JP6186083B2 - 成形品とその製作に使用される組成物 - Google Patents
成形品とその製作に使用される組成物 Download PDFInfo
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- JP6186083B2 JP6186083B2 JP2016529783A JP2016529783A JP6186083B2 JP 6186083 B2 JP6186083 B2 JP 6186083B2 JP 2016529783 A JP2016529783 A JP 2016529783A JP 2016529783 A JP2016529783 A JP 2016529783A JP 6186083 B2 JP6186083 B2 JP 6186083B2
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- automotive
- polyamide
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- poly
- molded article
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- 239000000203 mixture Substances 0.000 title claims description 97
- OMIHGPLIXGGMJB-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]hepta-1,3,5-triene Chemical compound C1=CC=C2OC2=C1 OMIHGPLIXGGMJB-UHFFFAOYSA-N 0.000 claims description 71
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 45
- 229920002647 polyamide Polymers 0.000 claims description 38
- 239000004952 Polyamide Substances 0.000 claims description 37
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 33
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 25
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 24
- 239000003795 chemical substances by application Substances 0.000 claims description 24
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 22
- 239000003365 glass fiber Substances 0.000 claims description 21
- GVLZQVREHWQBJN-UHFFFAOYSA-N 3,5-dimethyl-7-oxabicyclo[2.2.1]hepta-1,3,5-triene Chemical compound CC1=C(O2)C(C)=CC2=C1 GVLZQVREHWQBJN-UHFFFAOYSA-N 0.000 claims description 18
- 238000001914 filtration Methods 0.000 claims description 13
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 13
- 239000001530 fumaric acid Substances 0.000 claims description 12
- 229920002292 Nylon 6 Polymers 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 11
- -1 optionally Substances 0.000 claims description 11
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 10
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 10
- 239000011976 maleic acid Substances 0.000 claims description 10
- 239000000155 melt Substances 0.000 claims description 10
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 9
- 239000003963 antioxidant agent Substances 0.000 claims description 9
- 239000002216 antistatic agent Substances 0.000 claims description 9
- 239000000975 dye Substances 0.000 claims description 9
- 239000006078 metal deactivator Substances 0.000 claims description 9
- 239000002480 mineral oil Substances 0.000 claims description 9
- 239000000049 pigment Substances 0.000 claims description 9
- 239000003381 stabilizer Substances 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 8
- 238000009826 distribution Methods 0.000 claims description 8
- 239000004088 foaming agent Substances 0.000 claims description 8
- 239000000314 lubricant Substances 0.000 claims description 8
- 239000010718 automatic transmission oil Substances 0.000 claims description 6
- 230000002787 reinforcement Effects 0.000 claims description 5
