JP5956372B2 - Water treatment apparatus and water treatment method - Google Patents

Description

  The present invention relates to a water treatment apparatus and a water treatment method using a water treatment process for biological treatment using activated sludge.

An example of conventional sewage treatment is described in Patent Document 1. In this publication, in order to always maintain good quality of nitrogen and phosphorus in the treated water flowing out from the sewage treatment plant, C / N, which is a ratio of the nitrogen component and the organic component in the influent water flowing into the sewage treatment plant. It is disclosed that at least one of a circulation flow rate, a return flow rate, an aeration air flow rate, a carbon source injection rate, an excess sludge flow rate, a return water flow rate, and a primary sedimentation bypass valve in a sewage treatment plant is controlled using the ratio. .

  Patent Document 2 discloses a control system that measures the ammonia nitrogen concentration in the aerobic tank and adjusts the aeration air volume according to the deviation from the set value. A control method is disclosed in which an organic source is added according to the denitrification rate in the tank.

JP 2003-200190 A JP 2012-66231 A Japanese Patent Laid-Open No. 2001-170685

In the sewage treatment plant water quality control device described in Patent Document 1, since an anaerobic-anoxic-aerobic method is used, the anaerobic tank is installed in the front stage of the aerobic tank. By this arrangement, denitrifying bacteria can ingest organic matter prior to other aerobic heterotrophic bacteria, and denitrification performance can be ensured. However, it is necessary to circulate the nitrification liquid containing a large amount of NO ₃ -N from the aerobic tank in the subsequent stage to the anaerobic tank, and a great amount of power is required to return the aerobic tank to the anoxic tank. The air volume of the aeration means provided in the aerobic tank is controlled according to the quality of the raw water and the concentration of ammoniacal nitrogen in the aerobic tank. The air volume control of the aeration means in the aerobic tank is controlled by the aerobic tank. This is for the purpose of maintaining the nitrification performance in the process, and there is a problem that the denitrification performance in the anoxic tank into which the nitrification solution flows is not necessarily guaranteed.

  This situation is the same in the water treatment system described in Patent Document 2, and in the nitrogen-containing wastewater treatment apparatus described in Patent Document 3, since the denitrification performance is maintained by adding organic substances, the processing cost is increased. There is a risk of inviting.

  The present invention has been made in view of the above-described problems of the prior art, and its purpose is to treat the inflow of water treatment including sewage treatment while reducing power required for water treatment and reducing costs required for water treatment. Enables more stable nitrogen removal against fluctuations in water quality and flow rate.

In order to solve the above problems, the present invention provides at least a first aerobic tank into which raw water flows, an anoxic tank for treating effluent water from the first aerobic tank, and effluent water from the anoxic tank. A second aerobic tank for treating the water, a final sedimentation basin for precipitating the outflow water of the second aerobic tank, a first aeration means capable of aerating the inside of the first aerobic tank and controlling the air volume, and the second A second aeration means for aerating the inside of the aerobic tank, and guiding the outflow water of the second aerobic tank to the final settling basin without returning to the anaerobic tank and the first aerobic tank, An organic substance concentration measuring means for measuring the concentration and a nitrogen concentration measuring means for measuring the nitrogen concentration of the raw water are provided on the upstream side of the first aerobic tank and into the portion where the raw water flows, and the organic substance concentration measuring means and the wherein the organic substance concentration and the nitrogen concentration of the raw water of the raw water to nitrogen concentration measuring means detects the first aerobic tank A set value of the nitrification rate in the first aerobic tank is obtained based on the organic matter removal amount and the organic matter consumption amount per denitrification amount with respect to the nitrification amount, and the ammonia nitrogen concentration and nitrate concentration in the first aerobic tank The nitrification rate setting means for obtaining the ratio of the nitrate nitrogen concentration in the total amount of nitrogen concentration as a calculated value of the nitrification rate in the first aerobic tank, and the first aerobic obtained by the nitrification rate setting means A set value of the nitrification rate in the tank and a calculated value of the nitrification rate in the first aerobic tank, and a first aeration control means for controlling the air volume of the first aeration means according to the comparison result ; Is provided.

