JP5743544B2 - 開放セルポリウレタン発泡体およびその製造プロセス - Google Patents

開放セルポリウレタン発泡体およびその製造プロセス Download PDF

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Publication number
JP5743544B2
JP5743544B2 JP2010524846A JP2010524846A JP5743544B2 JP 5743544 B2 JP5743544 B2 JP 5743544B2 JP 2010524846 A JP2010524846 A JP 2010524846A JP 2010524846 A JP2010524846 A JP 2010524846A JP 5743544 B2 JP5743544 B2 JP 5743544B2
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Prior art keywords
polyether
hydrogen
carbon atoms
polyurethane foam
aba
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JP2010524846A
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Japanese (ja)
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JP2010539280A (ja
JP2010539280A5 (enExample
Inventor
ブラウン，ウィリアム，エル
マトロック，ポール，エル
ミューラー，ルイス
ポンセ，ファブリス
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Momentive Performance Materials Inc
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Momentive Performance Materials Inc
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4816—Two or more polyethers of different physical or chemical nature mixtures of two or more polyetherpolyols having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/487—Polyethers containing cyclic groups
    • C08G18/4883—Polyethers containing cyclic groups containing cyclic groups having at least one oxygen atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0058—≥50 and <150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
JP2010524846A 2007-09-11 2008-09-08 開放セルポリウレタン発泡体およびその製造プロセス Active JP5743544B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/900,374 2007-09-11
US11/900,374 US8436064B2 (en) 2007-09-11 2007-09-11 Open-cell polyurethane foam and process for its manufacture
PCT/US2008/010488 WO2009035563A1 (en) 2007-09-11 2008-09-08 Open-cell polyurethane foam and process for its manufacture

Publications (3)

Publication Number Publication Date
JP2010539280A JP2010539280A (ja) 2010-12-16
JP2010539280A5 JP2010539280A5 (enExample) 2014-01-30
JP5743544B2 true JP5743544B2 (ja) 2015-07-01

Family

ID=40122316

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2010524846A Active JP5743544B2 (ja) 2007-09-11 2008-09-08 開放セルポリウレタン発泡体およびその製造プロセス

Country Status (6)

Country Link
US (1) US8436064B2 (enExample)
EP (1) EP2195362A1 (enExample)
JP (1) JP5743544B2 (enExample)
CN (1) CN101952340A (enExample)
TW (1) TWI437017B (enExample)
WO (1) WO2009035563A1 (enExample)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112012009266A2 (pt) * 2009-10-21 2016-05-31 Bayer Materialscience Ag hidrogel biodegradável
CN101962473B (zh) * 2010-10-28 2012-03-21 苏州新纶超净技术有限公司 耐磨耐水解抗静电聚氨酯材料的制备方法及其制成的鞋材
CN102432994B (zh) * 2011-09-28 2013-08-21 安徽佳泰矿业科技有限公司 聚氨酯基阻燃抗静电多纳米成份发泡材料及制备方法
CN102558831B (zh) * 2011-10-22 2013-11-06 上海华篷防爆科技有限公司 一种有机阻隔防爆材料及其制备方法
JP5878357B2 (ja) * 2011-12-15 2016-03-08 株式会社ブリヂストン ポリウレタンフォーム及びシートパッド
MX2014009720A (es) * 2012-02-24 2015-03-09 Gojo Ind Inc Composiciones alcoholicas espumables y antimicrobianas.
WO2015138719A1 (en) * 2014-03-12 2015-09-17 Keane Craig Patrick Solid self-leveling underlayment
US20160017086A1 (en) * 2014-04-30 2016-01-21 Honeywell International Inc. Flexible, open-cell thermoset foams and blowing agents and methods for making same
DE102014218635A1 (de) 2014-09-17 2016-03-17 Evonik Degussa Gmbh Herstellung von viskoelastischen Polyurethansystemen unter Einsatz von Blockpolymeren mit verknüpften Siloxanblöcken als Zellöffner
US20170306077A1 (en) * 2014-10-21 2017-10-26 Momentive Performance Materials Inc. Rigid polyurethane foams comprising modified phenolic resins additives
US10717872B2 (en) 2015-04-14 2020-07-21 Dow Toray Co., Ltd. Polyether-polysiloxane block copolymer composition, surfactant and foam stabilizer including same, polyurethane foam-forming composition, cosmetic, and preparation method thereof
BR112018008470A2 (pt) * 2015-11-05 2018-11-06 Basf Se processo para preparar polissiloxanos, e, usos de polidimetilsiloxanos lineares e de polissiloxanos.
DK3219738T3 (da) 2016-03-15 2020-07-27 Evonik Operations Gmbh Fremstilling af viskoelastiske polyurethansystemer under anvendelse af blokpolymerer med forbundne siloxanblokke som celleåbnere
WO2017204782A1 (en) * 2016-05-23 2017-11-30 Boral Ip Holdings (Australia) Pty Limited Filled polyurethane foam having tailored microstructures
JP7075347B2 (ja) 2016-10-18 2022-05-25 ダウ・東レ株式会社 ポリエーテル変性シリコーン組成物、それを含む界面活性剤、整泡剤、ポリウレタン発泡体形成組成物、化粧料およびその製造方法
US11447594B2 (en) * 2017-03-28 2022-09-20 Covestro Deutschland Ag Translucent polyurethane or polyisocyanurate foams
US10766998B2 (en) 2017-11-21 2020-09-08 Covestro Llc Flexible polyurethane foams
EP3732222B1 (en) * 2017-12-27 2022-08-17 Dow Global Technologies LLC Two-component solventless adhesive compositions for adhesion to polymeric barrier substrates
CN109593344A (zh) * 2018-10-30 2019-04-09 中投（天津）热力股份有限公司 一种阻燃保温发泡材料及其制备工艺
CN110591037B (zh) * 2019-11-01 2022-03-11 上海东大聚氨酯有限公司 全水软质阻燃低密度组合聚醚、聚氨酯泡沫、断桥铝及其制备方法
ES3037932T3 (en) * 2020-11-05 2025-10-08 Huntsman Int Llc Reactive formulations for forming a strong polyurethane-polyurea comprising water blown foam
US11572433B2 (en) 2021-03-12 2023-02-07 Covestro Llc In-situ formed polyols, a process for their preparation, foams prepared from these in-situ formed polyols and a process for their preparation
JP7634392B2 (ja) * 2021-03-19 2025-02-21 株式会社イノアックコーポレーション ポリウレタンフォーム
US11718705B2 (en) 2021-07-28 2023-08-08 Covestro Llc In-situ formed polyether polyols, a process for their preparation, and a process for the preparation of polyurethane foams