- 238000003860 storage Methods 0.000 claims description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 3
- 239000011231 conductive filler Substances 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- 239000000047 product Substances 0.000 description 19
- 210000003660 reticulum Anatomy 0.000 description 19
- 125000001183 hydrocarbyl group Chemical group 0.000 description 17
- DDTHMESPCBONDT-UHFFFAOYSA-N 4-(4-oxocyclohexa-2,5-dien-1-ylidene)cyclohexa-2,5-dien-1-one Chemical group C1=CC(=O)C=CC1=C1C=CC(=O)C=C1 DDTHMESPCBONDT-UHFFFAOYSA-N 0.000 description 16
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 239000002253 acid Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 238000000465 moulding Methods 0.000 description 7
- 230000001590 oxidative effect Effects 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 150000001412 amines Chemical group 0.000 description 6
- 150000008064 anhydrides Chemical group 0.000 description 6
- 229910052736 halogen Inorganic materials 0.000 description 6
- 150000002367 halogens Chemical class 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- QDRFIDSUGRGGAY-UHFFFAOYSA-N 4-(3,5-dimethyl-4-oxocyclohexa-2,5-dien-1-ylidene)-2,6-dimethylcyclohexa-2,5-dien-1-one Chemical compound C1=C(C)C(=O)C(C)=CC1=C1C=C(C)C(=O)C(C)=C1 QDRFIDSUGRGGAY-UHFFFAOYSA-N 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 230000003078 antioxidant effect Effects 0.000 description 5
- 235000010446 mineral oil Nutrition 0.000 description 5
- 239000006082 mold release agent Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- MIHINWMALJZIBX-UHFFFAOYSA-N cyclohexa-2,4-dien-1-ol Chemical compound OC1CC=CC=C1 MIHINWMALJZIBX-UHFFFAOYSA-N 0.000 description 4
- 125000004430 oxygen atom Chemical group O* 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000003368 amide group Chemical group 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 3
- 125000002843 carboxylic acid group Chemical group 0.000 description 3
- 238000011067 equilibration Methods 0.000 description 3
- 125000004185 ester group Chemical group 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 125000002092 orthoester group Chemical group 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- KPTMGJRRIXXKKW-UHFFFAOYSA-N 2,3,5-trimethyl-7-oxabicyclo[2.2.1]hepta-1,3,5-triene Chemical group O1C2=C(C)C(C)=C1C=C2C KPTMGJRRIXXKKW-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004609 Impact Modifier Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 125000002619 bicyclic group Chemical group 0.000 description 2
- MKUWVMRNQOOSAT-UHFFFAOYSA-N but-3-en-2-ol Chemical compound CC(O)C=C MKUWVMRNQOOSAT-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 150000004820 halides Chemical group 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000005462 imide group Chemical group 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000001630 malic acid Substances 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- NJMOHBDCGXJLNJ-UHFFFAOYSA-N trimellitic anhydride chloride Chemical compound ClC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 NJMOHBDCGXJLNJ-UHFFFAOYSA-N 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