The present invention also provides a first aerobic tank into which raw water flows, an anaerobic tank for treating effluent water from the first aerobic tank, a second aerobic tank for treating effluent water from the anoxic tank, The water treatment method of the water treatment apparatus in which the final settling basin for precipitating the effluent water of the second aerobic tank is connected in series is an organic material for measuring the organic matter concentration of the raw water provided on the upstream side in the first aerobic tank Based on the amount of organic matter removed and the amount of organic matter consumed per amount of denitrification in the first aerobic tank , using the detected value of the concentration measuring means and the nitrogen concentration measuring means for measuring the nitrogen concentration of the raw water . A step of obtaining a set value of a nitrification rate in an aerobic tank; and a ratio of the nitrate nitrogen concentration in a total amount of ammonia nitrogen concentration and nitrate nitrogen concentration in the first aerobic tank to the first aerobic A step of obtaining a calculated value of the nitrification rate in the tank, and the obtained first preference The set value of the nitrification rate in the tank and the calculated value of the nitrification rate in the first aerobic tank are compared, and the air volume of the first aeration means provided in the first aerobic tank is determined according to the comparison result. And a step of controlling .

  According to the present invention, in water treatment including sewage treatment, an aerobic tank is disposed upstream and downstream of the anaerobic tank, and a return circuit from the downstream aerobic tank to the upstream anaerobic tank is provided. It is unnecessary, and at least the air volume of the aeration means in the upstream aerobic tank is variable. Thereby, the power in water treatment can be reduced and water treatment cost can be reduced. In addition, nitrogen removal can be more stably performed against fluctuations in water quality and flow rate of the treated water that flows in.

It is a block diagram which shows the structure of one Example of the water treatment apparatus which concerns on this invention. It is a flowchart of the air volume control of the 1st blower with which the water treatment apparatus shown in FIG. 1 is provided. It is a figure explaining the relationship between a nitrification rate and a denitrification rate. It is a figure explaining the relationship between a nitrification rate and a nitrogen removal rate. It is a block diagram which shows the structure of the modification of the water treatment apparatus shown in FIG. It is a block diagram which shows the structure of the other modification of the water treatment apparatus shown in FIG. It is a block diagram which shows the structure of the other Example of the water treatment apparatus which concerns on this invention. It is a flowchart of the air volume control of the 1st, 2nd blower with which the water treatment apparatus shown in FIG. 7 is provided.

  In a standard activated sludge method that uses organic matter removal in water treatment plants such as sewage treatment plants, aerobic heterotrophic bacteria ingest organic matter and remove organic matter in an aerobic state. Further, in order to further improve the quality of treated water, advanced treatment for removing nitrogen and phosphorus in addition to organic substances is also used. In these sewage treatment methods, biological nitrogen removal is realized by nitrification in an aerobic tank and denitrification in an oxygen-free tank.

That is, the nitrification step is performed in an aerobic state, and ammonia nitrogen (NH ₄ -N) in sewage is oxidized to nitrate nitrogen (NO ₃ -N) by nitrifying bacteria. On the other hand, a denitrification process is performed in an oxygen-free state, and NO ₃ —N is reduced to N ₂ gas by denitrifying bacteria. Since N ₂ gas is released into the atmosphere, nitrogen is removed from the liquid phase.

As a specific nitrogen removal method, there is a method in which an oxygen-free tank is installed at a subsequent stage of an aerobic tank, such as a nitrification endogenous denitrification method or an anaerobic-nitrification / endogenous denitrification method (AOAO method). These methods may or may not include an anaerobic tank for removing phosphorus before the first aerobic tank, but the reaction is performed in the order of the first aerobic tank, the anaerobic tank, and the second aerobic tank. A tank is installed, and NO ₃ -N nitrified in the first aerobic tank is denitrified in the subsequent oxygen-free tank. These methods do not require nitrification liquid circulation and can reduce power.

  Several embodiments of the water treatment apparatus according to the present invention in which the aerobic tanks are arranged on the upstream side and the downstream side of the anaerobic tank in this way and modifications thereof will be described below with reference to the drawings.

  FIG. 1 is a block diagram showing a configuration of an embodiment of a water treatment device Sa according to the present invention. In the water treatment device Sa, organic matter and nitrogen are removed using activated sludge by water treatment using a nitrification endogenous denitrification method. The water treatment device Sa includes a first aerobic tank 1, an oxygen-free tank 2, a second aerobic tank 3, and a final sedimentation tank 4 as main components.

  The first aerobic tank 1 has a first aeration unit 5 that diffuses into the first aerobic tank 1 and a first blower 6 as aeration means for supplying air to the first aeration unit 5. ing. In the first aerobic tank 1, the sewage 100 as the water to be treated and the return sludge 102 from the final sedimentation tank 4 flow.