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE536296A (enExample) * 1954-03-22
IT535373A (enExample) * 1954-06-10
US2846458A (en) * 1956-05-23 1958-08-05 Dow Corning Organosiloxane ethers
BE595337A (enExample) * 1957-09-25
NL245622A (enExample) 1958-11-24
CA695633A (en) * 1961-07-31 1964-10-06 A. Haluska Loren Siloxane glycol branch copolymers
FR1370886A (fr) 1962-09-14 1964-08-28 Dow Corning Polyéther-uréthanes organosiloxanes
US3246048A (en) * 1962-09-14 1966-04-12 Dow Corning Organosiloxane-polyether urethanes
BE727244A (enExample) * 1968-03-16 1969-07-01
US3629310A (en) * 1969-08-28 1971-12-21 Union Carbide Corp Organo-siloxane-oxyalkylene block copolymers
US3654195A (en) * 1970-05-27 1972-04-04 Gen Electric Process for the preparation of polyurethane foams in the presence of an organopolysiloxane copolymer surfactant
US3836560A (en) * 1971-03-08 1974-09-17 Union Carbide Corp Organosilicone polymers
US3957843A (en) * 1971-03-30 1976-05-18 Union Carbide Corporation Non-isomerizable olefinic polyoxyalkylene polymers and siloxane-polyoxyalkylene copolymer derivatives thereof
US3793237A (en) * 1972-08-11 1974-02-19 Union Carbide Corp Open-cell rigid polyether polyurethane foam
JPS528879B2 (enExample) * 1972-09-18 1977-03-11
US3980688A (en) * 1974-09-20 1976-09-14 Union Carbide Corporation Polysiloxane-polyoxyalkylene block copolymers
US4855329A (en) * 1987-08-31 1989-08-08 Union Carbide Corporation Polysiloxane-polyoxyalkylene terpolymers for polyurethane foam manufacture
DE3829583A1 (de) * 1988-09-01 1990-03-08 Bayer Ag Verfahren zur herstellung von formkunststoffen auf polyurethan-basis und deren verwendung als schuhsohlen
JPH03275741A (ja) * 1990-03-26 1991-12-06 Kao Corp 吸収性ポリウレタンフォームの製造法
US5145879A (en) * 1990-12-31 1992-09-08 Union Carbide Chemicals & Plastics Technology Corporation Surfactants for manufacture of urethane foams
US5192812A (en) * 1991-02-12 1993-03-09 Union Carbide Chemicals & Plastics Technology Corporation Cell openers for urethane foam surfactants
DE19836260A1 (de) * 1998-08-11 2000-02-24 Wacker Chemie Gmbh Lineare Polyether-Polysiloxan-Copolymere, deren Herstellung und Verwendung
US6239186B1 (en) * 1999-10-28 2001-05-29 Air Products And Chemicals, Inc. Silicone surfactants for the production of open cell polyurethane flexible foams
US6528557B2 (en) * 2001-02-02 2003-03-04 Xerox Corporation Inks comprising linear Asbs‘A’ block copolymers of alkylene oxide and siloxane
US20070060661A1 (en) * 2005-09-15 2007-03-15 Clark Roger C High mobility low emission surfactants for polyurethane foams
EP1911781A1 (en) 2006-10-12 2008-04-16 Arizona Chemical Company Oil absorbing foam

Also Published As

Publication number Publication date
EP2195362A1 (en) 2010-06-16
CN101952340A (zh) 2011-01-19
WO2009035563A1 (en) 2009-03-19
US8436064B2 (en) 2013-05-07
US20090069457A1 (en) 2009-03-12
JP2010539280A (ja) 2010-12-16
TWI437017B (zh) 2014-05-11
TW200932774A (en) 2009-08-01

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