- OJMZQYGIPTULAQ-UHFFFAOYSA-N 2,5-dioxooxolane-3-carbonyl chloride Chemical compound ClC(=O)C1CC(=O)OC1=O OJMZQYGIPTULAQ-UHFFFAOYSA-N 0.000 description 1
- FVNJVBDCJZYQEV-UHFFFAOYSA-N 2,6-dioxooxane-3-carbonyl chloride Chemical compound ClC(=O)C1CCC(=O)OC1=O FVNJVBDCJZYQEV-UHFFFAOYSA-N 0.000 description 1
- GBFMDWWQSKICTH-UHFFFAOYSA-N 2-(2-chloroacetyl)pentanedioic acid Chemical compound OC(=O)CCC(C(O)=O)C(=O)CCl GBFMDWWQSKICTH-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- WCASXYBKJHWFMY-NSCUHMNNSA-N 2-Buten-1-ol Chemical compound C\C=C\CO WCASXYBKJHWFMY-NSCUHMNNSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- YIXSKDRXJTZCHT-UHFFFAOYSA-N 2-acetylbutanedioic acid Chemical compound CC(=O)C(C(O)=O)CC(O)=O YIXSKDRXJTZCHT-UHFFFAOYSA-N 0.000 description 1
- RKIUJXGITAEIIG-UHFFFAOYSA-N 2-carbonochloridoylbutanedioic acid Chemical compound OC(=O)CC(C(O)=O)C(Cl)=O RKIUJXGITAEIIG-UHFFFAOYSA-N 0.000 description 1
- WSUBIRCPENZBDS-UHFFFAOYSA-N 2-carbonochloridoylpentanedioic acid Chemical compound OC(=O)CCC(C(O)=O)C(Cl)=O WSUBIRCPENZBDS-UHFFFAOYSA-N 0.000 description 1
- WROUWQQRXUBECT-UHFFFAOYSA-N 2-ethylacrylic acid Chemical compound CCC(=C)C(O)=O WROUWQQRXUBECT-UHFFFAOYSA-N 0.000 description 1
- IMQYZLJIDNYQLX-UHFFFAOYSA-N 2-hydroxy-4-octadecoxy-2-(2-octadecoxy-2-oxoethyl)-4-oxobutanoic acid Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CC(O)(C(O)=O)CC(=O)OCCCCCCCCCCCCCCCCCC IMQYZLJIDNYQLX-UHFFFAOYSA-N 0.000 description 1
- HZLCGUXUOFWCCN-UHFFFAOYSA-N 2-hydroxynonadecane-1,2,3-tricarboxylic acid Chemical compound CCCCCCCCCCCCCCCCC(C(O)=O)C(O)(C(O)=O)CC(O)=O HZLCGUXUOFWCCN-UHFFFAOYSA-N 0.000 description 1
- WXBXVVIUZANZAU-UHFFFAOYSA-N 2E-decenoic acid Natural products CCCCCCCC=CC(O)=O WXBXVVIUZANZAU-UHFFFAOYSA-N 0.000 description 1
- AGULWIQIYWWFBJ-UHFFFAOYSA-N 3,4-dichlorofuran-2,5-dione Chemical compound ClC1=C(Cl)C(=O)OC1=O AGULWIQIYWWFBJ-UHFFFAOYSA-N 0.000 description 1
- FNEKYGYYCSEBNI-UHFFFAOYSA-N 3-(2-chloroacetyl)oxolane-2,5-dione Chemical compound ClCC(=O)C1CC(=O)OC1=O FNEKYGYYCSEBNI-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- OCXMYNMKUFUCKP-UHFFFAOYSA-N 4-(dodecylamino)-4-oxobutanoic acid Chemical compound CCCCCCCCCCCCNC(=O)CCC(O)=O OCXMYNMKUFUCKP-UHFFFAOYSA-N 0.000 description 1
- WWXUGNUFCNYMFK-UHFFFAOYSA-N Acetyl citrate Chemical compound CC(=O)OC(=O)CC(O)(C(O)=O)CC(O)=O WWXUGNUFCNYMFK-UHFFFAOYSA-N 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- GZZPOFFXKUVNSW-UHFFFAOYSA-N Dodecenoic acid Natural products OC(=O)CCCCCCCCCC=C GZZPOFFXKUVNSW-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- BGRDGMRNKXEXQD-UHFFFAOYSA-N Maleic hydrazide Chemical compound OC1=CC=C(O)N=N1 BGRDGMRNKXEXQD-UHFFFAOYSA-N 0.000 description 1
- 239000005983 Maleic hydrazide Substances 0.000 description 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- REVZBRXEBPWDRA-UHFFFAOYSA-N Stearyl citrate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CC(O)(C(O)=O)CC(O)=O REVZBRXEBPWDRA-UHFFFAOYSA-N 0.000 description 1
