JP5490445B2 - 粘着型光学フィルム、その製造方法および画像表示装置、並びに粘着剤塗布液およびその製造方法 - Google Patents
粘着型光学フィルム、その製造方法および画像表示装置、並びに粘着剤塗布液およびその製造方法 Download PDFInfo
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- JP5490445B2 JP5490445B2 JP2009136539A JP2009136539A JP5490445B2 JP 5490445 B2 JP5490445 B2 JP 5490445B2 JP 2009136539 A JP2009136539 A JP 2009136539A JP 2009136539 A JP2009136539 A JP 2009136539A JP 5490445 B2 JP5490445 B2 JP 5490445B2
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- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- 229920006316 polyvinylpyrrolidine Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- AAYRWMCIKCRHIN-UHFFFAOYSA-N propane-1-sulfonic acid;prop-2-enamide Chemical compound NC(=O)C=C.CCCS(O)(=O)=O AAYRWMCIKCRHIN-UHFFFAOYSA-N 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 238000009849 vacuum degassing Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Images
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- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
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- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
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- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
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- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
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- G—PHYSICS
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- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
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- G—PHYSICS
- G02—OPTICS
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- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133509—Filters, e.g. light shielding masks
- G02F1/133514—Colour filters
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Description
前記粘着剤層は、溶存酸素濃度が、0.02〜3mg/Lの粘着剤塗布液を塗布した後、乾燥することにより形成されたものであることを特徴とする粘着型光学フィルム、に関する。
粘着剤塗布液を、溶存酸素濃度が、0.02〜3mg/Lになるように脱泡処理を行なう工程(1)、
支持基材の片面または両面に、脱泡処理工程(1)が行なわれた粘着剤塗布液を塗布する工程(2)、および、
塗布された粘着剤塗布液を乾燥して粘着剤層を形成する工程(3)を有することを特徴とする粘着型光学フィルムの製造方法、に関する。
当該粘着剤塗布液は、溶存酸素濃度が、0.02〜3mg/Lであることを特徴とする粘着剤塗布液、に関する。
粘着剤塗布液に、溶存酸素濃度が、0.02〜3mg/Lになるように脱泡処理を行なうことを特徴とする、粘着剤塗布液の製造方法、に関する。
