TWI437017B - 開孔式聚胺甲酸酯發泡體及其製法 - Google Patents
開孔式聚胺甲酸酯發泡體及其製法 Download PDFInfo
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- TWI437017B TWI437017B TW097134702A TW97134702A TWI437017B TW I437017 B TWI437017 B TW I437017B TW 097134702 A TW097134702 A TW 097134702A TW 97134702 A TW97134702 A TW 97134702A TW I437017 B TWI437017 B TW I437017B
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- Prior art keywords
- polyether
- hydrogen
- open
- block
- polyurethane foam
- Prior art date
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- 229920005830 Polyurethane Foam Polymers 0.000 title claims description 84
- 239000011496 polyurethane foam Substances 0.000 title claims description 84
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- 239000001257 hydrogen Substances 0.000 claims description 44
- 229910052739 hydrogen Inorganic materials 0.000 claims description 44
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 38
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- VYSYZMNJHYOXGN-UHFFFAOYSA-N ethyl n-aminocarbamate Chemical compound CCOC(=O)NN VYSYZMNJHYOXGN-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000005337 ground glass Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- BTSIZIIPFNVMHF-UHFFFAOYSA-N nor-leaf alcohol Natural products CCC=CCO BTSIZIIPFNVMHF-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- LQAVWYMTUMSFBE-UHFFFAOYSA-N pent-4-en-1-ol Chemical compound OCCCC=C LQAVWYMTUMSFBE-UHFFFAOYSA-N 0.000 description 1
- ZHZCYWWNFQUZOR-UHFFFAOYSA-N pent-4-en-2-ol Chemical compound CC(O)CC=C ZHZCYWWNFQUZOR-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 238000001782 photodegradation Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- ZUFQCVZBBNZMKD-UHFFFAOYSA-M potassium 2-ethylhexanoate Chemical compound [K+].CCCCC(CC)C([O-])=O ZUFQCVZBBNZMKD-UHFFFAOYSA-M 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- BYKRNSHANADUFY-UHFFFAOYSA-M sodium octanoate Chemical compound [Na+].CCCCCCCC([O-])=O BYKRNSHANADUFY-UHFFFAOYSA-M 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4816—Two or more polyethers of different physical or chemical nature mixtures of two or more polyetherpolyols having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/487—Polyethers containing cyclic groups
- C08G18/4883—Polyethers containing cyclic groups containing cyclic groups having at least one oxygen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0058—≥50 and <150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/900,374 US8436064B2 (en) | 2007-09-11 | 2007-09-11 | Open-cell polyurethane foam and process for its manufacture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200932774A TW200932774A (en) | 2009-08-01 |
| TWI437017B true TWI437017B (zh) | 2014-05-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW097134702A TWI437017B (zh) | 2007-09-11 | 2008-09-10 | 開孔式聚胺甲酸酯發泡體及其製法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8436064B2 (enExample) |
| EP (1) | EP2195362A1 (enExample) |
| JP (1) | JP5743544B2 (enExample) |
| CN (1) | CN101952340A (enExample) |
| TW (1) | TWI437017B (enExample) |
| WO (1) | WO2009035563A1 (enExample) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112012009266A2 (pt) * | 2009-10-21 | 2016-05-31 | Bayer Materialscience Ag | hidrogel biodegradável |
| CN101962473B (zh) * | 2010-10-28 | 2012-03-21 | 苏州新纶超净技术有限公司 | 耐磨耐水解抗静电聚氨酯材料的制备方法及其制成的鞋材 |
