JP5554419B2 - 炭化水素を酸素によって酸化する方法 - Google Patents
炭化水素を酸素によって酸化する方法 Download PDFInfo
- Publication number
- JP5554419B2 JP5554419B2 JP2012543598A JP2012543598A JP5554419B2 JP 5554419 B2 JP5554419 B2 JP 5554419B2 JP 2012543598 A JP2012543598 A JP 2012543598A JP 2012543598 A JP2012543598 A JP 2012543598A JP 5554419 B2 JP5554419 B2 JP 5554419B2
- Authority
- JP
- Japan
- Prior art keywords
- oxidation
- condensate
- reaction
- reactor
- recycled
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims description 58
- 229930195733 hydrocarbon Natural products 0.000 title claims description 22
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 22
- 230000001590 oxidative effect Effects 0.000 title claims description 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 10
- 239000001301 oxygen Substances 0.000 title claims description 10
- 229910052760 oxygen Inorganic materials 0.000 title claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 68
- 230000003647 oxidation Effects 0.000 claims description 58
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 49
- 239000007789 gas Substances 0.000 claims description 42
- 239000012071 phase Substances 0.000 claims description 30
- 238000006243 chemical reaction Methods 0.000 claims description 28
- 239000012429 reaction media Substances 0.000 claims description 25
- 239000004215 Carbon black (E152) Substances 0.000 claims description 14
- -1 alkyl hydroperoxide Chemical compound 0.000 claims description 14
- 238000004064 recycling Methods 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 9
- 238000009833 condensation Methods 0.000 claims description 4
- 230000005494 condensation Effects 0.000 claims description 4
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 4
- 239000007791 liquid phase Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- DDTBPAQBQHZRDW-UHFFFAOYSA-N cyclododecane Chemical compound C1CCCCCCCCCCC1 DDTBPAQBQHZRDW-UHFFFAOYSA-N 0.000 claims description 2
- WJTCGQSWYFHTAC-UHFFFAOYSA-N cyclooctane Chemical compound C1CCCCCCC1 WJTCGQSWYFHTAC-UHFFFAOYSA-N 0.000 claims description 2
- 239000004914 cyclooctane Substances 0.000 claims description 2
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 claims description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 34
- 239000000047 product Substances 0.000 description 18
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 17
- FGGJBCRKSVGDPO-UHFFFAOYSA-N hydroperoxycyclohexane Chemical compound OOC1CCCCC1 FGGJBCRKSVGDPO-UHFFFAOYSA-N 0.000 description 14
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- 238000004821 distillation Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 150000002576 ketones Chemical class 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000012074 organic phase Substances 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 235000011037 adipic acid Nutrition 0.000 description 4
- 239000001361 adipic acid Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000000543 intermediate Substances 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- PWVHLUKAENFZIA-UHFFFAOYSA-N cyclohexanol;cyclohexanone Chemical compound OC1CCCCC1.O=C1CCCCC1 PWVHLUKAENFZIA-UHFFFAOYSA-N 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 150000002432 hydroperoxides Chemical class 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000005844 autocatalytic reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D5/00—Condensation of vapours; Recovering volatile solvents by condensation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Claims (9)
- 液相中で飽和炭化水素を酸素含有気体で酸化することによってアルキルヒドロペルオキシドを製造する方法において、
該反応を連続した複数の工程で実施し、前記炭化水素を少なくとも最初の工程に100℃〜250℃の範囲の温度において供給し、反応の少なくとも最後の工程を冷却して該工程の温度を最初の工程の温度以下のレベルに保って制御することを含む前記方法であって、
前記反応の各工程が該工程における気体状オーバーヘッドを形成する気相と液相とを含み、このオーバーヘッドを形成する気相を取り出して排出させて少なくとも一部凝縮させること、並びに
1つの工程の気相から回収された凝縮液を前記酸化工程の内の1つにリサイクルし、その際、該酸化工程に供給される反応媒体中の酸化生成物の濃度がリサイクルされる凝縮液又は該凝縮液の混合物中の酸化生成物の濃度に少なくとも等しいこと、並びに
得られた凝縮液又は該凝縮液の混合物を少なくとも1つの工程に直接リサイクルし、ここで、この工程に供給される反応媒体中の酸化生成物の濃度は、リサイクルされるべき凝縮液又は該凝縮液の混合物中に含有される酸化生成物の濃度に少なくとも等しいこと、並びに
前記飽和炭化水素がシクロヘキサン、シクロオクタン、シクロドデカン及びデカリンより成る群から選択されること
を特徴とする、前記方法。 - 前記の1つの工程にリサイクルされる凝縮液が、少なくとも2つの酸化工程から導かれた凝縮液又は気相を混合することによって得られたものであることを特徴とする、請求項1に記載の方法。
- 1つの反応工程のヘッドにおいて回収された気相の一部を凝縮させ、得られた凝縮液を前の工程への供給物にリサイクルすることを特徴とする、請求項1又は2に記載の方法。
- 最後の反応工程のヘッドにおいて回収された気相の一部を凝縮させ、得られた凝縮液を前の工程への供給物にリサイクルすることを特徴とする、請求項1〜3のいずれかに記載の方法。
- 前記飽和炭化水素がシクロヘキサンであることを特徴とする、請求項1〜4のいずれかに記載の方法。
- 各工程のオーバーヘッドを形成する気相の一部を凝縮させた後に、未凝縮部分を完全に凝縮させ、次いで得られた凝縮液をフラッシュ処理して水性液状部分及び有機部分を得て、この有機部分を最初の酸化工程にリサイクルすることを特徴とする、請求項1〜5のいずれかに記載の方法。
- 直列に又はカスケード式に配置された複数の酸化反応器を含み、各反応器が酸化工程を構成するプラント中で前記酸化を実施することを特徴とする、請求項1〜6のいずれかに記載の方法。
- 前記反応器がバブルカラムタイプのものであることを特徴とする、請求項7に記載の方法。
- 酸化反応器として仕切り付きバブルカラムを含み、各区画が酸化工程を構成するプラント中で前記酸化を実施することを特徴とする、請求項1〜6のいずれかに記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0959113 | 2009-12-17 | ||
FR0959113A FR2954314B1 (fr) | 2009-12-17 | 2009-12-17 | Procede d'oxydation d'hydrocarbures par l'oxygene |
PCT/EP2010/069031 WO2011073053A1 (fr) | 2009-12-17 | 2010-12-07 | Procédé d'oxydation d'hydrocarbures par l'oxygène |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2013514292A JP2013514292A (ja) | 2013-04-25 |
JP5554419B2 true JP5554419B2 (ja) | 2014-07-23 |
Family
ID=42331000
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012543598A Expired - Fee Related JP5554419B2 (ja) | 2009-12-17 | 2010-12-07 | 炭化水素を酸素によって酸化する方法 |
Country Status (14)
Country | Link |
---|---|
US (1) | US8835695B2 (ja) |
EP (1) | EP2513049B1 (ja) |
JP (1) | JP5554419B2 (ja) |
KR (1) | KR101441771B1 (ja) |
CN (1) | CN102656143B (ja) |
BR (1) | BR112012013154B1 (ja) |
ES (1) | ES2693689T3 (ja) |
FR (1) | FR2954314B1 (ja) |
PL (1) | PL2513049T3 (ja) |
RU (1) | RU2540857C2 (ja) |
SG (1) | SG181747A1 (ja) |
TW (1) | TW201134802A (ja) |
UA (1) | UA109539C2 (ja) |
WO (1) | WO2011073053A1 (ja) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111471004A (zh) * | 2019-01-24 | 2020-07-31 | 中国石化工程建设有限公司 | 一种乙苯氢过氧化物的制备方法 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB777087A (en) | 1954-05-12 | 1957-06-19 | Du Pont | Improvements in or relating to the oxidation of cyclohexane |
BE630366A (ja) | 1962-04-02 | |||
FR1466528A (fr) | 1965-12-10 | 1967-01-20 | Rhone Poulenc Sa | Procédé d'oxydation de cycloalcanes |
FR1505363A (fr) | 1966-04-20 | 1967-12-15 | Rhone Poulenc Sa | Perfectionnement à la préparation des cycloalcanols et des mélanges cycloalcanols/cycloalcanones |
FR1491518A (fr) * | 1966-06-30 | 1967-08-11 | Rhone Poulenc Sa | Préparation d'hydroperoxydes |
