JP5996162B2 - 制御されたブロック配列分布及び少なくとも一つの低結晶性ハードブロックを有する触媒オレフィンブロックコポリマー - Google Patents

制御されたブロック配列分布及び少なくとも一つの低結晶性ハードブロックを有する触媒オレフィンブロックコポリマー Download PDF

Info

Publication number
JP5996162B2
JP5996162B2 JP2010517083A JP2010517083A JP5996162B2 JP 5996162 B2 JP5996162 B2 JP 5996162B2 JP 2010517083 A JP2010517083 A JP 2010517083A JP 2010517083 A JP2010517083 A JP 2010517083A JP 5996162 B2 JP5996162 B2 JP 5996162B2
Authority
JP
Japan
Prior art keywords
ethylene
weight percent
weight
olefin interpolymer
content
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2010517083A
Other languages
English (en)
Japanese (ja)
Other versions
JP2010533774A (ja
JP2010533774A5 (OSRAM
Inventor
ピ シャン，コリン リ
ピ シャン，コリン リ
クールマン，ロジャー
ラス，ガリー
ケニー，マメラ
ヒューズ，モーガン
コング，ロンジャン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Publication of JP2010533774A publication Critical patent/JP2010533774A/ja
Publication of JP2010533774A5 publication Critical patent/JP2010533774A5/ja
Application granted granted Critical
Publication of JP5996162B2 publication Critical patent/JP5996162B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
JP2010517083A 2007-07-13 2008-07-11 制御されたブロック配列分布及び少なくとも一つの低結晶性ハードブロックを有する触媒オレフィンブロックコポリマー Active JP5996162B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US94969007P 2007-07-13 2007-07-13
US60/949,690 2007-07-13
PCT/US2008/069801 WO2009012152A1 (en) 2007-07-13 2008-07-11 Catalytic olefin block copolymers with controlled block sequence distribution and at least one low crystallinity hard block

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2014165314A Division JP5970035B2 (ja) 2007-07-13 2014-08-14 制御されたブロック配列分布及び少なくとも一つの低結晶性ハードブロックを有する触媒オレフィンブロックコポリマー

Publications (3)

Publication Number Publication Date
JP2010533774A JP2010533774A (ja) 2010-10-28
JP2010533774A5 JP2010533774A5 (OSRAM) 2013-08-29
JP5996162B2 true JP5996162B2 (ja) 2016-09-21

Family

ID=40260006

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2010517083A Active JP5996162B2 (ja) 2007-07-13 2008-07-11 制御されたブロック配列分布及び少なくとも一つの低結晶性ハードブロックを有する触媒オレフィンブロックコポリマー
JP2014165314A Active JP5970035B2 (ja) 2007-07-13 2014-08-14 制御されたブロック配列分布及び少なくとも一つの低結晶性ハードブロックを有する触媒オレフィンブロックコポリマー

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2014165314A Active JP5970035B2 (ja) 2007-07-13 2014-08-14 制御されたブロック配列分布及び少なくとも一つの低結晶性ハードブロックを有する触媒オレフィンブロックコポリマー

Country Status (6)

