JP5858772B2 - 粉末ガラスで充填された難燃性ポリアミド組成物 - Google Patents
粉末ガラスで充填された難燃性ポリアミド組成物 Download PDFInfo
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- JP5858772B2 JP5858772B2 JP2011281053A JP2011281053A JP5858772B2 JP 5858772 B2 JP5858772 B2 JP 5858772B2 JP 2011281053 A JP2011281053 A JP 2011281053A JP 2011281053 A JP2011281053 A JP 2011281053A JP 5858772 B2 JP5858772 B2 JP 5858772B2
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- 239000002210 silicon-based material Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- BPILDHPJSYVNAF-UHFFFAOYSA-M sodium;diiodomethanesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C(I)I BPILDHPJSYVNAF-UHFFFAOYSA-M 0.000 description 1
- HHJJPFYGIRKQOM-UHFFFAOYSA-N sodium;oxido-oxo-phenylphosphanium Chemical compound [Na+].[O-][P+](=O)C1=CC=CC=C1 HHJJPFYGIRKQOM-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000012899 standard injection Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- VLCLHFYFMCKBRP-UHFFFAOYSA-N tricalcium;diborate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]B([O-])[O-].[O-]B([O-])[O-] VLCLHFYFMCKBRP-UHFFFAOYSA-N 0.000 description 1
- NFMWFGXCDDYTEG-UHFFFAOYSA-N trimagnesium;diborate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]B([O-])[O-].[O-]B([O-])[O-] NFMWFGXCDDYTEG-UHFFFAOYSA-N 0.000 description 1
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
- NSBGJRFJIJFMGW-UHFFFAOYSA-N trisodium;stiborate Chemical compound [Na+].[Na+].[Na+].[O-][Sb]([O-])([O-])=O NSBGJRFJIJFMGW-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- GKXVJHDEWHKBFH-UHFFFAOYSA-N xylylenediamine group Chemical group C=1(C(=CC=CC1)CN)CN GKXVJHDEWHKBFH-UHFFFAOYSA-N 0.000 description 1
- AKJVMGQSGCSQBU-UHFFFAOYSA-N zinc azanidylidenezinc Chemical compound [Zn++].[N-]=[Zn].[N-]=[Zn] AKJVMGQSGCSQBU-UHFFFAOYSA-N 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 description 1
- BHTBHKFULNTCHQ-UHFFFAOYSA-H zinc;tin(4+);hexahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Zn+2].[Sn+4] BHTBHKFULNTCHQ-UHFFFAOYSA-H 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/40—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
A)5〜95重量%、好ましくは20〜90重量%、特に好ましくは30〜80重量%の熱可塑性樹脂と;
C)10〜300μm、好ましくは20〜150μm、特に好ましくは35〜80μmのd90を有する、5〜80重量%、好ましくは10〜60重量%、特に好ましくは15〜50重量%の非繊維質未発泡粉末ガラスと、
を含む組成物を提供する。
A)5〜95重量%、好ましくは20〜90重量%、特に好ましくは30〜80重量%の熱可塑性ポリアミドと;
B)0.01〜40重量%のシアヌル酸メラミンと;
C)10〜200μm、好ましくは20〜150μm、特に好ましくは35〜80μmのd90を有する、5〜80重量%、好ましくは10〜60重量%、特に好ましくは15〜40重量%の非繊維質未発泡粉末ガラスと、
を含む組成物を提供する。
C’)非繊維質未発泡粉末ガラスの量に基づいて好ましくは0.01重量%〜1.5重量%の量の少なくとも1つのアミノアルキルトリアルコキシシランでサイジングされている。
d10は、粒子の10%の粒度より大きい粒度であり、
d50は、粒子の50%の粒度(中央値)より大きい粒度であり、
