JP5600002B2 - ウラン抽出サイクルにおける、硝酸水相(phaseaqueusenitrique)から得られるウランからの化学元素の分離プロセス - Google Patents
ウラン抽出サイクルにおける、硝酸水相(phaseaqueusenitrique)から得られるウランからの化学元素の分離プロセス Download PDFInfo
- Publication number
- JP5600002B2 JP5600002B2 JP2009517245A JP2009517245A JP5600002B2 JP 5600002 B2 JP5600002 B2 JP 5600002B2 JP 2009517245 A JP2009517245 A JP 2009517245A JP 2009517245 A JP2009517245 A JP 2009517245A JP 5600002 B2 JP5600002 B2 JP 5600002B2
- Authority
- JP
- Japan
- Prior art keywords
- phase
- uranium
- nitric acid
- extractor
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 title claims abstract description 74
- 229910052770 Uranium Inorganic materials 0.000 title claims abstract description 73
- 239000008346 aqueous phase Substances 0.000 title claims abstract description 65
- 229910052729 chemical element Inorganic materials 0.000 title claims abstract description 58
- 238000000605 extraction Methods 0.000 title claims abstract description 50
- 229910002651 NO3 Inorganic materials 0.000 title claims description 29
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 title claims description 28
- 238000000926 separation method Methods 0.000 title claims description 25
- 239000012071 phase Substances 0.000 claims abstract description 48
- ZSLUVFAKFWKJRC-AHCXROLUSA-N thorium-228 Chemical compound [228Th] ZSLUVFAKFWKJRC-AHCXROLUSA-N 0.000 claims abstract description 12
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 71
- 229910017604 nitric acid Inorganic materials 0.000 claims description 71
- 239000012074 organic phase Substances 0.000 claims description 64
- 238000000034 method Methods 0.000 claims description 47
- 230000008569 process Effects 0.000 claims description 45
- AAORDHMTTHGXCV-UHFFFAOYSA-N uranium(6+) Chemical compound [U+6] AAORDHMTTHGXCV-UHFFFAOYSA-N 0.000 claims description 24
- 238000009825 accumulation Methods 0.000 claims description 16
- 229910052781 Neptunium Inorganic materials 0.000 claims description 15
- LFNLGNPSGWYGGD-UHFFFAOYSA-N neptunium atom Chemical compound [Np] LFNLGNPSGWYGGD-UHFFFAOYSA-N 0.000 claims description 15
- 238000000746 purification Methods 0.000 claims description 10
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical group CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 229910052768 actinide Inorganic materials 0.000 claims description 6
- 150000001255 actinides Chemical class 0.000 claims description 6
- 239000003085 diluting agent Substances 0.000 claims description 5
- 238000012958 reprocessing Methods 0.000 claims description 5
- 239000002915 spent fuel radioactive waste Substances 0.000 claims description 5
- 239000003456 ion exchange resin Substances 0.000 claims description 4
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000284 extract Substances 0.000 claims description 3
- 239000007790 solid phase Substances 0.000 claims description 3
- 235000013619 trace mineral Nutrition 0.000 abstract description 7
- 239000011573 trace mineral Substances 0.000 abstract description 7
- NBSLIVIAZBZBFZ-UHFFFAOYSA-N [Np+4] Chemical compound [Np+4] NBSLIVIAZBZBFZ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 2
- 238000005202 decontamination Methods 0.000 description 10
