission product trap for salt pipe and pump shaft seals and methods of use thereof
US12431253B2 (en) 2023-06-21 2025-09-30 Abilene Christian University Fission product extraction system and methods of use thereof
WO2025029454A2 (en) 2023-07-31 2025-02-06 Abilene Christian University Methods for the purification of molybdenum-99 with phase transfer agents
AU2024351044A1 (en) 2023-09-29 2026-04-09 Abilene Christian University Separation of fission products in a molten salt reactor via adsorbent frameworks
CN119409264B (zh) * 2024-11-08 2025-10-03 杨凌核盛辐照技术有限公司 一种利用锆功能化吸附树脂去除锑的方法
CN120600370B (zh) * 2025-08-08 2025-10-03 中科核润(陕西)生态环境有限公司 一种放射性废水的资源化处理方法

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JP2540401B2 (ja) 1991-11-05 1996-10-02 動力炉・核燃料開発事業団 放射性ヨウ素化合物の沈澱分離方法
JPH1062593A (ja) * 1996-08-19 1998-03-06 Hitachi Ltd 放射性ヨウ素の除去方法およびその除去装置
JP2005288363A (ja) * 2004-04-01 2005-10-20 Nihon Kaisui:Kk 砒素吸着剤及びその製造方法
WO2004096433A1 (ja) * 2003-05-01 2004-11-11 Nihon Kaisui Co., Ltd. 吸着剤及びその製造方法
JP2004330012A (ja) * 2003-05-01 2004-11-25 Shin Nihon Salt Co Ltd ホウ素吸着剤及びその製造方法
JP2008024912A (ja) * 2006-06-23 2008-02-07 Nippon Sheet Glass Co Ltd 希土類化合物造粒成形体およびその製造方法
JP2012251912A (ja) * 2011-06-03 2012-12-20 Kaneka Corp ヨウ化物イオンの除去・吸着方法
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JP6131450B2 (ja) * 2013-04-23 2017-05-24 株式会社化研 放射性汚染水または工場排水浄化方法及び放射性汚染水または工場排水浄化方法に用いられる酸化セリウム担持活性炭の形成方法
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CN107847902B (zh) 2021-07-13
US10388419B2 (en) 2019-08-20
CA2986717A1 (en) 2016-12-08
JP2017000909A (ja) 2017-01-05
US20180158558A1 (en) 2018-06-07
EP3305403A1 (en) 2018-04-11
CA2986717C (en) 2022-05-10
CN107847902A (zh) 2018-03-27
EP3305403A4 (en) 2019-02-13
WO2016195096A1 (ja) 2016-12-08

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