  An anaerobic tank 2 is installed on the downstream side of the first aerobic tank 1, and the outflow water overflowing and flowing out of the first aerobic tank 1 connects the first aerobic tank 1 and the anaerobic tank 2. It flows into the anaerobic tank 2 from the flowing out water channel 21. A second aerobic tank 3 is installed on the downstream side of the anaerobic tank 2, and the outflow water that overflows and flows out of the anoxic tank 2 connects the anaerobic tank 2 and the second aerobic tank 3. It flows into the second aerobic tank 3 from the effluent water flow path 22. The second aerobic tank 3 has a second air diffuser 7 that diffuses into the second aerobic tank 3 and a second blower 8 as aeration means for supplying air to the second air diffuser 7. .

  On the downstream side of the second aerobic tank 3, a final sedimentation basin 4 in which effluent water overflowed from the second aerobic tank 3 flows in through the effluent water flow path 23 is installed. The final sedimentation tank 4 and the first aerobic tank 1 are communicated with each other through a flow path 800. A return pump 9 for returning the return sludge 102 generated in the final sedimentation basin 4 to the first aerobic tank 1 is disposed in the middle of the flow path 800.

  In the sewage treatment apparatus Sa configured as described above, various measuring means are provided in order to monitor the quality of the sewage 100 flowing in and the quality of the sewage being treated. That is, on the upstream side of the first aerobic tank 1, the organic matter concentration meter 10 for measuring the concentration of organic matter contained in the sewage 100 and the first nitrogen concentration for measuring the concentration of nitrogen contained in the sewage 100 are provided. A total of 11 are installed. The first aerobic tank 1 is provided with an oxidation-reduction potentiometer (ORP meter) 12 in order to evaluate the progress of nitrification in the first aerobic tank 1.

  The organic substance concentration meter 10 and the first nitrogen concentration meter 11 are connected to a nitrification rate setting unit 13 that sets the degree of nitrification progress. The nitrification rate setting unit 13 calculates and sets the optimum nitrification rate in the first aerobic tank 1 from the organic matter concentration and nitrogen concentration of the sewage 100 measured by the organic matter concentration meter 10 and the first nitrogen concentration meter 11. . The nitrification rate setting unit 13 and the ORP meter 12 are connected to the first aeration control means 14. The first aeration control means 14 controls the aeration air volume of the first blower 6 so that the nitrification rate of the first aerobic tank 1 measured by the ORP meter 12 satisfies the setting value set by the nitrification rate setting unit 13. .

In the sewage treatment apparatus Sa configured as described above, sewage treatment is performed as follows using the nitrification endogenous denitrification method. First, the sewage 100 flows into the first aerobic tank 1. In the first aerobic tank 1, NH ₄ -N in the sewage 100 is nitrified to NO ₃ -N by nitrifying bacteria in the activated sludge. At the same time, in the first aerobic tank 1, organic substances in the sewage 100 are removed by aerobic heterotrophic bacteria in the activated sludge.

Next, NO ₃ -N is denitrified by denitrifying bacteria in the anaerobic tank 2 from the effluent water that overflows from the first aerobic tank 1 and flows out to the anoxic tank 2. The outflow water overflowing from the anaerobic tank 2 and flowing out into the second aerobic tank 3 is aerated in the second aerobic tank 3 by bubbles generated from the second blower, and nitrogen bubbles are removed. Since the nitrogen bubbles are released to the atmosphere in the second aerobic tank 3, the activated sludge in the effluent flowing out to the final sedimentation basin 4 has almost no nitrogen bubbles attached thereto.

  Therefore, the trouble that activated sludge floats with nitrogen bubbles in the final sedimentation basin 4 can be suppressed. In the final sedimentation tank 4, the activated sludge brought from the second aerobic tank 3 is subjected to solid-liquid separation. The supernatant liquid generated by solid-liquid separation is discharged out of the system as treated water 101. On the other hand, the activated sludge separated in the final sedimentation basin 4 is returned to the first aerobic tank 1 as the return sludge 102 by the return pump 9.

  By the way, in the nitrification endogenous denitrification method so far, the first blower is operated at a constant air flow rate, or is operated at a constant flow rate ratio in which the ratio of the air flow rate of the first blower to the sewage inflow water amount is constant, One airflow control operation was performed according to the concentration of ammoniacal nitrogen remaining in the aerobic tank. Thereby, the air volume of the 1st blower was increased and the removal of organic substance was promoted with nitrification.