- 230000003588 decontaminative effect Effects 0.000 description 10
- 229910052778 Plutonium Inorganic materials 0.000 description 9
- OYEHPCDNVJXUIW-UHFFFAOYSA-N plutonium atom Chemical compound [Pu] OYEHPCDNVJXUIW-UHFFFAOYSA-N 0.000 description 9
- 239000000243 solution Substances 0.000 description 7
- 238000011144 upstream manufacturing Methods 0.000 description 7
- 238000005406 washing Methods 0.000 description 6
- 238000009833 condensation Methods 0.000 description 5
- 230000005494 condensation Effects 0.000 description 5
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 5
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 4
- 229910052776 Thorium Inorganic materials 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- IYQHAABWBDVIEE-UHFFFAOYSA-N [Pu+4] Chemical compound [Pu+4] IYQHAABWBDVIEE-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- WYOWZDGKSKEXCI-UHFFFAOYSA-N [Np+6] Chemical compound [Np+6] WYOWZDGKSKEXCI-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000004992 fission Effects 0.000 description 2
- 229940094933 n-dodecane Drugs 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- KUKDDTFBSTXDTC-UHFFFAOYSA-N uranium;hexanitrate Chemical compound [U].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O KUKDDTFBSTXDTC-UHFFFAOYSA-N 0.000 description 2
- 229910002007 uranyl nitrate Inorganic materials 0.000 description 2
- BZJTUOGZUKFLQT-UHFFFAOYSA-N 1,3,5,7-tetramethylcyclooctane Chemical group CC1CC(C)CC(C)CC(C)C1 BZJTUOGZUKFLQT-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- TUWJQNVAGYRRHA-UHFFFAOYSA-N Menadiol dibutyrate Chemical compound C1=CC=C2C(OC(=O)CCC)=CC(C)=C(OC(=O)CCC)C2=C1 TUWJQNVAGYRRHA-UHFFFAOYSA-N 0.000 description 1
- 150000001224 Uranium Chemical class 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- ZLYXMBXMECZBSN-UHFFFAOYSA-N [Pu+3] Chemical compound [Pu+3] ZLYXMBXMECZBSN-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- BWRHOYDPVJPXMF-UHFFFAOYSA-N cis-Caran Natural products C1C(C)CCC2C(C)(C)C12 BWRHOYDPVJPXMF-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000658 coextraction Methods 0.000 description 1
- KNZUAMRYQXIWSR-RUAUHYFQSA-N curan Chemical compound C1=CC=C2[C@@]3([C@@H]4C5)CCN4C[C@@H](CC)[C@H]5[C@@H](C)[C@@H]3NC2=C1 KNZUAMRYQXIWSR-RUAUHYFQSA-N 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000003758 nuclear fuel Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- JFALSRSLKYAFGM-VENIDDJXSA-N uranium-232 Chemical compound [232U] JFALSRSLKYAFGM-VENIDDJXSA-N 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0446—Juxtaposition of mixers-settlers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0488—Flow sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D11/00—Solvent extraction
- B01D11/04—Solvent extraction of solutions which are liquid
- B01D11/0492—Applications, solvents used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D59/00—Separation of different isotopes of the same chemical element
- B01D59/22—Separation by extracting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C19/00—Arrangements for treating, for handling, or for facilitating the handling of, fuel or other materials which are used within the reactor, e.g. within its pressure vessel
