JP5463356B2 - フラッシュ火災及びアーク防護を改善するための結晶化メタ系アラミド混紡品 - Google Patents
フラッシュ火災及びアーク防護を改善するための結晶化メタ系アラミド混紡品 Download PDFInfo
- Publication number
- JP5463356B2 JP5463356B2 JP2011517639A JP2011517639A JP5463356B2 JP 5463356 B2 JP5463356 B2 JP 5463356B2 JP 2011517639 A JP2011517639 A JP 2011517639A JP 2011517639 A JP2011517639 A JP 2011517639A JP 5463356 B2 JP5463356 B2 JP 5463356B2
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- JP
- Japan
- Prior art keywords
- fiber
- fabric
- aramid
- weight
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920003235 aromatic polyamide Polymers 0.000 title claims abstract description 46
- 239000004760 aramid Substances 0.000 title abstract description 44
- 239000000203 mixture Substances 0.000 title description 15
- 239000000835 fiber Substances 0.000 claims abstract description 140
- 229920006231 aramid fiber Polymers 0.000 claims abstract description 51
- 229920002821 Modacrylic Polymers 0.000 claims abstract description 39
- 229920001577 copolymer Polymers 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 150000001462 antimony Chemical class 0.000 claims description 2
- 239000004744 fabric Substances 0.000 abstract description 124
- 229920000784 Nomex Polymers 0.000 description 16
- 239000000463 material Substances 0.000 description 16
- 239000004763 nomex Substances 0.000 description 16
- 238000012360 testing method Methods 0.000 description 16
- 230000001681 protective effect Effects 0.000 description 15
- 238000000034 method Methods 0.000 description 13
- 239000002356 single layer Substances 0.000 description 9
- 238000003763 carbonization Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 6
- 239000003063 flame retardant Substances 0.000 description 6
- 238000009987 spinning Methods 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 238000007655 standard test method Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 238000010891 electric arc Methods 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 229920000889 poly(m-phenylene isophthalamide) Polymers 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 229920003368 Kevlar® 29 Polymers 0.000 description 3
- 238000001069 Raman spectroscopy Methods 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000009941 weaving Methods 0.000 description 3
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- 239000004953 Aliphatic polyamide Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 229920003231 aliphatic polyamide Polymers 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- SXZSFWHOSHAKMN-UHFFFAOYSA-N 2,3,4,4',5-Pentachlorobiphenyl Chemical compound C1=CC(Cl)=CC=C1C1=CC(Cl)=C(Cl)C(Cl)=C1Cl SXZSFWHOSHAKMN-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 238000005079 FT-Raman Methods 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- 229920000271 Kevlar® Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 238000003841 Raman measurement Methods 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000000333 X-ray scattering Methods 0.000 description 1
- 238000002679 ablation Methods 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000010042 air jet spinning Methods 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 1
- 150000001463 antimony compounds Chemical class 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- QGGZBXOADPVUPN-UHFFFAOYSA-N beta-phenylpropiophenone Natural products C=1C=CC=CC=1C(=O)CCC1=CC=CC=C1 QGGZBXOADPVUPN-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- QZUPTXGVPYNUIT-UHFFFAOYSA-N isophthalamide Chemical compound NC(=O)C1=CC=CC(C(N)=O)=C1 QZUPTXGVPYNUIT-UHFFFAOYSA-N 0.000 description 1
- 239000004761 kevlar Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003366 poly(p-phenylene terephthalamide) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000007378 ring spinning Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000790 scattering method Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- -1 yarns Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/443—Heat-resistant, fireproof or flame-retardant yarns or threads
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/047—Blended or other yarns or threads containing components made from different materials including aramid fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/10—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
- D10B2321/101—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide modacrylic
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
- D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2915—Rod, strand, filament or fiber including textile, cloth or fabric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
- Y10T428/2969—Polyamide, polyimide or polyester
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3976—Including strand which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous composition, water solubility, heat shrinkability, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3976—Including strand which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous composition, water solubility, heat shrinkability, etc.]