| CN102432994B (zh) * | 2011-09-28 | 2013-08-21 | 安徽佳泰矿业科技有限公司 | 聚氨酯基阻燃抗静电多纳米成份发泡材料及制备方法 |
| CN102558831B (zh) * | 2011-10-22 | 2013-11-06 | 上海华篷防爆科技有限公司 | 一种有机阻隔防爆材料及其制备方法 |
| JP5878357B2 (ja) * | 2011-12-15 | 2016-03-08 | 株式会社ブリヂストン | ポリウレタンフォーム及びシートパッド |
| MX2014009720A (es) * | 2012-02-24 | 2015-03-09 | Gojo Ind Inc | Composiciones alcoholicas espumables y antimicrobianas. |
| WO2015138719A1 (en) * | 2014-03-12 | 2015-09-17 | Keane Craig Patrick | Solid self-leveling underlayment |
| US20160017086A1 (en) * | 2014-04-30 | 2016-01-21 | Honeywell International Inc. | Flexible, open-cell thermoset foams and blowing agents and methods for making same |
| DE102014218635A1 (de) | 2014-09-17 | 2016-03-17 | Evonik Degussa Gmbh | Herstellung von viskoelastischen Polyurethansystemen unter Einsatz von Blockpolymeren mit verknüpften Siloxanblöcken als Zellöffner |
| US20170306077A1 (en) * | 2014-10-21 | 2017-10-26 | Momentive Performance Materials Inc. | Rigid polyurethane foams comprising modified phenolic resins additives |
| US10717872B2 (en) | 2015-04-14 | 2020-07-21 | Dow Toray Co., Ltd. | Polyether-polysiloxane block copolymer composition, surfactant and foam stabilizer including same, polyurethane foam-forming composition, cosmetic, and preparation method thereof |
| BR112018008470A2 (pt) * | 2015-11-05 | 2018-11-06 | Basf Se | processo para preparar polissiloxanos, e, usos de polidimetilsiloxanos lineares e de polissiloxanos. |
| DK3219738T3 (da) | 2016-03-15 | 2020-07-27 | Evonik Operations Gmbh | Fremstilling af viskoelastiske polyurethansystemer under anvendelse af blokpolymerer med forbundne siloxanblokke som celleåbnere |
| WO2017204782A1 (en) * | 2016-05-23 | 2017-11-30 | Boral Ip Holdings (Australia) Pty Limited | Filled polyurethane foam having tailored microstructures |
| JP7075347B2 (ja) | 2016-10-18 | 2022-05-25 | ダウ・東レ株式会社 | ポリエーテル変性シリコーン組成物、それを含む界面活性剤、整泡剤、ポリウレタン発泡体形成組成物、化粧料およびその製造方法 |
| US11447594B2 (en) * | 2017-03-28 | 2022-09-20 | Covestro Deutschland Ag | Translucent polyurethane or polyisocyanurate foams |
| US10766998B2 (en) | 2017-11-21 | 2020-09-08 | Covestro Llc | Flexible polyurethane foams |
| EP3732222B1 (en) * | 2017-12-27 | 2022-08-17 | Dow Global Technologies LLC | Two-component solventless adhesive compositions for adhesion to polymeric barrier substrates |
| CN109593344A (zh) * | 2018-10-30 | 2019-04-09 | 中投(天津)热力股份有限公司 | 一种阻燃保温发泡材料及其制备工艺 |
| CN110591037B (zh) * | 2019-11-01 | 2022-03-11 | 上海东大聚氨酯有限公司 | 全水软质阻燃低密度组合聚醚、聚氨酯泡沫、断桥铝及其制备方法 |
| ES3037932T3 (en) * | 2020-11-05 | 2025-10-08 | Huntsman Int Llc | Reactive formulations for forming a strong polyurethane-polyurea comprising water blown foam |
| US11572433B2 (en) | 2021-03-12 | 2023-02-07 | Covestro Llc | In-situ formed polyols, a process for their preparation, foams prepared from these in-situ formed polyols and a process for their preparation |
| JP7634392B2 (ja) * | 2021-03-19 | 2025-02-21 | 株式会社イノアックコーポレーション | ポリウレタンフォーム |
| US11718705B2 (en) | 2021-07-28 | 2023-08-08 | Covestro Llc | In-situ formed polyether polyols, a process for their preparation, and a process for the preparation of polyurethane foams |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE536296A (enExample) * | 1954-03-22 | |||
| IT535373A (enExample) * | 1954-06-10 | |||
| US2846458A (en) * | 1956-05-23 | 1958-08-05 | Dow Corning | Organosiloxane ethers |
| BE595337A (enExample) * | 1957-09-25 | |||
| NL245622A (enExample) | 1958-11-24 | |||