Country Link
US (1) US8569422B2 (OSRAM)
EP (1) EP2170993B1 (OSRAM)
JP (2) JP5996162B2 (OSRAM)
CN (1) CN101802086B (OSRAM)
BR (1) BRPI0812644B1 (OSRAM)
WO (1) WO2009012152A1 (OSRAM)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8492322B2 (en) * 2007-07-13 2013-07-23 Dow Global Technologies, Llc Viscosity index improver for lubricant compositions
US8569422B2 (en) * 2007-07-13 2013-10-29 Dow Global Technologies, Llc Catalytic olefin block copolymers with controlled block sequence distribution and at least one low crystallinity hard block
EP2170604B1 (en) * 2007-07-13 2019-05-15 Dow Global Technologies LLC Ethylene/alpha-olefin interpolymers having low crystallinity hard blocks
CN101802150A (zh) * 2007-07-13 2010-08-11 陶氏环球技术公司 润滑剂组合物的粘度指数改性剂
EP2238186B1 (en) * 2008-01-30 2018-11-28 Dow Global Technologies LLC Ethylene/alpha-olefin block interpolymers
JP5154473B2 (ja) * 2009-02-20 2013-02-27 三井化学株式会社 ブロック共重合体の解析方法およびブロック共重合体の製造方法
US8476366B2 (en) 2009-10-02 2013-07-02 Dow Global Technologies, Llc Block compositions in thermoplastic vulcanizate applications
JP2013506743A (ja) * 2009-10-02 2013-02-28 ダウ グローバル テクノロジーズ エルエルシー ソフトコンパウンドにおけるブロックコポリマー
CN103958548B (zh) 2011-12-02 2016-05-18 住友化学株式会社 使用多种过渡金属催化剂的烯烃嵌段聚合物的制造方法
US20150025165A1 (en) * 2012-03-16 2015-01-22 Dow Global Technologies Llc Foamable compositions, foams and articles thereof
US20130281340A1 (en) 2012-04-19 2013-10-24 Exxonmobil Chemical Patents Inc. Lubricant Compositions Comprising Ethylene Propylene Copolymers and Methods for Making Them
JP6057955B2 (ja) * 2014-08-14 2017-01-11 ダウ グローバル テクノロジーズ エルエルシー 低結晶化度ハードブロックを含むエチレン／α−オレフィンインターポリマー
BR112017012916B1 (pt) 2014-12-23 2021-11-30 Dow Global Technologies Llc Composição de vulcanizado termoplástico
US10344154B2 (en) 2014-12-23 2019-07-09 Dow Global Technologies Llc Thermoplastic vulcanizate including a block composite
JP6791871B2 (ja) 2015-03-26 2020-11-25 ダウ グローバル テクノロジーズ エルエルシー 鎖シャトリング剤の添加方法
PL3408325T3 (pl) 2016-01-26 2023-07-24 Dynasol Elastómeros, S.A.De C.V. Elastomery termoplastyczne o przeciwnym gradiencie
JP6456905B2 (ja) * 2016-12-14 2019-01-23 ダウ グローバル テクノロジーズ エルエルシー 低結晶化度ハードブロックを含むエチレン／α−オレフィンインターポリマー
US12460082B2 (en) 2017-01-26 2025-11-04 Dynasol Elastómeros, S.A. De C.V. Counter tapered thermoplastic elastomers
CN109627366A (zh) * 2017-10-09 2019-04-16 中国石化扬子石油化工有限公司 一种茂金属催化剂及在环烯烃共聚物制备中的应用
AR117125A1 (es) * 2018-11-20 2021-07-14 Dow Global Technologies Llc Método de fabricación de fibras rizadas y bandas no tejidas que tienen tales fibras
AR117126A1 (es) * 2018-11-20 2021-07-14 Dow Global Technologies Llc UNA TELA NO TEJIDA QUE TIENE FIBRAS DE POLÍMEROS DE ETILENO / a-OLEFINA
CN115315453B (zh) * 2020-02-11 2024-08-30 埃克森美孚化学专利公司 使用过渡金属双(酚盐)催化剂络合物获得的丙烯共聚物及生产该丙烯共聚物的均相方法
CN112724343A (zh) * 2021-01-19 2021-04-30 天津大学 一种聚烯烃嵌段共聚物及其制备方法
WO2024206912A1 (en) 2023-03-29 2024-10-03 Cornell University Gradient copolymers, methods of making same, and uses thereof