(水分散型粘着剤の調製)
冷却管、窒素導入管、温度計および撹拌装置を備えた反応容器に、水30部および過硫酸アンモニウム0.3部を仕込み、撹拌下に1時間窒素置換した。このときの水溶液の溶存酸素濃度は0.2mg/Lであった。ここにアクリル酸ブチル95部、アクリル酸5部および乳化剤としてポリオキシエチレンラウリルエーテル硫酸アンモニウム(第一工業製薬(株)の商品名「ハイテノールLA−16」)1.0部(固形分換算)を水70部で乳化したものを80℃で3時間かけて滴下し、さらに80℃で2時間熟成を行った。その後、室温まで冷却し、10重量%アンモニア水によりpH8に調整して、固形分39%のアクリル系共重合体エマルションを得た。なお、本乳化重合時の溶存酸素濃度は熟成完成段階までのいずれの工程においても0.2mg/Lであった。その後、冷却し、窒素置換しないで中和工程を行なった。こうして、得られたアクリル系共重合体エマルションの溶存酸素濃度は6.50mg/Lであった。このアクリル系共重合体エマルションに、その固形分(アクリル系共重合体)100部に対し、オキサゾリン基を含有する水溶性架橋剤として(株)日本触媒の商品名「エポクロスWS−700」(オキサゾリン基当量:220g・solid/eq.)0.1部(固形分換算)を混合して、水分散型アクリル系粘着剤(架橋剤を含めたものの固形分39%,粘度6000mPa・s)とした。
図1に従って、下記操作を行なった。先ず、上記水分散型粘着剤(80kg)2を脱泡装置1の密閉タンク11内に投入した。この状態で水分散型粘着剤2をサンプリングして溶存酸素計100を介して脱泡前の溶存酸素濃度を測定したところ、7.25mg/Lであった。
上記の搬送された水分散型粘着剤2を、剥離処理したポリエチレンテレフタレートフィルム(厚さ38μm)からなるセパレータの表面に、乾燥後の厚みが20μmになるようにダイコーターにより塗布した後、120℃で5分間乾燥して、粘着剤層を形成した。当該粘着剤層を、偏光板(日東電工社製,3G−DU)に転写して、粘着型偏光板を得た。なお、塗布される水分散型粘着剤2に溶存酸素濃度は、2.98mg/Lであった。当該塗布直前の水分散型粘着剤2の溶存酸素濃度は、塗布装置94の手前(コーターの寸前の箇所)で、水分散型粘着剤2をサンプリングして測定した。
実施例1において、水分散型粘着剤に対する脱泡処理の条件を表1に示すように変えたこと以外は、実施例1と同様にして粘着型偏光板を得た。
(有機溶剤型粘着剤の調製)
冷却管、窒素導入管、温度計及び撹拌装置を備えた反応容器に、アクリル酸ブチル100部、アクリル酸5部、アクリル酸2−ヒドロキシエチル0.075部および2,2´−アゾビスイソブチロニトリル0.3部を酢酸エチルと共に加えて溶液を調製した。次いで、この溶液に窒素ガスを吹き込みながら撹拌して、60℃で4時間反応させて、重量平均分子量220万のアクリル系ポリマーを含有する溶液を得た。さらに、この(メタ)アクリル系ポリマーを含有する溶液に、酢酸エチルを加えて固形分濃度を30%に調整したアクリル系ポリマー溶液(A)を得た。
実施例1において、水分散型粘着剤の代わりに、上記で調製した有機溶剤型粘着剤を用いたこと以外は、実施例1と同様にして脱泡処理、搬送処理を行なった後、実施例1と同様にして粘着剤層を形成した。また、実施例1と同様に当該粘着剤層を、偏光板(日東電工社製,3G−DU)に転写して、粘着型偏光板を得た。
実施例7において、有機溶剤型粘着剤に対する脱泡処理の条件を表2に示すように変えたこと以外は、実施例7と同様にして粘着型偏光板を得た。
(放射線硬化型の有機溶剤型粘着剤の調製)
実施例7と同様の方法で調製したアクリル系ポリマー溶液(A)の固形分100部に対して、メタクリル酸グリシジル4.5部及び触媒として、ジブチルスズラウレート0.3部を添加し、常温常圧下で24時間反応させて、前記アクリル系ポリマー(A)にメタクリロイル基を導入した、放射線硬化性ベースポリマーを得た。当該放射線硬化性ベースポリマーの固形分100部に対して、光重合開始剤(1−ヒドロキシシクロヘキシルフェニルケトン)0.4部を配合して、放射線硬化型の有機溶剤型粘着剤を調製した。
実施例1において、水分散型粘着剤の代わりに、上記で調製した放射線硬化型の有機溶剤型粘着剤を用いたこと以外は、実施例1と同様にして脱泡処理、搬送処理を行なった後、実施例1と同様の操作を行なった。さらに、紫外線をセパレータ側から照射して(高圧水銀灯120W灯,照射距離10cm,ラインスピード5m/min)、粘着剤層を形成した。また、実施例1と同様に当該粘着剤層を、偏光板(日東電工社製,3G−DU)に転写して、粘着型偏光板を得た。
実施例12において、放射線硬化型の有機溶剤型粘着剤に対する脱泡処理の条件を表3に示すように変えたこと以外は、実施例12と同様にして粘着型偏光板を得た。
