JP5711766B2 - 置換アミドエステル内部電子供与体を有するプロ触媒組成物 - Google Patents

置換アミドエステル内部電子供与体を有するプロ触媒組成物 Download PDF

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JP5711766B2
JP5711766B2 JP2012555136A JP2012555136A JP5711766B2 JP 5711766 B2 JP5711766 B2 JP 5711766B2 JP 2012555136 A JP2012555136 A JP 2012555136A JP 2012555136 A JP2012555136 A JP 2012555136A JP 5711766 B2 JP5711766 B2 JP 5711766B2
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group
carbon atoms
electron donor
procatalyst
procatalyst composition
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JP2013521340A (ja
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ホワン,シャオドン
チェン,リンフェン
レオン,タク,ダブリュ.
タオ,タオ
ガオ,クアンクイアン
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ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00Carboxylic acid amides
    • C07C233/01Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/12Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by halogen atoms or by nitro or nitroso groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00Carboxylic acid amides
    • C07C233/01Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/02Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00Carboxylic acid amides
    • C07C233/64Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings
    • C07C233/67Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/68Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/69Carboxylic acid amides having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom of an acyclic saturated carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24Nitrogen compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06Catalyst characterized by its size
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C08F4/6545Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium and metals of C08F4/64 or compounds thereof

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP2012555136A 2010-02-26 2011-02-24 置換アミドエステル内部電子供与体を有するプロ触媒組成物 Active JP5711766B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US30859610P 2010-02-26 2010-02-26
US61/308,596 2010-02-26
PCT/US2011/026024 WO2011106494A1 (en) 2010-02-26 2011-02-24 Procatalyst composition with substituted amide ester internal electron donor

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JP5711766B2 true JP5711766B2 (ja) 2015-05-07

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JP2014203442A Active JP6061908B2 (ja) 2010-02-26 2014-10-01 置換アミドエステル内部電子供与体を有するプロ触媒組成物

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US (2) US8604144B2 (ru)
EP (1) EP2545087B1 (ru)
JP (2) JP5711766B2 (ru)
KR (1) KR101874650B1 (ru)
CN (1) CN102971347B (ru)
BR (1) BR112012021399B1 (ru)
MY (1) MY157180A (ru)
RU (1) RU2586973C2 (ru)
SG (1) SG183460A1 (ru)
WO (1) WO2011106494A1 (ru)

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JP2015061910A (ja) * 2010-02-26 2015-04-02 ダウ グローバル テクノロジーズ エルエルシー 置換アミドエステル内部電子供与体を有するプロ触媒組成物

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US8551903B2 (en) 2010-02-26 2013-10-08 Dow Global Technologies Llc Amide ester internal electron donor and process
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EP2712875A1 (en) * 2012-09-28 2014-04-02 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
US9790291B2 (en) * 2013-03-14 2017-10-17 Formosa Plastics Corporation, Usa Non-phthalate compounds as electron donors for polyolefin catalysts
RU2630228C1 (ru) * 2013-09-09 2017-09-06 Базелл Полиолефин Италия С.Р.Л. Компоненты катализатора для полимеризации олефинов
CN105940021A (zh) 2013-12-20 2016-09-14 沙特基础工业公司 用于烯烃聚合的催化剂体系
US10059656B2 (en) 2013-12-20 2018-08-28 Sabic Global Technologies B.V. Catalyst composition for polymerization of olefins
CN105934449B (zh) 2013-12-20 2018-07-10 沙特基础工业公司 用于烯烃聚合的催化剂组合物
KR20160102018A (ko) 2013-12-20 2016-08-26 사우디 베이식 인더스트리즈 코포레이션 올레핀 중합용 전구 촉매
WO2015091981A2 (en) 2013-12-20 2015-06-25 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
BR112016014183B1 (pt) 2013-12-20 2021-10-05 Saudi Basic Industries Corporation Poliolefina, sistema de catalisador para polimerização de uma olefina, processos para a preparação dos mesmos e artigo moldado de poliolefina
US9926391B2 (en) 2013-12-20 2018-03-27 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
US20170240665A1 (en) * 2014-06-02 2017-08-24 Sabic Global Technologies B.V. Procatalyst for polymerization of olefins comprising a monoester and an amidobenzoate internal donor
JP6427689B2 (ja) * 2015-04-01 2018-11-21 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ オレフィン重合用触媒成分
EP3298048B1 (en) * 2015-05-19 2019-07-03 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
CN108349873B (zh) * 2015-09-22 2022-12-23 Sabic环球技术有限责任公司 取代的酰胺基苯甲酸酯化合物的合成及其作为不含邻苯二甲酸酯的内给电子体的用途
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US11117989B2 (en) 2016-09-29 2021-09-14 Sabic Global Technologies B.V. Process to prepare procatalyst for polymerization of olefins
CN109790251B (zh) 2016-09-29 2021-11-23 Sabic环球技术有限责任公司 用于制备用于烯烃聚合的主催化剂的方法
CN109790252B (zh) * 2016-09-29 2021-09-28 Sabic环球技术有限责任公司 用于烯烃聚合的主催化剂
WO2018060413A1 (en) * 2016-09-29 2018-04-05 Sabic Global Technologies B.V. Procatalyst for polymerization of olefins
JP7113817B2 (ja) 2016-10-06 2022-08-05 ダブリュー・アール・グレース・アンド・カンパニー-コーン 複数の内部電子供与体の組合せを用いて作製されるプロ触媒組成物
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* Cited by examiner, † Cited by third party
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JP2015061910A (ja) * 2010-02-26 2015-04-02 ダウ グローバル テクノロジーズ エルエルシー 置換アミドエステル内部電子供与体を有するプロ触媒組成物

Also Published As

Publication number Publication date
BR112012021399B1 (pt) 2020-01-21
US8604144B2 (en) 2013-12-10
KR101874650B1 (ko) 2018-07-04
WO2011106494A1 (en) 2011-09-01
BR112012021399A2 (pt) 2016-10-25
CN102971347A (zh) 2013-03-13
US20140163184A1 (en) 2014-06-12
JP6061908B2 (ja) 2017-01-18
US20120322962A1 (en) 2012-12-20
JP2013521340A (ja) 2013-06-10
MY157180A (en) 2016-05-10
SG183460A1 (en) 2012-09-27
US9441058B2 (en) 2016-09-13
EP2545087B1 (en) 2016-06-22
JP2015061910A (ja) 2015-04-02
CN102971347B (zh) 2015-06-17
EP2545087A1 (en) 2013-01-16
KR20130028075A (ko) 2013-03-18
RU2012141048A (ru) 2014-04-10
RU2586973C2 (ru) 2016-06-10

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