Family Cites Families (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5610506A (en) * 1979-07-09 1981-02-03 Mitsui Petrochem Ind Ltd Production of ethylene polymer composition
US4792595A (en) 1983-06-15 1988-12-20 Exxon Research & Engineering Co. Narrow MWD alpha-olefin copolymers
US4507515A (en) 1983-12-21 1985-03-26 Exxon Research & Engineering Co. Lubricating oil compositions containing ethylene-alpha-olefin polymers of controlled sequence distribution and molecular heterogeneity
US4950541A (en) 1984-08-15 1990-08-21 The Dow Chemical Company Maleic anhydride grafts of olefin polymers
US4762890A (en) 1986-09-05 1988-08-09 The Dow Chemical Company Method of grafting maleic anhydride to polymers
US4927888A (en) 1986-09-05 1990-05-22 The Dow Chemical Company Maleic anhydride graft copolymers having low yellowness index and films containing the same
US4798081A (en) 1985-11-27 1989-01-17 The Dow Chemical Company High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers
US5391629A (en) * 1987-01-30 1995-02-21 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
US4804794A (en) 1987-07-13 1989-02-14 Exxon Chemical Patents Inc. Viscosity modifier polymers
US5244590A (en) 1989-10-12 1993-09-14 Exxon Chemical Patents Inc. Viscosity index improver
US5310490A (en) 1991-03-13 1994-05-10 Exxon Chemical Products Inc. Viscosity modifer polymers
US5310814A (en) 1991-03-15 1994-05-10 Exxon Chemical Patents Inc. Viscosity modifier polybutadiene polymers
RU2149878C1 (ru) * 1994-04-06 2000-05-27 Эксон Кемикэл Пейтентс Инк. ЭТИЛЕН-α-ОЛЕФИНОВЫЕ БЛОК-СОПОЛИМЕРЫ И СПОСОБЫ ИХ ПОЛУЧЕНИЯ
EP0758348B1 (en) * 1994-04-06 1999-07-14 Infineum USA L.P. Ethylene alpha-olefin block copolymers and methods for production thereof
US5405901A (en) * 1994-07-06 1995-04-11 Union Carbide Chemicals & Plastics Technology Corporation Process of producing ethylene polymer blends in gas phase
CN1120849C (zh) 1996-03-27 2003-09-10 陶氏环球技术公司 高度可溶性烯烃聚合反应催化活化剂
WO1998006727A1 (en) 1996-08-08 1998-02-19 The Dow Chemical Company 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process
US6110880A (en) * 1997-06-24 2000-08-29 Exxon Chemical Patents Inc Polyolefin block copolymer viscosity modifier
DE69909057T2 (de) 1998-02-20 2004-05-06 Dow Global Technologies, Inc., Midland Expandierte Anionen enthaltende Katalysatoraktivatoren
JP4558951B2 (ja) 1999-03-30 2010-10-06 三井化学株式会社 潤滑油用粘度調整剤および潤滑油組成物
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
WO2002046251A2 (en) 2000-12-04 2002-06-13 Exxonmobil Chemical Patents Inc. Ethylene copolymer compositions suitable for viscosity index improvers and lubricant compositions
US20030004268A1 (en) 2001-05-14 2003-01-02 General Electric Company Polyimide blends, method of making, and articles made therefrom
JP4100961B2 (ja) * 2001-05-31 2008-06-11 三井化学株式会社 オレフィンブロック共重合体、潤滑油用粘度指数向上剤および潤滑油組成物
US6960635B2 (en) 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US6919467B2 (en) 2001-12-18 2005-07-19 Univation Technologies, Llc Imino-amide catalyst compositions for the polymerization of olefins
DE60335459D1 (de) 2002-04-24 2011-02-03 Symyx Solutions Inc Verbrückte bi-aromatische liganden, komplexe, katalysatoren, verfahren zur polymerisierung und entstehende polymere
JP2005539060A (ja) 2002-09-12 2005-12-22 ダウ・グローバル・テクノロジーズ・インコーポレイテッド 金属錯体の製造方法
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
US7524911B2 (en) * 2004-03-17 2009-04-28 Dow Global Technologies Inc. Adhesive and marking compositions made from interpolymers of ethylene/α-olefins
US7897689B2 (en) * 2004-03-17 2011-03-01 Dow Global Technologies Inc. Functionalized ethylene/α-olefin interpolymer compositions
US7608668B2 (en) 2004-03-17 2009-10-27 Dow Global Technologies Inc. Ethylene/α-olefins block interpolymers
US7622529B2 (en) * 2004-03-17 2009-11-24 Dow Global Technologies Inc. Polymer blends from interpolymers of ethylene/alpha-olefin with improved compatibility
