JP6151731B2 - 伝熱方法 - Google Patents
伝熱方法 Download PDFInfo
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- JP6151731B2 JP6151731B2 JP2015026010A JP2015026010A JP6151731B2 JP 6151731 B2 JP6151731 B2 JP 6151731B2 JP 2015026010 A JP2015026010 A JP 2015026010A JP 2015026010 A JP2015026010 A JP 2015026010A JP 6151731 B2 JP6151731 B2 JP 6151731B2
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/122—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/126—Unsaturated fluorinated hydrocarbons
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- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
本発明は特に、ヒートポンプでのヒドロクロロフルオロ・オレフィンを含む組成物の使用に関するものである。
温室効果に対する流体の寄与は規格GWP(地球温暖化係数)によって定量化される。このGWPは二酸化炭素の基準値を1にして温暖化可能性を指数化したものである。
(i) 冷媒液がその低沸点によって周囲環境の熱と接触して液体から気体に変化する蒸発の段階、
(ii) 上記階段からのガスを高圧にする圧縮段階、
(iii)ガスの熱を加熱回路に伝える凝縮段階(冷媒はさらに圧縮されて再び液体になる)、
(iv)冷媒液の圧力を低下させて冷媒液を膨張させる段階。冷媒液は冷たい周囲環境から熱を新たに吸収する準備ができている。
,2,3,3−ヘキサフルオロ−2−(トリフルオロメチル)−3−メトオキシブタンの形で入手できる。
以下の実施例で、
EvapPは蒸発器の圧力、
CondPは凝縮器の圧力、
Tcondは凝縮温度、
Te compはコンプレッサの吸込み温度、
比: 圧縮比、
T outlet compはコンプレッサ吐出温度、
COP:成績係数(ヒートポンプでは系が取り入れたまたは消費した動力に対する系によって提供された有効な熱パワーで定義される)
CAP:容積能力(volumetric capacity)(単位容積当たりの熱容量)(kJ/m3)、
%CAPまたはCOPはHCFC−114で得られる同じ値に対する冷媒液のCAPまたはCOPの値の比である。
蒸発器温度を10℃にセットし、凝縮器温度を100℃にセットした上記ヒートポンプ運転条件下での冷媒液の運転性能を以下に示す。
HCFC−114の場合、以下の運転状態下で、公称運転圧力は14.19バール、容積能力は785kJ/m3、COPは2.07である:
コンプレッサの有効効率(insentropic efficiency):80%
蒸発器温度を50℃にセットし、凝縮器温度を80℃にセットした上記ヒートポンプ運
転条件下での冷媒液の運転性能を以下に示す。
HCFC−114の場合、以下の運転状態下で、公称運転圧力は9.3バール、容積能
力は3321kJ/m3、COPは8.19である:
コンプレッサの有効効率(insentropic efficiency):80%
蒸発器温度を50℃にセットし、凝縮器温度を95℃にセットした上記ヒートポンプ運
転条件下での冷媒液の運転性能を以下に示す。
HCFC−114の場合、以下の運転状態下で、公称運転圧力は12.82バール、容
積能力は2976kJ/m3、COPは5.19である:
コンプレッサの有効効率(insentropic efficiency):80%
蒸発器温度を50℃にセットし、凝縮器温度を110℃にセットした上記ヒートポンプ
運転条件下での冷媒液の運転性能を以下に示す。
HCFC−114の場合、以下の運転状態下で、公称運転圧力は17.26バール、容
積能力は2573kJ/m3、COPは3.46である:
コンプレッサの有効効率(insentropic efficiency):80%
蒸発器温度を50℃にセットし、凝縮器温度を120℃にセットした上記ヒートポンプ
運転条件下での冷媒液の運転性能を以下に示す。
HCFC−114の場合、以下の運転状態下で、公称運転圧力は20.82バール、容
積能力は2257kJ/m3、COPは2.76である:
コンプレッサの有効効率(insentropic efficiency):80%
蒸発器温度を80℃にセットし、凝縮器温度を110℃にセットした上記ヒートポンプ
運転条件下での冷媒液の運転性能を以下に示す。
HCFC−114の場合、以下の運転状態下で、公称運転圧力は17.26バール、容
積能力は5475kJ/m3、COPは7.94である:
コンプレッサの有効効率(insentropic efficiency):80%
蒸発器温度を80℃にセットし、凝縮器温度を120℃にセットした上記ヒートポンプ
運転条件下での冷媒液の運転性能を以下に示す。
HCFC−114の場合、以下の運転状態下で、公称運転圧力は20.82バール、容
積能力は4810kJ/m3、COPは5.45である:
コンプレッサの有効効率(insentropic efficiency):80%
蒸発器温度を80℃にセットし、凝縮器温度を130℃にセットした上記ヒートポンプ
運転条件下での冷媒液の運転性能を以下に示す。
HCFC−114の場合、以下の運転状態下で、公称運転圧力は24.96バール、容
積能力は4027kJ/m3、COPは3.79である:
コンプレッサの有効効率(insentropic efficiency):80%
蒸発器温度を80℃にセットし、凝縮器温度を140℃にセットした上記ヒートポンプ
運転条件下での冷媒液の運転性能を以下に示す。
HCFC−114の場合、以下の運転状態下で、公称運転圧力は29.61バール、容
積能力は297kJ/m3、COPは2.46である:
コンプレッサの有効効率(insentropic efficiency):80%
Claims (8)
- 少なくとも一種のヒドロクロロ−フルオロオレフィンの、冷媒液の蒸発段階と、圧縮段階と、70℃以上の高い温度での冷媒液の凝縮段階と、冷媒液の膨張段階とを順次有する少なくとも一つのステージを有する圧縮システムを使用した伝熱方法での冷媒液としての使用。
- 上記温度が70〜140℃の間にある請求項1に記載の使用。
- 上記温度が95〜125℃の間にある請求項2に記載の使用。
- 冷媒液が少なくとも一種のハイドロフルオロカーボンをさらに含む請求項1〜3のいずれか一項に記載の使用。
- 冷媒液が少なくとも一種のヒドロフルオロエーテルをさらに含む請求項1〜4のいずれか一項に記載の使用。
- 冷媒液が少なくとも一種のフルオロアルケンをさらに含む請求項1〜5のいずれか一項に記載の使用。
- ヒドロクロロ−フルオロオレフィンが少なくとも3つのフッ素原子を有する請求項1〜6のいずれか一項に記載の使用。
- ヒドロクロロ−フルオロオレフィンが1−クロル−3,3,3−トリフルオロプロペンおよび2−クロル−3,3,3−トリフルオロプロペンの中から選択をされる請求項1〜7のいずれか一項に記載の使用。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0857032A FR2937328B1 (fr) | 2008-10-16 | 2008-10-16 | Procede de transfert de chaleur |
FR0857032 | 2008-10-16 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2011531537A Division JP6077744B2 (ja) | 2008-10-16 | 2009-10-13 | 伝熱方法 |
Publications (2)
Publication Number | Publication Date |
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JP2015129633A JP2015129633A (ja) | 2015-07-16 |
JP6151731B2 true JP6151731B2 (ja) | 2017-06-21 |
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Application Number | Title | Priority Date | Filing Date |
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JP2011531537A Active JP6077744B2 (ja) | 2008-10-16 | 2009-10-13 | 伝熱方法 |
JP2015026010A Active JP6151731B2 (ja) | 2008-10-16 | 2015-02-13 | 伝熱方法 |
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JP2011531537A Active JP6077744B2 (ja) | 2008-10-16 | 2009-10-13 | 伝熱方法 |
Country Status (10)
Country | Link |
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US (2) | US20110197602A1 (ja) |
EP (1) | EP2334750B1 (ja) |
JP (2) | JP6077744B2 (ja) |
CN (2) | CN106244112B (ja) |
ES (1) | ES2668968T3 (ja) |
FR (1) | FR2937328B1 (ja) |
HU (1) | HUE037538T2 (ja) |
PL (1) | PL2334750T3 (ja) |
PT (1) | PT2334750T (ja) |
WO (1) | WO2010043807A1 (ja) |
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FR3070982B1 (fr) | 2017-09-12 | 2019-08-30 | Arkema France | Composition a base d'hydrochlorofluoroolefine et d'huile minerale |
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- 2009-10-13 CN CN201610607752.3A patent/CN106244112B/zh active Active
- 2009-10-13 US US13/122,890 patent/US20110197602A1/en not_active Abandoned
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- 2009-10-13 PL PL09756010T patent/PL2334750T3/pl unknown
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HUE037538T2 (hu) | 2018-09-28 |
JP2015129633A (ja) | 2015-07-16 |
CN106244112A (zh) | 2016-12-21 |
CN102177215A (zh) | 2011-09-07 |
US20190048241A1 (en) | 2019-02-14 |
EP2334750B1 (fr) | 2018-04-18 |
ES2668968T3 (es) | 2018-05-23 |
CN106244112B (zh) | 2023-04-07 |
FR2937328A1 (fr) | 2010-04-23 |
PT2334750T (pt) | 2018-05-22 |
US20110197602A1 (en) | 2011-08-18 |
FR2937328B1 (fr) | 2010-11-12 |
WO2010043807A1 (fr) | 2010-04-22 |
PL2334750T3 (pl) | 2018-07-31 |
JP6077744B2 (ja) | 2017-02-08 |
US10858561B2 (en) | 2020-12-08 |
EP2334750A1 (fr) | 2011-06-22 |
JP2012505946A (ja) | 2012-03-08 |
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