JP5864194B2 - 水性分散体 - Google Patents
水性分散体 Download PDFInfo
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- JP5864194B2 JP5864194B2 JP2011220487A JP2011220487A JP5864194B2 JP 5864194 B2 JP5864194 B2 JP 5864194B2 JP 2011220487 A JP2011220487 A JP 2011220487A JP 2011220487 A JP2011220487 A JP 2011220487A JP 5864194 B2 JP5864194 B2 JP 5864194B2
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- meth
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- acrylate
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- 239000006185 dispersion Substances 0.000 title claims description 54
- 239000002270 dispersing agent Substances 0.000 claims description 48
- 229920000642 polymer Polymers 0.000 claims description 46
- 229920005672 polyolefin resin Polymers 0.000 claims description 31
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 29
- 239000000178 monomer Substances 0.000 claims description 23
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000003365 glass fiber Substances 0.000 claims description 11
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 10
- 238000004513 sizing Methods 0.000 claims description 10
- -1 polypropylene Polymers 0.000 description 232
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 94
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 48
- 229920001577 copolymer Polymers 0.000 description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 30
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 26
- 239000004743 Polypropylene Substances 0.000 description 21
- 238000004519 manufacturing process Methods 0.000 description 21
- 229920001155 polypropylene Polymers 0.000 description 21
- 239000000126 substance Substances 0.000 description 18
- 150000005215 alkyl ethers Chemical class 0.000 description 17
- 238000006116 polymerization reaction Methods 0.000 description 17
- 238000000034 method Methods 0.000 description 11
- 229920002554 vinyl polymer Polymers 0.000 description 11
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 description 10
- 239000002253 acid Substances 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 239000003505 polymerization initiator Substances 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 239000006096 absorbing agent Substances 0.000 description 8
- 230000032683 aging Effects 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000004945 emulsification Methods 0.000 description 8
