JP5972382B2 - （２−イソプロピル−５−メチル）ヘキシル（メタ）アクリレートを使用して調製される（メタ）アクリル系エラストマー材料を含む感圧性接着剤 - Google Patents
（２−イソプロピル−５−メチル）ヘキシル（メタ）アクリレートを使用して調製される（メタ）アクリル系エラストマー材料を含む感圧性接着剤 Download PDFInfo
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- JP5972382B2 JP5972382B2 JP2014531864A JP2014531864A JP5972382B2 JP 5972382 B2 JP5972382 B2 JP 5972382B2 JP 2014531864 A JP2014531864 A JP 2014531864A JP 2014531864 A JP2014531864 A JP 2014531864A JP 5972382 B2 JP5972382 B2 JP 5972382B2
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- Prior art keywords
- meth
- acrylate
- weight percent
- methyl
- monomer
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- 239000000463 material Substances 0.000 title claims description 141
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- -1 (2-isopropyl-5-methyl) hexyl Chemical group 0.000 title claims description 110
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- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 21
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- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 4
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- 125000003342 alkenyl group Chemical group 0.000 description 4
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- 238000004458 analytical method Methods 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
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- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
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- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 4
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- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
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- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SWPMNMYLORDLJE-UHFFFAOYSA-N n-ethylprop-2-enamide Chemical compound CCNC(=O)C=C SWPMNMYLORDLJE-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 description 1
- AWGZKFQMWZYCHF-UHFFFAOYSA-N n-octylprop-2-enamide Chemical compound CCCCCCCCNC(=O)C=C AWGZKFQMWZYCHF-UHFFFAOYSA-N 0.000 description 1
- QNILTEGFHQSKFF-UHFFFAOYSA-N n-propan-2-ylprop-2-enamide Chemical compound CC(C)NC(=O)C=C QNILTEGFHQSKFF-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- OPECTNGATDYLSS-UHFFFAOYSA-N naphthalene-2-sulfonyl chloride Chemical compound C1=CC=CC2=CC(S(=O)(=O)Cl)=CC=C21 OPECTNGATDYLSS-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
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- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
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- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
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- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
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- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- YLQLIQIAXYRMDL-UHFFFAOYSA-N propylheptyl alcohol Chemical compound CCCCCC(CO)CCC YLQLIQIAXYRMDL-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
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- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
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- 229910052708 sodium Inorganic materials 0.000 description 1
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- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
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- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
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- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910001427 strontium ion Inorganic materials 0.000 description 1
- PWYYWQHXAPXYMF-UHFFFAOYSA-N strontium(2+) Chemical compound [Sr+2] PWYYWQHXAPXYMF-UHFFFAOYSA-N 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
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- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
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- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
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- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/10—Esters
- C08F120/12—Esters of monohydric alcohols or phenols
- C08F120/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F120/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1811—C10or C11-(Meth)acrylate, e.g. isodecyl (meth)acrylate, isobornyl (meth)acrylate or 2-naphthyl (meth)acrylate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2852—Adhesive compositions
- Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
- Y10T428/2891—Adhesive compositions including addition polymer from unsaturated monomer including addition polymer from alpha-beta unsaturated carboxylic acid [e.g., acrylic acid, methacrylic acid, etc.] Or derivative thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesive Tapes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161538996P | 2011-09-26 | 2011-09-26 | |
| US61/538,996 | 2011-09-26 | ||
| PCT/US2012/054836 WO2013048735A1 (en) | 2011-09-26 | 2012-09-12 | Pressure-sensitive adhesives with (meth)acrylic-based elastomeric materials prepared using (2-isopropyl-5-methyl)hexyl (meth)acrylate |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014531497A JP2014531497A (ja) | 2014-11-27 |
| JP2014531497A5 JP2014531497A5 (OSRAM) | 2015-09-17 |
