JP5986796B2 - 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法 - Google Patents

複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法 Download PDF

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Publication number
JP5986796B2
JP5986796B2 JP2012109948A JP2012109948A JP5986796B2 JP 5986796 B2 JP5986796 B2 JP 5986796B2 JP 2012109948 A JP2012109948 A JP 2012109948A JP 2012109948 A JP2012109948 A JP 2012109948A JP 5986796 B2 JP5986796 B2 JP 5986796B2
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Prior art keywords
absorption
amine
solution
tower
gas
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Japanese (ja)
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JP2013236987A5 (enExample
JP2013236987A (ja
Inventor
田中　裕士
裕士 田中
長安　弘貢
弘貢 長安
琢也 平田
琢也 平田
大石　剛司
剛司 大石
上條　孝
孝 上條
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Kansai Electric Power Co Inc
Mitsubishi Heavy Industries Ltd
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Kansai Electric Power Co Inc
Mitsubishi Heavy Industries Ltd
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Priority to JP2012109948A priority Critical patent/JP5986796B2/ja
Application filed by Kansai Electric Power Co Inc, Mitsubishi Heavy Industries Ltd filed Critical Kansai Electric Power Co Inc
Priority to EP13788078.7A priority patent/EP2848298B1/en
Priority to PCT/JP2013/062259 priority patent/WO2013168588A1/ja
Priority to AU2013258901A priority patent/AU2013258901B2/en
Priority to CA2872593A priority patent/CA2872593C/en
Priority to US14/399,107 priority patent/US10137407B2/en
Publication of JP2013236987A publication Critical patent/JP2013236987A/ja
Publication of JP2013236987A5 publication Critical patent/JP2013236987A5/ja
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/52—Hydrogen sulfide
    • B01D53/526—Mixtures of hydrogen sulfide and carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425—Regeneration of liquid absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77—Liquid phase processes
    • B01D53/78—Liquid phase processes with gas-liquid contact
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20405—Monoamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/2041—Diamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20421—Primary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20426—Secondary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20436—Cyclic amines
    • B01D2252/20447—Cyclic amines containing a piperazine-ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20484—Alkanolamines with one hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50—Combinations of absorbents
    • B01D2252/504—Mixtures of two or more absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/304—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Organic Chemistry (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
JP2012109948A 2012-05-11 2012-05-11 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法 Active JP5986796B2 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2012109948A JP5986796B2 (ja) 2012-05-11 2012-05-11 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法
PCT/JP2013/062259 WO2013168588A1 (ja) 2012-05-11 2013-04-25 複合アミン吸収液、ｃｏ2又はｈ2ｓ又はその双方の除去装置及び方法
AU2013258901A AU2013258901B2 (en) 2012-05-11 2013-04-25 Composite amine absorbing solution, and device and method for removing CO2, H2S, or both
CA2872593A CA2872593C (en) 2012-05-11 2013-04-25 Complex amine absorbent, and device and method for removing one or both of co2 and h2s
EP13788078.7A EP2848298B1 (en) 2012-05-11 2013-04-25 Composite amine absorbing solution and method for removing co2, h2s, or both
US14/399,107 US10137407B2 (en) 2012-05-11 2013-04-25 Complex amine absorbent, and device and method for removing one or both of CO2 and H2S

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2012109948A JP5986796B2 (ja) 2012-05-11 2012-05-11 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法

Publications (3)

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JP2013236987A JP2013236987A (ja) 2013-11-28
JP2013236987A5 JP2013236987A5 (enExample) 2014-11-06
JP5986796B2 true JP5986796B2 (ja) 2016-09-06

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Country Status (6)

Country Link
US (1) US10137407B2 (enExample)
EP (1) EP2848298B1 (enExample)
JP (1) JP5986796B2 (enExample)
AU (1) AU2013258901B2 (enExample)
CA (1) CA2872593C (enExample)
WO (1) WO2013168588A1 (enExample)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6841676B2 (ja) 2017-01-31 2021-03-10 三菱重工エンジニアリング株式会社 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法
GB201813839D0 (en) * 2018-06-26 2018-10-10 Carbon Clean Solutions Ltd System and process of capturing carbon dioxide from flue gases
CN113457382A (zh) * 2021-07-22 2021-10-01 浙江天地环保科技股份有限公司 一种低粘度的co2捕集混合吸收剂配方
EP4395917A4 (en) 2021-08-31 2025-10-15 Univ Yale CARBON SEQUESTRATION SYSTEMS AND METHODS USING ENHANCED WEATHERING
CN116371146A (zh) * 2023-02-24 2023-07-04 国家能源集团新能源技术研究院有限公司 一种二氧化碳吸收剂及其制备方法与应用