- Y10T442/3984—Strand is other than glass and is heat or fire resistant
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Woven Fabrics (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/218,125 US7744999B2 (en) | 2008-07-11 | 2008-07-11 | Crystallized meta-aramid blends for improved flash fire and arc protection |
| US12/218,125 | 2008-07-11 | ||
| PCT/US2009/050184 WO2010006222A1 (en) | 2008-07-11 | 2009-07-10 | Crystallized meta-aramid blends for improved flash fire and arc protection |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011527734A JP2011527734A (ja) | 2011-11-04 |
| JP2011527734A5 JP2011527734A5 (enExample) | 2012-08-23 |
| JP5463356B2 true JP5463356B2 (ja) | 2014-04-09 |
Family
ID=41334397
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011517639A Active JP5463356B2 (ja) | 2008-07-11 | 2009-07-10 | フラッシュ火災及びアーク防護を改善するための結晶化メタ系アラミド混紡品 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7744999B2 (enExample) |
| EP (1) | EP2318579B1 (enExample) |
| JP (1) | JP5463356B2 (enExample) |
| KR (1) | KR101605925B1 (enExample) |
| CN (1) | CN102124152B (enExample) |
| AT (1) | ATE541968T1 (enExample) |
| CA (1) | CA2726109C (enExample) |
| MX (1) | MX2011000295A (enExample) |
| WO (1) | WO2010006222A1 (enExample) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8069642B2 (en) * | 2009-06-02 | 2011-12-06 | E.I. Du Pont De Nemours And Company | Crystallized meta-aramid blends for improved flash fire and superior arc protection |
| US8069643B2 (en) * | 2009-06-02 | 2011-12-06 | E. I. Du Pont De Nemours And Company | Limited-antimony-content and antimony-free modacrylic / aramid blends for improved flash fire and arc protection |
| US20110000004A1 (en) * | 2009-07-06 | 2011-01-06 | Lydon Beverly B | Fingerezz |
| US20110138523A1 (en) * | 2009-12-14 | 2011-06-16 | Layson Jr Hoyt M | Flame, Heat and Electric Arc Protective Yarn and Fabric |
| US20130118635A1 (en) * | 2009-12-14 | 2013-05-16 | International Global Trading Usa, Inc. | Flame, Heat and Electric Arc Protective Yarn and Fabric |
| US8133584B2 (en) * | 2010-04-08 | 2012-03-13 | E.I. Du Pont De Nemours And Company | Crystallized meta-aramid blends for flash fire and arc protection having improved comfort |
| US9169582B2 (en) | 2011-09-02 | 2015-10-27 | E I Du Pont De Nemours And Company | High moisture regain yarn, fabrics, and garments having superior arc protection |
| US8695319B2 (en) * | 2011-12-05 | 2014-04-15 | E I Du Pont De Nemours And Company | Yarns of polyoxadiazole and modacrylic fibers and fabrics and garments made therefrom and methods for making same |
| US20140026303A1 (en) * | 2012-07-27 | 2014-01-30 | E I Du Pont De Nemours And Company | Fiber blends, yarns, fabrics, and garments for arc and flame protection |
| US9745674B2 (en) * | 2012-07-27 | 2017-08-29 | Drifire, Llc | Fiber blends for wash durable thermal and comfort properties |
| CN102839469A (zh) * | 2012-09-24 | 2012-12-26 | 江苏通海线业有限公司 | 一种腈纶和金属纤维混纺纱 |
| JP6162462B2 (ja) * | 2013-04-17 | 2017-07-12 | 帝人株式会社 | 紡績糸および布帛および衣料 |
| JP6158602B2 (ja) * | 2013-06-11 | 2017-07-05 | 帝人株式会社 | 伸縮性難燃布帛および繊維製品 |
| KR101463384B1 (ko) * | 2013-06-21 | 2014-11-19 | 주식회사 휴비스 | 차열성, 투습성, 및 정전기 방지 기능이 우수한 전기공사용 작업복 |
| CN103361855A (zh) * | 2013-08-06 | 2013-10-23 | 太仓市珠江线带厂 | 防火墙布 |
| JP6170814B2 (ja) * | 2013-11-12 | 2017-07-26 | 帝人株式会社 | 布帛および繊維製品 |
| WO2016010659A1 (en) * | 2014-07-15 | 2016-01-21 | Drifire, Llc | Lightweight, dual hazard fabrics |
| WO2016111116A1 (ja) * | 2015-01-06 | 2016-07-14 | 株式会社カネカ | 耐アーク性アクリル系繊維、アーク防護服用布帛、及びアーク防護服 |