- G21C19/42—Reprocessing of irradiated fuel
- G21C19/44—Reprocessing of irradiated fuel of irradiated solid fuel
- G21C19/46—Aqueous processes, e.g. by using organic extraction means, including the regeneration of these means
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/06—Processing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Plasma & Fusion (AREA)
- Geology (AREA)
- Metallurgy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Organic Chemistry (AREA)
- Extraction Or Liquid Replacement (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0652772A FR2903025B1 (fr) | 2006-07-03 | 2006-07-03 | Procede pour separer un element chimique de l'uranium a partir d'une phase aqueuse acide, dans un cycle d'extraction de l'uranium |
| FR0652772 | 2006-07-03 | ||
| PCT/EP2007/056651 WO2008003681A1 (fr) | 2006-07-03 | 2007-07-02 | Procede pour separer un element chimique de l'uranium(vi) a partir d'une phase aqueuse nitrique, dans un cycle d'extraction de l'uranium |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009541763A JP2009541763A (ja) | 2009-11-26 |
| JP2009541763A5 JP2009541763A5 (https=) | 2013-06-20 |
| JP5600002B2 true JP5600002B2 (ja) | 2014-10-01 |
Family
ID=37671258
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009517245A Expired - Fee Related JP5600002B2 (ja) | 2006-07-03 | 2007-07-02 | ウラン抽出サイクルにおける、硝酸水相(phaseaqueusenitrique)から得られるウランからの化学元素の分離プロセス |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US8182773B2 (https=) |
| EP (1) | EP2038030B1 (https=) |
| JP (1) | JP5600002B2 (https=) |
| KR (1) | KR101450162B1 (https=) |
| CN (1) | CN101484226B (https=) |
| AT (1) | ATE499978T1 (https=) |
| AU (1) | AU2007271166B2 (https=) |
| CA (1) | CA2656142C (https=) |
| DE (1) | DE602007012878D1 (https=) |
| FR (1) | FR2903025B1 (https=) |
| RU (1) | RU2429041C2 (https=) |
| WO (1) | WO2008003681A1 (https=) |
| ZA (1) | ZA200810833B (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103451455B (zh) * | 2012-05-28 | 2015-01-07 | 中国原子能科学研究院 | Purex流程中铀、钚分离工艺 |
| CN103014380B (zh) * | 2012-12-17 | 2014-07-30 | 中国原子能科学研究院 | 一种使用teva-uteva萃取色层柱分离铀产品中镎的方法 |
| CN104004927B (zh) * | 2014-05-30 | 2016-09-14 | 中国原子能科学研究院 | Purex流程钚纯化循环中锆的净化工艺 |
| CN104498739B (zh) * | 2014-12-02 | 2016-03-09 | 益阳鸿源稀土有限责任公司 | 一种稀土矿分解余渣中铀、钍、稀土的分离回收方法 |
| CN109036609A (zh) * | 2018-07-13 | 2018-12-18 | 清华大学 | 一种球形核燃料元件生产线返品回收处理方法 |
| CN111398469B (zh) * | 2020-04-09 | 2020-10-27 | 中国科学院地质与地球物理研究所 | 一种小样品量的第四纪土壤碳酸盐的定年方法 |
| US20210354993A1 (en) * | 2020-05-18 | 2021-11-18 | Westinghouse Electric Company Llc | Methods and systems for separation of thorium from uranium and their decay products |
| CN114388159B (zh) * | 2021-12-23 | 2025-01-21 | 中国核电工程有限公司 | 分相方法及装置、以及乏燃料后处理厂萃取分离方法及系统 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2460145C2 (de) * | 1974-12-19 | 1982-03-04 | Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe | Verfahren zur Abtrennung von Neptunium aus bestrahlten Kernbrenn- und/oder Brutstoffen |
| CN85105352B (zh) * | 1985-07-13 | 1988-12-07 | 清华大学 | 从放射性废液中分离锕系元素的方法 |
| DE3546128A1 (de) * | 1985-12-24 | 1987-07-02 | Kernforschungsz Karlsruhe | Verfahren zur verbesserung eines fluessig-fluessig-extraktionsprozesses |