  However, when the concentration of the organic matter contained in the sewage 100 is lowered, the amount of organic matter is insufficient in the oxygen-free tank 2 and denitrification does not proceed sufficiently, and the denitrification performance is lowered. On the other hand, when there is little air volume of a 1st blower, removal of the organic substance in a 1st aerobic tank is suppressed. As a result, in the downstream anaerobic tank, the amount of organic matter is ensured, but in the first aerobic tank, nitrification is limited and nitrogen removal performance is reduced.

  Therefore, in the present embodiment, the nitrification rate in the first aerobic tank 1 is set so that the amount of denitrification in the anoxic tank 2 is maximized from the concentration of organic matter contained in the sewage 100 and the concentration of nitrogen. Then, the air volume of the first blower 6 is controlled according to the set value of the nitrification rate.

  FIG. 2 is a flowchart of the air volume control of the first blower 6. The air volume control of the first blower 6 using the first aeration control means 14 for controlling the first blower 6 will be described in detail with reference to this flowchart.

First, in step S101, an initial value (default value) of the air volume (q ₁ ) of the first blower 6 is determined in accordance with the amount of inflowing sewage 100 or the capacity of the sewage treatment device Sa. Next, in step S102, the organic substance concentration (C _CiN ) of the sewage 100 into which the organic substance concentration meter 10 provided on the upstream side of the first aerobic tank 1 flows is similarly converted to nitrogen provided on the upstream side of the first aerobic tank 1. The concentration meter 11 detects the nitrogen concentration (C _NiN ) of the sewage 100 into which it flows. The detected organic substance concentration (C _CiN ) and nitrogen concentration (C _NiN ) are input to the nitrification rate setting unit 13.

In step S103, the nitrification rate setting unit 13, organic matter concentration _{(C CIN)} of sewage 100 that has been input and nitrogen concentration _{(C NiN)} because, nitrification rate should be actually nitrification in a first aerobic tank 1 _{(R N -0} ) is set. Here, nitrification rate _{(R N)} is, NO ₃ -N concentration in the total amount of NH ₄ -N concentration in the first aerobic tank in 1 _{(C NH4)} and NO ₃ -N concentration _{(C NO3) (C NO3} ) and is expressed by equation (1).

An example of the set value (R _N-0 ) of the nitrification rate in the first aerobic tank 1 is shown in Formula (2).

Here, the contents of the variables and constants in the equation (2) are as follows.
a: Amount of organic matter removed relative to the amount of nitrification in the first aerobic tank 1,
C _N : Organic consumption per denitrification amount.

From the equation (2), the set value (R _N-0 ) of the nitrification rate is inversely proportional to the constant a, and directly proportional to the ratio of organic matter concentration to nitrogen concentration (C / N ratio) in the sewage 100. That is, when the ratio of nitrifying bacteria is high or when the organic matter concentration of the sewage 100 is high, the set value (R _N-0 ) of the nitrification rate is increased. On the other hand, when the ratio of nitrifying bacteria is low or when the organic matter concentration of the sewage 100 is low, the set value (R _N-0 ) of the nitrification rate is decreased.

In addition, the set value (R _N-0 ) of the nitrification rate represented by the formula (2) is a value when it is assumed that all organic substances contained in the sewage 100 are consumed in the following two steps. . That is, it is assumed that a part is consumed by aerobic heterotrophic bacteria in the first aerobic tank 1 and the rest is consumed during denitrification by denitrifying bacteria in the anaerobic tank 2. The set value (R _N-0 ) of the nitrification rate may be corrected based on the results of obtaining the behaviors of organic substances and nitrogen components in advance in actual sewage treatment.

In step S104, the first aeration control means 14 for controlling the air volume of the first blower 6 provided in the first aerobic tank 1 detects the ORP of the water to be treated in the first aerobic tank 1 detected by the ORP meter 12. Capture the detection value. Next, in step S105, the nitrification rate (R _N ) in the first aerobic tank 1 is calculated from the ORP value of the water to be treated in the first aerobic tank 1 detected by the ORP meter 12. The nitrification rate (R _N ) in the first aerobic tank 1 is calculated by the following equation (3).

Next, in step S106, the set value (R _N-0 ) of the nitrification rate in the first aerobic tank 1 is compared with the calculated value (R _N ) of the nitrification rate calculated from the detected value of the ORP meter 12. The first aeration control means 14 controls the air volume of the first blower 6 according to the comparison result.