d90は、粒子の90%の粒子より大きい粒度である。
E.1 5〜95重量%、好ましくは30〜90重量%の少なくとも1つのビニルモノマー、
E.2 95〜5重量%、好ましくは70〜10重量%の、10℃未満、好ましくは0℃未満、特に好ましくは−20℃未満のガラス遷移温度を有する1つ以上のグラフト塩基類、
の1つ以上のグラフトポリマーを包含する。
E.1.1 50〜99重量%のビニル芳香族化合物類および/または環置換ビニル芳香族化合物類、詳細にはスチレン、α−メチルスチレン、p−メチルスチレン、p−クロロスチレンおよび/または(C1−C8)−メタクリル酸アルキル類、詳細にはメタクリル酸メチル、メタクリル酸エチルと、
E.1.2 1〜50重量%のシアン化ビニル類、詳細には不飽和ニトリル類、例えばアクリロニトリルおよびメタクリロニトリル、および/または(C1−C8)−アルキル(メト)アクリル酸、詳細にはメタクリル酸メチル、メタクリル酸グリシジル、アクリル酸n−ブチル、アクリル酸tert−ブチル、および/または詳細には不飽和カルボン酸類の誘導体、詳細には無水物類およびイミド類、詳細には無水マレイン酸およびN−フェニルマレイミドと、
の混合物である。
(I) (X-(CH2)q)k-Si-(O-CrH2r+1)4-k
という一般式(I)のシラン化合物であり、式中
Xは、NH2−、カルボキシ−、HO−または
qは2〜10、好ましくは3〜4の整数であり、
rは1〜5、好ましくは1〜2の整数であり、かつ
kは1〜3の整数、好ましくは1である。
1.可塑化/溶融、
2.射出段階(投入手順)、
3.保持圧力段階(結晶化中の熱収縮を考慮に入れるため)、および
4.離型
− ランナーシステム
− 造形用インサート
− ベント
− 機械マウントおよび動力取込み口
− 離型システムおよび動作伝達装置
− 温度制御機構。
単軸スクリュー押出機および二軸スクリュー押出機ならびにそれぞれのサブグループ、
従来型単軸スクリュー押出機、搬送型単軸スクリュー押出機、
反転二軸スクリュー押出機および共回転二軸押出機。
1.押出機内での熱可塑性メルトの可塑化および提供、
2.押出し加工すべき異形材の横断面を有する較正器シェルを通した、熱可塑性メルトストランドの押出し加工、
3.較正用テーブル上での押出し加工済み異形材の冷却、
4.較正用テーブルの後ろの引取装置を用いた、異形材の前方輸送、
5.カッターシステム内での連続異形材の一定長切断、
6.一定長カットされた異形材の収集テーブル上での収集。
1.押出機内での熱可塑性メルトの可塑化および提供、
2.垂直方向下向きに流動させるためのメルトの偏向、および管状メルト「パリソン」の造形、
3.金型、つまり一般的に2つの半シェルで構成されたブロー金型を用いた、ヘッドの下に自由に懸垂したパリソンの閉込め、
4.ブロー成形用マンドレルまたは1つ以上のブロー成形用ピンの挿入、
5.プラスチックが冷却し硬化し成形部品の最終的形状をとるブロー成形用金型の冷却壁上へのプラスチックパリソンのブロー成形、
6.金型の開放およびブロー成形された部品の離型、
7.ブロー成形部品の両端部における、喰切られた「バリ」廃棄物の除去。
成分A:Durethan(登録商標)B26、Lanxess Germany GmbH、Leverkusen、Germany)
成分B:シアヌル酸メラミン(BASF、Ludwigshafen、Germany製のMelapur(登録商標)MC25)
成分C:Lanxess Germany GmbH、Leverkusen、Germany製のMF7900[各々の場合において粒子の表面積に基づいて、d90が54μm、d50が14μm、d10が2.4μmであり平均粒度が21μmである、トリエトキシ(3−アミノプロピル)シランサイズ剤C’)を約0.1重量%含むEガラスをベースとする非繊維質未発泡粉末ガラス]
成分E:衝撃改質剤(Paraloid(登録商標)EXL−2300、Dow Corning Corporation、Midland Michigan、USA)
成分F:離型剤(Clariant GmbH、Muttenz、Switzerland製のN,N’−エチレンビスステアリルアミドまたはLicowax(登録商標)E)
成分G1:ガラス短繊維CS7928、サイジングあり、Lanxess Germany GmbH、Leverkusen、Germany
成分G2:粉末ガラス短繊維MF7982、サイジングあり、Lanxess Germany GmbH、Leverkusen、Germany
成分G3:35μmの領域内の典型的粒度を有するガラスビーズ(アミノアルキルトリアルコキシシランサイズ剤0.2重量%)(Potters Industries Inc.、Valley Forge、USA製のPotters Spheriglass(登録商標)3000 CP 0302)
成分G4:顆粒化エキスパンデッドガラス(Poraver(登録商標)0.04、Bennert Poraver GmbH、Postbauer Heng、Germany)
成分G5:鉱物タルク粉末(Luzenac(登録商標)A60H、Luzenac Europe SAS、Toulouse、France)
成分G6:鉱物タルク粉末(Luzenac(登録商標)1445、Luzenac Europe SAS、Toulouse、France)
成分G7:鉱物ウォラストナイト(Nyglos M3、Nyco Minerals、New York、USA)
成分H1:熱安定剤(Irganox(登録商標)1098、BASF、Ludwigshafen、Germany)
Claims (19)
- A)5〜95重量%の熱可塑性ポリアミドと;
B)0.01〜40重量%のシアヌル酸メラミンと;
C)10〜200μmのd90を有する、5〜80重量%のEガラスをベースとする非繊維質未発泡粉末ガラスと、
を含む組成物。 - 前記非繊維質未発泡粉末ガラスのd90が20〜150μmであることを特徴とする、請求項1に記載の組成物。