US7579408B2 (en) * 2004-03-17 2009-08-25 Dow Global Technologies Inc. Thermoplastic vulcanizate comprising interpolymers of ethylene/α-olefins
US7687442B2 (en) * 2004-03-17 2010-03-30 Dow Global Technologies Inc. Low molecular weight ethylene/α-olefin interpolymer as base lubricant oils
US7795321B2 (en) * 2004-03-17 2010-09-14 Dow Global Technologies Inc. Rheology modification of interpolymers of ethylene/α-olefins and articles made therefrom
JP4879882B2 (ja) 2004-03-17 2012-02-22 ダウ グローバル テクノロジーズ エルエルシー より高次のオレフィンマルチブロックコポリマーを形成するためのシャトリング剤を含む触媒組成物
JP5133050B2 (ja) 2004-03-17 2013-01-30 ダウ グローバル テクノロジーズ エルエルシー エチレンマルチブロックコポリマーを形成するためのシャトリング剤を含む触媒組成物
US7863379B2 (en) * 2004-03-17 2011-01-04 Dow Global Technologies Inc. Impact modification of thermoplastics with ethylene/alpha-olefin interpolymers
US7671106B2 (en) * 2004-03-17 2010-03-02 Dow Global Technologies Inc. Cap liners, closures and gaskets from multi-block polymers
KR101277095B1 (ko) 2004-03-17 2013-06-20 다우 글로벌 테크놀로지스 엘엘씨 셔틀링제를 포함하는, 에틸렌 공중합체 형성용 촉매 조성물
US7714071B2 (en) * 2004-03-17 2010-05-11 Dow Global Technologies Inc. Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom
US8816006B2 (en) * 2004-03-17 2014-08-26 Dow Global Technologies Llc Compositions of ethylene/α-olefin multi-block interpolymer suitable for films
US7582716B2 (en) * 2004-03-17 2009-09-01 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for blown films with high hot tack
TWI374150B (en) * 2005-03-17 2012-10-11 Dow Global Technologies Llc Filled polymer compositions made from interpolymers of ethylene α-olefins and uses thereof
CA2601292A1 (en) * 2005-03-17 2006-09-28 Dow Global Technologies Inc. Ethylene/alpha-olefins block interpolymers
TW200641115A (en) 2005-03-17 2006-12-01 Dow Global Technologies Inc Low molecular weight ethylene/ α-olefin interpolymer as base lubricant oils
US7737215B2 (en) * 2005-03-17 2010-06-15 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
US7910658B2 (en) * 2005-03-17 2011-03-22 Dow Global Technologies Llc Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
US8084537B2 (en) * 2005-03-17 2011-12-27 Dow Global Technologies Llc Polymer blends from interpolymers of ethylene/α-olefin with improved compatibility
KR101319124B1 (ko) * 2005-03-17 2013-10-23 다우 글로벌 테크놀로지스 엘엘씨 상용성이 개선된 에틸렌/알파-올레핀의 혼성중합체로부터의중합체 블렌드
JP5570115B2 (ja) * 2005-03-17 2014-08-13 ダウ グローバル テクノロジーズ エルエルシー 擬似ブロックコポリマーおよび可逆的連鎖移動剤（ｃｈａｉｎｓｈｕｔｔｌｉｎｇａｇｅｎｔ）を用いる方法
US7786216B2 (en) * 2005-03-17 2010-08-31 Dow Global Technologies Inc. Oil based blends of interpolymers of ethylene/α-olefins
BRPI0609837A2 (pt) 2005-03-17 2010-05-04 Dow Global Technologies Inc composição lubrificante
MY158058A (en) * 2005-03-17 2016-08-30 Dow Global Technologies Inc ADHESIVE AND MARKING COMPOSITIONS MADE FROM INTERPOLYMERS OF ETHYLENE/a-OLEFINS
AR058450A1 (es) 2005-09-15 2008-02-06 Dow Global Technologies Inc Copolimeros de bloque de olefina cataliticos con distibucion de secuencia de bloque controlada
US7906587B2 (en) * 2005-09-16 2011-03-15 Dow Global Technologies Llc Polymer blends from interpolymer of ethylene/α olefin with improved compatibility
US7695812B2 (en) * 2005-09-16 2010-04-13 Dow Global Technologies, Inc. Fibers made from copolymers of ethylene/α-olefins
US7928022B2 (en) * 2006-11-30 2011-04-19 Dow Global Technologies Llc Olefin block compositions for heavy weight stretch fabrics
US20080269366A1 (en) * 2007-04-27 2008-10-30 Dow Global Technologies Inc. Microporous films from compatibilized polymeric blends
CN101802150A (zh) * 2007-07-13 2010-08-11 陶氏环球技术公司 润滑剂组合物的粘度指数改性剂
US8492322B2 (en) * 2007-07-13 2013-07-23 Dow Global Technologies, Llc Viscosity index improver for lubricant compositions
US8569422B2 (en) * 2007-07-13 2013-10-29 Dow Global Technologies, Llc Catalytic olefin block copolymers with controlled block sequence distribution and at least one low crystallinity hard block
EP2170604B1 (en) 2007-07-13 2019-05-15 Dow Global Technologies LLC Ethylene/alpha-olefin interpolymers having low crystallinity hard blocks