Specifically, if the difference between the set value (R _N-0 ) and the calculated value (R _N ) of the nitrification rate in the first aerobic tank 1 is within the allowable range δ, the air volume of the first blower 6 is determined as the current amount. Do not change as is. On the other hand, if the difference between the set value (R _N-0 ) of the nitrification rate in the first aerobic tank 1 and the calculated value (R _N ) is larger than the allowable range δ, the air volume of the first blower 6 is reduced (set value). (R _N-0 ) <calculated value (R _N )) or the air volume of the first blower 6 is increased (when set value (R _N-0 )> calculated value (R _N )). Formula (4) shows a calculation formula for the change amount (Δq ₁ ) of the air volume (q ₁ ) of the first blower 6.

By controlling the air volume of the first blower 6 described above, the nitrogen removal performance can be maintained in the nitrogen removal using the nitrification endogenous denitrification method. That is, when the organic matter concentration in the sewage 100 is high, even if nitrification and removal of organic matter are promoted in the first aerobic tank 1, many organic substances that can be used for denitrifying bacteria remain in the anaerobic tank 2. Set the nitrification rate setting value (RN ₀ ) in the aerobic tank 1 high. On the other hand, when the organic matter concentration in the sewage 100 is low, if a large amount of organic matter is consumed in the first aerobic tank 1, the remaining amount of organic matter that can be used for denitrifying bacteria in the anaerobic tank 2 is reduced. The set value (R _N-0 ) of the nitrification rate in one aerobic tank 1 is set low, and the air volume of the first blower 6 is suppressed.

FIG. 3 is a graph showing the relationship between the denitrification rate (R _D ) and the nitrification rate (R _N ). FIG. 3 shows the relationship between the nitrification rate (R _N ) in the first aerobic tank 1 and the denitrification rate (R _D ) in the anaerobic tank 2 in the sewage treatment method using the AOAO method. This is a result of an experiment conducted by the inventors. It was confirmed that the denitrification rate (R _D ) decreases as the nitrification rate (R _N ) increases.

Here, the denitrification rate ( _RD ) is calculated from the total nitrogen concentration (TN _iN ) of the inflow water flowing into the anoxic tank 2 and the total nitrogen concentration (TN _Out ) of the effluent flowing out of the anoxic tank 2. Calculated. The calculation formula is shown in Formula (5).

FIG. 4 is a graph showing the results of experiments conducted by the present inventors on the relationship between the nitrification rate (R _N ) and the nitrogen removal rate of the entire sewage treatment system. This is a case where the same experimental means as shown in FIG. 3 is used. In FIG. 4, the nitrogen removal rate has a maximum value in the vicinity of R _N = 0.7 with respect to the nitrification rate (R _N ). Therefore, in this experiment, the air volume of the first blower 6 provided in the first aerobic tank 1 is controlled so that the nitrification rate (R _N ) in the first aerobic tank 1 is approximately 0.7. I understand that

  Thereby, also in the general sewage treatment apparatus which has an anoxic tank between the 1st, 2nd aerobic tank, by controlling the nitrification rate in a 1st aerobic tank to a specific value, in the whole sewage treatment apparatus It has been found that the nitrogen removal rate can be maximized. Since this specific value is generally not 100%, it is not necessary to operate the first blower with an excessive air volume, and the power consumption of the first blower can be reduced as compared with the conventional one.

  In the above example, the organic matter concentration of the sewage 100 was measured by the organic matter concentration meter 10. The organic concentration meter 10 may be any device that can directly or indirectly calculate the organic concentration such as an absorptiometer (UV meter), a total organic carbon meter, a BOD meter, or a COD meter. Similarly, the nitrogen concentration of the sewage 100 is measured by the first nitrogen concentration meter 11. The first nitrogen concentration meter 11 may be any device capable of calculating the nitrogen concentration, such as a total nitrogen concentration meter or an ammonia nitrogen concentration meter.

Further, instead of providing the organic substance concentration meter 10 or the first nitrogen concentration meter 11, based on the recording database the variation of concentration of organic substances of the sewage 100 _{(C CIN)} or nitrogen concentration _{(C NiN),} organic matter concentration of the sewage 100 (C The maximum value of _CiN ) or nitrogen concentration ( _CNiN ) may be estimated and used.

  In the said Example, although the nitrification rate of the 1st aerobic tank 1 was computed from the detected value of the ORP meter 12, instead of the ORP meter 12, the total nitrogen concentration meter, the ammonia nitrogen concentration meter, and the nitrate nitrogen concentration meter were used. Thus, the nitrification rate may be calculated.

