JP5721238B2 - 低品位グリセリンからのアリルアルコールとプロピレンの製造方法、及びそのための触媒 - Google Patents

低品位グリセリンからのアリルアルコールとプロピレンの製造方法、及びそのための触媒 Download PDF

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Publication number
JP5721238B2
JP5721238B2 JP2012503169A JP2012503169A JP5721238B2 JP 5721238 B2 JP5721238 B2 JP 5721238B2 JP 2012503169 A JP2012503169 A JP 2012503169A JP 2012503169 A JP2012503169 A JP 2012503169A JP 5721238 B2 JP5721238 B2 JP 5721238B2
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catalyst
glycerin
composite oxide
propylene
mass
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Japanese (ja)
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JPWO2011108509A1 (ja
Inventor
多湖　輝興
輝興 多湖
隆夫 増田
隆夫 増田
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Hokkaido University NUC
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Hokkaido University NUC
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/009—Preparation by separation, e.g. by filtration, decantation, screening
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with alkali- or alkaline earth metals or beryllium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2012503169A 2010-03-01 2011-03-01 低品位グリセリンからのアリルアルコールとプロピレンの製造方法、及びそのための触媒 Expired - Fee Related JP5721238B2 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2012503169A JP5721238B2 (ja) 2010-03-01 2011-03-01 低品位グリセリンからのアリルアルコールとプロピレンの製造方法、及びそのための触媒

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2010044302 2010-03-01
JP2010044302 2010-03-01
PCT/JP2011/054565 WO2011108509A1 (fr) 2010-03-01 2011-03-01 Procédé de production d'alcool allylique et de propylène à partir de glycérol de faible qualité, et catalyseur pour ce procédé
JP2012503169A JP5721238B2 (ja) 2010-03-01 2011-03-01 低品位グリセリンからのアリルアルコールとプロピレンの製造方法、及びそのための触媒

Publications (2)

Publication Number Publication Date
JPWO2011108509A1 JPWO2011108509A1 (ja) 2013-06-27
JP5721238B2 true JP5721238B2 (ja) 2015-05-20

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JP2012503169A Expired - Fee Related JP5721238B2 (ja) 2010-03-01 2011-03-01 低品位グリセリンからのアリルアルコールとプロピレンの製造方法、及びそのための触媒

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JP (1) JP5721238B2 (fr)
WO (1) WO2011108509A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3015447B1 (fr) * 2013-06-27 2019-04-17 LG Chem, Ltd. Procédé de préparation d'un alcool allylique
KR101679717B1 (ko) * 2013-06-27 2016-11-25 주식회사 엘지화학 알릴 알코올의 제조방법 및 이에 의하여 제조된 알릴 알코올
JP6684113B2 (ja) * 2015-09-08 2020-04-22 株式会社ダイセル オレフィン化反応用触媒及びオレフィンの製造方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000044984A (ja) * 1998-05-25 2000-02-15 Ronfoodo:Kk 油脂類から脂肪酸の低級アルキルエステルを製造する方法
JP2008162907A (ja) * 2006-12-27 2008-07-17 Nippon Shokubai Co Ltd グリセリンからのアリルアルコールおよびアクリル酸の製造方法
WO2008092534A1 (fr) * 2007-01-29 2008-08-07 Evonik Degussa Gmbh Procédé de régénération d'un catalyseur pour la déshydratation de glycérine
WO2009044081A1 (fr) * 2007-09-20 2009-04-09 Arkema France Procede de fabrication d'acroleine a partir de glycerol

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000044984A (ja) * 1998-05-25 2000-02-15 Ronfoodo:Kk 油脂類から脂肪酸の低級アルキルエステルを製造する方法
JP2008162907A (ja) * 2006-12-27 2008-07-17 Nippon Shokubai Co Ltd グリセリンからのアリルアルコールおよびアクリル酸の製造方法
WO2008092534A1 (fr) * 2007-01-29 2008-08-07 Evonik Degussa Gmbh Procédé de régénération d'un catalyseur pour la déshydratation de glycérine
WO2009044081A1 (fr) * 2007-09-20 2009-04-09 Arkema France Procede de fabrication d'acroleine a partir de glycerol

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
JPN6011020105; 向田光志　他: '"ＦｅＯｘ系触媒によるグリセリンの石油化学関連有用物質への変換反応"' 第１０４回触媒討論会討論会Ａ予稿集 , 20090927, ｐ．１３９ *
JPN6011020108; 向田光志　他: '"酸化鉄系触媒を用いたグリセリンからの石油化学関連有用物質の合成"' 第１０３回触媒討論会討論会Ａ予稿集 , 20090330, ｐ．１４２ *

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WO2011108509A1 (fr) 2011-09-09

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