JP5860524B2 - 方ソーダ石を含む組成物およびポリエステル複合材料 - Google Patents
方ソーダ石を含む組成物およびポリエステル複合材料 Download PDFInfo
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- JP5860524B2 JP5860524B2 JP2014237576A JP2014237576A JP5860524B2 JP 5860524 B2 JP5860524 B2 JP 5860524B2 JP 2014237576 A JP2014237576 A JP 2014237576A JP 2014237576 A JP2014237576 A JP 2014237576A JP 5860524 B2 JP5860524 B2 JP 5860524B2
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- Prior art keywords
- sodalite
- acid
- glycol
- precursor
- composite material
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- 229910052665 sodalite Inorganic materials 0.000 title claims description 157
- 239000000203 mixture Substances 0.000 title claims description 81
- 239000002131 composite material Substances 0.000 title claims description 46
- 229920000728 polyester Polymers 0.000 title claims description 37
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 135
- 239000002245 particle Substances 0.000 claims description 72
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 69
- 239000002243 precursor Substances 0.000 claims description 44
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 26
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 22
- KBIWNQVZKHSHTI-UHFFFAOYSA-N 4-n,4-n-dimethylbenzene-1,4-diamine;oxalic acid Chemical compound OC(=O)C(O)=O.CN(C)C1=CC=C(N)C=C1 KBIWNQVZKHSHTI-UHFFFAOYSA-N 0.000 claims description 20
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Natural products OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 20
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 18
- -1 polyethylene terephthalate Polymers 0.000 claims description 15
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 12
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 10
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 9
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 9
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims description 8
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 8
- HCPOCMMGKBZWSJ-UHFFFAOYSA-N ethyl 3-hydrazinyl-3-oxopropanoate Chemical compound CCOC(=O)CC(=O)NN HCPOCMMGKBZWSJ-UHFFFAOYSA-N 0.000 claims description 8
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 5
- 229960005137 succinic acid Drugs 0.000 claims description 5
- 229920002961 polybutylene succinate Polymers 0.000 claims description 3
- 239000004631 polybutylene succinate Substances 0.000 claims description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 2
- 235000015165 citric acid Nutrition 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 claims description 2
- 239000011112 polyethylene naphthalate Substances 0.000 claims description 2
- 229920002215 polytrimethylene terephthalate Polymers 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 claims 1
- 239000007788 liquid Substances 0.000 description 91
- 239000000843 powder Substances 0.000 description 45
- 239000002253 acid Substances 0.000 description 37
- 238000000354 decomposition reaction Methods 0.000 description 30
- 238000006116 polymerization reaction Methods 0.000 description 18
- 239000000463 material Substances 0.000 description 17
- 239000010419 fine particle Substances 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 12
- 238000005886 esterification reaction Methods 0.000 description 12
- 238000005292 vacuum distillation Methods 0.000 description 12
- 239000000919 ceramic Substances 0.000 description 11
- 239000003054 catalyst Substances 0.000 description 10
- 239000004594 Masterbatch (MB) Substances 0.000 description 8
- 239000012153 distilled water Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000002270 dispersing agent Substances 0.000 description 7
- 239000000084 colloidal system Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000005498 polishing Methods 0.000 description 6
- 230000005855 radiation Effects 0.000 description 6
- 208000012886 Vertigo Diseases 0.000 description 5
- XCBJLAUUUJAELM-UHFFFAOYSA-N ethane-1,1-diol;hydrate Chemical compound O.CC(O)O XCBJLAUUUJAELM-UHFFFAOYSA-N 0.000 description 5
- 238000009987 spinning Methods 0.000 description 5
- 238000000635 electron micrograph Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 150000002334 glycols Chemical class 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 241000272814 Anser sp. Species 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 206010033675 panniculitis Diseases 0.000 description 2
- 210000004304 subcutaneous tissue Anatomy 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000005003 food packaging material Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000008279 sol Substances 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW103123532 | 2014-07-08 | ||
| TW103123532A TWI458683B (zh) | 2014-07-08 | 2014-07-08 | 含方鈉石組合物及聚酯複合材料 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2016017179A JP2016017179A (ja) | 2016-02-01 |
| JP5860524B2 true JP5860524B2 (ja) | 2016-02-16 |
Family
ID=52388343
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014237576A Active JP5860524B2 (ja) | 2014-07-08 | 2014-11-25 | 方ソーダ石を含む組成物およびポリエステル複合材料 |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP5860524B2 (zh) |
| TW (1) | TWI458683B (zh) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI702258B (zh) * | 2018-10-29 | 2020-08-21 | 豐陽產業科技股份有限公司 | 農用披覆材組成物、農用披覆材及農用披覆材的製造方法 |
| TWI845292B (zh) * | 2023-05-02 | 2024-06-11 | 豐陽產業科技股份有限公司 | 用於聚酯聚合反應的催化劑以及催化聚酯聚合反應的方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59213616A (ja) * | 1983-05-19 | 1984-12-03 | Nippon Kogaku Kk <Nikon> | 非晶質アルミノ珪酸塩及びその製法 |
| CN1131164A (zh) * | 1995-03-15 | 1996-09-18 | 天津石油化工公司研究所 | 远红外陶瓷聚酯的制备方法 |
| KR0155608B1 (ko) * | 1995-07-14 | 1998-12-01 | 박홍기 | 원적외선 방사성 폴리에스테르 섬유의 제조방법 |
| JP2006008843A (ja) * | 2004-06-25 | 2006-01-12 | Nippon Chem Ind Co Ltd | 非晶質アルミノシリケート粒子、絶縁性向上剤組成物及び絶縁性樹脂組成物 |
| CN101311390A (zh) * | 2008-06-11 | 2008-11-26 | 浙江恒逸集团有限公司 | 一种竹炭聚酯纤维的生产方法 |
| CN103789868B (zh) * | 2014-01-26 | 2016-04-06 | 东华大学 | 一种功能聚酯纤维的制备方法 |
-
2014
- 2014-07-08 TW TW103123532A patent/TWI458683B/zh active
- 2014-11-25 JP JP2014237576A patent/JP5860524B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2016017179A (ja) | 2016-02-01 |
| TWI458683B (zh) | 2014-11-01 |
| TW201441154A (zh) | 2014-11-01 |
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