JP6054980B2 - エポキシ化触媒を製造する方法、及び該触媒を用いたエポキシ化法 - Google Patents
エポキシ化触媒を製造する方法、及び該触媒を用いたエポキシ化法 Download PDFInfo
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- JP6054980B2 JP6054980B2 JP2014538812A JP2014538812A JP6054980B2 JP 6054980 B2 JP6054980 B2 JP 6054980B2 JP 2014538812 A JP2014538812 A JP 2014538812A JP 2014538812 A JP2014538812 A JP 2014538812A JP 6054980 B2 JP6054980 B2 JP 6054980B2
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
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- B01J35/612—Surface area less than 10 m2/g
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- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
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- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
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- C07C213/04—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reaction of ammonia or amines with olefin oxides or halohydrins
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- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
- C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
- C07C29/103—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
- C07C29/106—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers of oxiranes
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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- C07C41/01—Preparation of ethers
- C07C41/02—Preparation of ethers from oxiranes
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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- C07C41/01—Preparation of ethers
- C07C41/02—Preparation of ethers from oxiranes
- C07C41/03—Preparation of ethers from oxiranes by reaction of oxirane rings with hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C68/00—Preparation of esters of carbonic or haloformic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/02—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 2
- C07D317/04—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 2 not condensed with other rings
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
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- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Nanotechnology (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161553577P | 2011-10-31 | 2011-10-31 | |
| US61/553,577 | 2011-10-31 | ||
| PCT/US2012/058755 WO2013066557A1 (en) | 2011-10-31 | 2012-10-04 | Methods for producing epoxidation catalysts and epoxidation methods utilizing these |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014532552A JP2014532552A (ja) | 2014-12-08 |
| JP6054980B2 true JP6054980B2 (ja) | 2016-12-27 |
Family
ID=47040825
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014538812A Active JP6054980B2 (ja) | 2011-10-31 | 2012-10-04 | エポキシ化触媒を製造する方法、及び該触媒を用いたエポキシ化法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9162215B2 (enExample) |
| EP (1) | EP2773456B1 (enExample) |
| JP (1) | JP6054980B2 (enExample) |
| CN (2) | CN107020094B (enExample) |
| CA (1) | CA2853566C (enExample) |
| IN (1) | IN2014CN03223A (enExample) |
| SG (1) | SG11201401948UA (enExample) |
| TW (1) | TWI587921B (enExample) |
| WO (1) | WO2013066557A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI772322B (zh) * | 2016-09-02 | 2022-08-01 | 美商陶氏科技投資有限公司 | 製備環氧化催化劑之方法 |
| EP3731963A1 (en) | 2017-12-28 | 2020-11-04 | Dow Technology Investments LLC | Process for preparing an epoxidation catalyst |
| US20210039074A1 (en) | 2018-02-07 | 2021-02-11 | Basf Se | Method for preparing a silver impregnation solution |
| EP3639923A1 (en) | 2018-10-15 | 2020-04-22 | Basf Se | Process for producing ethylene oxide by gas-phase oxidation of ethylene |
| EP3639924A1 (en) | 2018-10-15 | 2020-04-22 | Basf Se | Catalyst for producing ethylene oxide by gas-phase oxidation |
| EP3659703A1 (en) | 2018-11-28 | 2020-06-03 | Basf Se | Catalyst for producing ethylene oxide by gas-phase oxidation |
| WO2021038027A1 (en) | 2019-08-28 | 2021-03-04 | Basf Se | Process for preparing an epoxidation catalyst |
Family Cites Families (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3575888A (en) | 1969-04-28 | 1971-04-20 | Shell Oil Co | Silver catalyst |
| US3702259A (en) | 1970-12-02 | 1972-11-07 | Shell Oil Co | Chemical production of metallic silver deposits |
| US4102820A (en) | 1975-12-29 | 1978-07-25 | Texaco Development Corp. | Silver catalyst for ethylene epoxidation |
| FR2412538A1 (fr) | 1977-12-22 | 1979-07-20 | Ugine Kuhlmann | Catalyseurs a base d'argent pour la production d'oxyde d'ethylene |
| US4916243A (en) | 1979-03-20 | 1990-04-10 | Union Carbide Chemicals And Plastics Company Inc. | New catalyst composition and process for oxidation of ethylene to ethylene oxide |
| DE2914640C2 (de) * | 1979-04-11 | 1986-01-30 | Hüls AG, 4370 Marl | Verfahren zur Herstellung von Silberkatalysatoren für die Herstellung von Ethylenoxid |
| US4248741A (en) * | 1979-05-29 | 1981-02-03 | The Dow Chemical Company | Method of making catalysts for the production of ethylene oxide |
| CA1283906C (en) * | 1983-05-09 | 1991-05-07 | Makoto Sunagawa | .beta.-LACTAM COMPOUNDS AND PRODUCTION THEREOF |
| US5059481A (en) | 1985-06-17 | 1991-10-22 | Viskase Corporation | Biaxially stretched, heat shrinkable VLDPE film |
| JPH084745B2 (ja) | 1986-05-09 | 1996-01-24 | 三菱化学株式会社 | エチレンオキシド製造用銀触媒 |
| US4761394A (en) | 1986-10-31 | 1988-08-02 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| IL84232A (en) | 1986-10-31 | 1992-06-21 | Shell Int Research | Catalyst and process for the catalytic production of ethylene oxide |
| US4766105A (en) | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| US4820675A (en) | 1986-10-31 | 1989-04-11 | Shell Oil Company | Ethylene oxide catalyst & process for preparing the catalyst |
| US4833261A (en) | 1986-10-31 | 1989-05-23 | Shell Oil Company | Ethylene oxide process |
| US4808738A (en) | 1986-10-31 | 1989-02-28 | Shell Oil Company | Ethylene oxide process |
| US4908343A (en) | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
| US5057481A (en) | 1987-02-20 | 1991-10-15 | Union Carbide Chemicals And Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
| CN1009437B (zh) | 1988-02-03 | 1990-09-05 | 中国石油化工总公司 | 乙烯氧化制环氧乙烷高效银催化剂 |
| CA1337722C (en) | 1989-04-18 | 1995-12-12 | Madan Mohan Bhasin | Alkylene oxide catalysts having enhanced activity and/or stability |
| US5187140A (en) | 1989-10-18 | 1993-02-16 | Union Carbide Chemicals & Plastics Technology Corporation | Alkylene oxide catalysts containing high silver content |
| US5173469A (en) * | 1989-11-09 | 1992-12-22 | Huels Aktiengesellschaft | Silver catalyst suitable for oxidation of ethylene and process for the production of the catalyst |
| US5102848A (en) | 1990-09-28 | 1992-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
| CA2053411C (en) | 1990-10-12 | 1997-06-03 | Albert Cheng-Yu Liu | Alkylene oxide catalysts having enhanced activity and/or stability |
| US5939354A (en) | 1996-04-10 | 1999-08-17 | Catalytic Solutions, Inc. | Perovskite-type metal oxide compounds and method for preparing the compounds |
| US6080897A (en) | 1998-03-19 | 2000-06-27 | Mitsubishi Chemical Corporation | Method for producing monoethylene glycol |
| CN100553763C (zh) | 2002-02-25 | 2009-10-28 | 国际壳牌研究有限公司 | 负载的银催化剂和使用该催化剂的环氧化方法 |
| US6831037B2 (en) | 2002-02-25 | 2004-12-14 | Saint-Gobain Norpro Corporation | Catalyst carriers |
| RU2314156C2 (ru) * | 2002-06-28 | 2008-01-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ улучшения селективности катализатора и способ эпоксидирования олефина |
| CN1301791C (zh) | 2003-12-31 | 2007-02-28 | 中国石油化工股份有限公司北京燕山分公司研究院 | 用于环氧乙烷生产用银催化剂的载体、其制备方法及其应用 |
| KR101369619B1 (ko) | 2005-06-07 | 2014-03-05 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 산화올레핀, 1,2-디올, 1,2-디올 에테르 또는 알칸올아민의제조방법, 이를 위한 촉매, 이 촉매의 제조방법 |
| CN100577289C (zh) | 2006-01-28 | 2010-01-06 | 中国石油化工股份有限公司 | 环氧乙烷生产用银催化剂的载体、其制备方法及其应用 |
| CN103252235B (zh) * | 2006-04-18 | 2015-09-16 | 陶氏环球技术公司 | 环氧烷催化剂及其应用 |
| JP4267015B2 (ja) | 2006-09-29 | 2009-05-27 | 株式会社日本触媒 | エチレンオキシド製造用触媒およびエチレンオキシドの製造方法 |
| US7932408B2 (en) | 2006-09-29 | 2011-04-26 | Scientific Design Company, Inc. | Catalyst with bimodal pore size distribution and the use thereof |
| US7977274B2 (en) * | 2006-09-29 | 2011-07-12 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Catalyst with bimodal pore size distribution and the use thereof |
| EP2152411B1 (en) * | 2007-05-09 | 2019-12-04 | Shell International Research Maatschappij B.V. | An epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| US7714152B2 (en) | 2007-08-30 | 2010-05-11 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Carrier for olefin oxide catalyst |
| US8349765B2 (en) * | 2008-07-18 | 2013-01-08 | Scientific Design Company, Inc. | Mullite-containing carrier for ethylene oxide catalysts |
| EP2421643A2 (en) * | 2009-04-21 | 2012-02-29 | Dow Technology Investments LLC | Rhenium-promoted epoxidation catalysts and methods of making and using them |
| JP6062417B2 (ja) | 2011-04-14 | 2017-01-18 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | エチレンをエチレンオキシドに酸化するための触媒の製造方法 |
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2012
- 2012-10-04 SG SG11201401948UA patent/SG11201401948UA/en unknown
- 2012-10-04 CN CN201710217065.5A patent/CN107020094B/zh active Active
- 2012-10-04 WO PCT/US2012/058755 patent/WO2013066557A1/en not_active Ceased
- 2012-10-04 US US14/354,126 patent/US9162215B2/en active Active
- 2012-10-04 CN CN201280053365.XA patent/CN103906570B/zh active Active
- 2012-10-04 CA CA2853566A patent/CA2853566C/en active Active
- 2012-10-04 JP JP2014538812A patent/JP6054980B2/ja active Active
- 2012-10-04 EP EP12773472.1A patent/EP2773456B1/en active Active
- 2012-10-04 IN IN3223CHN2014 patent/IN2014CN03223A/en unknown
- 2012-10-22 TW TW101138873A patent/TWI587921B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| CN103906570A (zh) | 2014-07-02 |
| CA2853566A1 (en) | 2013-05-10 |
| TW201325722A (zh) | 2013-07-01 |
| WO2013066557A1 (en) | 2013-05-10 |
| EP2773456A1 (en) | 2014-09-10 |
| JP2014532552A (ja) | 2014-12-08 |
| CN103906570B (zh) | 2017-05-03 |
| EP2773456B1 (en) | 2019-04-17 |
| IN2014CN03223A (enExample) | 2015-07-03 |
| CN107020094A (zh) | 2017-08-08 |
| US9162215B2 (en) | 2015-10-20 |
| US20140371470A1 (en) | 2014-12-18 |
| CN107020094B (zh) | 2019-10-11 |
| CA2853566C (en) | 2021-01-05 |
| SG11201401948UA (en) | 2014-09-26 |
| TWI587921B (zh) | 2017-06-21 |
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