| CN106032602A (zh) * | 2015-03-17 | 2016-10-19 | 常熟市宝沣特种纤维有限公司 | 永久阻燃的防暴燃防电弧面料及其制备方法 |
| EP3385418B1 (en) | 2015-12-02 | 2021-07-14 | Teijin Limited | Fabric and protective product |
| CN105350341A (zh) * | 2015-12-04 | 2016-02-24 | 江南大学 | 一种隔热织物的生产方法 |
| US10760189B2 (en) * | 2016-04-22 | 2020-09-01 | General Recycled | Protective fabric and process of manufacturing same |
| ES3022205T3 (en) | 2016-06-23 | 2025-05-28 | Southern Mills Inc | Flame resistant fabrics having fibers containing energy absorbing and/or reflecting additives |
| US9598797B1 (en) * | 2016-09-01 | 2017-03-21 | E I Du Pont De Nemours And Company | Carbon-containing arc-resistant aramid fabrics from dissimilar yarns |
| JPWO2018084040A1 (ja) * | 2016-11-01 | 2019-06-24 | 帝人株式会社 | 布帛およびその製造方法および繊維製品 |
| ES2971055T3 (es) * | 2018-02-08 | 2024-06-03 | Southern Mills Inc | Tejidos resistentes a las llamas para la protección contra salpicaduras de metal fundido |
| WO2020129746A1 (ja) | 2018-12-17 | 2020-06-25 | 帝人株式会社 | 布帛および防護製品 |
| MY206388A (en) | 2019-03-28 | 2024-12-14 | Southern Mills Inc | Flame resistant fabrics |
| KR102272456B1 (ko) | 2019-09-25 | 2021-07-05 | (주)부성텍스텍 | 전기안전 난연 보호복 적층원단 |
| US11598027B2 (en) | 2019-12-18 | 2023-03-07 | Patrick Yarn Mills, Inc. | Methods and systems for forming a composite yarn |
| US11946173B2 (en) | 2020-05-20 | 2024-04-02 | Glen Raven, Inc. | Yarns and fabrics including modacrylic fibers |
| AU2022326461A1 (en) | 2021-08-10 | 2024-02-29 | Southern Mills, Inc. | Flame resistant fabrics |
| CN115161827A (zh) * | 2022-08-01 | 2022-10-11 | 优普泰(深圳)科技有限公司 | 一种用于电弧和火焰防护的纱线、织物和服装 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3193602A (en) | 1962-08-13 | 1965-07-06 | Monsanto Co | Process for the production of flame retarded acrylic fibers |
| US3354127A (en) | 1966-04-18 | 1967-11-21 | Du Pont | Aromatic copolyamides |
| US3819587A (en) | 1969-05-23 | 1974-06-25 | Du Pont | Wholly aromatic carbocyclic polycarbonamide fiber having orientation angle of less than about 45{20 |
| US3673143A (en) | 1970-06-24 | 1972-06-27 | Du Pont | Optically anisotropic spinning dopes of polycarbonamides |
| US3869429A (en) | 1971-08-17 | 1975-03-04 | Du Pont | High strength polyamide fibers and films |
| US3748302A (en) | 1971-11-17 | 1973-07-24 | Du Pont | Flame-retarded acrylonitrile fibers |
| US3803453A (en) | 1972-07-21 | 1974-04-09 | Du Pont | Synthetic filament having antistatic properties |
| JPS53294A (en) | 1976-06-23 | 1978-01-05 | Teijin Ltd | Preparation of aromatic polyamide with high degree of polymerization |
| US4612150A (en) | 1983-11-28 | 1986-09-16 | E. I. Du Pont De Nemours And Company | Process for combining and codrawing antistatic filaments with undrawn nylon filaments |
| EP0183014B1 (en) | 1984-10-05 | 1994-02-02 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Flame-retarded fiber blend |
| US5208105A (en) | 1984-10-05 | 1993-05-04 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Flame-retarded composite fiber |
| US4668234A (en) | 1985-08-15 | 1987-05-26 | E. I. Du Pont De Nemours And Company | Aromatic polyamide fibers and process for stabilizing such fibers with surfactants |
| US4755335A (en) | 1986-09-12 | 1988-07-05 | E. I. Du Pont De Nemours And Company | Method of improving impregnation of poly (meta-phenylene isophthalamide) fibers |
| US4883496A (en) | 1988-02-14 | 1989-11-28 | E. I. Du Pont De Nemours And Company | Process for dyeing crystalline aromatic polyamide fibers with water-insoluble dyes |
