JP5584284B2 - レニウム促進されたエポキシ化触媒の効率を高める方法及びこれらの方法を利用したエポキシ化方法 - Google Patents

レニウム促進されたエポキシ化触媒の効率を高める方法及びこれらの方法を利用したエポキシ化方法 Download PDF

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JP5584284B2
JP5584284B2 JP2012507241A JP2012507241A JP5584284B2 JP 5584284 B2 JP5584284 B2 JP 5584284B2 JP 2012507241 A JP2012507241 A JP 2012507241A JP 2012507241 A JP2012507241 A JP 2012507241A JP 5584284 B2 JP5584284 B2 JP 5584284B2
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catalyst
temperature
epoxidation
concentration
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チェン−ユ リュー アルバート
チャン リーピン
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ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/70—Constitutive chemical elements of heterogeneous catalysts of Group VII (VIIB) of the Periodic Table
    • B01J2523/74—Rhenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
JP2012507241A 2009-04-21 2010-04-05 レニウム促進されたエポキシ化触媒の効率を高める方法及びこれらの方法を利用したエポキシ化方法 Active JP5584284B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US17120709P 2009-04-21 2009-04-21
US61/171,207 2009-04-21
PCT/US2010/029948 WO2010123675A1 (en) 2009-04-21 2010-04-05 Methods for enhancing the efficiency of rhenium-promoted epoxidation catalysts and epoxidation methods utilizing these

Publications (3)

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JP2012524656A JP2012524656A (ja) 2012-10-18
JP2012524656A5 JP2012524656A5 (https=) 2013-05-30
JP5584284B2 true JP5584284B2 (ja) 2014-09-03

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JP2012507241A Active JP5584284B2 (ja) 2009-04-21 2010-04-05 レニウム促進されたエポキシ化触媒の効率を高める方法及びこれらの方法を利用したエポキシ化方法

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US (1) US8084632B2 (https=)
EP (1) EP2421839B1 (https=)
JP (1) JP5584284B2 (https=)
KR (1) KR101704079B1 (https=)
CN (1) CN102421766B (https=)
CA (1) CA2759390C (https=)
SG (1) SG175762A1 (https=)
TW (2) TWI625165B (https=)
WO (1) WO2010123675A1 (https=)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101369619B1 (ko) * 2005-06-07 2014-03-05 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 산화올레핀, 1,2-디올, 1,2-디올 에테르 또는 알칸올아민의제조방법, 이를 위한 촉매, 이 촉매의 제조방법
CA2759560C (en) * 2009-04-21 2017-05-30 Dow Technology Investments Llc Rhenium-promoted epoxidation catalysts and methods of making and using them
US8742146B2 (en) * 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
US8742147B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
KR101886462B1 (ko) 2010-12-10 2018-08-07 다우 테크놀로지 인베스트먼츠 엘엘씨. 고효율 촉매를 사용하는 알킬렌 옥사이드 제조 방법에서 알킬렌 옥사이드 생산 변수의 값을 감소시키는 방법
SG190901A1 (en) 2010-12-15 2013-07-31 Dow Technology Investments Llc Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst
CN103502229B (zh) 2011-04-29 2016-02-03 国际壳牌研究有限公司 用于改善环氧乙烷催化剂选择性的方法
WO2013059225A1 (en) * 2011-10-18 2013-04-25 Al-Ahmadi Hassan Eisa Epoxidation process with added moderator
EP2788337B1 (en) 2011-12-09 2016-03-02 Dow Technology Investments LLC Method of maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst
WO2014105770A1 (en) 2012-12-31 2014-07-03 Scientific Design Company, Inc. Start-up process for high selectivity ethylene oxide catalysts
WO2014110194A1 (en) * 2013-01-11 2014-07-17 Scientific Design Company, Inc. Epoxidation process with post-conditioning step
JP6824909B2 (ja) 2015-06-02 2021-02-03 サイエンティフィック・デザイン・カンパニー・インコーポレーテッドＳｃｉｅｎｔｉｆｉｃ Ｄｅｓｉｇｎ Ｃｏｍｐａｎｙ Ｉｎｃｏｒｐｏｒａｔｅｄ 改善した細孔構造を有する多孔質体
CN106311234B (zh) * 2015-07-02 2018-11-30 中国石油化工股份有限公司 复合型银催化剂的制备方法、该催化剂及其应用
US10449520B2 (en) 2017-05-15 2019-10-22 Scientific Design Company, Inc. Porous bodies with enhanced crush strength
CN110357836B (zh) * 2018-03-26 2021-04-13 中国石油化工股份有限公司 一种环氧乙烷生产方法