FIG. 5 is a block diagram showing the configuration of a sewage treatment device Sb that is a modification of the above embodiment. In the above-described embodiment, the feed forward control that controls the air volume of the first blower 6 based on the quality of the sewage 100 is used. On the other hand, in this modification, the 2nd nitrogen concentration meter 15 is installed in the anoxic tank 2 with which the sewage treatment device Sb is provided or on the downstream side of the anoxic tank 2, and the measured value ( Feedback type control for controlling the air volume of the first blower 6 based on C _Nout ) is added. Since the feedback circuit is provided, the air flow control of the first blower can be performed more finely, and the operating cost of the sewage treatment apparatus Sb can be further reduced.

  FIG. 6 is a block diagram showing the configuration of a sewage treatment apparatus Sc that is another modification of the above embodiment. In the above embodiment, the sewage 100 was first flowing into the first aerobic tank 1. In this modification, an anaerobic tank 16 is installed on the upstream side of the first aerobic tank 1 to form a sewage treatment apparatus Sc using an anaerobic / nitrification endogenous denitrification method (AOAO method).

  Here, the anaerobic tank 16 is provided in order to ingest organic matter that is an energy source of phosphorus-removing bacteria in activated sludge. The phosphorus-removing bacteria ingest phosphorus from the sewage 100 in the first aerobic tank 1, the anoxic tank 2, and the second aerobic tank 3 disposed on the downstream side using the ingested organic matter. Therefore, if the anaerobic tank 16 is added to the nitrification endogenous denitrification method, phosphorus can also be removed.

  The operation control method of the first blower 6 in this modification using the AOAO method is the same as the operation control method of the first blower 6 in the first embodiment using the nitrification endogenous denitrification method. However, in the sewage treatment apparatus Sa using the nitrification endogenous denitrification method, the organic substance concentration meter 10 and the first nitrogen concentration meter 11 are installed on the upstream side of the first aerobic tank 1 to measure the quality of the sewage 100. It was. In the sewage treatment apparatus Sc of the present modification, in addition to the upstream side of the first aerobic tank 1, the organic substance concentration in the anaerobic tank 16 or in the flow path 20 that connects the anaerobic tank 16 and the first aerobic tank 1. It is also possible to install a total 10 and a first nitrogen concentration meter 11.

  According to this modification, as in the above embodiment, the consumption of organic matter in the first aerobic tank is controlled to set the nitrification rate in the first aerobic tank to a specific value, and the overall nitrogen removal rate of the sewage treatment apparatus Sc. Can be maximized, and the power consumption of the first blower can be reduced. Furthermore, phosphorus contained in sewage can also be removed.

FIG. 7 is a block diagram showing a configuration of another embodiment of the sewage treatment apparatus according to the present invention. The sewage treatment apparatus Sd shown in the present embodiment has a second aeration control means 17 for controlling the air volume of the second blower 8 in addition to the configuration of the sewage treatment apparatus Sa of the first embodiment shown in FIG. In order to improve the overall nitrogen removal rate of the sewage treatment device Sd, when nitrification is limited in the first aerobic tank 1 as shown in FIG. 4, NH ₄ -N that has not been nitrified in the first aerobic tank 1 is reduced. It is necessary to nitrify in the second aerobic tank 3. Therefore, in this embodiment, the air volume of the second blower 8 is controlled according to the nitrification rate of the inflow water in the first aerobic tank 1.

  FIG. 8 shows a flowchart of the air volume control of the first and second blowers 8. In this flowchart, the same steps as those in the flowchart of the first embodiment shown in FIG. 2 are assigned the same step numbers. As can be seen from FIG. 8, the control of the first blower 6 is the same as in the first embodiment. Therefore, in the following description, the control flow of the air volume of the second blower 8 by the second aeration control means 17 will be mainly described.

In step S103, a set value (R _N-0 ) of the nitrification rate of the first aerobic tank 1 is set. In steps S104 to S208, similarly to the first embodiment, the air volume of the first blower 6 is controlled so as to satisfy the set value (R _N-0 ) of the nitrification rate.

In step S209, using the set value of the nitrification rate (R _N-0 ) and the detected value of the nitrogen concentration (C _NiN ) of the sewage 100, the ammonia nitrogen concentration (C _NH4 ) is calculated. Formula (6) shows the formula for calculating the ammoniacal nitrogen concentration (C _NH4 ).