Family Cites Families (26)

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AU506199B2 (en) 1975-06-26 1979-12-20 Exxon Research And Engineering Company Absorbtion of co2 from gaseous feeds
DE2551717C3 (de) * 1975-11-18 1980-11-13 Basf Ag, 6700 Ludwigshafen und ggf. COS aus Gasen
CA1091429A (en) * 1977-01-06 1980-12-16 Guido Sartori Process for removing carbon dioxide containing acidic gases from gaseous mixtures
US4100257A (en) * 1977-02-14 1978-07-11 Exxon Research & Engineering Co. Process and amine-solvent absorbent for removing acidic gases from gaseous mixtures
US4100099A (en) * 1977-03-28 1978-07-11 The Dow Chemical Company Quaternary salt-polyamine inhibitor for sour gas conditioning solutions
JPH0644972B2 (ja) * 1988-03-11 1994-06-15 ユニオン・カーバイド・コーポレーション エチレンアミン促進剤を含有する第三級アルカノールアミン吸収剤及びその使用法
JPH04349921A (ja) * 1991-05-27 1992-12-04 Mitsubishi Heavy Ind Ltd 排煙脱炭吸収剤
JP2809368B2 (ja) * 1993-04-05 1998-10-08 関西電力株式会社 燃焼排ガス中の二酸化炭素の回収方法
JPH06343858A (ja) * 1993-06-08 1994-12-20 Mitsubishi Heavy Ind Ltd 二酸化炭素吸収剤
JPH0751537A (ja) 1993-06-30 1995-02-28 Mitsubishi Heavy Ind Ltd Ｃｏ２ 含有ガス中のｃｏ２ を除去する方法
DE19828977A1 (de) * 1998-06-29 1999-12-30 Basf Ag Verfahren zur Entfernung saurer Gasbestandteile aus Gasen
US6165433A (en) * 1999-06-10 2000-12-26 Praxair Technology, Inc. Carbon dioxide recovery with composite amine blends
JP4690659B2 (ja) 2004-03-15 2011-06-01 三菱重工業株式会社 Ｃｏ２回収装置
US7368476B2 (en) * 2004-04-07 2008-05-06 Pharmacyclics, Inc. Hydroxamates as therapeutic agents
RU2417824C2 (ru) * 2006-02-14 2011-05-10 Басф Се Переоборудование установок для удаления кислых газов
ATE547163T1 (de) * 2006-03-16 2012-03-15 Basf Se Verfahren zum inkontaktbringen zweier phasen, deren kontakt von wärmeentwicklung begleitet ist
JP5230080B2 (ja) 2006-06-06 2013-07-10 三菱重工業株式会社 吸収液、ｃｏ２の除去装置及び方法
JP2008013400A (ja) 2006-07-05 2008-01-24 Research Institute Of Innovative Technology For The Earth 排ガス中の二酸化炭素を吸収及び脱離して回収する方法
US7901488B2 (en) * 2006-10-04 2011-03-08 Board Of Regents, The University Of Texas System Regeneration of an aqueous solution from an acid gas absorption process by matrix stripping
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US9266102B2 (en) * 2013-03-29 2016-02-23 The University Of Kentucky Research Foundation Catalysts and methods of increasing mass transfer rate of acid gas scrubbing solvents

Also Published As

Publication number Publication date
WO2013168588A1 (ja) 2013-11-14
US20150132207A1 (en) 2015-05-14
AU2013258901A1 (en) 2014-11-27
EP2848298A1 (en) 2015-03-18
AU2013258901B2 (en) 2016-07-14
EP2848298A4 (en) 2016-02-17
US10137407B2 (en) 2018-11-27
CA2872593C (en) 2017-12-12
JP2013236987A (ja) 2013-11-28
CA2872593A1 (en) 2013-11-14
EP2848298B1 (en) 2018-12-26

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