JP6026518B2 - 硬質ポリウレタン発泡体 - Google Patents
硬質ポリウレタン発泡体 Download PDFInfo
- Publication number
- JP6026518B2 JP6026518B2 JP2014513042A JP2014513042A JP6026518B2 JP 6026518 B2 JP6026518 B2 JP 6026518B2 JP 2014513042 A JP2014513042 A JP 2014513042A JP 2014513042 A JP2014513042 A JP 2014513042A JP 6026518 B2 JP6026518 B2 JP 6026518B2
- Authority
- JP
- Japan
- Prior art keywords
- rigid polyurethane
- polyurethane foam
- mol
- producing
- polyol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
- C08G18/4247—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids
- C08G18/425—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups derived from polyols containing at least one ether group and polycarboxylic acids the polyols containing one or two ether groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0038—Use of organic additives containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011074988 | 2011-05-31 | ||
| CNPCT/CN2011/074988 | 2011-05-31 | ||
| PCT/CN2012/076322 WO2012163279A1 (en) | 2011-05-31 | 2012-05-31 | Polyurethane rigid foams |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014517114A JP2014517114A (ja) | 2014-07-17 |
| JP2014517114A5 JP2014517114A5 (enExample) | 2015-07-16 |
| JP6026518B2 true JP6026518B2 (ja) | 2016-11-16 |
Family
ID=47258378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014513042A Active JP6026518B2 (ja) | 2011-05-31 | 2012-05-31 | 硬質ポリウレタン発泡体 |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JP6026518B2 (enExample) |
| KR (1) | KR101970842B1 (enExample) |
| CN (1) | CN103619898A (enExample) |
| AU (1) | AU2012265397A1 (enExample) |
| BR (1) | BR112013030712A2 (enExample) |
| RU (1) | RU2013158466A (enExample) |
| WO (1) | WO2012163279A1 (enExample) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016136998A (ja) * | 2015-01-26 | 2016-08-04 | ホーチキ株式会社 | 消火法及び消火器 |
| CN104558483B (zh) * | 2015-02-04 | 2017-07-04 | 哈尔滨工业大学(威海) | 一种喷涂型聚氨酯硬质泡沫及其制备方法 |
| JP6529072B2 (ja) | 2015-03-20 | 2019-06-12 | 株式会社イノアックコーポレーション | 軟質ポリウレタンフォーム |
| JP6480775B2 (ja) * | 2015-03-26 | 2019-03-13 | 積水化学工業株式会社 | ウレタン樹脂組成物、建材の耐火補強方法、および建材の耐火補強構造 |
| CN106147205A (zh) * | 2015-04-27 | 2016-11-23 | 天津奇才科技发展有限公司 | 扦插复合型高阻燃聚异氰脲酸酯硬质泡沫材料 |
| CN104877102A (zh) * | 2015-06-03 | 2015-09-02 | 威海云山科技有限公司 | 一种阻燃聚氨酯硬质泡沫保温板材 |
| CN105237704A (zh) * | 2015-09-18 | 2016-01-13 | 扬中市天正合成材料研究中心 | 一种环保高阻燃高速列车吧台用pu发泡材料及其制备方法 |
| CN106084167A (zh) * | 2016-07-07 | 2016-11-09 | 扬中市天正合成材料研究中心 | 一种半硬质弹性体环保高阻燃发泡材料及其制备方法 |
| CN106432669A (zh) * | 2016-07-07 | 2017-02-22 | 扬中市天正合成材料研究中心 | 一种拖拉机水箱用环保高阻燃高密度发泡材料及其制备方法 |
| CN106188460A (zh) * | 2016-07-07 | 2016-12-07 | 扬中市天正合成材料研究中心 | 一种卫生洁具环保高阻燃发泡材料及其制备方法 |
| CN106008874A (zh) * | 2016-07-07 | 2016-10-12 | 扬中市天正合成材料研究中心 | 一种货架环保高阻燃发泡材料及其制备方法 |
| CN106046297A (zh) * | 2016-07-07 | 2016-10-26 | 扬中市天正合成材料研究中心 | 一种汽车油箱用环保高阻燃聚氨酯发泡材料及其制备方法 |
| CN106046306A (zh) * | 2016-07-07 | 2016-10-26 | 扬中市天正合成材料研究中心 | 一种油罐车罐体用环保高阻燃聚氨酯发泡材料及其制备方法 |
| CN106046296A (zh) * | 2016-07-07 | 2016-10-26 | 扬中市天正合成材料研究中心 | 一种垃圾箱环保高阻燃发泡材料及其制备方法 |
| CN106146793A (zh) * | 2016-07-07 | 2016-11-23 | 扬中市天正合成材料研究中心 | 一种硬质旅行箱环保高阻燃发泡材料及其制备方法 |
| CN106084165A (zh) * | 2016-07-07 | 2016-11-09 | 扬中市天正合成材料研究中心 | 一种包装用环保高阻燃发泡材料及其制备方法 |
| CN106117484A (zh) * | 2016-07-07 | 2016-11-16 | 扬中市天正合成材料研究中心 | 一种农用水勺环保高阻燃发泡材料及其制备方法 |
| CN106146795A (zh) * | 2016-07-07 | 2016-11-23 | 扬中市天正合成材料研究中心 | 一种车用面罩用环保高阻燃发泡材料及其制备方法 |
| CN106008886A (zh) * | 2016-07-07 | 2016-10-12 | 扬中市天正合成材料研究中心 | 一种环保高阻燃硬泡聚氨酯门窗内胆填充发泡材料及制备方法 |