粘着型偏光板(15インチサイズ)を、無アルカリガラス(コーニング1737,厚み0.7mm)に貼り付け、50℃、0.5MPaのオートクレーブにて15分間処理を行った。次いで、このサンプルを80℃の条件下で500時間の処理を行った。処理されたサンプル(粘着型偏光板における粘着剤層)の気泡の発生度合いを下記の基準により、光学顕微鏡にて、その個数と大きさを確認し、下記基準で評価した。(但し、処理前からある気泡は除いて評価した。)
5:最大長さ100μm以上の気泡が1cm2中になし。
4:最大長さ100μm以上の気泡が1cm2中に5個以下。
3:最大長さ100μm以上の気泡が1cm2中に6個から10個。
2:最大長さ100μm以上の気泡が1cm2中に11個から100個。
1:最大長さ100μm以上の気泡が1cm2中に6個から101個以上。
粘着型偏光板(15インチサイズ)を、無アルカリガラス(コーニング1737,厚み0.7mm)に貼り付け、50℃、0.5MPaのオートクレーブにて15分間処理を行った。次いで、このサンプルを60℃、95%R.H.の環境下で、500時間の処理を行った。処理されたサンプルの粘着型偏光板と無アルカリガラスの間の剥がれの度合いを目視で確認し、下記基準で評価した。
5:剥がれの発生なし。
4:粘着型偏光板の端部から0.1mm以内の箇所に剥がれが発生。
3:粘着型偏光板の端部から0.5mm以内の箇所に剥がれが発生。
2:粘着型偏光板の端部から1.0mm以内の箇所に剥がれが発生。
1:粘着型偏光板の端部から1.0mm以上の箇所に剥がれが発生。
VAモードの液晶セルを含む市販の液晶表示装置(ソニー社製,40インチ液晶テレビ,商品名「BraviaKDL−46V1」)から液晶パネルを取り出し、液晶セルの上下に配置されていた偏光板等の光学フィルムを全て取り除いた。この液晶セルのガラス板の表裏を洗浄したものを液晶セルAとした。当該液晶セルAの視認側に、実施例および比較例で得られた粘着型偏光板を、偏光板の吸収軸方向が液晶セルAの長辺方向と実質的に平行になるように、粘着型偏光板の粘着剤層側を液晶セルAに貼り合せた。次いで、液晶セルAの視認側とは反対側(バックライト側)にも、前記と同じ実施例および比較例で得られた粘着型偏光板を、偏光板の吸収軸方向が液晶セルAの長辺方向と実質的に直交するように、粘着型偏光板の粘着剤層側を液晶セルAに貼り合せた。これを液晶パネルAとする。液晶パネルAの視認側の粘着型偏光板とバックライト側の粘着型偏光板の各偏光板の吸収軸方向は実質的に直交である。液晶パネルAを、元の液晶表示装置のバックライトユニットと結合し、液晶表示装置Aを作製した。
液晶表示装置Aの正面方向のコントラスト比の測定方法:23℃の暗室でバックライトを点灯させてから30分間経過した後、トプコン社製の製品名「BM−5」を用いて、レンズをパネル情報の50cm位置に配置し、白画像および黒画像を表示した婆いのXYZ表示系のY値を測定した。白画像におけるY値(YW:白輝度)と黒画像におけるY値(YB:黒輝度)とから、正面方向のコントラスト比「YW/YB」を算出した。
コントラストは、2600以上であることが好ましく、2700以上、2800以上、2900以上、さらには3000以上であるのが好ましい。
2 粘着剤塗布液
3 バッファタンク
4 連結管
5 ポンプセットタンク
7 真空ポンプ
6 連結管
11 密閉タンク
13 真空バルブ
31 密閉タンク
51 密閉タンク
Claims (10)
- 光学フィルムの少なくとも片側に、粘着剤層が積層されている粘着型光学フィルムであって、
前記粘着剤層は、溶存酸素濃度が、0.02〜3mg/Lの粘着剤塗布液を塗布した後、乾燥することにより形成されたものであり、かつ、前記粘着剤塗布液が、少なくともベースポリマーが水中に分散含有されている分散液からなる水分散型粘着剤であることを特徴とする粘着型光学フィルム。 - 前記水分散型粘着剤の溶存酸素濃度が、0.05〜2mg/Lであることを特徴とする請求項1記載の粘着型光学フィルム。
- 前記水分散型粘着剤の溶存酸素濃度が、0.1〜1mg/Lであることを特徴とする請求項1記載の粘着型光学フィルム。
- 前記水分散型粘着剤の溶存酸素濃度が、0.1〜0.5mg/Lであることを特徴とする請求項1記載の粘着型光学フィルム。
- 前記水分散型粘着剤におけるベースポリマーが、(メタ)アクリル系ポリマーであることを特徴とする請求項1〜4のいずれかに記載の粘着型光学フィルム。
- 前記ベースポリマーである、(メタ)アクリル系ポリマーが、乳化重合により得られたものであることを特徴とする請求項5記載の粘着型光学フィルム。
- 請求項1〜6のいずれかに記載の粘着型光学フィルムの製造方法であって、
粘着剤塗布液を、溶存酸素濃度が、0.02〜3mg/Lになるように脱泡処理を行なう工程(1)、
支持基材の片面または両面に、脱泡処理工程(1)が行なわれた粘着剤塗布液を塗布する工程(2)、および、
塗布された粘着剤塗布液を乾燥して粘着剤層を形成する工程(3)を有することを特徴とする粘着型光学フィルムの製造方法。 - 請求項1〜6のいずれかに記載の粘着型光学フィルムを少なくとも1枚用いていることを特徴とする画像表示装置。
