JP5729765B2 - ヘリウムガスの精製方法および精製装置 - Google Patents
ヘリウムガスの精製方法および精製装置 Download PDFInfo
- Publication number
- JP5729765B2 JP5729765B2 JP2011261596A JP2011261596A JP5729765B2 JP 5729765 B2 JP5729765 B2 JP 5729765B2 JP 2011261596 A JP2011261596 A JP 2011261596A JP 2011261596 A JP2011261596 A JP 2011261596A JP 5729765 B2 JP5729765 B2 JP 5729765B2
- Authority
- JP
- Japan
- Prior art keywords
- helium gas
- carbon monoxide
- oxygen
- hydrogen
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000007789 gas Substances 0.000 title claims description 222
- 239000001307 helium Substances 0.000 title claims description 204
- 229910052734 helium Inorganic materials 0.000 title claims description 204
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 title claims description 204
- 238000000034 method Methods 0.000 title claims description 96
- 238000000746 purification Methods 0.000 title claims description 12
- 238000001179 sorption measurement Methods 0.000 claims description 176
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 119
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 119
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 98
- 239000001301 oxygen Substances 0.000 claims description 98
- 229910052760 oxygen Inorganic materials 0.000 claims description 98
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 97
- 239000001257 hydrogen Substances 0.000 claims description 95
- 229910052739 hydrogen Inorganic materials 0.000 claims description 95
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 93
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 79
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 62
- 229910001868 water Inorganic materials 0.000 claims description 58
- 239000012535 impurity Substances 0.000 claims description 51
- 239000001569 carbon dioxide Substances 0.000 claims description 48
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 48
- 229910052757 nitrogen Inorganic materials 0.000 claims description 46
- 239000003463 adsorbent Substances 0.000 claims description 40
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 37
- 239000003054 catalyst Substances 0.000 claims description 34
- 238000006243 chemical reaction Methods 0.000 claims description 28
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 24
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims description 24
- 229910052707 ruthenium Inorganic materials 0.000 claims description 24
- 229910052763 palladium Inorganic materials 0.000 claims description 18
- 150000002431 hydrogen Chemical class 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 20
- 238000004140 cleaning Methods 0.000 description 19
- 239000003507 refrigerant Substances 0.000 description 18
- 238000001816 cooling Methods 0.000 description 16
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 14
- 238000003795 desorption Methods 0.000 description 12
- 239000000203 mixture Substances 0.000 description 9
- 239000010457 zeolite Substances 0.000 description 9
- 229910021536 Zeolite Inorganic materials 0.000 description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 8
- 229910052786 argon Inorganic materials 0.000 description 7
- 239000013307 optical fiber Substances 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 230000018044 dehydration Effects 0.000 description 5
- 238000006297 dehydration reaction Methods 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 239000002808 molecular sieve Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 239000012024 dehydrating agents Substances 0.000 description 4
- 238000012681 fiber drawing Methods 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 230000008929 regeneration Effects 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000003584 silencer Effects 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000000769 gas chromatography-flame ionisation detection Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- -1 moisture Chemical compound 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Separation Of Gases By Adsorption (AREA)
