US20110197602A1 - Heat transfer method - Google Patents

Heat transfer method Download PDF

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Publication number
US20110197602A1
US20110197602A1 US13/122,890 US200913122890A US2011197602A1 US 20110197602 A1 US20110197602 A1 US 20110197602A1 US 200913122890 A US200913122890 A US 200913122890A US 2011197602 A1 US2011197602 A1 US 2011197602A1
Authority
US
United States
Prior art keywords
refrigerant fluid
cop
cap
hcfc
cond
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US13/122,890
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English (en)
Inventor
Laurent Abbas
Wissam Rached
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
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Arkema France SA
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Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=40670978&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=US20110197602(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Arkema France SA filed Critical Arkema France SA
Assigned to ARKEMA FRANCE reassignment ARKEMA FRANCE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ABBAS, LAURENT, RACHED, WISSAM
Publication of US20110197602A1 publication Critical patent/US20110197602A1/en
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
    • C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
    • C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
    • C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10—Components
    • C09K2205/12—Hydrocarbons
    • C09K2205/122—Halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
    • C09K2205/10—Components
    • C09K2205/12—Hydrocarbons
    • C09K2205/126—Unsaturated fluorinated hydrocarbons

Definitions

  • the present invention relates to a heat transfer process using a composition containing hydrochlorofluoroolefins. It relates more particularly to the use of a composition containing hydrochlorofluoroolefins in heat pumps.
  • HFC-134a Hydrofluorocarbon (1,1,1,2-tetrafluoroethane: HFC-134a) refrigerant fluid which is less harmful to the ozone layer.
  • CFC-12 chlorofluorocarbon
  • HFC-134a hydrofluorocarbon (1,1,1,2-tetrafluoroethane: HFC-134a) refrigerant fluid which is less harmful to the ozone layer.
  • the contribution to the greenhouse effect of a fluid is quantified by a criterion, the GWP (Global Warming Potential), which indexes the warming potential by taking a reference value of 1 for carbon dioxide.
  • carbon dioxide is non-toxic and non-flammable and has a very low GWP
  • it has been proposed as a refrigerant fluid for air conditioning systems as a replacement for HFC-134a.
  • carbon dioxide there are several disadvantages to the use of carbon dioxide, related in particular to the very high pressure of the use thereof as a refrigerant fluid in existing devices and technologies.
  • compositions comprising at least one fluoroalkene having three or four carbon atoms, in particular pentafluoropropene and tetrafluoropropene, preferably having a GWP at most of 150, as heat transfer fluids.
  • fluorohaloalkenes having from to 6 carbon atoms in particular tetrafluoropropenes, pentafluoropropenes and chlorotrifluoropropenes, have been described as capable of being used as a heat transfer fluid.
  • compositions containing hydrochlorofluoroolefins are very particularly suitable as heat transfer fluid in heat pumps, in particular heat pumps that operate at a high condensing temperature. Moreover, these compositions have a negligible ODP and a GWP below that of existing heat transfer fluids.
  • hydrofluoroolefins is understood to mean olefins having from 3 to 4 carbon atoms that comprise one chlorine atom and at least one fluorine atom.
  • the chlorine atom is borne by the unsaturated carbon.
  • a heat pump is a thermodynamic device allowing the transfer of heat from the coldest medium to the hottest medium.
  • the heat pumps used for heating are referred to as compression heat pumps and the operation is based on the principle of the compression cycle of fluids, referred to as refrigerant fluids.
  • These heat pumps operate with compression systems comprising a single or several stage(s). At a given stage, when the refrigerant fluid is compressed and passes from the gaseous state to the liquid state, an exothermic reaction (condensation) takes place that produces heat. Conversely, if the fluid is expanded by passing it from the liquid state to the gaseous state, an endothermic reaction (evaporation) takes place, which produces a cold sensation. Everything therefore relies on the change of state of a fluid used in a closed circuit.
  • Each stage of a compression system comprises (i) a step of evaporation during which, in contact with heat drawn from the surroundings, the refrigerant fluid, by virtue of its low boiling point, changes from the liquid state to the gaseous state, (ii) a step of compression during which the gas from the preceding step is brought to high pressure, (iii) a step of condensation during which the gas will transmit its heat to the heating circuit; the refrigerant, still compressed, becomes liquid again and (iv) a step of expansion during which the pressure of the fluid is reduced.
  • the fluid is ready for a new absorption of heat from the cold environment.
  • One subject of the present invention is a heat transfer process using a compression system having at least one stage successively comprising a step of evaporation of a refrigerant fluid, a step of compression, a step of condensation of said fluid at a temperature greater than or equal to 70° C. and a step of expansion of said fluid characterized in that the refrigerant fluid comprises at least one hydrochlorofluoroolefin.
  • the condensing temperature of the refrigerant fluid is between 70 and 140° C., and advantageously between 95 and 125° C.
  • the hydrochlorofluoroolefins comprise at least three fluorine atoms.
  • hydrochlorofluoroolefins are chlorotrifluoropropenes (HCFO-1233), in particular 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) and 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf).
  • HCFO-1233 chlorotrifluoropropenes
  • HCFO-1233zd 1-chloro-3,3,3-trifluoropropene
  • 2-chloro-3,3,3-trifluoropropene HCFO-1233xf
  • the 1-chloro-3,3,3-trifluoropropene may be in either cis form or trans form.
  • the refrigerant fluid may comprise at least one hydrofluorocarbon.
  • hydrofluorocarbons mention may especially be made of 1,1,1,3,3-pentafluorobutane, 1,1,1,2-tetrafluoroethane, pentafluoroethane, 1,1,1,3,3-pentafluoropropane, 1,1,1,2,3-pentafluoropropane, 1,1,1,2,2-penta-fluoropropane and 1,1,1,2,3,3,3-heptafluoropropane.
  • the refrigerant fluid may also comprise at least one fluoroether, preferably at least one hydrofluoroether and advantageously at least one hydrofluoroether having from three to six carbon atoms.
  • hydrofluoroethers mention may especially be made of heptafluoromethoxypropane, nonafluoromethoxybutane and nonafluoroethoxybutane.
  • the hydrofluoroether is available in several isomeric forms such as 1,1,1,2,2,3,3,4,4-nonafluoroethoxybutane, 1,1,1,2,3,3-hexafluoro-2-(trifluoromethyl)-3-ethoxybutane, 1,1,1,2,2,3,3,4,4-nonafluoromethoxybutane and 1,1,1,2,3,3-hexafluoro-2-(trifluoromethyl)-3-methoxybutane.
  • the refrigerant fluid may also comprise at least one fluoroalkene having from 3 to 6 carbon atoms.
  • the fluoroalkene is chosen from fluoropropenes, in particular trifluoropropenes such as 1,1,1-trifluoropropene, tetrafluoropropenes such as 2,3,3,3-tetrafluoropropene (HFO-1234yf), 1,3,3,3-tetrafluoropropene and fluorobutenes. Fluoromethyl-propenes may be suitable.
  • the refrigerant fluid comprises at least 10% by weight of hydrochlorofluoroolefins.
  • the refrigerant fluid used in the present invention may comprise a stabilizer of the hydrochlorofluoroolefin.
  • the stabilizer represents at most 5% by weight relative to the total composition of the fluid.
  • nitromethane ascorbic acid, terephthalic acid, azoles such as tolutriazole or benzotriazole, phenolic compounds such as tocopherol, hydroquinone, t-butylhydroguinone, 2,6-di-cert-butyl-4-methylphenol, epoxides (alkyl, optionally fluorinated or perfluorinated, or alkenyl or aromatic epoxides) such as n-butyl glycidyl ether, hexanediol diglycidyl ether, allyl glycidyl ether or butylphenyl glycidyl ether, phosphites, phosphates, phosphonates, thiols and lactones.
  • epoxides alkyl, optionally fluorinated or perfluorinated, or alkenyl or aromatic epoxides
  • the refrigerant used in the process according to the present invention may comprise lubricants such as mineral oil, alkylbenzene, polyalkylene glycol and polyvinyl ether.
  • Evap P is the pressure at the evaporator
  • Cond P is the pressure at the condenser
  • T cond is the condensing temperature
  • Te comp is the compressor inlet temperature
  • T outlet comp is the compressor outlet temperature
  • COP coefficient of performance and is defined, where a heat pump is concerned, as being the useful heat power provided the system over the power taken in or consumed by the system
  • % CAP or COP is the ratio of the value of the CAP or COP of the fluid relative to that obtained with HCFC-114.
  • the nominal operating pressure is 14.19 bar
  • the volumetric capacity is 785 kJ/m 3
  • the COP is 2.07 under the following operating conditions:
  • the nominal operating pressure is 9.3 bar
  • the volumetric capacity is 3321 kJ/m 3
  • the COP is 8.19 under the following operating conditions:
  • the nominal operating pressure is 12.82 bar
  • the volumetric capacity is 2976 kJ/m 3
  • the COP is 5.19 under the following operating conditions:
  • the nominal operating pressure is 17.26 bar
  • the volumetric capacity is 2573 kJ/m 3
  • the COP is 3.56 under the following operating conditions:
  • the nominal operating pressure is 20.82 bar
  • the volumetric capacity is 2257 kJ/m 3
  • the COP is 2.79 under the following operating conditions:
  • the nominal operating pressure is 17.26 bar
  • the volumetric capacity is 5475 kJ/m 3
  • the COP is 7.94 under the following operating conditions:
  • the nominal operating pressure is 20.82 bar
  • the volumetric capacity is 4810 kJ/m 3
  • the COP is 5.45 under the following operating conditions:
  • the nominal operating pressure is 24.92 bar
  • the volumetric capacity is 4027 kJ/m 3
  • the COP is 3.79 under the following operating conditions:
  • the nominal operating pressure is 29.61 bar
  • the volumetric capacity is 2971 kJ/m 3
  • the COP is 2.46 under the following operating conditions:

