CN102421766B - 提高铼助催化的环氧化催化剂的效率的方法以及使用它们的环氧化方法 - Google Patents

提高铼助催化的环氧化催化剂的效率的方法以及使用它们的环氧化方法 Download PDF

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Publication number
CN102421766B
CN102421766B CN201080017690.1A CN201080017690A CN102421766B CN 102421766 B CN102421766 B CN 102421766B CN 201080017690 A CN201080017690 A CN 201080017690A CN 102421766 B CN102421766 B CN 102421766B
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catalyst
temperature
epoxidation
feed
concentration
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CN102421766A (zh
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刘正宇
张丽萍
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Dow Technology Investments LLC
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Dow Technology Investments LLC
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/70—Constitutive chemical elements of heterogeneous catalysts of Group VII (VIIB) of the Periodic Table
    • B01J2523/74—Rhenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
CN201080017690.1A 2009-04-21 2010-04-05 提高铼助催化的环氧化催化剂的效率的方法以及使用它们的环氧化方法 Active CN102421766B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US17120709P 2009-04-21 2009-04-21
US61/171,207 2009-04-21
PCT/US2010/029948 WO2010123675A1 (en) 2009-04-21 2010-04-05 Methods for enhancing the efficiency of rhenium-promoted epoxidation catalysts and epoxidation methods utilizing these

Publications (2)

Publication Number Publication Date
CN102421766A CN102421766A (zh) 2012-04-18
CN102421766B true CN102421766B (zh) 2015-03-25

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Country Status (9)

Country Link
US (1) US8084632B2 (https=)
EP (1) EP2421839B1 (https=)
JP (1) JP5584284B2 (https=)
KR (1) KR101704079B1 (https=)
CN (1) CN102421766B (https=)
CA (1) CA2759390C (https=)
SG (1) SG175762A1 (https=)
TW (2) TWI625165B (https=)
WO (1) WO2010123675A1 (https=)

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CA2759560C (en) * 2009-04-21 2017-05-30 Dow Technology Investments Llc Rhenium-promoted epoxidation catalysts and methods of making and using them
US8742146B2 (en) * 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
US8742147B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
KR101886462B1 (ko) 2010-12-10 2018-08-07 다우 테크놀로지 인베스트먼츠 엘엘씨. 고효율 촉매를 사용하는 알킬렌 옥사이드 제조 방법에서 알킬렌 옥사이드 생산 변수의 값을 감소시키는 방법
SG190901A1 (en) 2010-12-15 2013-07-31 Dow Technology Investments Llc Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst
CN103502229B (zh) 2011-04-29 2016-02-03 国际壳牌研究有限公司 用于改善环氧乙烷催化剂选择性的方法
WO2013059225A1 (en) * 2011-10-18 2013-04-25 Al-Ahmadi Hassan Eisa Epoxidation process with added moderator
EP2788337B1 (en) 2011-12-09 2016-03-02 Dow Technology Investments LLC Method of maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst
WO2014105770A1 (en) 2012-12-31 2014-07-03 Scientific Design Company, Inc. Start-up process for high selectivity ethylene oxide catalysts
WO2014110194A1 (en) * 2013-01-11 2014-07-17 Scientific Design Company, Inc. Epoxidation process with post-conditioning step
JP6824909B2 (ja) 2015-06-02 2021-02-03 サイエンティフィック・デザイン・カンパニー・インコーポレーテッドＳｃｉｅｎｔｉｆｉｃ Ｄｅｓｉｇｎ Ｃｏｍｐａｎｙ Ｉｎｃｏｒｐｏｒａｔｅｄ 改善した細孔構造を有する多孔質体
CN106311234B (zh) * 2015-07-02 2018-11-30 中国石油化工股份有限公司 复合型银催化剂的制备方法、该催化剂及其应用
US10449520B2 (en) 2017-05-15 2019-10-22 Scientific Design Company, Inc. Porous bodies with enhanced crush strength
CN110357836B (zh) * 2018-03-26 2021-04-13 中国石油化工股份有限公司 一种环氧乙烷生产方法

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Publication number Publication date
KR101704079B1 (ko) 2017-02-07
KR20120006551A (ko) 2012-01-18
CN102421766A (zh) 2012-04-18
CA2759390A1 (en) 2010-10-28
SG175762A1 (en) 2011-12-29
EP2421839B1 (en) 2014-05-07
JP2012524656A (ja) 2012-10-18
US20100267973A1 (en) 2010-10-21
TW201041652A (en) 2010-12-01
JP5584284B2 (ja) 2014-09-03
EP2421839A1 (en) 2012-02-29
WO2010123675A1 (en) 2010-10-28
TWI625165B (zh) 2018-06-01
TW201601837A (zh) 2016-01-16
CA2759390C (en) 2017-08-22
TWI504440B (zh) 2015-10-21
US8084632B2 (en) 2011-12-27

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