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 7
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 7
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 239000004480 active ingredient Substances 0.000 description 7
- 150000001414 amino alcohols Chemical class 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- 238000001816 cooling Methods 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical class C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000007822 coupling agent Substances 0.000 description 6
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 5
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 239000006087 Silane Coupling Agent Substances 0.000 description 5
- 239000003513 alkali Substances 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 229920000578 graft copolymer Polymers 0.000 description 5
- 238000005342 ion exchange Methods 0.000 description 5
- 239000000314 lubricant Substances 0.000 description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 5
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 4
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 4
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 description 4
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 239000012736 aqueous medium Substances 0.000 description 4
- 229920001400 block copolymer Polymers 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229960002887 deanol Drugs 0.000 description 4
- 239000012972 dimethylethanolamine Substances 0.000 description 4
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 235000019441 ethanol Nutrition 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 239000011151 fibre-reinforced plastic Substances 0.000 description 4
- 238000005984 hydrogenation reaction Methods 0.000 description 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 238000006386 neutralization reaction Methods 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- 229920005604 random copolymer Polymers 0.000 description 4
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- PSYGHMBJXWRQFD-UHFFFAOYSA-N 2-(2-sulfanylacetyl)oxyethyl 2-sulfanylacetate Chemical compound SCC(=O)OCCOC(=O)CS PSYGHMBJXWRQFD-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical class CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 239000004611 light stabiliser Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 3