- Carbon And Carbon Compounds (AREA)
- Catalysts (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011261596A JP5729765B2 (ja) | 2011-01-21 | 2011-11-30 | ヘリウムガスの精製方法および精製装置 |
| CN201210021263.1A CN102602899B (zh) | 2011-01-21 | 2012-01-11 | 氦气的纯化方法及纯化装置 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011010907 | 2011-01-21 | ||
| JP2011010907 | 2011-01-21 | ||
| JP2011261596A JP5729765B2 (ja) | 2011-01-21 | 2011-11-30 | ヘリウムガスの精製方法および精製装置 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012162444A JP2012162444A (ja) | 2012-08-30 |
| JP2012162444A5 JP2012162444A5 (enExample) | 2014-08-21 |
| JP5729765B2 true JP5729765B2 (ja) | 2015-06-03 |
Family
ID=46842247
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011261596A Active JP5729765B2 (ja) | 2011-01-21 | 2011-11-30 | ヘリウムガスの精製方法および精製装置 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5729765B2 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI625297B (zh) * | 2014-03-28 | 2018-06-01 | 住友精化股份有限公司 | 氦氣之純化方法及純化系統 |
| RU2605593C2 (ru) * | 2014-10-27 | 2016-12-20 | Юоп Ллк | Способ извлечения гелия и устройство для его осуществления |
| FR3035656B1 (fr) * | 2015-04-30 | 2019-03-22 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Production d'helium a partir d'un courant gazeux contenant de l'hydrogene |
| CN113735080B (zh) * | 2021-01-04 | 2024-05-17 | 李保军 | 一种含氦天然气常温梯级提取超纯氦气的方法及生产装置 |
| JP7641791B2 (ja) | 2021-03-29 | 2025-03-07 | 大阪瓦斯株式会社 | 圧力変動吸着式ガス精製装置 |
| CN116789091A (zh) * | 2023-06-30 | 2023-09-22 | 杭氧集团股份有限公司 | 一种非低温法净化粗氖氦的装置及其使用方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2977606B2 (ja) * | 1990-11-29 | 1999-11-15 | 日本パイオニクス株式会社 | 希ガスの精製方法 |
| FR2690357B1 (fr) * | 1992-04-24 | 1994-09-16 | Air Liquide | Procédé d'épuration d'air. |
| JP3639087B2 (ja) * | 1997-05-09 | 2005-04-13 | エア・ウォーター株式会社 | ヘリウム回収方法 |
| JP2000072419A (ja) * | 1998-08-20 | 2000-03-07 | Japan Pionics Co Ltd | 希ガスの回収方法 |
| JP3782288B2 (ja) * | 1999-06-04 | 2006-06-07 | エヌ・イーケムキャット株式会社 | ガス精製剤及びその製造方法並びにガス精製方法、ガス精製器及びガス精製装置 |
| JP4058278B2 (ja) * | 2002-02-26 | 2008-03-05 | 住友精化株式会社 | ヘリウム精製装置 |
| JP5372607B2 (ja) * | 2009-05-29 | 2013-12-18 | 住友精化株式会社 | ヘリウム精製方法およびヘリウム精製装置 |
| JP5134588B2 (ja) * | 2009-06-12 | 2013-01-30 | 住友精化株式会社 | アルゴン精製方法、アルゴン精製装置、目的ガス精製方法、および目的ガス精製装置 |
-
2011
- 2011-11-30 JP JP2011261596A patent/JP5729765B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP2012162444A (ja) | 2012-08-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US20120222551A1 (en) | Swing Adsorption Processes Utilizing Controlled Adsorption Fronts | |
| JP5743215B2 (ja) | ヘリウムガスの精製方法および精製装置 | |
| JP5846641B2 (ja) | ヘリウムガスの精製方法および精製装置 | |
| JP5729765B2 (ja) | ヘリウムガスの精製方法および精製装置 | |
| CN102602899B (zh) | 氦气的纯化方法及纯化装置 | |
| JP5614808B2 (ja) | ヘリウムガスの精製方法および精製装置 | |
| JP5748272B2 (ja) | ヘリウムガスの精製方法および精製装置 | |
| JP5683390B2 (ja) | ヘリウムガスの精製方法および精製装置 | |
| JP2011167629A (ja) | 水素ガスの分離方法、および水素ガス分離装置 | |
| JP5896467B2 (ja) | アルゴンガスの精製方法および精製装置 | |
| JP5791113B2 (ja) | アルゴンガスの精製方法および精製装置 | |
| JP5665120B2 (ja) | アルゴンガスの精製方法および精製装置 | |
| JP5745434B2 (ja) | アルゴンガスの精製方法および精製装置 | |
| JP5403685B2 (ja) | アルゴンガスの精製方法および精製装置 | |
| KR20120046008A (ko) | 아르곤 가스의 정제 방법 및 정제 장치 | |
| JP2012106904A (ja) | アルゴンガスの精製方法および精製装置 | |
| JP5761751B2 (ja) | アルゴンガスの精製方法および精製装置 | |
| CN102807199B (zh) | 氩气的提纯方法及提纯装置 | |
| KR101800031B1 (ko) | 아르곤 가스의 정제 방법 및 정제 장치 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140704 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20140704 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150225 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20150227 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150317 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20150401 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20150402 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5729765 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |