JP6053236B2 - 難燃性樹脂組成物を用いたケーブル - Google Patents
難燃性樹脂組成物を用いたケーブル Download PDFInfo
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- JP6053236B2 JP6053236B2 JP2015551539A JP2015551539A JP6053236B2 JP 6053236 B2 JP6053236 B2 JP 6053236B2 JP 2015551539 A JP2015551539 A JP 2015551539A JP 2015551539 A JP2015551539 A JP 2015551539A JP 6053236 B2 JP6053236 B2 JP 6053236B2
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 66
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/098—Metal salts of carboxylic acids
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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Description
<条件>
熱分解装置における昇温速度:50℃/min
温度範囲:70〜700℃
カラムオーブン温度:320℃
キャリアーガス:ヘリウム
圧力:90.0kPa
カラム流量:0.92mL/min
図1は、本発明に係るケーブルの第1実施形態を示す部分側面図である。図2は、図1のII−II線に沿った断面図である。図1及び図2に示すように、ケーブル10は、1本の絶縁電線4と、1本の絶縁電線4を被覆するシース3とを備えている。そして、絶縁電線4は、内部導体1と、内部導体1を被覆する絶縁層2とを有している。
次に、上述したケーブル10の製造方法について説明する。
まず内部導体1を準備する。内部導体1は、1本の素線のみで構成されてもよく、複数本の素線を束ねて構成されたものであってもよい。また、内部導体1は、導体径や導体の材質などについて特に限定されるものではなく、用途に応じて適宜定めることができる。
一方、上記難燃性樹脂組成物を準備する。難燃性樹脂組成物は、上述したように、ポリオレフィン樹脂と、ポリオレフィン樹脂100質量部に対して1.5質量部以上20質量部以下の割合で配合されるシリコーン系化合物と、ポリオレフィン樹脂100質量部に対して5質量部以上20質量部以下の割合で配合される脂肪酸含有化合物と、ポリオレフィン樹脂100質量部に対して5質量部以上40質量部以下の割合で配合される無機系難燃剤とを含んでいる。
上述したように、ポリオレフィン樹脂としては、例えばエチレン系樹脂、及び、プロピレン系樹脂などが挙げられる。これらは1種類単独で又は2種以上を混合して用いてもよい。ここで、エチレン系樹脂とは、エチレンを構成単位として含む樹脂を言い、エチレン系樹脂としては、例えばポリエチレン樹脂(PE)、エチレンアクリル酸エチル共重合体(EEA)及びエチレン酢酸ビニル共重合体(EVA)が挙げられる。またプロピレン系樹脂としては、プロピレンを構成単位として含む樹脂を言い、プロピレン系樹脂としては、例えばポリプロピレン樹脂(PP)などが挙げられる。
シリコーン系化合物は、難燃助剤として機能するものであり、ポリオルガノシロキサンなどが挙げられる。ここで、ポリオルガノシロキサンは、シロキサン結合を主鎖とし側鎖に有機基を有するものであり、有機基としては、例えばメチル基、ビニル基、エチル基、プロピル基、フェニル基などが挙げられる。具体的にはポリオルガノシロキサンとしては、例えばジメチルポリシロキサン、メチルエチルポリシロキサン、メチルオクチルポリシロキサン、メチルビニルポリシロキサン、メチルフェニルポリシロキサン、メチル(3,3,3−トリフルオロプロピル)ポリシロキサンなどが挙げられる。ポリオルガノシロキサンとして、シリコーンパウダー、シリコーンガム及びシリコーンレジンが挙げられる。中でも、シリコーンガムが好ましい。この場合、ブルームが起こりにくくなる。
脂肪酸含有化合物は、難燃助剤として機能するものである。脂肪酸含有化合物とは、脂肪酸又はその金属塩を含有するものを言う。ここで、脂肪酸としては、例えば炭素原子数が12〜28である脂肪酸が用いられる。このような脂肪酸としては、例えばラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ツベルクロステアリン酸、オレイン酸、リノール酸、アラキドン酸、ベヘン酸及びモンタン酸が挙げられる。中でも、脂肪酸としては、ステアリン酸又はツベルクロステアリン酸が好ましく、ステアリン酸が特に好ましい。この場合、ステアリン酸又はツベルクロステアリン酸以外の脂肪酸を用いる場合に比べて、より優れた難燃性が得られる。
無機系難燃剤は、シリコーン系化合物の分解開始温度(T1)よりも低い分解開始温度(T3)を有する無機系の難燃剤であれば特に限定されるものではない。
上記難燃性樹脂組成物は、添加剤を必要に応じてさらに含んでもよい。添加剤は、上述したポリオレフィン樹脂、シリコーン系化合物、脂肪酸含有化合物及び無機系難燃剤とは異なる材料で構成される。このような添加剤としては、例えば酸化防止剤、紫外線劣化防止剤、加工助剤、着色剤及び帯電防止剤が挙げられる。これらは単独で又は2種以上を組み合せて用いることができる。ここで、酸化防止剤、紫外線劣化防止剤、加工助剤、着色剤及び帯電防止剤はいずれも、上述した難燃性樹脂組成物に含まれることで、難燃性樹脂組成物の難燃性を向上させない添加剤を言う。ここで、「難燃性樹脂組成物の難燃性を向上させない」とは、酸化防止剤、紫外線劣化防止剤、加工助剤、着色剤又は帯電防止剤を含む難燃性樹脂組成物について、後述する実施例及び比較例で難燃性樹脂組成物の難燃性の評価に使用される垂直一条燃焼試験による評価結果が、酸化防止剤、紫外線劣化防止剤、加工助剤、着色剤及び帯電防止剤のいずれも含まない点でのみ異なる難燃性樹脂組成物についての難燃性の評価結果に対して同じか、又は劣ることを言う。
最後に、上記のようにして得られた絶縁電線4を1本用意し、これら絶縁電線4を、上述した難燃性樹脂組成物を用いて作製したシース3で被覆する。シース3は、絶縁層2を物理的又は化学的な損傷から保護するものである。
ベース樹脂、シリコーンマスターバッチ(シリコーンMB)、脂肪酸含有化合物及び無機系難燃剤を、表1〜5に示す配合量で配合し、バンバリーミキサによって160℃にて15分間混練し、難燃性樹脂組成物を得た。なお、表1〜5において、各配合成分の配合量の単位は質量部である。また表1〜5において、ポリエチレン樹脂(PE)、エチレンアクリル酸エチル共重合体(EEA)、エチレン酢酸ビニル共重合体(EVA)又はポリプロピレン樹脂(PP)の配合量が100質量部となっていないが、シリコーンMB中にも樹脂が含まれており、PE、EEA、EVA又はPPとシリコーンMB中の樹脂とを合計すればベース樹脂の合計量は100質量部となる。さらに表1〜5には、無機系難燃剤の分解開始温度(T3)、シリコーン系化合物の分解開始温度(T1)及びベース樹脂の分解開始温度(T2)も示した。
(1)ベース樹脂
(A)ポリエチレン樹脂(PE)(商品名「エクセレンGMH GH030」、住友化学社製)
(B)エチレンアクリル酸エチル共重合体(EEA、商品名「DPDJ−6503」、日本ユニカー社製)
(C)エチレン酢酸ビニル共重合体(EVA、商品名「エバフレックス V5274」、三井デュポンポリケミカル社製)
(D)ポリプロピレン樹脂(PP、商品名「E111G」、プライムポリマー社製)
(2)シリコーンMB(商品名「X−22−2125H」、信越化学社製)
50質量%シリコーンガムと50質量%PEとを含有
(3)脂肪酸含有化合物
ステアリン酸Mg(商品名「エフコケムMGS」、ADEKA社製)
ステアリン酸Ca(商品名「SC−P」、堺化学工業社製)
(4)無機系難燃剤
A)水酸化アルミニウム(商品名「BF013」、日本軽金属社製、平均粒径:1.2μm)
B)水酸化マグネシウム(商品名「マグシーズN6」、神島化学工業社製)
C)水酸化カルシウム(吉澤石灰工業社製)
実施例1〜14及び比較例1〜7の絶縁電線をそれぞれ10本用意し、これらについて、JIS C3665−1に基づいて垂直一条燃焼試験を行い、難燃性を評価した。このとき、具体的には、絶縁電線を上部で支持する上部支持材の下端から炭化の終了点までの長さが50mm以上540mm以下であれば「合格」とし、50mm未満又は540mm超の場合には「不合格」とした。そして、合格率(%)を求めた。結果を表1〜5に示す。なお、燃焼試験においては、絶縁電線に対してバーナーの炎を60秒間接触させた。また表1〜5において、難燃性の合否基準は下記の通りとした。
合格率が70%以上:合格
合格率が70%未満:不合格
機械的特性の評価は、実施例1〜14及び比較例1〜7の絶縁電線について、JIS C3005により引張試験を行い、測定された引張強度に基づいて行った。結果を表1〜5に示す。表1〜5において、引張強度の単位はMPaであり、引張強度の合否基準は下記の通りとした。引張試験において、引張速度は200mm/min、標線間距離は20mmとした。
10MPa以上:合格
10MPa未満:不合格
2…絶縁層
3,25,35…シース
4…絶縁電線
10,20,30…ケーブル
Claims (5)
- シースと、
前記シースの内側に設けられ又は前記シースを貫通するように設けられる光ファイバとを有し、
前記シースが難燃性樹脂組成物で構成され、
前記難燃性樹脂組成物が、
ポリオレフィン樹脂と、
前記ポリオレフィン樹脂100質量部に対して1.5質量部以上20質量部以下の割合で配合されるシリコーン系化合物と、
前記ポリオレフィン樹脂100質量部に対して5質量部以上20質量部以下の割合で配合される脂肪酸含有化合物と、
前記ポリオレフィン樹脂100質量部に対して5質量部以上40質量部以下の割合で配合される無機系難燃剤とを含み、
前記無機系難燃剤の分解開始温度が前記シリコーン系化合物の分解開始温度よりも低い難燃性樹脂組成物である、ケーブルであって、