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- LAQYHRQFABOIFD-UHFFFAOYSA-N 2-methoxyhydroquinone Chemical compound COC1=CC(O)=CC=C1O LAQYHRQFABOIFD-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- 125000003469 3-methylhexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229920005603 alternating copolymer Polymers 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 125000006165 cyclic alkyl group Chemical group 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
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- RAJUSMULYYBNSJ-UHFFFAOYSA-N prop-1-ene-1-sulfonic acid Chemical compound CC=CS(O)(=O)=O RAJUSMULYYBNSJ-UHFFFAOYSA-N 0.000 description 1
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- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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Landscapes
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
本発明で用いられるポリオレフィン樹脂(A)は、重量平均分子量が2万以上である。重量平均分子量が2万未満であると、得られる乾燥皮膜の強度が低くなる。該重量平均分子量は、好ましくは3万以上、より好ましくは5万以上である。また、重量平均分子量の上限は特に制限されないが、乳化性を考慮すれば、好ましくは40万以下であり、より好ましくは20万以下である。なお、ポリオレフィン樹脂(A)の重量平均分子量は、ゲル浸透クロマトグラフィ(GPC)により測定した値を採用するものとする。
本発明で用いられる高分子分散剤(B)は、不飽和カルボン酸(b−1)および(メタ)アクリルアミド単量体(b−2)を含む単量体成分を共重合して得られるポリマーである。高分子分散剤(B)の形態は特に限定されず、交互共重合体、ランダム共重合体、ブロック共重合体、グラフト共重合体のいずれであってもよい。
本発明の高分子分散剤の(b−1)成分である不飽和カルボン酸の例としては、例えば、アクリル酸、メタクリル酸、クロトン酸、イタコン酸、マレイン酸、無水マレイン酸、フマル酸、シトラコン酸、無水シトラコン酸、メサコン酸などが挙げられる。これらは単独でも、または2種以上組み合わせても用いることができる。これらの中でも、メタクリル酸、イタコン酸が好ましい。
本発明の高分子分散剤の(b−2)成分である(メタ)アクリルアミド単量体の例としては、例えば、(メタ)アクリルアミド、N−メチル(メタ)アクリルアミド、N−エチル(メタ)アクリルアミド、N−プロピル(メタ)アクリルアミド、N−n−ブチル(メタ)アクリルアミド、N−tert−ブチル(メタ)アクリルアミド、N−ブトキシメチル(メタ)アクリルアミド、N−イソプロピル(メタ)アクリルアミド、N−メチロール(メタ)アクリルアミド、N,N−ジメチル(メタ)アクリルアミド、N,N−ジエチル(メタ)アクリルアミド、N−メチル−N−エチル(メタ)アクリルアミド、N−ヒドロキシエチル(メタ)アクリルアミド、N−ヒドロキシエチル−N−メチル(メタ)アクリルアミド、(メタ)アクリロイルモルフォリンなどが挙げられる。これらは単独でも、または2種以上組み合わせても用いることができる。これらの中でも、分散剤の水溶液中での安定性を得る観点から、(メタ)アクリルアミド、N−ヒドロキシエチル(メタ)アクリルアミドが好ましい。
本発明で用いられる(メタ)アクリル酸エステルは特に制限されないが、エステル部分に炭素数1〜22の直鎖状、分枝状、または環状のアルキル基を有する(メタ)アクリル酸エステルが好ましい。
エチレン性不飽和単量体の例としては、例えば、1,3−ブタジエン、イソプレン等のジエン化合物;ビニルスルホン酸、メチルビニルスルホン酸、p−スチレンスルホン酸、(メタ)アリルスルホン酸、(メタ)アクリルスルホン酸、(メタ)アクリル酸−2−スルホン酸エチル、2−アクリルアミド−2−ヒドロキシプロパンスルホン酸等のエチレン性不飽和スルホン酸もしくはその塩;塩化ビニル、臭化ビニル、塩化ビニリデン等のハロゲン化ビニル単量体;スチレン、α−メチルスチレン、ビニルトルエン、2,4−ジメチルスチレン、ハロゲンで核置換されたスチレン、1−ビニルナフタレン、p−メチルスチレン、p−プロピルスチレン、p−シクロヘキシルスチレン、p−ドデシルスチレン等の芳香族ビニル単量体;酢酸ビニル等が挙げられる。