Next, in step S210, based on the ammonia nitrogen concentration (C _NH4 ) of the effluent flowing out from the first aerobic tank 1 calculated in step S209, the second aeration control means 17 uses the air volume of the second blower 8 ( q ₂ ) is calculated. An example of an expression for calculating the air volume (q ₂ ) of the second blower 8 is shown in Expression (7).

Examples of the second blower air volume control method include the following methods. The target value of the ammonia nitrogen concentration remaining in the effluent water and the treated water flowing out from the second aerobic tank 3 is set in advance. The difference between the set target value and the ammonia nitrogen concentration (C _NH4 ) of the effluent actually flowing out from the first aerobic tank 1 is taken. This difference is a nitrification reaction amount to be executed in the second aerobic tank 3. The nitrification reaction is NH ₄ ⁺ + 2O ₂ → NO ₃ ⁻ + H ₂ O + 2H ⁺ (NH ₄ −N → NO ₃ −N). _Therefore , if the ammoniacal nitrogen concentration (C _{NH 4} ) is known in advance, the nitrification reaction The amount of oxygen necessary for the second blower 8 can be determined in advance as the amount of oxygen necessary for the nitrification reaction. Here, the target value of the residual ammonia nitrogen concentration in the effluent flowing out of the second aerobic tank 3 and the treated water is a value that can flow out as treated water from the second aerobic tank 3 via the final sedimentation tank 4. Yes, a value obtained by multiplying an allowable limit value by a margin coefficient.

As other methods, a method using the set value (R _N-0 ) of the nitrification rate of the first aerobic tank 1 or the ammonia nitrogen concentration (C _NH4 ) in the effluent water flowing out from the first aerobic tank 1 is used. For example, a method of previously determining the air volume of the corresponding second blower can be used.

According to the present embodiment, even if the air volume of the first blower 6 is limited to suppress nitrification in the first aerobic tank 1, the air volume of the second blower 8 is controlled, so NH ₄ —N remaining in the inflowing water flowing into the air tank can be appropriately nitrified. Thus, compared with Example 1, can be further reduced NH ₄ -N ingredients, without any post-treatment, it is possible to drain the treated water into rivers and the like.

  The present invention is not limited to the above-described embodiments, and the scope of the present invention is indicated by the appended claims, and all modifications that fall within the scope of the claims are included in the present invention. Is.

  DESCRIPTION OF SYMBOLS 1 ... 1st aerobic tank, 2 ... Anoxic tank, 3 ... 2nd aerobic tank, 4 ... Final sedimentation tank, 5 ... 1st aeration part, 6 ... 1st blower (aeration means), 7 ... 2nd Air diffuser, 8 ... second blower (aeration means), 9 ... return pump, 10 ... organic concentration meter, 11 ... nitrogen concentration meter, 12 ... ORP meter (nitrification rate detection means), 13 ... nitrification rate setting unit (nitrification) (Rate setting means), 14 ... first aeration control means, 15 ... second nitrogen concentration meter, 16 ... anaerobic tank, 17 ... second aeration control means, 20 ... flow path, 21 to 23 ... effluent water flow path, 100 ... sewage DESCRIPTION OF SYMBOLS 101 ... Treated water, 102 ... Return sludge, 800 ... Transfer flow path of return sludge, Sa-Sd ... Water treatment apparatus.

Claims (12)