前記無機系難燃剤が水酸化アルミニウムである、ケーブル。 - 前記難燃性樹脂組成物において、前記無機系難燃剤が前記ポリオレフィン樹脂100質量部に対して10質量部以上25質量部以下の割合で配合されている、請求項1に記載のケーブル。
- 前記脂肪酸含有化合物がステアリン酸マグネシウム又はステアリン酸カルシウムである請求項1又は2に記載のケーブル。
- 前記難燃性樹脂組成物が、前記ポリオレフィン樹脂と、前記シリコーン系化合物と、前記脂肪酸含有化合物と、前記無機系難燃剤と、酸化防止剤、紫外線劣化防止剤、加工助剤、着色剤及び帯電防止剤からなる群より選択される少なくとも1種の添加剤とで構成される、請求項1〜3のいずれか一項に記載のケーブル。
- 前記酸化防止剤が、フェノール系酸化防止剤、アミン系酸化防止剤、硫黄系酸化防止剤、リン系酸化防止剤、ヒドラジン系酸化防止剤、アミド系酸化防止剤、リン酸及びクエン酸からなる群より選ばれる少なくとも1種で構成され、
前記紫外線劣化防止剤が、ベンゾフェノン系紫外線劣化防止剤、サルチレート系紫外線劣化防止剤、ベンゾトリアゾール系紫外線劣化防止剤、アクリロニトリル系紫外線劣化防止剤、金属錯塩系紫外線劣化防止剤及びヒンダートアミン系紫外線劣化防止剤からなる群より選ばれる少なくとも1種で構成され、
前記加工助剤が、炭化水素系加工助剤、脂肪酸系加工助剤、脂肪酸アミド系加工助剤、エステル系加工助剤、アルコール系加工助剤、金属石鹸及びワックスからなる群より選ばれる少なくとも1種で構成され、
前記着色剤が、無機顔料、有機顔料、染料及びカーボンブラックからなる群より選ばれる少なくとも1種で構成され、
前記帯電防止剤が、陽イオン活性剤、アニオン活性剤、非イオン活性剤及び両性活性剤からなる群より選ばれる少なくとも1種で構成される、請求項4に記載のケーブル。
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WO2023056207A1 (en) | 2021-09-30 | 2023-04-06 | Exxonmobil Chemical Patents Inc. | Fluorine-free polymer processing aids |
WO2023056250A1 (en) | 2021-09-30 | 2023-04-06 | Exxonmobil Chemical Patents Inc. | Fluoropolymer-free processing aids for ethylene-based polymers |
CN114213743A (zh) * | 2022-01-05 | 2022-03-22 | 四川安费尔高分子材料科技有限公司 | 一种低烟无卤阻燃电缆料的生产工艺 |
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WO2023154744A1 (en) | 2022-02-14 | 2023-08-17 | Exxonmobil Chemical Patents Inc. | Polyethylene glycol-based polymer processing aids |
CN115933081B (zh) * | 2022-11-18 | 2023-07-25 | 宏安集团有限公司 | 一种半干式光纤带光缆 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03231947A (ja) * | 1989-12-05 | 1991-10-15 | Sakai Chem Ind Co Ltd | ポリオレフィン系樹脂組成物およびその製造方法 |
JPH07296649A (ja) * | 1994-04-22 | 1995-11-10 | Hitachi Cable Ltd | ノンハロゲン難燃絶縁電線 |
JP2001152035A (ja) * | 1999-11-30 | 2001-06-05 | Shin Etsu Chem Co Ltd | 流動性及び機械的特性に優れた熱可塑性樹脂組成物 |
JP2001348466A (ja) * | 2000-06-06 | 2001-12-18 | Fujikura Ltd | 難燃性樹脂組成物 |
WO2005013291A1 (ja) * | 2003-07-30 | 2005-02-10 | Sumitomo Electric Industries, Limited | 非ハロゲン系難燃ケーブル |
JP2013108053A (ja) * | 2011-10-28 | 2013-06-06 | Fujikura Ltd | 難燃性樹脂組成物、及び、これを用いたケーブル |
JP2013133411A (ja) * | 2011-12-27 | 2013-07-08 | Fujikura Ltd | 難燃性樹脂組成物、及び、これを用いたケーブル |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4273691A (en) * | 1979-10-18 | 1981-06-16 | General Electric Company | Flame retardant compositions and coated article |