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5102A (en) 1847-05-08 Ball-caster
US848A (en) 1838-07-19 Plating-mill fob making spoons
US4916243A (en) 1979-03-20 1990-04-10 Union Carbide Chemicals And Plastics Company Inc. New catalyst composition and process for oxidation of ethylene to ethylene oxide
US4379134A (en) 1981-02-13 1983-04-05 Union Carbide Corporation Process of preparing high purity alumina bodies
GB8423044D0 (en) * 1984-09-12 1984-10-17 Ici Plc Production of ethylene oxide
US5059481A (en) 1985-06-17 1991-10-22 Viskase Corporation Biaxially stretched, heat shrinkable VLDPE film
GB2190855A (en) 1986-05-28 1987-12-02 Shell Int Research Process for the preparation of a silver-containing catalyst
US4766105A (en) 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4833261A (en) 1986-10-31 1989-05-23 Shell Oil Company Ethylene oxide process
US4761394A (en) 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4808738A (en) 1986-10-31 1989-02-28 Shell Oil Company Ethylene oxide process
US4820675A (en) 1986-10-31 1989-04-11 Shell Oil Company Ethylene oxide catalyst & process for preparing the catalyst
IL84232A (en) * 1986-10-31 1992-06-21 Shell Int Research Catalyst and process for the catalytic production of ethylene oxide
US5057481A (en) 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US4908343A (en) 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
CN1009437B (zh) 1988-02-03 1990-09-05 中国石油化工总公司 乙烯氧化制环氧乙烷高效银催化剂
CA1339317C (en) 1988-07-25 1997-08-19 Ann Marie Lauritzen Process for producing ethylene oxide
CA1337722C (en) 1989-04-18 1995-12-12 Madan Mohan Bhasin Alkylene oxide catalysts having enhanced activity and/or stability
CN1031044C (zh) * 1989-04-18 1996-02-21 联合碳化化学品及塑料有限公司 增强活性和/或稳定性的烯化氧催化剂
US5187140A (en) * 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
JP2720124B2 (ja) 1990-10-12 1998-02-25 ユニオン・カーバイド、ケミカルズ、アンド、プラスチックス、テクノロジー、コーポレーション 向上された活性度及び／又は安定度を有するアルキレンオキシド触媒
US5100859A (en) * 1991-01-22 1992-03-31 Norton Company Catalyst carrier
US5384302A (en) 1993-09-08 1995-01-24 Norton Chemical Process Products Corp. Catalyst carrier
WO1996013493A1 (en) 1994-11-01 1996-05-09 Shell Internationale Research Maatschappij B.V. Process for preparing ethylene oxide catalysts
US5770746A (en) * 1997-06-23 1998-06-23 Arco Chemical Technology, L.P. Epoxidation process using supported silver catalysts pretreated with organic chloride
US6080897A (en) * 1998-03-19 2000-06-27 Mitsubishi Chemical Corporation Method for producing monoethylene glycol
US6831037B2 (en) 2002-02-25 2004-12-14 Saint-Gobain Norpro Corporation Catalyst carriers
KR100980123B1 (ko) 2002-06-28 2010-09-03 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 촉매 선택성을 향상시키는 방법 및 올레핀 에폭시화 방법
RU2005102097A (ru) 2002-06-28 2005-08-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способ введения в действие способа эпоксидирования и способ эпоксидирования олефина
JP2009525848A (ja) * 2006-02-03 2009-07-16 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒の処理方法、触媒、および触媒の使用
US7553980B2 (en) * 2007-09-26 2009-06-30 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for initiating a highly selective ethylene oxide catalyst

Also Published As

Publication number Publication date
KR101704079B1 (ko) 2017-02-07
KR20120006551A (ko) 2012-01-18
CN102421766A (zh) 2012-04-18
CA2759390A1 (en) 2010-10-28
SG175762A1 (en) 2011-12-29
EP2421839B1 (en) 2014-05-07
JP2012524656A (ja) 2012-10-18
US20100267973A1 (en) 2010-10-21
TW201041652A (en) 2010-12-01
EP2421839A1 (en) 2012-02-29
CN102421766B (zh) 2015-03-25
WO2010123675A1 (en) 2010-10-28
TWI625165B (zh) 2018-06-01
TW201601837A (zh) 2016-01-16
CA2759390C (en) 2017-08-22
TWI504440B (zh) 2015-10-21
US8084632B2 (en) 2011-12-27

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