- 前記非繊維質未発泡粉末ガラスのd90が35〜80μmであることを特徴とする、請求項1に記載の組成物。
- 成分C)が、C’)少なくとも1つのアミノアルキルトリアルコキシシランでサイジングされてもいることを特徴とする、請求項1〜3のいずれか一項に記載の組成物。
- D) 成分B)とは異なる0.01〜60重量%の、少なくとも1つのハロゲン含有難燃剤または少なくとも1つのハロゲンを含まない難燃剤をも含むことを特徴とする、請求項1〜4のいずれか一項に記載の組成物。
- E)0.01〜50重量%の少なくとも1つのエラストマー改質剤を含むことを特徴とする、請求項1〜5のいずれか一項に記載の組成物。
- F)0.01〜5重量%の少なくとも1つの潤滑剤および/または離型剤を含むことを特徴とする、請求項1〜6のいずれか一項に記載の組成物。
- G)0.01〜50重量%の成分C)以外の少なくとも1つの充填材を含むことを特徴とする、請求項1〜7のいずれか一項に記載の組成物。
- H)0.01〜20重量%の、UV安定剤、ガンマ放射線安定剤、加水分解安定剤、熱安定剤、帯電防止剤、乳化剤、核形成剤、可塑化剤、加工助剤、衝撃改質剤、染料および顔料から成る群から選択される少なくとも1つのさらなる添加剤を含むことを特徴とする、請求項1〜8のいずれか一項に記載の組成物。
- ポリアミド成分A)に加えて、少なくとも1つのさらなる熱可塑性ポリマーを含むことを特徴とする、請求項1〜9のいずれか一項に記載の組成物。
- 成分C)として使用すべき前記非繊維質未発泡粉末ガラスが、5未満の直径:厚み比を有する非円筒形の微粒子形状のものであることを特徴とする、請求項1〜10のいずれか一項に記載の組成物。
- 成分C)として使用すべき前記非繊維質未発泡粉末ガラスが、可能性のあるいずれかの気体封入による密度の減少を全く示さないことを特徴とする、請求項1〜11のいずれか一項に記載の組成物。
- 成分C)として使用すべき前記非繊維質未発泡粉末ガラスが、繊維質ガラスに典型的で、かつ長さ:直径比(L/D比)が5を超える円筒形または楕円形の横断面を含む幾何形状を示さないことを特徴とする、請求項1〜12のいずれか一項に記載の組成物。
- 成分C)が、ガラスの全ての成分に基づくK2Oの含有量が2重量%以下であるタイプのガラスを使用することを特徴とする、請求項1〜13のいずれか一項に記載の組成物。
- 成分A)にPA6またはPA66を使用することを特徴とする、請求項1〜14のいずれか一項に記載の組成物。
- 前記非繊維質未発泡粉末ガラスのd10がさらに0.6〜10μmであることを特徴とする、請求項1〜15のいずれか一項に記載の組成物。
- 前記非繊維質未発泡粉末ガラスのd50がさらに3〜50μmであることを特徴とする、請求項16に記載の組成物。
- 射出成形または押出し加工を介して請求項1〜17のいずれかに記載の組成物から得ることのできる製品。
- 自動車産業、電気産業、エレクトロニクス産業、電気通信産業またはコンピュータ産業、もしくはスポーツ、医療、家庭用品、建設産業または娯楽産業における、請求項18に記載の製品の使用。
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2010
- 2010-12-23 EP EP10196724A patent/EP2468809A1/de not_active Withdrawn
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2011
- 2011-12-19 US US13/329,421 patent/US20120165439A1/en not_active Abandoned
- 2011-12-21 ES ES11194962.4T patent/ES2475146T3/es active Active
- 2011-12-21 EP EP11194962.4A patent/EP2468810B1/de active Active
- 2011-12-21 PL PL11194962T patent/PL2468810T3/pl unknown
- 2011-12-22 JP JP2011281053A patent/JP5858772B2/ja active Active
- 2011-12-23 CN CN201110437845.3A patent/CN102585490B/zh active Active
- 2011-12-23 KR KR1020110140800A patent/KR101905184B1/ko active IP Right Grant
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US20120165439A1 (en) | 2012-06-28 |
CN102585490B (zh) | 2017-07-21 |
KR101905184B1 (ko) | 2018-10-05 |
PL2468810T3 (pl) | 2014-09-30 |
ES2475146T3 (es) | 2014-07-10 |
JP2012132010A (ja) | 2012-07-12 |
EP2468810A1 (de) | 2012-06-27 |
JP6153981B2 (ja) | 2017-06-28 |
CN102585490A (zh) | 2012-07-18 |
EP2468810B1 (de) | 2014-04-30 |
JP2015232148A (ja) | 2015-12-24 |
US20130296468A1 (en) | 2013-11-07 |
HRP20140728T1 (hr) | 2014-08-29 |
EP2468809A1 (de) | 2012-06-27 |
KR20120092001A (ko) | 2012-08-20 |
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