本発明の水性分散体は、上記の重量平均分子量が2万以上であるポリオレフィン樹脂(A)と、上記の高分子分散剤(B)とを含む。
(製造例1)
温度計、冷却器、攪拌機、および窒素導入管を備えた五つ口フラスコに、シクロヘキシルメタクリレート 100.5質量部、2−エチルヘキシルアクリレート 28.7質量部、メタクリル酸 71.7質量部、40質量%アクリルアミド水溶液 215.3質量部、ターピノーレン 1質量部、メルカプトプロピオン酸−2−エチルヘキシル 0.5質量部、およびエチレングリコールビスチオグリコレート 1.5質量部をそれぞれ仕込んだ。さらに、水 290.9質量部、イソプロピルアルコール 280質量部を仕込み、80℃まで加熱を行った。その後、重合開始剤としてアゾビスイソブチロニトリル 5.8質量部を加え、80℃で4時間重合反応を行った。反応終了後、イソプロピルアルコールを留去し、さらに水で濃度を調製することで、重量平均分子量が101,000である高分子分散剤1を濃度30質量%で含む水性分散液1(分散液の粘度:960mPa・s)を得た。
製造例1と同様の反応装置に、シクロヘキシルメタクリレート 57.2質量部、n−ブチルアクリレート 57.2質量部、メタクリル酸 85.8質量部、40質量%アクリルアミド水溶液 214.5質量部、ターピノーレン 2.9質量部、α−メチルスチレンダイマー 2.9質量部、およびトリメチロールプロパントリスチオグリコレート 2.6質量部をそれぞれ仕込んだ。さらに、水 291.3質量部、イソプロピルアルコール 280質量部を仕込み、80℃まで加熱を行った。その後、重合開始剤として過硫酸アンモニウム 5.7質量部を加え、80℃で4時間重合反応を行った。反応終了後、イソプロピルアルコールを留去し、さらに水で濃度を調製することで、重量平均分子量が101,000である高分子分散剤2を濃度30質量%で含む水性分散液2(分散液の粘度:860mPa・s)を得た。
製造例1と同様の反応装置に、シクロヘキシルメタクリレート 56.7質量部、n−ブチルメタクリレート 28.4質量部、2−エチルヘキシルアクリレート 28.4質量部、40質量%アクリルアミド水溶液 248質量部、イタコン酸 56.7質量部、p−スチレンスルホン酸ナトリウム 8.5質量部、ビニルスルホン酸ナトリウム 5.7質量部、ターピノーレン 2.8質量部、α−メチルスチレンダイマー 2.8質量部、2−メルカプトエタノール 2.8質量部、およびエチレングリコールビスチオグリコレート 1.2質量部をそれぞれ仕込んだ。さらに、水 271.2質量部、イソプロピルアルコール 280質量部を加え、80℃まで加熱を行った。その後、重合開始剤として過硫酸アンモニウム 5.7質量部を添加し、80℃で4時間反応を行った。反応終了後、イソプロピルアルコールを留去し、水で濃度調整を行うことにより、重量平均分子量が120,000である高分子分散剤3を濃度30質量%で含む水性分散液3(分散液の粘度:800mPa・s)を得た。
製造例1と同様の反応装置に、シクロヘキシルメタクリレートを34.2質量部、2−エチルヘキシルアクリレート 22.8質量部、40質量%アクリルアミド水溶液 320.3質量部、イタコン酸 71.2質量部、メタアリルスルホン酸ナトリウム 14.2部、ビニルスルホン酸ナトリウムを14.2部、ターピノーレン 0.6質量部、2−メルカプトエタノール 5.7質量部、エチレングリコールビスチオグリコレート 1.0質量部、水 227.9質量部、およびイソプロピルアルコール 280質量部を加え、さらに重合開始剤としてアゾイソブチロニトリルを5.7質量部添加し、40℃で溶解した。その後80℃に加熱し、重合反応を4時間行った。反応終了後、イソプロピルアルコールを留去し、水で濃度調整を行うことにより、重量平均分子量が140,000である高分子分散剤4を濃度30質量%で含む水性分散液4(分散液の粘度:700mPa・s)を得た。
製造例1と同様の反応装置に、シクロヘキシルメタクリレート 76.1質量部、2−エチルヘキシルアクリレート 25.1質量部、40質量%アクリルアミド水溶液 379.02質量部、イタコン酸 190.05質量部、2−エチルヘキシル−3−メルカプトプロピオネート 12.3質量部、p−スチレンスルホン酸ナトリウム 30質量部、β−メルカプトプロピオン酸 10.7質量部、水 1109.0質量部、およびイソプロピルアルコール 291.0質量部を加え、さらに重合開始剤としてアゾイソブチロニトリル 4.8質量部を添加し40℃で溶解した。その後80℃まで加熱し、4時間重合反応を行った。反応終了後、イソプロピルアルコールの留去を行い、水で濃度調整を行うことにより、重量平均分子量が150,000である高分子分散剤5を濃度30質量%で含む水性分散液5(分散液の粘度:800mPa・s)を得た。
製造例1と同様の反応装置に、シクロヘキシルメタクリレート 76.1質量部、2−エチルヘキシルアクリレート 25.1質量部、イタコン酸 190.1質量部、40質量%アクリルアミド水溶液 189.5質量部、2−エチルヘキシル−3−メルカプトプロピオネート 12質量部、p−スチレンスルホン酸ナトリウム 30.0質量部、β−メルカプトプロピオン酸 7.2質量部、水 463.0質量部、およびイソプロピルアルコール 291質量部を加え、さらに重合開始剤としてアゾイソブチロニトリル 4.8質量部を添加し40℃で溶解した。その後80℃まで加熱し、4時間重合反応を行った。反応終了後、イソプロピルアルコールの留去を行い、水で濃度調整を行うことにより、重量平均分子量が160,000である高分子分散剤6を濃度30質量%で含む水性分散液6(分散液の粘度:800mPa・s)を得た。