Also Published As

Publication number Publication date
JP2010533774A (ja) 2010-10-28
JP2015013995A (ja) 2015-01-22
US8569422B2 (en) 2013-10-29
EP2170993A4 (en) 2011-03-30
EP2170993A1 (en) 2010-04-07
US20100197864A1 (en) 2010-08-05
EP2170993B1 (en) 2019-05-15
BRPI0812644B1 (pt) 2019-07-09
CN101802086B (zh) 2013-10-02
WO2009012152A1 (en) 2009-01-22
BRPI0812644A2 (pt) 2015-09-15
CN101802086A (zh) 2010-08-11
JP5970035B2 (ja) 2016-08-17

Similar Documents

Publication Publication Date Title
JP5996162B2 (ja) 制御されたブロック配列分布及び少なくとも一つの低結晶性ハードブロックを有する触媒オレフィンブロックコポリマー
EP2170604B1 (en) Ethylene/alpha-olefin interpolymers having low crystallinity hard blocks
JP5367361B2 (ja) エチレン／α−オレフィンブロック共重合体
US7579408B2 (en) Thermoplastic vulcanizate comprising interpolymers of ethylene/α-olefins
KR101243003B1 (ko) 에틸렌/α-올레핀의 혼성중합체의 유변성 개질 및 그로부터제조한 성형품
KR20080006540A (ko) 탄성 필름 및 라미네이트용의 에틸렌/α―올레핀 멀티블록혼성중합체 조성물
CN101356206B (zh) 包含乙烯/α-烯烃共聚体的热塑性硫化橡胶
KR20070119638A (ko) 에틸렌/α-올레핀 혼성중합체를 이용한 열가소성 수지의충격 조절
AU2007226554A1 (en) Propylene/alpha-olefins block interpolymers
JP6057955B2 (ja) 低結晶化度ハードブロックを含むエチレン／α−オレフィンインターポリマー
JP6456905B2 (ja) 低結晶化度ハードブロックを含むエチレン／α−オレフィンインターポリマー
JP3607427B2 (ja) 熱可塑性エラストマー樹脂組成物
KR20070117592A (ko) 에틸렌/α-올레핀의 혼성중합체를 포함하는 열가소성가황물
CA2727437A1 (en) Processes to control fouling and improve compositions
KR20070117595A (ko) 에틸렌/α-올레핀 블록 혼성중합체

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20110707

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20121214

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130108

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20130405

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20130412

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20130708

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20140415

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20140814

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20140821

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20160226

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20160531

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20160824

R150 Certificate of patent or registration of utility model

Ref document number: 5996162

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250