IE920241A1 (en) * | 1991-08-23 | 1993-02-24 | Hitachi Cable | Non-halogenated fire retardant resin composition and wires¹and cables coated therewith |
CN1102615C (zh) | 1995-12-27 | 2003-03-05 | 住友电木株式会社 | 制造阻燃型硅烷交联的聚烯烃的方法 |
DE19610513B4 (de) | 1996-03-19 | 2006-10-19 | Alcatel Kabel Ag & Co. | Flammwidrige, halogenfreie Mischung |
DE60140524D1 (de) * | 2001-06-12 | 2009-12-31 | Borealis Tech Oy | Optisches Kabel mit verbesserter Kriechstromfestigkeit |
US8331747B1 (en) * | 2008-11-07 | 2012-12-11 | Southwire Company | Non-conductive fiber optic member |
US9231335B2 (en) | 2011-02-14 | 2016-01-05 | Asahi Kasei Chemicals Corporation | Connection structure for solar power generation module |
KR101202473B1 (ko) * | 2011-04-08 | 2012-11-16 | 주식회사 경신전선 | 엘리베이터 케이블 절연용 할로겐 프리 난연 피복조성물 |
JP5167428B1 (ja) | 2011-10-28 | 2013-03-21 | 株式会社フジクラ | 難燃性樹脂組成物、及び、これを用いたケーブル |
JP5877209B2 (ja) | 2012-01-20 | 2016-03-02 | 三井化学株式会社 | 難燃性樹脂組成物及びその製造方法、並びにその成形体及び電線 |
-
2013
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Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03231947A (ja) * | 1989-12-05 | 1991-10-15 | Sakai Chem Ind Co Ltd | ポリオレフィン系樹脂組成物およびその製造方法 |
JPH07296649A (ja) * | 1994-04-22 | 1995-11-10 | Hitachi Cable Ltd | ノンハロゲン難燃絶縁電線 |
JP2001152035A (ja) * | 1999-11-30 | 2001-06-05 | Shin Etsu Chem Co Ltd | 流動性及び機械的特性に優れた熱可塑性樹脂組成物 |
JP2001348466A (ja) * | 2000-06-06 | 2001-12-18 | Fujikura Ltd | 難燃性樹脂組成物 |
WO2005013291A1 (ja) * | 2003-07-30 | 2005-02-10 | Sumitomo Electric Industries, Limited | 非ハロゲン系難燃ケーブル |
JP2013108053A (ja) * | 2011-10-28 | 2013-06-06 | Fujikura Ltd | 難燃性樹脂組成物、及び、これを用いたケーブル |
JP2013133411A (ja) * | 2011-12-27 | 2013-07-08 | Fujikura Ltd | 難燃性樹脂組成物、及び、これを用いたケーブル |
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WO2015083737A1 (ja) | 2015-06-11 |
TWI598390B (zh) | 2017-09-11 |
US20180244903A1 (en) | 2018-08-30 |
JP5669924B1 (ja) | 2015-02-18 |
US10544293B2 (en) | 2020-01-28 |
TW201540766A (zh) | 2015-11-01 |
EP3078709A1 (en) | 2016-10-12 |
JPWO2015083737A1 (ja) | 2017-03-16 |
CN105492525B (zh) | 2017-03-22 |
CN105492525A (zh) | 2016-04-13 |
US9982119B2 (en) | 2018-05-29 |
US20170051136A1 (en) | 2017-02-23 |
EP3078709A4 (en) | 2017-07-12 |
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