| CN106084169A (zh) * | 2016-07-07 | 2016-11-09 | 扬中市天正合成材料研究中心 | 一种绿化树皮造型环保高阻燃发泡材料及其制备方法 |
| CN106084168A (zh) * | 2016-07-07 | 2016-11-09 | 扬中市天正合成材料研究中心 | 一种输油管环保高阻燃发泡材料及其制备方法 |
| CN106220809A (zh) * | 2016-08-05 | 2016-12-14 | 潍坊远航聚氨酯保温材料有限公司 | 一种高阻燃石墨喷涂聚氨酯及其制备方法和施工方法 |
| EP3532522B1 (en) | 2016-10-25 | 2025-12-03 | Elé Corporation | Low-viscosity phosphate polyols |
| WO2018165844A1 (en) * | 2017-03-14 | 2018-09-20 | Dow Global Technologies Llc | Intumescent coating system |
| CN108484863A (zh) * | 2018-04-13 | 2018-09-04 | 西安增材制造国家研究院有限公司 | 一种用于3d打印的聚合物建筑材料 |
| CN110857328A (zh) | 2018-08-23 | 2020-03-03 | 美国圣戈班性能塑料公司 | 聚氨酯泡沫和其形成方法 |
| WO2021013478A1 (en) * | 2019-07-22 | 2021-01-28 | Basf Se | Low tvoc flame-retardant polyurethane spray foam system |
| CN111378197A (zh) * | 2020-03-27 | 2020-07-07 | 山东省云山鼎节能工程有限公司 | 一种喷涂型聚氨酯硬质泡沫及其制备方法 |
| CN111393833B (zh) * | 2020-04-02 | 2021-12-07 | 张家港长泰汽车饰件材料有限公司 | 高开孔率耐水解聚氨酯泡沫及其制备方法和用途 |
| JP2022048708A (ja) * | 2020-09-15 | 2022-03-28 | 積水化学工業株式会社 | 難燃性ウレタン樹脂組成物 |
| CN112250814A (zh) * | 2020-10-10 | 2021-01-22 | 上海东大聚氨酯有限公司 | 一种经济环保型聚氨酯保温泡沫及其制备方法 |
| JP7545867B2 (ja) * | 2020-10-30 | 2024-09-05 | 株式会社イノアックコーポレーション | ポリウレタンフォームとその製造方法 |
| CN113637142B (zh) * | 2021-07-13 | 2022-05-10 | 广东图恩新材料有限公司 | 一种喷涂型阻燃聚氨酯组合料及其制备方法与使用方法 |
| WO2023249800A1 (en) | 2022-06-21 | 2023-12-28 | Basf Se | Polyurethane products with digital functionality through use of embedded sensor devices |
| CN116217861B (zh) * | 2023-02-23 | 2024-03-12 | 山东奥卓新材料有限公司 | 一种高阻燃无燃烧滴落物/微粒的聚氨酯减振隔声垫及其制备方法 |
| EP4497769A1 (en) * | 2023-07-24 | 2025-01-29 | RAMPF Advanced Polymers GmbH & Co. KG | Flame-retardant polyurethane composition |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0570540A (ja) * | 1991-09-17 | 1993-03-23 | Mitsui Kinzoku Toryo Kagaku Kk | 厚塗り発泡性耐火組成物 |
| DE10007980B4 (de) * | 2000-02-22 | 2007-07-12 | Hilti Ag | Zweikomponenten-Ortschaumsystem und dessen Verwendung zum Ausschäumen von Öffnungen zum Zwecke des Brandschutzes |
| CA2441246A1 (en) * | 2002-09-23 | 2004-03-23 | Hilti Aktiengesellschaft | Two-component foam system for producing constructional foams and their use |
| KR20050077551A (ko) * | 2004-01-28 | 2005-08-03 | 한혜순 | 팽창성 흑연을 사용한 건축단열용 폴리이소시아누레이트 발포체 및 이를 제조하기위한 폴리올 조성물 |
| CN101003611A (zh) * | 2007-01-16 | 2007-07-25 | 北京理工大学 | 一种用于防火封堵的双组分发泡体系及其制品 |
| SI2340269T1 (sl) * | 2008-10-15 | 2013-01-31 | Basf Se | Poliesterski polioli na bazi terefthalične kisline |
| JP2010184974A (ja) * | 2009-02-10 | 2010-08-26 | Alpha Kaken Kk | 耐火断熱被覆材 |
| CN101735425B (zh) * | 2009-12-07 | 2012-01-11 | 无锡双象化学工业有限公司 | 冷库用硬泡喷涂聚氨酯组合料的制备方法 |
-
2012
- 2012-05-31 JP JP2014513042A patent/JP6026518B2/ja active Active
- 2012-05-31 CN CN201280026932.2A patent/CN103619898A/zh active Pending
- 2012-05-31 RU RU2013158466/04A patent/RU2013158466A/ru not_active Application Discontinuation
- 2012-05-31 WO PCT/CN2012/076322 patent/WO2012163279A1/en not_active Ceased
- 2012-05-31 AU AU2012265397A patent/AU2012265397A1/en not_active Abandoned
- 2012-05-31 KR KR1020137034716A patent/KR101970842B1/ko active Active
- 2012-05-31 BR BR112013030712A patent/BR112013030712A2/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR101970842B1 (ko) | 2019-04-19 |
| JP2014517114A (ja) | 2014-07-17 |
| BR112013030712A2 (pt) | 2017-07-04 |
| WO2012163279A1 (en) | 2012-12-06 |
| RU2013158466A (ru) | 2015-07-10 |
| KR20140039239A (ko) | 2014-04-01 |
| AU2012265397A1 (en) | 2013-12-19 |
| CN103619898A (zh) | 2014-03-05 |
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