製造例1と同様の反応装置に、イタコン酸 129.7質量部、40質量%アクリルアミド水溶液 252.7質量部、β−メルカプトプロピオン酸 7.1質量部、水 342.4質量部、およびイソプロピルアルコール110.0質量部を加え、さらに重合開始剤としてアゾイソブチロニトリル 3.2質量部を添加し、40℃で溶解した。その後80℃まで加熱を行い、4時間重合反応行った。反応終了後、イソプロピルアルコールの留去を行い、水で濃度調整を行うことにより、重量平均分子量が180,000である高分子分散剤7を濃度30質量%で含む水性分散液7(分散液の粘度:1000mPa・s)を得た。
(実施例1)
攪拌機、温度計、温度コントローラーを備えた内容量1.0Lの乳化設備を有するオートクレーブに、無水マレイン酸変性ポリプロピレン(EASTMAN CHEMICAL COMPANY製「EASTMAN G3216」、重量平均分子量:60,000、酸価:16)170g、製造例5で製造した水性分散液5(高分子分散剤5の濃度:30質量%)25.6g、ポリオキシエチレンアルキルエーテル(青木油脂工業株式会社製、セフティカットLI−3085)16.8g、ポリオキシエチレンアルキルエーテル(東邦化学工業株式会社製、ペグノールO−4)18.4g、ドデシルベンゼンスルホン酸ソーダ(テイカ株式会社製、テイカパワーBN2060、有効成分:60質量%)6.5g、無水重亜硫酸ソーダ 0.7g、ジメチルエタノールアミン(日本乳化剤株式会社製、アミノアルコール 2Mabs)13.5g、イオン交換水 291.9gを加え、165℃まで加熱し500rpmで1時間熟成した。その後、140℃まで冷却し内圧を下げた後、別途用意した165℃のイオン交換水 170.0gを加え再度165℃まで加熱し、500rpmで1時間熟成した。熟成後40℃まで冷却し、無水マレイン酸変性ポリプロピレンの濃度が30質量%である水性分散体1を得た。
攪拌機、温度計、温度コントローラーを備えた内容量1.0Lの乳化設備を有するオートクレーブに、無水マレイン酸変性ポリプロピレン(EASTMAN CHEMICAL COMPANY製「EASTMAN G3216」、重量平均分子量:60,000、酸価:16)170g、製造例5で製造した水性分散液5(高分子分散剤5の濃度:30質量%)25.6g、ポリオキシエチレンアルキルエーテル(青木油脂工業株式会社製、セフティカットLI−3085)15.2g、ポリオキシエチレンアルキルエーテル(東邦化学工業株式会社製 ペグノールO−4)16.6g、ドデシルベンゼンスルホン酸ソーダ(テイカ株式会社製、テイカパワーBN2060、有効成分:60質量%)6.1g、無水重亜硫酸ソーダ 0.7g、ジメチルエタノールアミン(日本乳化剤株式会社製、アミノアルコール 2Mabs)5.8g、イオン交換水 286.3gを加え、165℃まで加熱し500rpmで1時間熟成した。その後、140℃まで冷却し内圧を下げた後、別途用意した165℃のイオン交換水 320gを導入し再度165℃まで加熱し、500rpmで1時間熟成した。熟成後40℃まで冷却し、無水マレイン酸変性ポリプロピレンの濃度が25質量%である水性分散体2を得た。
攪拌機、温度計、温度コントローラーを備えた内容量1.0Lの乳化設備を有するオートクレーブに無水マレイン酸変性ポリプロピレン(EASTMAN CHEMICAL COMPANY製「EASTMAN G3216」、重量平均分子量:60,000、酸価:16)170g、製造例6で製造した水性分散液6(高分子分散剤6の濃度:30質量%)28.4g、ポリオキシエチレンアルキルエーテル(青木油脂工業株式会社製、セフティカットLI−3085)16.8g、ポリオキシエチレンアルキルエーテル(東邦化学工業株式会社製 ペグノールO−4)18.4g、ドデシルベンゼンスルホン酸ソーダ(テイカ株式会社製、テイカパワーBN2060、有効成分:60質量%)6.5g、無水重亜硫酸ソーダ 0.7g、ジメチルエタノールアミン(日本乳化剤株式会社製、アミノアルコール 2Mabs)13.5g、およびイオン交換水 267.6g 165℃まで加熱し500rpmで1時間熟成した。その後、140℃まで冷却し内圧を下げた後、別途用意した165℃のイオン交換水 170.0gを導入し再度165℃まで加熱し、500rpmで1時間熟成した。熟成後40℃まで冷却し、無水マレイン酸変性ポリプロピレンの濃度が30質量%である水性分散体3を得た。
攪拌機、温度計、温度コントローラーを備えた内容量1.0Lの乳化設備を有するオートクレーブに、無水マレイン酸変性ポリプロピレン(EASTMAN CHEMICAL COMPANY製「EASTMAN G3216」、重量平均分子量:60,000、酸価:16)170g、製造例7で製造した水性分散液7(高分子分散剤7の濃度:30質量%)28.4g、ポリオキシエチレンアルキルエーテル(青木油脂工業株式会社製、セフティカットLI−3085)16.8g、ポリオキシエチレンアルキルエーテル(青木油脂工業株式会社製、ブラウノンEN−1502)18.4g、ドデシルベンゼンスルホン酸ソーダ(テイカ株式会社製、テイカパワーBN2060、有効成分:60質量%)6.5g、無水重亜硫酸ソーダ 0.7g、ジメチルエタノールアミン(日本乳化剤株式会社製、アミノアルコール 2Mabs)13.5g、およびイオン交換水 267.6gを加え、165℃まで加熱し500rpmで1時間熟成した。その後、140℃まで冷却し内圧を下げた後、別途用意した165℃のイオン交換水 170.0gを添加し再度165℃まで加熱し、500rpmで1時間熟成した。熟成後40℃まで冷却し、無水マレイン酸変性ポリプロピレンの濃度が30質量%である水性分散体4を得た。