- 229940091181 aconitic acid Drugs 0.000 description 1
- 229940040563 agaric acid Drugs 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- YIYBQIKDCADOSF-UHFFFAOYSA-N alpha-Butylen-alpha-carbonsaeure Natural products CCC=CC(O)=O YIYBQIKDCADOSF-UHFFFAOYSA-N 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- CJPIDIRJSIUWRJ-UHFFFAOYSA-N benzene-1,2,4-tricarbonyl chloride Chemical compound ClC(=O)C1=CC=C(C(Cl)=O)C(C(Cl)=O)=C1 CJPIDIRJSIUWRJ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- OZCRKDNRAAKDAN-UHFFFAOYSA-N but-1-ene-1,4-diol Chemical compound O[CH][CH]CCO OZCRKDNRAAKDAN-UHFFFAOYSA-N 0.000 description 1
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 1
- 239000001354 calcium citrate Substances 0.000 description 1
- 229960004256 calcium citrate Drugs 0.000 description 1
- OLOZVPHKXALCRI-UHFFFAOYSA-L calcium malate Chemical compound [Ca+2].[O-]C(=O)C(O)CC([O-])=O OLOZVPHKXALCRI-UHFFFAOYSA-L 0.000 description 1
- 239000001362 calcium malate Substances 0.000 description 1
- 229940016114 calcium malate Drugs 0.000 description 1
- 235000011038 calcium malates Nutrition 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- RMBGFUOEZINVEP-UHFFFAOYSA-N cyclohexa-2,5-diene-1,4-dione;phenol Chemical compound OC1=CC=CC=C1.O=C1C=CC(=O)C=C1 RMBGFUOEZINVEP-UHFFFAOYSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 125000004915 dibutylamino group Chemical group C(CCC)N(CCCC)* 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000010097 foam moulding Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- WCASXYBKJHWFMY-UHFFFAOYSA-N gamma-methylallyl alcohol Natural products CC=CCO WCASXYBKJHWFMY-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hcl hcl Chemical compound Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- WCJAFRYVCLHKTK-UHFFFAOYSA-N hexa-1,4-dien-3-ol Chemical compound CC=CC(O)C=C WCJAFRYVCLHKTK-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- FSQQTNAZHBEJLS-UPHRSURJSA-N maleamic acid Chemical class NC(=O)\C=C/C(O)=O FSQQTNAZHBEJLS-UPHRSURJSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 229940116396 monostearyl citrate Drugs 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- LQAVWYMTUMSFBE-UHFFFAOYSA-N pent-4-en-1-ol Chemical compound OCCCC=C LQAVWYMTUMSFBE-UHFFFAOYSA-N 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- SVICABYXKQIXBM-UHFFFAOYSA-L potassium malate Chemical compound [K+].[K+].[O-]C(=O)C(O)CC([O-])=O SVICABYXKQIXBM-UHFFFAOYSA-L 0.000 description 1
- 239000001415 potassium malate Substances 0.000 description 1
- 235000011033 potassium malate Nutrition 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000012260 resinous material Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000004616 structural foam Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- WXBXVVIUZANZAU-CMDGGOBGSA-N trans-2-decenoic acid Chemical compound CCCCCCC\C=C\C(O)=O WXBXVVIUZANZAU-CMDGGOBGSA-N 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- YIYBQIKDCADOSF-ONEGZZNKSA-N trans-pent-2-enoic acid Chemical compound CC\C=C\C(O)=O YIYBQIKDCADOSF-ONEGZZNKSA-N 0.000 description 1