| CA695633A (en) * | 1961-07-31 | 1964-10-06 | A. Haluska Loren | Siloxane glycol branch copolymers |
| FR1370886A (fr) | 1962-09-14 | 1964-08-28 | Dow Corning | Polyéther-uréthanes organosiloxanes |
| US3246048A (en) * | 1962-09-14 | 1966-04-12 | Dow Corning | Organosiloxane-polyether urethanes |
| BE727244A (enExample) * | 1968-03-16 | 1969-07-01 | ||
| US3629310A (en) * | 1969-08-28 | 1971-12-21 | Union Carbide Corp | Organo-siloxane-oxyalkylene block copolymers |
| US3654195A (en) * | 1970-05-27 | 1972-04-04 | Gen Electric | Process for the preparation of polyurethane foams in the presence of an organopolysiloxane copolymer surfactant |
| US3836560A (en) * | 1971-03-08 | 1974-09-17 | Union Carbide Corp | Organosilicone polymers |
| US3957843A (en) * | 1971-03-30 | 1976-05-18 | Union Carbide Corporation | Non-isomerizable olefinic polyoxyalkylene polymers and siloxane-polyoxyalkylene copolymer derivatives thereof |
| US3793237A (en) * | 1972-08-11 | 1974-02-19 | Union Carbide Corp | Open-cell rigid polyether polyurethane foam |
| JPS528879B2 (enExample) * | 1972-09-18 | 1977-03-11 | ||
| US3980688A (en) * | 1974-09-20 | 1976-09-14 | Union Carbide Corporation | Polysiloxane-polyoxyalkylene block copolymers |
| US4855329A (en) * | 1987-08-31 | 1989-08-08 | Union Carbide Corporation | Polysiloxane-polyoxyalkylene terpolymers for polyurethane foam manufacture |
| DE3829583A1 (de) * | 1988-09-01 | 1990-03-08 | Bayer Ag | Verfahren zur herstellung von formkunststoffen auf polyurethan-basis und deren verwendung als schuhsohlen |
| JPH03275741A (ja) * | 1990-03-26 | 1991-12-06 | Kao Corp | 吸収性ポリウレタンフォームの製造法 |
| US5145879A (en) * | 1990-12-31 | 1992-09-08 | Union Carbide Chemicals & Plastics Technology Corporation | Surfactants for manufacture of urethane foams |
| US5192812A (en) * | 1991-02-12 | 1993-03-09 | Union Carbide Chemicals & Plastics Technology Corporation | Cell openers for urethane foam surfactants |
| DE19836260A1 (de) * | 1998-08-11 | 2000-02-24 | Wacker Chemie Gmbh | Lineare Polyether-Polysiloxan-Copolymere, deren Herstellung und Verwendung |
| US6239186B1 (en) * | 1999-10-28 | 2001-05-29 | Air Products And Chemicals, Inc. | Silicone surfactants for the production of open cell polyurethane flexible foams |
| US6528557B2 (en) * | 2001-02-02 | 2003-03-04 | Xerox Corporation | Inks comprising linear Asbs‘A’ block copolymers of alkylene oxide and siloxane |
| US20070060661A1 (en) * | 2005-09-15 | 2007-03-15 | Clark Roger C | High mobility low emission surfactants for polyurethane foams |
| EP1911781A1 (en) | 2006-10-12 | 2008-04-16 | Arizona Chemical Company | Oil absorbing foam |
-
2007
- 2007-09-11 US US11/900,374 patent/US8436064B2/en active Active
-
2008
- 2008-09-08 CN CN2008801155661A patent/CN101952340A/zh active Pending
- 2008-09-08 JP JP2010524846A patent/JP5743544B2/ja active Active
- 2008-09-08 WO PCT/US2008/010488 patent/WO2009035563A1/en not_active Ceased
- 2008-09-08 EP EP08830980A patent/EP2195362A1/en not_active Withdrawn
- 2008-09-10 TW TW097134702A patent/TWI437017B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2195362A1 (en) | 2010-06-16 |
| CN101952340A (zh) | 2011-01-19 |
| WO2009035563A1 (en) | 2009-03-19 |
| US8436064B2 (en) | 2013-05-07 |
| US20090069457A1 (en) | 2009-03-12 |
| JP2010539280A (ja) | 2010-12-16 |
| JP5743544B2 (ja) | 2015-07-01 |
| TW200932774A (en) | 2009-08-01 |
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