攪拌機、温度計、温度コントローラーを備えた内容量1.0Lの乳化設備を有するオートクレーブに、無水マレイン酸変性ポリプロピレン(EASTMAN CHEMICAL COMPANY製「EASTMAN G3216」、重量平均分子量:60,000、酸価:16)170g、ポリオキシエチレンアルキルエーテル(青木油脂工業株式会社製、セフティカットLI−3085)18.9g、ポリオキシエチレンアルキルエーテル(東邦化学工業株式会社製、ペグノールO−4)20.6g、ドデシルベンゼンスルホン酸ソーダ(テイカ株式会社製、テイカパワーBN2060、有効成分:60質量%)6.1g、無水重亜硫酸ソーダ 0.7g、ジメチルエタノールアミン(日本乳化剤株式会社製、アミノアルコール 2Mabs)5.8g、イオン交換水 290.0gを加え、165℃まで加熱し500rpmで1時間熟成した。その後、140℃まで冷却し内圧を下げた後、別途用意した165℃のイオン交換水 320gを加え、再度165℃まで加熱し、500rpmで1時間熟成した。熟成後40℃まで冷却したが、未乳化物が多量に発生した。
攪拌機、温度計、温度コントローラーを備えた内容量1.0Lの乳化設備を有するオートクレーブに、無水マレイン酸変性ポリプロピレン(EASTMAN CHEMICAL COMPANY製「EASTMAN G3216」、重量平均分子量:60,000、酸価:16)170g、高分子分散剤(サートマー社製、スチレン−マレイン酸共重合体、SMA−1000)8.5g、ポリオキシエチレンアルキルエーテル(青木油脂工業株式会社製、セフティカットLI−3085)16.8g、ポリオキシエチレンアルキルエーテル(東邦化学工業株式会社製、ペグノールO−4)18.4g、ドデシルベンゼンスルホン酸ソーダ(テイカ株式会社製、テイカパワーBN2060、有効成分:60質量%)6.5g、無水重亜硫酸ソーダ 0.7g、ジメチルエタノールアミン(日本乳化剤株式会社製、アミノアルコール 2Mabs)13.5g、イオン交換水 311.8gを加え、165℃まで加熱し1時間熟成した。その後、140℃まで冷却し内圧を下げた後、別途用意した165℃のイオン交換水 170.0gを導入し再度165℃まで加熱し、1時間熟成した。熟成後40℃まで冷却したが、未乳化物が多量に発生した。
攪拌機、温度計、温度コントローラーを備えた内容量1.0Lの乳化設備を有するオートクレーブに、無水マレイン酸変性ポリプロピレン(EASTMAN CHEMICAL COMPANY製「EASTMAN G3216」、重量平均分子量:60,000、酸価:16)170g、高分子分散剤(サートマー社製、スチレン−マレイン酸共重合体、SMA−3000)8.5g、ポリオキシエチレンアルキルエーテル(青木油脂工業株式会社製、セフティカットLI−3085)16.8g、ポリオキシエチレンアルキルエーテル(東邦化学工業株式会社製、ペグノールO−4)18.4g、ドデシルベンゼンスルホン酸ソーダ(テイカ株式会社製、テイカパワーBN2060、有効成分:60質量%)6.5g、無水重亜硫酸ソーダ 0.7g、ジメチルエタノールアミン(日本乳化剤株式会社製、アミノアルコール 2Mabs)13.5g、イオン交換水 311.8gを加え、165℃まで加熱し1時間熟成した。その後、140℃まで冷却し内圧を下げた後、別途用意した165℃のイオン交換水 170.0gを加え165℃まで加熱し、1時間熟成した。熟成後40℃まで冷却したが、未乳化物が多量に発生した。
1.揮発残分
JIS K−6833(1980年)に準じて測定した。
JIS K−6833(1980年)に準じて測定した。
JIS Z−8803(1959年)に準じて測定した。
Particle sizing systems社製、NICOMP 380にて、散乱光の光強度分布より、樹脂粒子の平均粒径を測定した。
水性分散体製造後、常温(25℃)で1ヶ月保存した後の状態を、目視にて観察した。
Claims (3)
- 重量平均分子量が2万以上であるポリオレフィン樹脂(A)と、
不飽和カルボン酸(b−1) 3.5〜90質量部および(メタ)アクリルアミド単量体(b−2) 10〜96.5質量部(ただし、(b−1)と(b−2)との合計は100質量部)を含む単量体成分を共重合して得られる高分子分散剤(B)と、
を含む、水性分散体を含むガラス繊維用集束剤。 - 前記単量体成分が、さらに(メタ)アクリル酸エステルを(b−1)と(b−2)との合計100質量部に対して2〜90質量部含む、請求項1に記載のガラス繊維用集束剤。
- 前記ポリオレフィン樹脂(A)の含有量が前記水性分散体の全質量に対して10〜40質量%であり、
前記高分子分散剤(B)の含有量がポリオレフィン樹脂(A)の量を100質量部として、1〜35質量部である、請求項1または2に記載のガラス繊維用集束剤。
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