- 235000013337 tricalcium citrate Nutrition 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/092—Polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1535—Five-membered rings
- C08K5/1539—Cyclic anhydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
Description
下式で表される脂肪族ポリカルボン酸、酸エステルおよび酸アミドである:
Claims (10)
- 組成物の合計質量に対して、
30〜44質量%のポリアミド−6、ポリアミド−6,6あるいはこれらの組み合わせと、12〜23質量%のポリ(フェニレンエーテル)と、相溶化剤と、を含む成分の溶融混合生成物を含む45〜65質量%の相溶化ブレンドと;
35〜55質量%のガラス繊維と、
を含む組成物を含有し、前記相溶化剤の含有量は、前記相溶化ブレンドの合計質量に対して0.1〜1質量%であることを特徴とする成形品。 - 自動変速装置オイルクーラーブラケット、ボンネット内サポートシステム、車体下サポートシステム、自動車用バッテリートレイ、電気自動車サポートフレーム、自動車用ロールオーバークラッシュゾーン部品、自動車用パワートレインハウジング、自動車用バルブカバー、自動車用インテークマニホールド、自動車用ターボチャージャーエアインテークマニホールド、自動車用ターボチャージャーコンプレッサハウジング、自動車用ターボチャージャーコンプレッサホイール、自動車用ターボチャージャー圧縮空気ダクト、自動車用サンルーフ取付部またはフレームワーク、自動車用窓取付部またはフレームワーク、電気自動車バッテリーフレームまたはサポート、自動車用ロードフロアブラケットまたはサポート、自動車用アクティブグリルシャッター、自動車用グリル開口部補強材、自動車用ミラーブラケット、自動車用ルーフラックブラケットまたはフレーム、自動車用ランニングボード部品、自動車用ファンサポートまたはハウジングまたはブラケット、自動車用ボンネット、自動車用ボンネットフェアリング、自動車用ボンネットトリムサポート、自動車用シート構造、自動車用キャビン構造またはサポートまたは取付装置、自動車用貯蔵容器、自動車用スロットルボディハウジング、水道メータハウジング、配水ハウジング、水バルブ、給水接続具、送水ポンプハウジング、水濾過ハウジングまたは水濾過サポートシステムである請求項1に記載の成形品。
- 前記ポリアミドは、ポリアミド−6とポリアミド−6,6の組み合わせである請求項1又は2に記載の成形品。
- 前記ポリアミドは、ポリアミド−6,6である請求項1又は2に記載の成形品。
- 前記溶融混合生成物は、4質量%以下の耐衝撃性改良剤を含む請求項1乃至4のいずれか1項に記載の成形品。
- 前記組成物は難燃剤を含まない請求項1乃至5のいずれか1項に記載の成形品。
- 前記組成物は導電性充填剤を含まない請求項1乃至6のいずれか1項に記載の成形品。
- 前記組成物は、55〜65質量%の前記相溶化ブレンドと35〜45質量%の前記ガラス繊維とからなり;
前記相溶化ブレンドは、35〜44質量%の前記ポリアミド−6,6と、16〜23質量%の前記ポリ(フェニレンエーテル)と、前記相溶化剤と、任意に、酸化防止剤、安定剤、離型剤、潤滑剤、加工助剤、染料、顔料、帯電防止剤、発泡剤、鉱油、金属不活性化剤、ブロッキング防止剤およびこれらの組み合わせからなる群から選択された0.01〜2質量%の添加剤と、からなる成分の溶融混合生成物からなり、前記相溶化剤の含有量は相溶化ブレンドの合計質量に対して0.4〜1質量%である請求項1乃至4のいずれか1項に記載の成形品。 - 前記ポリ(フェニレンエーテル)は、ポリ(2,6−ジメチル−1,4−フェニレンエーテル)を含み;
前記相溶化剤は、クエン酸、フマル酸、マレイン酸、無水マレイン酸およびこれらの組み合わせからなる群から選択され;
前記組成物は、55〜65質量%の前記相溶化ブレンドと35〜45質量%の前記ガラス繊維とからなり;
前記相溶化ブレンドは、35〜44質量%の前記ポリアミド−6,6と、16〜23質量%の前記ポリ(フェニレンエーテル)と、前記相溶化剤と、任意に、酸化防止剤、安定剤、離型剤、潤滑剤、加工助剤、染料、顔料、帯電防止剤、発泡剤、鉱油、金属不活性化剤、ブロッキング防止剤およびこれらの組み合わせからなる群から選択された0.01〜2質量%の添加剤と、を含む成分の溶融混合生成物からなり、前記相溶化剤の含有量は相溶化ブレンドの合計質量に対して0.4〜1質量%である請求項1に記載の成形品。 - 組成物の合計質量に対して、
30〜44質量%のポリアミド−6,6と、12〜23質量%のポリ(2,6−ジメチル−1,4−フェニレンエーテル)と、クエン酸、フマル酸、マレイン酸、無水マレイン酸あるいはこれらの組み合わせを含む相溶化剤と、を含む成分の溶融混合生成物を含む45〜65質量%の相溶化ブレンドと;
35〜55質量%のガラス繊維と、
を含み、前記相溶化剤の含有量は相溶化ブレンドの合計質量に対して0.4〜1質量%であることを特徴とする組成物。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201361858174P | 2013-07-25 | 2013-07-25 | |
US61/858,174 | 2013-07-25 | ||
PCT/US2014/046612 WO2015013060A1 (en) | 2013-07-25 | 2014-07-15 | Molded article and composition used in its fabrication |
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JP2016525611A JP2016525611A (ja) | 2016-08-25 |
JP6186083B2 true JP6186083B2 (ja) | 2017-08-23 |
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JP2016529783A Active JP6186083B2 (ja) | 2013-07-25 | 2014-07-15 | 成形品とその製作に使用される組成物 |
Country Status (6)
Country | Link |
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US (1) | US20160130438A1 (ja) |
EP (1) | EP3024893A4 (ja) |
JP (1) | JP6186083B2 (ja) |
KR (1) | KR102090096B1 (ja) |