| JPH0178136U (https=) * | 1987-11-13 | 1989-05-25 | ||
| JP2551683B2 (ja) * | 1990-10-01 | 1996-11-06 | 動力炉・核燃料開発事業団 | ウラン・プルトニウム混合溶液からのウランおよびプルトニウムの分離方法 |
| JP3310765B2 (ja) * | 1994-02-25 | 2002-08-05 | 三菱重工業株式会社 | 再処理施設の高レベル廃液処理方法 |
| JP2971729B2 (ja) * | 1994-04-04 | 1999-11-08 | 核燃料サイクル開発機構 | ウラン、プルトニウム及びネプツニウムの共抽出方法 |
| JP2002516810A (ja) * | 1998-06-02 | 2002-06-11 | ブリティッシュ・ニュークリア・フューエルズ・パブリック・リミテッド・カンパニー | 核燃料再処理 |
| RU2155711C1 (ru) * | 1998-12-25 | 2000-09-10 | Государственный научный центр Российской Федерации Всероссийский научно-исследовательский институт неорганических материалов имени академика А.А. Бочвара | Способ совместного селективного восстановления плутония (iv) и нептуния (vi) для отделения их от урана (vi) |
| CN1229814C (zh) * | 2002-07-31 | 2005-11-30 | 中国原子能科学研究院 | 普雷克斯流程中铀、钚分离的方法 |
| RU2249267C2 (ru) * | 2003-04-09 | 2005-03-27 | Государственное унитарное предприятие Научно-производственное объединение "Радиевый институт им. В.Г. Хлопина" | Способ переработки облученного ядерного топлива (варианты) |
| FR2862804B1 (fr) * | 2003-11-20 | 2006-01-13 | Commissariat Energie Atomique | Procede de separation de l'uranium (vi) d'actinides (iv) et/ou (vi)et ses utilisations |
| FR2880180B1 (fr) * | 2004-12-29 | 2007-03-02 | Cogema | Perfectionnement du procede purex et ses utilisations |
-
2006
- 2006-07-03 FR FR0652772A patent/FR2903025B1/fr not_active Expired - Fee Related
-
2007
- 2007-07-02 US US12/307,264 patent/US8182773B2/en not_active Expired - Fee Related
- 2007-07-02 AT AT07765763T patent/ATE499978T1/de not_active IP Right Cessation
- 2007-07-02 RU RU2009103291A patent/RU2429041C2/ru not_active IP Right Cessation
- 2007-07-02 CN CN2007800251830A patent/CN101484226B/zh not_active Expired - Fee Related
- 2007-07-02 EP EP20070765763 patent/EP2038030B1/fr not_active Not-in-force
- 2007-07-02 CA CA 2656142 patent/CA2656142C/fr not_active Expired - Fee Related
- 2007-07-02 AU AU2007271166A patent/AU2007271166B2/en not_active Ceased
- 2007-07-02 WO PCT/EP2007/056651 patent/WO2008003681A1/fr not_active Ceased
- 2007-07-02 JP JP2009517245A patent/JP5600002B2/ja not_active Expired - Fee Related
- 2007-07-02 DE DE200760012878 patent/DE602007012878D1/de active Active
- 2007-07-02 KR KR1020097001676A patent/KR101450162B1/ko not_active Expired - Fee Related
-
2008
- 2008-12-23 ZA ZA200810833A patent/ZA200810833B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP2038030B1 (fr) | 2011-03-02 |
| CA2656142C (fr) | 2014-06-17 |
| KR20090029819A (ko) | 2009-03-23 |
| CN101484226A (zh) | 2009-07-15 |
| RU2429041C2 (ru) | 2011-09-20 |
| CN101484226B (zh) | 2012-06-27 |
| AU2007271166A1 (en) | 2008-01-10 |
| ATE499978T1 (de) | 2011-03-15 |
| WO2008003681A1 (fr) | 2008-01-10 |
| AU2007271166B2 (en) | 2011-03-17 |
| US20100034713A1 (en) | 2010-02-11 |
| US8182773B2 (en) | 2012-05-22 |
| DE602007012878D1 (de) | 2011-04-14 |
| KR101450162B1 (ko) | 2014-10-13 |
| EP2038030A1 (fr) | 2009-03-25 |
| FR2903025B1 (fr) | 2008-10-10 |
| FR2903025A1 (fr) | 2008-01-04 |
| JP2009541763A (ja) | 2009-11-26 |
| ZA200810833B (en) | 2009-11-25 |
| RU2009103291A (ru) | 2010-08-10 |
| CA2656142A1 (fr) | 2008-01-10 |
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