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
US13/122,890 2008-10-16 2009-10-13 Heat transfer method Abandoned US20110197602A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0857032 2008-10-16
FR0857032A FR2937328B1 (fr) 2008-10-16 2008-10-16 Procede de transfert de chaleur
PCT/FR2009/051943 WO2010043807A1 (fr) 2008-10-16 2009-10-13 Procede de transfert de chaleur

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2009/051943 A-371-Of-International WO2010043807A1 (fr) 2008-10-16 2009-10-13 Procede de transfert de chaleur

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US16/027,743 Continuation US10858561B2 (en) 2008-10-16 2018-07-05 Heat transfer method

Publications (1)

Publication Number Publication Date
US20110197602A1 true US20110197602A1 (en) 2011-08-18

Family

ID=40670978

Family Applications (2)

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US16/027,743 Active US10858561B2 (en) 2008-10-16 2018-07-05 Heat transfer method

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Application Number Title Priority Date Filing Date
US16/027,743 Active US10858561B2 (en) 2008-10-16 2018-07-05 Heat transfer method

Country Status (10)

Country Link
US (2) US20110197602A1 (ja)
EP (1) EP2334750B1 (ja)
JP (2) JP6077744B2 (ja)
CN (2) CN102177215A (ja)
ES (1) ES2668968T3 (ja)
FR (1) FR2937328B1 (ja)
HU (1) HUE037538T2 (ja)
PL (1) PL2334750T3 (ja)
PT (1) PT2334750T (ja)
WO (1) WO2010043807A1 (ja)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120329893A1 (en) * 2010-03-09 2012-12-27 Arkema France Hydrochlorofluoroolefin blowing agent compositions
US20140144066A1 (en) * 2011-01-25 2014-05-29 Technologies Holdings Corp. Portable heating system and method for pest control
US20160272561A1 (en) * 2015-03-18 2016-09-22 Arkema France Stabilization of 1-chloro-3,3,3-trifluoropropene
US20170101568A1 (en) * 2011-05-19 2017-04-13 Asahi Glass Company, Limited Working medium and heat cycle system
US9834499B2 (en) 2014-01-13 2017-12-05 Arkema France E-1-chloro-3,3,3-trifluoropropene production process from 1,1,3,3-tetrachloropropene
US10077221B2 (en) 2013-03-20 2018-09-18 Arkema France Composition comprising HF and E-3,3,3-trifluoro-1-chloropropene
US10119055B2 (en) 2010-07-09 2018-11-06 Arkema France Stable 2,3,3,3-tetrafluoropropene composition
US10215455B2 (en) 2013-08-14 2019-02-26 Central Glass Company, Limited Heat transmission method and high-temperature heat pump device
US10301236B2 (en) 2015-05-21 2019-05-28 The Chemours Company Fc, Llc Hydrofluorination of a halogenated olefin with SbF5 in the liquid phase
US10427998B2 (en) 2015-05-22 2019-10-01 Arkema France Compositions based on 1,1,3,3-tetrachloropropene
US10669465B2 (en) 2016-09-19 2020-06-02 Arkema France Composition comprising 1-chloro-3,3,3-trifluoropropene
US10858561B2 (en) 2008-10-16 2020-12-08 Arkema France Heat transfer method
US11053420B2 (en) 2017-09-12 2021-07-06 Arkema France Composition on the basis of hydrochlorofluoroolefin and mineral oil
US11242304B2 (en) 2018-05-16 2022-02-08 Arkema France Method for producing 1-chloro-3,3,3- trifluoropropene
US11286221B2 (en) 2018-06-27 2022-03-29 Arkema France Method for producing 1-chloro-3,3,3-trifluoropropene
US11952322B2 (en) 2018-09-26 2024-04-09 Arkema France Stabilization of 1-chloro-3,3,3-trifluoropropene
US12006274B2 (en) 2022-11-03 2024-06-11 The Chemours Company Fc, Llc Compositions including olefin and hydrofluoroalkane

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