- 光学フィルムの少なくとも片側に、粘着剤層が積層されている粘着型光学フィルムの当該粘着剤層の形成に用いる粘着剤塗布液であって、
当該粘着剤塗布液は、溶存酸素濃度が、0.02〜3mg/Lであり、かつ、少なくともベースポリマーが水中に分散含有されている分散液からなる水分散型粘着剤であることを特徴とする粘着剤塗布液。 - 請求項9記載の粘着剤塗布液の製造方法であって、
粘着剤塗布液に、溶存酸素濃度が、0.02〜3mg/Lになるように脱泡処理を行なうことを特徴とする、粘着剤塗布液の製造方法。
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JP2009136539A JP5490445B2 (ja) | 2009-06-05 | 2009-06-05 | 粘着型光学フィルム、その製造方法および画像表示装置、並びに粘着剤塗布液およびその製造方法 |
KR1020117029089A KR101674701B1 (ko) | 2009-06-05 | 2010-05-12 | 점착형 광학 필름, 그 제조 방법 및 화상 표시 장치, 및 점착제 도포액 및 그 제조 방법 |
PCT/JP2010/058043 WO2010140450A1 (ja) | 2009-06-05 | 2010-05-12 | 粘着型光学フィルム、その製造方法および画像表示装置、並びに粘着剤塗布液およびその製造方法 |
US13/320,851 US20120064340A1 (en) | 2009-06-05 | 2010-05-12 | Pressure-sensitive adhesive optical film, method for producing the adhesive optical film, image display, adhesive coating liquid, and method for producing the adhesive coating liquid |
CN201080022527.4A CN102439496B (zh) | 2009-06-05 | 2010-05-12 | 粘合型光学薄膜、其制造方法和图像显示装置以及粘合剂涂布液及其制造方法 |
TW099115958A TWI476264B (zh) | 2009-06-05 | 2010-05-19 | An adhesive type optical film, a manufacturing method thereof and an image display device, an adhesive coating liquid and a manufacturing method thereof |
US14/673,465 US20150203720A1 (en) | 2009-06-05 | 2015-03-30 | Pressure-sensitive adhesive optical film, method for producing the adhesive optical film, image display, adhesive coating liquid, and method for producing the adhesive coating liquid |
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JP6125157B2 (ja) * | 2012-05-25 | 2017-05-10 | 日東電工株式会社 | 粘着シート |
JP6256022B2 (ja) * | 2014-01-15 | 2018-01-10 | コニカミノルタ株式会社 | 塗布液送液システム |
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US10183471B2 (en) | 2016-02-22 | 2019-01-22 | Toray Plastics (America), Inc. | Metal transfer film and method of using same |
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CN114423598A (zh) * | 2019-11-19 | 2022-04-29 | 日东电工株式会社 | 光学层叠体的制造方法、粘接剂涂敷装置及光学层叠体的制造装置 |
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JPH09230138A (ja) * | 1996-02-23 | 1997-09-05 | Sekisui Chem Co Ltd | 粘着型偏光板 |
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