JP5905429B2 - エンジニアリングプラスチック組成物及び製造方法 - Google Patents
エンジニアリングプラスチック組成物及び製造方法 Download PDFInfo
- Publication number
- JP5905429B2 JP5905429B2 JP2013204941A JP2013204941A JP5905429B2 JP 5905429 B2 JP5905429 B2 JP 5905429B2 JP 2013204941 A JP2013204941 A JP 2013204941A JP 2013204941 A JP2013204941 A JP 2013204941A JP 5905429 B2 JP5905429 B2 JP 5905429B2
- Authority
- JP
- Japan
- Prior art keywords
- engineering plastic
- sample
- weight
- plastic composition
- behenate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920006351 engineering plastic Polymers 0.000 title claims description 24
- 239000000203 mixture Substances 0.000 title claims description 20
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- -1 aliphatic monocarboxylic acids Chemical class 0.000 claims description 40
- 239000000344 soap Substances 0.000 claims description 16
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 13
- 238000002844 melting Methods 0.000 claims description 13
- 230000008018 melting Effects 0.000 claims description 13
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 12
- 230000032050 esterification Effects 0.000 claims description 11
- 238000005886 esterification reaction Methods 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 229920006122 polyamide resin Polymers 0.000 claims description 6
- 229920005862 polyol Polymers 0.000 claims description 6
- 150000003077 polyols Chemical class 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 5
- 230000005494 condensation Effects 0.000 claims description 5
- 150000005846 sugar alcohols Polymers 0.000 claims description 5
- 230000018044 dehydration Effects 0.000 claims description 4
- 238000006297 dehydration reaction Methods 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229920001225 polyester resin Polymers 0.000 claims description 3
- 239000004645 polyester resin Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229940125773 compound 10 Drugs 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical compound C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 claims 1
- 229940116224 behenate Drugs 0.000 description 16
- UKMSUNONTOPOIO-UHFFFAOYSA-M behenate Chemical compound CCCCCCCCCCCCCCCCCCCCCC([O-])=O UKMSUNONTOPOIO-UHFFFAOYSA-M 0.000 description 15
- 229940105990 diglycerin Drugs 0.000 description 15
- 229940061587 calcium behenate Drugs 0.000 description 14
- SMBKCSPGKDEPFO-UHFFFAOYSA-L calcium;docosanoate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCC([O-])=O SMBKCSPGKDEPFO-UHFFFAOYSA-L 0.000 description 14
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 14
- 238000003756 stirring Methods 0.000 description 14
- 239000000047 product Substances 0.000 description 12
- UKMSUNONTOPOIO-UHFFFAOYSA-N Behenic acid Natural products CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 10
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 10
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 239000000314 lubricant Substances 0.000 description 8
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 6
- 235000021357 Behenic acid Nutrition 0.000 description 6
- 229940116226 behenic acid Drugs 0.000 description 6
- 239000004721 Polyphenylene oxide Substances 0.000 description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
- 238000011109 contamination Methods 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 229920006380 polyphenylene oxide Polymers 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N Octacosancarbonsaeure Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 235000013872 montan acid ester Nutrition 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- FIASKJZPIYCESA-UHFFFAOYSA-L calcium;octacosanoate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O FIASKJZPIYCESA-UHFFFAOYSA-L 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- OBQVOBQZMOXRAL-UHFFFAOYSA-L magnesium;docosanoate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCC([O-])=O OBQVOBQZMOXRAL-UHFFFAOYSA-L 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920005668 polycarbonate resin Polymers 0.000 description 2
- 239000004431 polycarbonate resin Substances 0.000 description 2