| JP5972382B2 true JP5972382B2 (ja) | 2016-08-17 |
Family
ID=47046831
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014531864A Expired - Fee Related JP5972382B2 (ja) | 2011-09-26 | 2012-09-12 | （２−イソプロピル−５−メチル）ヘキシル（メタ）アクリレートを使用して調製される（メタ）アクリル系エラストマー材料を含む感圧性接着剤 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9399724B2 (OSRAM) |
| EP (1) | EP2760959B1 (OSRAM) |
| JP (1) | JP5972382B2 (OSRAM) |
| KR (1) | KR20140074957A (OSRAM) |
| CN (1) | CN103827244B (OSRAM) |
| WO (1) | WO2013048735A1 (OSRAM) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6197048B2 (ja) | 2012-12-19 | 2017-09-13 | スリーエム イノベイティブ プロパティズ カンパニー | 分解性モノマー及びポリマーから調製される感圧性接着剤 |
| WO2015134249A1 (en) * | 2014-03-05 | 2015-09-11 | 3M Innovative Properties Company | Gentle to skin (meth)acrylate pressure-sensitive adhesive |
| KR101854493B1 (ko) * | 2014-08-29 | 2018-05-04 | 삼성에스디아이 주식회사 | 점착필름, 및 이를 이용한 디스플레이 부재 |
| KR102024481B1 (ko) | 2015-06-03 | 2019-09-23 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 가요성 디스플레이용 조립체 층 |
| JP2018526470A (ja) | 2015-06-03 | 2018-09-13 | スリーエム イノベイティブ プロパティズ カンパニー | アクリル系可撓性アセンブリ層 |
| JP6584867B2 (ja) * | 2015-08-24 | 2019-10-02 | 大阪有機化学工業株式会社 | アクリロイルオキシ基含有化合物系粘着剤 |
| WO2017040074A1 (en) | 2015-08-31 | 2017-03-09 | 3M Innovative Properties Company | Negative pressure wound therapy dressings comprising (meth)acrylate pressure-sensitive adhesive with enhanced adhesion to wet surfaces |
| EP3344720B1 (en) | 2015-08-31 | 2020-10-14 | 3M Innovative Properties Company | Articles comprising (meth)acrylate pressure-sensitive adhesive with enhanced adhesion to wet surfaces |
| JP6204633B2 (ja) * | 2015-09-14 | 2017-09-27 | リンテック株式会社 | 粘着剤組成物及び粘着シート |
| US11492515B2 (en) | 2016-12-02 | 2022-11-08 | 3M Innovative Properties Company | Low dielectric optically clear adhesives for flexible electronic display |
| JP7271169B2 (ja) * | 2018-12-27 | 2023-05-11 | 日東電工株式会社 | 粘着シート |
| WO2020136555A1 (en) | 2018-12-27 | 2020-07-02 | 3M Innovative Properties Company | Hot melt processable (meth)acrylate-based medical adhesives |
| WO2022221408A1 (en) * | 2021-04-13 | 2022-10-20 | The Regents Of The University Of Michigan | Preparation of pressure sensitive adhesives from post-consumer superabsorbent polymers |
| CN121127512A (zh) | 2023-05-02 | 2025-12-12 | 3M创新有限公司 | 相分离的光学透明粘合剂 |
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| DE1223822B (de) | 1965-01-27 | 1966-09-01 | Deutsche Erdoel Ag | Verfahren zur Herstellung von beta-verzweigten, gesaettigten und ungesaettigten Aldehyden |
| US4438286A (en) | 1981-10-16 | 1984-03-20 | Sumitomo Chemical Company, Limited | Substituted esters and alcohols |
| JPS63250347A (ja) * | 1987-04-07 | 1988-10-18 | Koei Chem Co Ltd | 新規なアクリル酸エステルおよびその製造法 |
| TW221061B (OSRAM) | 1991-12-31 | 1994-02-11 | Minnesota Mining & Mfg | |
| JP3723546B2 (ja) * | 2000-12-01 | 2005-12-07 | スリーエム イノベイティブ プロパティズ カンパニー | 架橋型感圧接着剤組成物、および高温での用途に有用な架橋型感圧接着剤組成物ベースの接着製品 |
| US20040229990A1 (en) * | 2003-05-16 | 2004-11-18 | Lord Corporation | Acrylic structural adhesive having improved T-peel strength |
| JP4578074B2 (ja) * | 2003-08-08 | 2010-11-10 | スリーエム イノベイティブ プロパティズ カンパニー | 非ハロゲン系難燃性アクリル系粘着シート又はテープ |
| JP4645797B2 (ja) | 2004-04-23 | 2011-03-09 | 株式会社スリーボンド | 難接着材質用光硬化性樹脂組成物 |
| US20060264573A1 (en) * | 2005-05-19 | 2006-11-23 | Bennett Ruth M | Ambient curable protective sealant |
| CN101522845A (zh) | 2006-10-12 | 2009-09-02 | 日东电工株式会社 | 丙烯酸系粘合带或粘合片及其制造方法 |
| US7385020B2 (en) | 2006-10-13 | 2008-06-10 | 3M Innovative Properties Company | 2-octyl (meth)acrylate adhesive composition |
| BRPI0719165A2 (pt) * | 2006-10-23 | 2014-02-04 | Basf Se | Adesivo sensível a pressão, e, uso de adesivo sensível a pressão |
| CN101959838B (zh) | 2008-02-27 | 2015-05-13 | 巴斯夫欧洲公司 | 制备c10醇混合物的(甲基)丙烯酸酯的方法 |
| EP2285927A1 (en) | 2008-04-23 | 2011-02-23 | 3M Innovative Properties Company | Microsphere pressure sensitive adhesive composition |
| US7632973B2 (en) | 2008-04-24 | 2009-12-15 | Loyola University Of Chicago | Methods for preparing aldehydes by self-aldol condensation |
| EP2310470B1 (en) | 2008-07-02 | 2012-02-15 | 3M Innovative Properties Company | Low surface energy adhesive |
| EP2496654B1 (de) * | 2009-11-05 | 2014-04-02 | Basf Se | Kleb- und dichtstoffe enthaltend ester auf basis von 2-propylheptanol |
| US8137807B2 (en) | 2010-03-26 | 2012-03-20 | 3M Innovative Properties Company | Pressure-sensitive adhesives derived from 2-alkyl alkanols |
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- 2012-09-12 JP JP2014531864A patent/JP5972382B2/ja not_active Expired - Fee Related
- 2012-09-12 US US14/345,060 patent/US9399724B2/en not_active Expired - Fee Related
- 2012-09-12 KR KR1020147010568A patent/KR20140074957A/ko not_active Withdrawn
- 2012-09-12 EP EP12775343.2A patent/EP2760959B1/en not_active Not-in-force
- 2012-09-12 CN CN201280046458.XA patent/CN103827244B/zh not_active Expired - Fee Related
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| US9399724B2 (en) | 2016-07-26 |
| US20140370281A1 (en) | 2014-12-18 |
| KR20140074957A (ko) | 2014-06-18 |
| WO2013048735A1 (en) | 2013-04-04 |
| JP2014531497A (ja) | 2014-11-27 |
| EP2760959A1 (en) | 2014-08-06 |
| EP2760959B1 (en) | 2015-10-21 |
| CN103827244B (zh) | 2016-02-03 |
| CN103827244A (zh) | 2014-05-28 |
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