JP5969042B2 - シールド塩類を含有する表面処理組成物 - Google Patents
シールド塩類を含有する表面処理組成物 Download PDFInfo
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- JP5969042B2 JP5969042B2 JP2014541145A JP2014541145A JP5969042B2 JP 5969042 B2 JP5969042 B2 JP 5969042B2 JP 2014541145 A JP2014541145 A JP 2014541145A JP 2014541145 A JP2014541145 A JP 2014541145A JP 5969042 B2 JP5969042 B2 JP 5969042B2
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- cationic polymer
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8194—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Description
本明細書で使用するとき、「コアセルベート」は、液相及び固相分離の双方を包含する。
好適なアニオン性界面活性剤は、液体洗剤製品で典型的に用いられる従来のアニオン性界面活性剤のいかなる種類のものであってもよい。このような界面活性剤としては、アルキルベンゼンスルホン酸及びそれらの塩、並びにアルコキシル化又は非アルコキシル化アルキル硫酸塩材料が挙げられる。代表的なアニオン性界面活性剤は、C10〜C16のアルキルベンゼンスルホン酸、好ましくは、C11〜C14のアルキルベンゼンスルホン酸のアルカリ金属塩である。一態様では、アルキル基は直鎖である。このような直鎖アルキルベンゼンスルホネートは「LAS」として公知である。そのような界面活性剤及びそれらの調製は、例えば、米国特許第2,220,099号及び同第2,477,383号に記載されている。特に好ましいものは、アルキル基の炭素原子の平均数が約11〜14の線状直鎖アルキルベンゼンスルホン酸ナトリウム及びカリウムである。ナトリウムC11〜C14 LAS、例えば、C12 LASはそのような界面活性剤の具体的な例である。
例えば、全てのポリマーが典型的には液体洗剤製品で使用されて、多様なカチオン性ポリマーが、本発明の表面処理組成物における使用に好適である。1つ以上の実施形態によると、カチオン性ポリマーは、最大で約10,000,000ダルトンの分子量、及びpH 7で算定される場合、0.05〜25ミリ当量/gの範囲で電荷密度を備える。理論に束縛されるものではないが、カチオン性ポリマーの、分子量、電荷密度、及びポリマー構造内の疎水性領域の存在は、ポリマー−界面活性剤錯体が形成されることを効果的に防止するためのシールド塩の能力に影響を及ぼす場合がある。特定の実施形態では、カチオン性ポリマーの分子量は、10,000,000未満、より好ましくは5,000,000未満、更により好ましくは1,000,000未満、なおより好ましくは600,000未満、なおより好ましくは約500,000ダルトン以下である。更に、電荷密度は、pH 7で計算される場合、0.05〜25meq/gの範囲であり、好ましくは7.0meq/g未満、より好ましくは5.0meq/g未満、更により好ましくは、pH 7で測定される場合、3.0meq/g未満である。本明細書で使用するとき、「電荷密度」は、最終的ポリマーの電荷密度を指し、モノマー原料とは異なり得る。電荷密度は、繰り返し単位当たりの正味電荷数を、繰り返し単位の分子量で除し、次いで1000を掛けることにより計算され得る。正電荷は、カチオン性ポリマーの主鎖上及び/又はカチオン性ポリマーの側鎖上に位置することができることに留意されるべきである。アミンモノマーを有するカチオン性ポリマーの場合には、電荷密度は、担体のpHに依存し、したがって、本開示との比較のために、電荷密度はpH 7で測定されるべきである。
上述のように、シールド塩類は、ボトルの内部のコアセルベート形成を低減又は排除するために、洗剤容器又はボトル内部のアニオン性界面活性剤とカチオン性ポリマーとの間の分離を封鎖又は維持する塩類である。本発明によると、シールド塩類は、水中で溶解される場合に、正帯電しているイオン(カチオン)及び負帯電しているイオン(アニオン)を形成するイオン種である。本発明の範囲内にあるものとして様々な重量が企図されるが、シールド塩の分子量は、約25と約500ダルトンの間である。更に、シールド塩は強塩基ではなく、これは、シールド塩が酸/塩基反応において非常に弱い酸を脱プロトン化することができないことを意味している。
本発明の表面処理組成物はまた、追加の補助的洗浄添加剤を含有してもよい。これら追加成分の明確な性質及びそれらを組み込む濃度は、組成物の物理的形態及びそれが使用される洗浄作業の明確な性質に依存する。
Claims (11)
- 表面処理組成物であって、
a)前記組成物の6重量%〜20重量%の、ポリ(ジアリルジメチルアンモニウムクロリド/コ−アクリル酸)コポリマー(ポリクアテルニウム−22)である、カチオン性ポリマーと、
b)前記組成物の6重量%〜40重量%の、アルキルベンゼンスルホン酸及びそれらの塩、アルコキシル化又は非アルコキシル化アルキル硫酸塩、並びにこれらの混合物からなる群から選択される、アニオン性界面活性剤と、
c)前記組成物の4重量%〜15重量%のシールド塩であって、前記シールド塩が、
25〜500の分子量を有し、並びに
最大0.01Mの濃度で水に添加される場合、水の表面張力を50mN/mより低く下降させることが不可能である、シールド塩と、
を含み、
前記カチオン性ポリマーに対する前記アニオン性界面活性剤の重量比が、0.5:1と4:1の間であり、
前記カチオン性ポリマーに対する前記シールド塩の重量比が、0.3:1と3:1の間であり、
前記表面処理組成物が、洗濯洗浄組成物及び洗剤、布地軟化組成物、布地向上組成物、布地フレッシュニング組成物、洗濯予洗組成物、洗濯前処理組成物、並びに他の洗濯添加剤からなる群から選択される、表面処理組成物。 - 前記シールド塩が、水中に溶解される場合にアニオンを形成し、前記アニオンの少なくとも一部が複数の負電荷を有し、複数の負電荷を有する前記アニオンの前記一部の前記負電荷の50%以下が、カルボキシレート基と会合している、請求項1に記載の組成物。
- 前記シールド塩が、クメンスルホネートのアンモニウム系、アルカリ又はアルカリ土類金属塩類、トルエンスルホネートのアンモニウム系、アルカリ又はアルカリ土類金属塩類、キシレンスルホネートのアンモニウム系、アルカリ又はアルカリ土類金属塩類、ベンゼンスルホネートのアンモニウム系、アルカリ又はアルカリ土類金属塩類、及びこれらの混合物の群から選択される、請求項1又は2に記載の組成物。
- 前記シールド塩が、クメンスルホン酸ナトリウム、トルエンスルホン酸ナトリウム、キシレンスルホン酸ナトリウム、ベンゼンスルホン酸ナトリウム、及びこれらの混合物の群から選択される、請求項1〜3のいずれか一項に記載の組成物。
- 前記シールド塩が、クメンスルホン酸ナトリウムを含む、請求項1〜4のいずれか一項に記載の組成物。
- 前記シールド塩が、ホウ素を含まない、請求項1〜5のいずれか一項に記載の組成物。
- 消泡剤を更に含む、請求項1〜6のいずれか一項に記載の組成物。
- 前記カチオン性ポリマーの電荷密度が、0.05meq/gと25meq/gの間である、請求項1〜7のいずれか一項に記載の組成物。
- 前記カチオン性ポリマーの分子量が、10,000,000未満である、請求項1〜8のいずれか一項に記載の組成物。
- 前記カチオン性ポリマーの分子量が、500,000以下である、請求項1〜9のいずれか一項に記載の組成物。
- 前記組成物が、染料、乳白化要素、又は不溶性要素の不在下で、80%を超えるパーセント透過率(%T)を有する、請求項1〜10のいずれか一項に記載の組成物。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US201161558480P | 2011-11-11 | 2011-11-11 | |
US61/558,480 | 2011-11-11 | ||
PCT/US2012/063629 WO2013070559A1 (en) | 2011-11-11 | 2012-11-06 | Surface treatment compositions including shielding salts |
Publications (2)
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JP2014534323A JP2014534323A (ja) | 2014-12-18 |
JP5969042B2 true JP5969042B2 (ja) | 2016-08-10 |
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JP2014541145A Expired - Fee Related JP5969042B2 (ja) | 2011-11-11 | 2012-11-06 | シールド塩類を含有する表面処理組成物 |
JP2014541146A Expired - Fee Related JP5940675B2 (ja) | 2011-11-11 | 2012-11-06 | シールド塩類を含有する表面処理組成物 |
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JP2014541146A Expired - Fee Related JP5940675B2 (ja) | 2011-11-11 | 2012-11-06 | シールド塩類を含有する表面処理組成物 |
Country Status (9)
Country | Link |
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US (2) | US8541352B2 (ja) |
EP (2) | EP2776008B1 (ja) |
JP (2) | JP5969042B2 (ja) |
CN (2) | CN103930092B (ja) |
AR (2) | AR088798A1 (ja) |
BR (2) | BR112014011245A2 (ja) |
CA (2) | CA2853487C (ja) |
MX (2) | MX2014005562A (ja) |
WO (2) | WO2013070559A1 (ja) |
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2012
- 2012-11-06 WO PCT/US2012/063629 patent/WO2013070559A1/en active Application Filing
- 2012-11-06 JP JP2014541145A patent/JP5969042B2/ja not_active Expired - Fee Related
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EP2776008A1 (en) | 2014-09-17 |
US20130121946A1 (en) | 2013-05-16 |
CA2853192A1 (en) | 2013-05-16 |
WO2013070559A1 (en) | 2013-05-16 |
CN103930092A (zh) | 2014-07-16 |
CA2853487A1 (en) | 2013-05-16 |
EP2776009B1 (en) | 2017-02-15 |
AR088798A1 (es) | 2014-07-10 |
US20130123161A1 (en) | 2013-05-16 |
AR088676A1 (es) | 2014-06-25 |
BR112014010907A2 (pt) | 2017-05-16 |
MX2014005562A (es) | 2014-05-30 |
BR112014011245A2 (pt) | 2017-05-09 |
CA2853192C (en) | 2016-08-30 |
EP2776008B1 (en) | 2017-02-15 |
US8541352B2 (en) | 2013-09-24 |
US8546314B2 (en) | 2013-10-01 |
JP2014534323A (ja) | 2014-12-18 |
CA2853487C (en) | 2016-08-02 |
CN103917221A (zh) | 2014-07-09 |
JP2015502995A (ja) | 2015-01-29 |
CN103930092B (zh) | 2016-08-03 |
MX2014005560A (es) | 2014-05-30 |
WO2013070560A1 (en) | 2013-05-16 |
JP5940675B2 (ja) | 2016-06-29 |
CN103917221B (zh) | 2016-08-24 |
EP2776009A1 (en) | 2014-09-17 |
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