CN (1) | CN105392840B (ja) |
WO (1) | WO2015013060A1 (ja) |
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KR102343491B1 (ko) | 2021-07-27 | 2021-12-24 | 코오롱글로텍주식회사 | 자동차 배터리 커버 제조방법 및 이에 의해 제조된 자동차 배터리 커버 |
KR102466615B1 (ko) | 2021-07-27 | 2022-11-16 | 코오롱글로텍주식회사 | 복합소재 난연 자동차 배터리 커버 및 이의 제조방법 |
KR102466614B1 (ko) | 2021-07-27 | 2022-11-14 | 코오롱글로텍주식회사 | 복합소재 난연 자동차 배터리 커버 |
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CA2030054A1 (en) * | 1989-12-28 | 1991-06-29 | Gim F. Lee, Jr. | Compatibilized polyphenylene ether resin/nylon resin blends containing aromatic phosphorous-containing compounds |
JPH04146959A (ja) * | 1990-10-11 | 1992-05-20 | Mitsubishi Gas Chem Co Inc | 表面平滑性繊維強化樹脂組成物 |
EP0685527B1 (en) * | 1994-06-01 | 1997-03-05 | General Electric Company | Thermoplastic composition comprising a compatibilized polyphenylene ether- polyamide base resin and electroconductive carbon black |
SG45409A1 (en) * | 1995-06-07 | 1998-01-16 | Gen Electric | Compositions of poly(phenylene ether) and polyamide resins which exhibit improved melt strength |
US6469093B1 (en) * | 1999-11-12 | 2002-10-22 | General Electric Company | Conductive polyphenylene ether-polyamide blend |
US7166243B2 (en) * | 2003-08-16 | 2007-01-23 | General Electric Company | Reinforced poly(arylene ether)/polyamide composition |
US7592382B2 (en) * | 2004-11-22 | 2009-09-22 | Sabic Innovative Plastics Ip B.V. | Flame retardant poly(arylene ether)/polyamide compositions, methods, and articles |
WO2006112058A1 (ja) * | 2005-04-13 | 2006-10-26 | Asahi Kasei Chemicals Corporation | ポリアミド-ポリフェニレンエーテル樹脂組成物 |
JP5388165B2 (ja) * | 2008-04-25 | 2014-01-15 | 旭化成ケミカルズ株式会社 | 難燃性樹脂組成物 |
US8178610B2 (en) * | 2008-06-10 | 2012-05-15 | Sabic Innovative Plastics Ip B.V. | Polyamide/poly(arylene ether) composition, method, and article |
JP5629477B2 (ja) * | 2009-02-27 | 2014-11-19 | 旭化成ケミカルズ株式会社 | 外装材用樹脂組成物 |
US20120325083A1 (en) * | 2011-06-27 | 2012-12-27 | Sai-Pei Ting | Piston guide ring comprising polyamide-poly(arylene ether) composition |
US9090999B2 (en) * | 2011-09-28 | 2015-07-28 | Sabic Global Technologies B.V. | Polyamide/polyphenylene ether fibers and fiber-forming method |
-
2014
- 2014-07-15 US US14/888,957 patent/US20160130438A1/en not_active Abandoned
- 2014-07-15 KR KR1020167004948A patent/KR102090096B1/ko active IP Right Grant
- 2014-07-15 WO PCT/US2014/046612 patent/WO2015013060A1/en active Application Filing
- 2014-07-15 EP EP14828659.4A patent/EP3024893A4/en not_active Withdrawn
- 2014-07-15 CN CN201480041272.4A patent/CN105392840B/zh active Active
- 2014-07-15 JP JP2016529783A patent/JP6186083B2/ja active Active
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EP3024893A4 (en) | 2017-04-26 |
CN105392840B (zh) | 2017-08-25 |
KR102090096B1 (ko) | 2020-03-18 |
KR20160035056A (ko) | 2016-03-30 |
CN105392840A (zh) | 2016-03-09 |
WO2015013060A1 (en) | 2015-01-29 |
JP2016525611A (ja) | 2016-08-25 |
US20160130438A1 (en) | 2016-05-12 |
EP3024893A1 (en) | 2016-06-01 |
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