| GB8921636D0 (en) * | 1989-09-25 | 1989-11-08 | Universal Carbon Fibres Limite | Fabric |
| US5096459A (en) | 1990-09-26 | 1992-03-17 | E. I. Du Pont De Nemours And Company | Method of dyeing aromatic polyamide fibers with water-soluble dyes |
| JP2693129B2 (ja) * | 1995-02-16 | 1997-12-24 | 鐘淵化学工業株式会社 | 難燃繊維複合体およびそれを用いて製造した布帛 |
| JP3453901B2 (ja) * | 1995-02-22 | 2003-10-06 | 鐘淵化学工業株式会社 | 難燃性と強力および耐摩耗性に優れた複合繊維糸ならびに布帛 |
| JP3660746B2 (ja) * | 1996-05-09 | 2005-06-15 | 帝人ファイバー株式会社 | 防寒作業衣 |
| JP4114995B2 (ja) * | 1998-04-14 | 2008-07-09 | 帝国繊維株式会社 | 防炎性布帛 |
| US6237672B1 (en) * | 1998-12-30 | 2001-05-29 | Dbm Industries, Ltd. | Self lubricating and cleaning injection piston for cold chamber injection unit |
| FR2805718A1 (fr) * | 2000-03-03 | 2001-09-07 | Duflot Ind Sa | Barriere isolante thermique antifeu, procede de fabrication d'une telle barriere, vetement comprenant au moins une telle barriere en tant qu'isolant interne |
| US20060084337A1 (en) * | 2004-10-19 | 2006-04-20 | Southern Mills, Inc. | Blended outer shell fabrics |
| US20070094763A1 (en) * | 2002-08-30 | 2007-05-03 | Safety-Short Workwair Inc. | Safety outerwear with fire resistant mesh |
| DE10248999B3 (de) * | 2002-10-21 | 2004-05-06 | Theodolf Fritsche Gmbh & Co. | Mehrschichtiges, atmungsaktives textiles Flächengebilde |
| US20050025963A1 (en) | 2003-07-28 | 2005-02-03 | Reiyao Zhu | Flame retardant fiber blends comprising modacrylic fibers and fabrics and garments made therefrom |
| US20050208855A1 (en) * | 2004-03-18 | 2005-09-22 | Reiyao Zhu | Modacrylic/cotton/aramid fiber blends for arc and flame protection |
| US7348059B2 (en) * | 2004-03-18 | 2008-03-25 | E. I. Du Pont De Nemours And Company | Modacrylic/aramid fiber blends for arc and flame protection and reduced shrinkage |
| US20050204487A1 (en) * | 2004-03-18 | 2005-09-22 | Reiyao Zhu | Dyeing of modacrylic/aramid fiber blends |
| US7065950B2 (en) * | 2004-03-18 | 2006-06-27 | E. I. Du Pont De Nemours And Company | Modacrylic/aramid fiber blends for arc and flame protection |
| US7229937B2 (en) * | 2004-03-23 | 2007-06-12 | E. I. Du Pont De Nemours And Company | Reinforced nonwoven fire blocking fabric, method for making such fabric, and articles fire blocked therewith |
| US7484256B2 (en) * | 2004-11-26 | 2009-02-03 | Murtzco, Llc | Fire retardant cover for mattresses |
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- 2008-07-11 US US12/218,125 patent/US7744999B2/en active Active
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- 2009-07-10 WO PCT/US2009/050184 patent/WO2010006222A1/en not_active Ceased
- 2009-07-10 AT AT09790249T patent/ATE541968T1/de active
- 2009-07-10 JP JP2011517639A patent/JP5463356B2/ja active Active
- 2009-07-10 KR KR1020117003121A patent/KR101605925B1/ko active Active
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- 2009-07-10 CA CA2726109A patent/CA2726109C/en active Active
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| Publication number | Publication date |
|---|---|
| EP2318579B1 (en) | 2012-01-18 |
| CN102124152A (zh) | 2011-07-13 |
| WO2010006222A1 (en) | 2010-01-14 |
| CN102124152B (zh) | 2013-06-19 |
| CA2726109C (en) | 2016-05-10 |
| CA2726109A1 (en) | 2010-01-14 |
| JP2011527734A (ja) | 2011-11-04 |
| US20100009186A1 (en) | 2010-01-14 |
| KR20110033851A (ko) | 2011-03-31 |
| KR101605925B1 (ko) | 2016-03-23 |
| MX2011000295A (es) | 2011-03-02 |
| ATE541968T1 (de) | 2012-02-15 |
| EP2318579A1 (en) | 2011-05-11 |
| US7744999B2 (en) | 2010-06-29 |
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