At least a first aerobic tank into which raw water flows, an anaerobic tank for treating effluent water from the first aerobic tank, a second aerobic tank for treating effluent water from the anaerobic tank, A final settling basin for precipitating the outflow water of the second aerobic tank, a first aeration means capable of aerating the inside of the first aerobic tank and controlling the air volume, and a second aeration means for aeration of the inside of the second aerobic tank And
An organic substance concentration measuring means for measuring the organic substance concentration of the raw water, introducing the effluent water of the second aerobic tank to the final sedimentation basin without returning to the anaerobic tank and the first aerobic tank, and the nitrogen concentration of the raw water A nitrogen concentration measuring means for measuring is provided at a portion upstream of the first aerobic tank and into which raw water flows,
Based on the organic matter concentration per unit of nitrification in the first aerobic tank and the organic matter consumption per denitrification amount from the organic matter concentration of raw water and the nitrogen concentration of raw water detected by the organic matter concentration measuring means and the nitrogen concentration measuring means The set value of the nitrification rate in the first aerobic tank is obtained, and the ratio of the nitrate nitrogen concentration to the total amount of ammonia nitrogen concentration and nitrate nitrogen concentration in the first aerobic tank is determined as the first aerobic tank. Nitrification rate setting means to obtain as a calculated value of nitrification rate in the air tank ,
The set value of the nitrification rate in the first aerobic tank obtained by the nitrification rate setting means and the calculated value of the nitrification rate in the first aerobic tank are compared, and the first value is determined according to the comparison result . by providing a first aeration control means for controlling the air volume of the aeration unit, the water treatment apparatus according to claim. When the difference between the set value of the nitrification rate in the first aerobic tank and the calculated value of the nitrification rate in the first aerobic tank is within an allowable range, the first aeration control unit The water treatment apparatus according to claim 1, wherein the air volume is kept as it is. When the set value of the nitrification rate in the first aerobic tank is smaller than the calculated value of the nitrification rate in the first aerobic tank, the first aeration control unit decreases the air volume of the first aeration unit. The water treatment apparatus according to claim 1 , wherein the water treatment apparatus is controlled as follows . When the set value of the nitrification rate in the first aerobic tank is larger than the calculated value of the nitrification rate in the first aerobic tank, the first aeration control unit increases the air volume of the first aeration unit. water treatment device according to claim 1, wherein the controller controls so. The first aerobic tank is provided with a nitrification rate detection means for detecting the nitrification rate in the first aerobic tank, and the nitrification rate detection means includes an ammonia nitrogen concentration meter, a nitrate nitrogen concentration meter, an oxidation-reduction potential. The water treatment device according to any one of claims 2 to 4, wherein the water treatment device is at least one of a total (ORP meter) . The second aeration means provided in the second aerobic tank is an aeration means capable of controlling the air volume, provided with a second aeration control means for controlling the air volume of the second aeration means, and provided in the first aerobic tank. in response to said nitrification rate detecting means detects the nitrification rate, according to claim 5, wherein the second aeration control means and controls the air volume of the second aeration means provided in the second aerobic tank Water treatment equipment. The anaerobic tank for guiding the raw water upstream of the first aerobic tank provided, wherein the effluent from the anaerobic tank guided to the first aerobic tank, water according to claim 1, characterized in also perform phosphorus removal Processing equipment . A second nitrogen concentration meter for detecting the nitrogen concentration of the effluent water flowing out from the anoxic tank is provided, and the first aeration control means is provided in the first aerobic tank according to the detection value of the second nitrogen concentration meter. The water treatment apparatus according to any one of claims 1 to 7, wherein an aeration amount of the first aeration means provided is controlled . A first aerobic tank into which raw water flows, an anaerobic tank for treating effluent water from the first aerobic tank, a second aerobic tank for treating effluent water from the anaerobic tank, and the second aerobic tank The water treatment method of the water treatment device connected in series with the final sedimentation basin that settles the effluent of
In the first aerobic tank, the detection value of the organic substance concentration measuring means for measuring the organic substance concentration of the raw water provided on the upstream side in the first aerobic tank and the nitrogen concentration measuring means for measuring the nitrogen concentration of the raw water is used. Obtaining a set value of the nitrification rate in the first aerobic tank based on the organic matter removal amount and the organic matter consumption amount per denitrification amount with respect to the nitrification amount of
Obtaining a ratio of the nitrate nitrogen concentration in the total amount of ammonia nitrogen concentration and nitrate nitrogen concentration in the first aerobic tank as a calculated value of the nitrification rate in the first aerobic tank;
The calculated set value of the nitrification rate in the first aerobic tank and the calculated value of the nitrification rate in the first aerobic tank are compared, and in the first aerobic tank according to the comparison result water treatment method you and a step of controlling the air volume of the first aeration means provided, the. The step of controlling the air volume of the first aeration means is performed when the difference between the set value of the nitrification rate in the first aerobic tank and the calculated value of the nitrification rate in the first aerobic tank is within an allowable range. The water treatment method according to claim 9, wherein the air volume of the first aeration unit is kept as it is . The step of controlling the air volume of the first aeration means is performed when the set value of the nitrification rate in the first aerobic tank is smaller than the calculated value of the nitrification rate in the first aerobic tank. The water treatment method according to claim 9, wherein the air volume is controlled to decrease . The step of controlling the air volume of the first aeration means is performed when the set value of the nitrification rate in the first aerobic tank is larger than the calculated value of the nitrification rate in the first aerobic tank. The water treatment method according to claim 9, wherein the air flow is controlled to increase .

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