FR1547427A (fr) | 1967-05-26 | 1968-11-29 | Rhone Poulenc Sa | Perfectionnement à la préparation de mélanges cycloalcanols/cycloalcanones |
NL6809391A (ja) * | 1967-07-03 | 1969-01-07 | ||
DE2951956A1 (de) * | 1979-12-22 | 1981-07-23 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von gemischen aus cyclohexylhydroperoxid |
DE3513568A1 (de) * | 1985-04-16 | 1986-10-16 | Basf Ag, 6700 Ludwigshafen | Verfahren zur aufarbeitung von cyclohexanol, cyclohexanon sowie cyclohexylhydroperoxid enthaltenden reaktionsgemischen |
FR2604998B1 (fr) | 1986-10-10 | 1989-06-09 | Rhone Poulenc Chimie | Procede de preparation d'un melange renfermant du cyclohexanol et de la cyclohexanone a partir du cyclohexane |
US5043481A (en) * | 1990-09-28 | 1991-08-27 | Arco Chemical Technology, Inc. | Cyclohexane oxidation |
NL9201269A (nl) * | 1992-07-15 | 1994-02-01 | Dsm Nv | Werkwijze voor de bereiding van cyclohexylhydroperoxide. |
CN1063419C (zh) * | 1994-04-22 | 2001-03-21 | 肖藻生 | 从环己烷制备环己醇、环己酮的工艺 |
FR2830775B1 (fr) | 2001-10-12 | 2004-08-27 | Rhodia Polyamide Intermediates | Reacteur pour reaction d'oxydation d'un liquide avec un gaz |
US6888034B1 (en) * | 2003-11-05 | 2005-05-03 | Invista North America S.A.R.L. | Process for oxidation of cyclohexane |
RU2358942C1 (ru) * | 2008-02-28 | 2009-06-20 | Юлия Алексеевна Щепочкина | Способ получения глазурованного силикатного кирпича |
-
2009
- 2009-12-17 FR FR0959113A patent/FR2954314B1/fr not_active Expired - Fee Related
-
2010
- 2010-07-12 UA UAA201208847A patent/UA109539C2/ru unknown
- 2010-12-07 CN CN201080057544.1A patent/CN102656143B/zh active Active
- 2010-12-07 WO PCT/EP2010/069031 patent/WO2011073053A1/fr active Application Filing
- 2010-12-07 EP EP10787127.9A patent/EP2513049B1/fr active Active
- 2010-12-07 ES ES10787127.9T patent/ES2693689T3/es active Active
- 2010-12-07 KR KR1020127014847A patent/KR101441771B1/ko active IP Right Grant
- 2010-12-07 BR BR112012013154-0A patent/BR112012013154B1/pt active IP Right Grant
- 2010-12-07 PL PL10787127T patent/PL2513049T3/pl unknown
- 2010-12-07 US US13/516,664 patent/US8835695B2/en active Active
- 2010-12-07 RU RU2012130067/04A patent/RU2540857C2/ru not_active Application Discontinuation
- 2010-12-07 SG SG2012044384A patent/SG181747A1/en unknown
- 2010-12-07 JP JP2012543598A patent/JP5554419B2/ja not_active Expired - Fee Related
- 2010-12-16 TW TW099144248A patent/TW201134802A/zh unknown
Also Published As
Publication number | Publication date |
---|---|
BR112012013154B1 (pt) | 2018-05-22 |
TW201134802A (en) | 2011-10-16 |
RU2012130067A (ru) | 2014-01-27 |
US8835695B2 (en) | 2014-09-16 |
WO2011073053A1 (fr) | 2011-06-23 |
ES2693689T3 (es) | 2018-12-13 |
KR20120081243A (ko) | 2012-07-18 |
FR2954314A1 (fr) | 2011-06-24 |
SG181747A1 (en) | 2012-07-30 |
KR101441771B1 (ko) | 2014-09-22 |
RU2540857C2 (ru) | 2015-02-10 |
BR112012013154A2 (pt) | 2016-03-01 |
CN102656143B (zh) | 2015-09-09 |
CN102656143A (zh) | 2012-09-05 |
JP2013514292A (ja) | 2013-04-25 |
UA109539C2 (uk) | 2015-09-10 |
US20120310017A1 (en) | 2012-12-06 |
FR2954314B1 (fr) | 2012-01-27 |
EP2513049A1 (fr) | 2012-10-24 |
PL2513049T3 (pl) | 2019-02-28 |
EP2513049B1 (fr) | 2018-09-05 |
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