- 238000006068 polycondensation reaction Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229930185605 Bisphenol Natural products 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920003189 Nylon 4,6 Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000008431 aliphatic amides Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- UNONODSVOQZQRL-UHFFFAOYSA-N butan-2-yl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OC(C)CC UNONODSVOQZQRL-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- HIAAVKYLDRCDFQ-UHFFFAOYSA-L calcium;dodecanoate Chemical compound [Ca+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O HIAAVKYLDRCDFQ-UHFFFAOYSA-L 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Description
表1、表2のように配合処方を変更し、シリンダー温度260℃に設定したスクリュー径15mmφの2軸押出機で溶融混練を行った。
Claims (5)
- エンジニアリングプラスチック100重量部に対して、(A)炭素数18〜28の脂肪族モノカルボン酸1種以上と3価以上の多価アルコールを脱水縮合して得られるポリオール1種以上からなるエステル化合物10〜90重量%と、(B)炭素数18〜28の脂肪族モノカルボン酸のアルカリ土類金属石鹸10〜90重量%を溶融混合又は溶融反応して得られる化合物を0.01〜10重量部添加してなることを特徴とするエンジニアリングプラスチック組成物の製造方法
- (A)のエステル化合物のエステル化度が80%以上である請求項1に記載のエンジニアリングプラスチック組成物の製造方法
- アルカリ土類金属石鹸に使用されるアルカリ土類金属がカルシウムである請求項1または請求項2に記載のエンジニアリングプラスチック組成物の製造方法
- エンジニアリングプラスチックが、ポリエステル樹脂又はポリアミド樹脂である請求項1〜3のいずれかに記載のエンジニアリングプラスチック組成物の製造方法
- (A)炭素数18〜28の脂肪族モノカルボン酸1種以上と3価以上の多価アルコールを脱水縮合して得られるポリオール1種以上からなるエステル化合物10〜90重量%と、(B)炭素数18〜28の脂肪族モノカルボン酸のアルカリ土類金属石鹸10〜90重量%を150℃以上に加熱して溶融混合又は溶融反応して得た化合物の0.01〜10重量部をエンジニアリングプラスチック100重量部に添加してなることを特徴とするエンジニアリングプラスチック組成物の製造方法
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013204941A JP5905429B2 (ja) | 2013-09-30 | 2013-09-30 | エンジニアリングプラスチック組成物及び製造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013204941A JP5905429B2 (ja) | 2013-09-30 | 2013-09-30 | エンジニアリングプラスチック組成物及び製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2015067782A JP2015067782A (ja) | 2015-04-13 |
JP5905429B2 true JP5905429B2 (ja) | 2016-04-20 |
Family
ID=52834802
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013204941A Active JP5905429B2 (ja) | 2013-09-30 | 2013-09-30 | エンジニアリングプラスチック組成物及び製造方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP5905429B2 (ja) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP7010009B2 (ja) * | 2018-01-16 | 2022-02-10 | 東ソー株式会社 | ポリアリーレンスルフィド組成物 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003020414A (ja) * | 2001-07-06 | 2003-01-24 | Katsuta Kako Kk | 含ハロゲン樹脂組成物 |
JP2004238516A (ja) * | 2003-02-06 | 2004-08-26 | Shin Etsu Chem Co Ltd | 射出成形用塩化ビニル系樹脂組成物及びそれを用いた成形体 |
US8071695B2 (en) * | 2004-11-12 | 2011-12-06 | Eastman Chemical Company | Polyeste blends with improved stress whitening for film and sheet applications |
EP2607418A1 (de) * | 2011-12-21 | 2013-06-26 | LANXESS Deutschland GmbH | Entformungsmittelkombinationen |
-
2013
- 2013-09-30 JP JP2013204941A patent/JP5905429B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
JP2015067782A (ja) | 2015-04-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101498591B1 (ko) | 액정 폴리에스테르 조성물 및 이를 사용한 성형 물품 | |
JP2013147641A (ja) | 離型剤の組合せ物 | |
JP2008174735A (ja) | ポリ乳酸樹脂組成物 | |
WO2012081381A1 (ja) | ポリブチレンテレフタレート樹脂組成物、及びそのペレット | |
JP4297510B2 (ja) | ポリ乳酸樹脂成形体の製造方法 | |
JP4530426B2 (ja) | ポリ乳酸樹脂射出成形体の製造方法 | |
JP5905429B2 (ja) | エンジニアリングプラスチック組成物及び製造方法 | |
JP5789349B1 (ja) | ポリブチレンテレフタレート樹脂組成物 | |
JP2009270090A (ja) | ポリ乳酸樹脂組成物 | |
JPH02208353A (ja) | 液晶性ポリエステル樹脂組成物 | |
JP7079699B2 (ja) | 計量性向上ポリブチレンテレフタレート樹脂ペレット | |
JP7121451B2 (ja) | 計量性向上ポリブチレンテレフタレート樹脂ペレット | |
CN104629354B (zh) | 一种尼龙用成核润滑剂及其制备方法 | |
WO2019189328A1 (ja) | 樹脂組成物およびそれからなるフィラメント状成形体 | |
JP4530427B2 (ja) | ポリ乳酸樹脂射出成形体の製造方法 | |
JPH06340807A (ja) | ポリアミド樹脂組成物および成型品の製造方法 | |
JP5107792B2 (ja) | ポリ乳酸樹脂射出成形体の製造方法 | |
WO2021140557A1 (ja) | 計量性向上ポリブチレンテレフタレート樹脂ペレット | |
JP5999686B2 (ja) | 耐熱性ポリ乳酸系成形体、およびその製造方法 | |
JP4160230B2 (ja) | 樹脂ペレット混合物およびこれを用いる成形品の製造方法 | |
JP6348363B2 (ja) | ポリアミド樹脂組成物ペレットおよび成形品 | |
CN100434475C (zh) | 阻燃性注塑制品 | |
JP5815061B2 (ja) | 射出成形品とその製造方法 | |
JP3596200B2 (ja) | ポリアミド樹脂組成物 | |
CN111171506B (zh) | 一种低内应力聚碳酸酯材料及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150210 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150330 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150508 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20151110 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160108 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20160308 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20160316 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5905429 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |